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At least 1,027 records · Page 57

Pursuing graphite-based K-ion O 2 batteries: a lesson from Li-ion batteries

The replacement of lithium metal by lithium intercalated graphite was crucial for developing safe lithium-ion batteries. Superoxide-based potassium–oxygen batteries represent an exciting metal–oxygen battery with the highest energy efficiencies. However, using potassium metal is a more serious safety threat than lithium. Herein, we explore the possibility of graphite-intercalation anodes for potassium-ion oxygen batteries (PIOBs) with enhanced safety. This work demonstrates for the first time that establishing an artificial potassium salt-rich solid electrolyte interphase (SEI) enables a reversible graphite-intercalation anode (249.6 mA h g -1 after 600 cycles) in a potassium bis(trifluoromethanesulfonyl)imide (KTFSI)-based localized high-concentration electrolyte. Such an electrolyte is stable with the superoxide cathode. The PIOB delivers energy efficiencies above 90% at a depth of discharge (DOD) of 25% for 80 cycles. A three-electrode measurement shows that its overpotential mainly comes from the anode. The lifespan is limited to the gradual degradation of the artificial SEI caused by oxygen crossover. This work represents a step towards achieving holistic anode–electrolyte–cathode compatibility in a PIOB and its realistic evaluation under a controlled DOD.

25 ENERGY STORAGE↗

Hydrologic response of artificially drained agricultural watersheds: insights from high-resolution integrated surface/subsurface simulations

Artificial drainage systems comprising subsurface networks of perforated pipes (tile drains) and engineered surface ditches are widely used to remove excess water from poorly drained agricultural regions. Artificial drainage lowers the water table by design but also has inadvertent effects on the watershed-scale hydrologic response with important implications for flood risk and nutrient exports. We investigated the effects of tile drains on watershed-scale hydrologic response in the Portage River, OH, Watershed using a high-resolution physically based integrated surface/subsurface hydrology model with recently developed capabilities to represent artificial drainage. Tile drains were found to enhance streamflow during times of low flow, generally consistent with previous studies. Streamflow flashiness was found to have a non-monotonic dependence on tile spacing with a minimum at intermediate spacings (∼50 m). Flashiness and the event hydrographs for small tile spacing were similar to the situation with no tiles, but flow paths from farm to stream were very different for those two end member cases, emphasizing the limitations of the stream hydrograph in characterizing hydrologic response. For typical tile spacings, peak flow can either be enhanced or attenuated by the presence of tiles, depending on the size of the event and the antecedent meteorological conditions. Tiles enhance peak flow when the event is below a threshold of ∼25 mm or when events arrive in dry conditions. Peak flow is reduced by tiles when events are large and arrive in conditions that are not overly dry. The dependence on event size and antecedent conditions is explained by differences in available storage and flow paths to the streams. These results provide additional insights into how tile drainage modulates event-scale hydrologic response, an important control on flood generation mechanisms and nutrient exports.

agricultural watershed↗

Tundra SGS – Critical Importance of Site-Specific Injectivity Testing for Carbon Dioxide Injection Well Simulation Calibration

Paper presented at 16th International Conference on Greenhouse Gas Control Technologies (GHGT-16), October 23–27, 2022, Lyon, France. Brine injectivity tests were conducted on both the Broom Creek (BC) and Deadwood (DW) storage formations in one of the cored stratigraphic test wells prior to finalized simulations. The injectivity tests entailed injection of brine into the formations, followed by shutting in the wells. The shut-in duration represents the fall-off period which was used to carry out pressure transient analyses of the tests. The analysis of injectivity tests indicated that core-indicated and modeled permeability distributions should be conservatively multiplied by 2.5× and 5× in the BC and DW geologic models, respectively, prior to numerical simulations of CO 2 injection using Computer Modelling Group’s (CMG’s) GEM equation-of-state reservoir simulator. The scaler permeability multipliers allowed the fluid flow simulations to fully represent well test-measured injection well rates in the respective formations.

20 FOSSIL-FUELED POWER PLANTS↗

Supporting adaptive shared cache management

Embodiment of this disclosure provides a mechanism to use a portion of an inactive processing element's private cache as an extended last-level cache storage space to adaptively adjust the size of shared cache. In one embodiment, a processing device is provided. The processing device comprising a cache controller is to identify a cache line to evict from a shared cache. An inactive processing core is selected by the cache controller from a plurality of processing cores associated with the shared cache. Then, a private cache of the inactive processing core is notified of an identifier of a cache line associated with the shared cache. Thereupon, the cache line is evicted from the shared cache to install in the private cache.

97 MATHEMATICS AND COMPUTING↗

Low Carbon Technology Strategies: Large Office

This document includes steps that building owners and operators can implement to achieve smart, healthy, and low-carbon large office buildings within their existing building portfolios. Large offices are typically over 50,000 square feet and often include complex heating and cooling systems.

analytics↗

Low Carbon Technology Strategies: Small Office

This document includes steps that building owners and operators can implement to achieve smart, healthy, and low-carbon small office buildings within their existing building portfolios. Small offices are typically less than 50,000 square feet and often use packaged rooftop units for heating, cooling, and ventilation.

analytics↗

Data Analysis Approach for Large Data Volumes in a Connected Community

Recent advancements within smart neighborhoods where utilities are enabling automatic control of appliances such as heating, ventilation, and air conditioning (HVAC) and water heater (WH) systems are providing new opportunities to minimize energy costs through reduced peak load. This requires systematic collection, storage, management, and in-memory processing of large volumes of streaming data for fast performance. In this paper, we propose a multi-tier layered IoT software framework that enables effective descriptive and predictive data analysis for understanding live operation of the neighborhood, fault identification, and future opportunities for further optimization of load curves. We then demonstrate how we achieve live situational awareness of the connected neighborhood through a suite of visualization components. Finally, we discuss a few analytic dashboards that address questions such as peak load reductions obtained due to optimization, customer preference for automatic control of appliances (do they override the automatic control of HVAC?, etc.). 1 1 This manuscript has been authored by UT-Battelle, LLC under Contract No. DE-AC05-00OR22725 with the U.S. Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a nonexclusive, paid-up, irrevocable, world-wide license to publish or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes. The Department of Energy will provide public access to these results of federally sponsored research in accordance with the DOE Public Access Plan (http://energy.gov/downloads/doe-public-access-plan).

Chinthavali, Supriya↗

A review of functions, attributes, properties and measurements for the quality control of proton exchange membrane fuel cell components

Quality control (QC) is an essential part of fuel cell technology industrialization, providing means to reduce cost of components, enhancing the reliability of the final product, and offering specification guidance for new entrants in the supply chain. The membrane electrode assembly (MEA), including membrane, catalyst layer (CL), and gas diffusion layer (GDL), as well as bipolar plate (BP), are key components of a proton exchange membrane (PEM) fuel cell, and the attributes of each component strongly correlate with the cell performance and longevity. To ensure the quality of the fuel cell, it is of great importance to characterize the properties with respect to the standardization of component/sub-component specifications. In collaboration with the fuel cell industry, this work aims at establishing compendiums of attributes, or so-called books of attributes, of key fuel cell components for the QC of PEM fuel cells through reviewing, identifying, categorizing, and prioritizing the main attributes/properties that determine their functionalities. The books of attributes for the major PEM fuel cell components include catalyst coated membrane (CCM) as a sub-assembly, GDL, and BP. To address the full spectrum of fuel cell components, gaskets and sub-gaskets are also included.

25 ENERGY STORAGE↗

Special Issue of IJGGC: Nexus of Water and Carbon Capture and Storage

The mission of the Regional Carbon Sequestration Partnership (RCSP) Water Working Group (WWG) is to address stakeholder concerns regarding emerging carbon capture and storage (CCS) technology and potential interactions with local and regional water resources. As part of that mission, the WWG has been working with the International Journal of Greenhouse Gas Control (IJGGC) to develop a Special Issue dedicated to the nexus of water and CCS. Research papers were solicited, edited, and subsequently published in IJGGC. These articles were then submitted to IJGGC on December, 29, 2016, to be published online in a virtual special issue. The articles published in the virtual special issue build upon the research that has been published in IJGGC over the previous 4 years to complete a more comprehensive understanding of water issues associated with CCS.

54 ENVIRONMENTAL SCIENCES↗

Integrated Thermal Energy Storage and Brayton Cycle Equipment Demonstration (Integrated TESTBED) Project Design Basis

The Integrated Thermal Energy Storage and Brayton cycle Equipment Demonstration (Integrated TESTBED) project seeks to retire commercial-scale risks associated with the design, integration,and operation of a supercritical carbon dioxide (sCO2) power cycle and concentrating solar power (CSP) thermal energy storage (TES) system. This requires an understanding of commercial-scale collector system transient impacts on the TES system, the dynamics of heat exchange from theTES to the power cycle, and the control and operation of the power cycle to accommodate various dispatch strategies. In order to retire these risks, Heliogen has proposed to construct a 5 MWe CSP demonstration facility based on directly heated particle and sCO2 technology. The receivers, primary heat exchanger, and power cycle will be deployed at a full commercial scale based on Heliogen’s modular plant architecture to ensure actual system integration risks are validated during design, construction, and operation. This work summarizes the design basis for the Integrated TESTBED project demonstration facility including a design target for capacity factor to support test operations, hours of storage, particle silo arrangement, centrifugal article receivers, a diffusion bonded particle-sCO2 heat exchanger, and a 5 MWe (net) integrally geared sCO2 recompression Brayton cycle.

14 SOLAR ENERGY↗

Mitigating Data Center Impact on Grid Stability: A Coordinated Control Strategy Using Verrus StabiliGrid Architecture

Large data centers, which now represent a significant and growing share of the total U.S. grid load, can inadvertently destabilize the electrical grid when they disconnect simultaneously during brief voltage disturbances. The July 10, 2024, Eastern Interconnection incident, in which a sub-100-millisecond transmission fault triggered the cascading loss of approximately 1,500 MW of data center load, illustrates this vulnerability. While commercial battery energy storage systems (BESS) deployed in data centers provide device-level fault ride-through per IEEE 1547, they lack coordination with facility protection logic and uninterruptible power supplies (UPS), limiting their effectiveness as grid-stabilizing assets. This report presents the Verrus StabiliGrid architecture, a coordinated control framework that integrates BESS, UPS, and point-of-interconnection (POI) protection settings to enable data centers to ride through both undervoltage and overvoltage grid contingencies without disconnecting. The four-step strategy encompasses: (1) high-resolution power quality monitoring to detect the grid state during events such as undervoltage, overvoltage, underfrequency, and overfrequency; (2) POI protection settings that allow for extended ride-through and grid-connected operation during grid contingencies; (3) grid state-driven autonomous dispatch of assets to improve grid resilience by reducing power draw during undervoltage or absorbing more power during overvoltage events; and (4) coordinated post-recovery dispatch of data center assets to restore firm load to pre-contingency levels. Validated through controller-hardware-in-the-loop (C-HIL) simulations at the National Laboratory of the Rockies, results show grid import restoration to pre-fault levels within 100 milliseconds of voltage recovery. This work advances the ability of data centers to transition from passive, disturbance-sensitive loads to active participants in grid stability, a capability increasingly required by emerging NERC and ERCOT regulatory frameworks.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Manatee County Clear Sky Assessment Process: Prioritizing Solar + Storage for Resilient Facilities & Communities

The Clear Sky Tampa Bay project was a 15-month collaborative research effort to support solar + storage deployment for community resilience in Florida. The Clear Sky Decision Support Toolkit is a collection of resources designed to support users in conducting solar + storage prioritization and feasibility screening assessments at critical facilities. The Tampa Bay Regional Planning Council worked with four local governments in the region to test and apply the Toolkit. This case study series describes how each partner government used the Toolkit and highlights key insights and lessons learned that other users could follow to replicate the process. Manatee County applied the Clear Sky Decision Support Toolkit to two of the county's critical facilities: Nolan Middle School, which serves as a special needs emergency shelter, and its Public Safety Complex (PSC), which houses critical services including emergency management, communications, and medical services, traffic control, and more. The PSC serves as the Emergency Operations Center during activation events. The Clear Sky assessment process improved interagency communication and coordination and informed siting decisions for a potential solar + storage system for the Manatee County PSC.

14 SOLAR ENERGY↗

SUBTASK 1.6 – BASIN ELECTRIC CARBON STORAGE RESEARCH PROJECT: NOVEL MONITORING TECHNIQUES

The Energy & Environmental Research Center (EERC) conducted baseline activities associated with an applied research project at Basin Electric Power Cooperative’s (Basin’s) carbon capture and storage (CCS) site in Beulah, North Dakota, to establish novel carbon storage-monitoring techniques as commercial methods under Cooperative Agreement No. DE-FE0024233, Subtask 1.6. The following report summarizes the baseline activities performed and briefly describes the subsequent (operational monitoring) activities that have been proposed to the U.S. Department of Energy (DOE) as part of the overall project to develop and demonstrate novel monitoring techniques at North America’s largest permitted CCS operation. Dakota Gasification Company (DGC), a wholly owned subsidiary of Basin, owns and operates the Great Plains Synfuels Plant (GPSP) approximately 5 miles northwest of the town of Beulah, North Dakota (Figure 1). In 2023, DGC received approval from the North Dakota Industrial Commission (NDIC) to develop a storage facility on-site for injecting a stream of carbon dioxide (CO2) captured from GPSP. DGC will transport the captured CO2 stream with approximately 6.8 miles of transmission lines that extend north of GPSP and inject >1 million tonnes (MMt) of CO2 annually (>1 MMt/yr) over a 12-year period with up to six underground injection control (UIC) Class VI-compliant injection wells completed in the Broom Creek Formation, a predominantly sandstone reservoir and saline aquifer underlying GPSP. The Broom Creek Formation lies approximately 5900 feet (ft) below ground surface (bgs) at GPSP. The commercial scale (i.e., >1 MMt/yr) of DGC’s permitted carbon storage project is ideal for developing and testing the novel monitoring techniques included within Subtask 1.6. The goals of this project are to demonstrate 1) the cost-effectiveness of novel monitoring technologies included as part of this research, 2) technology capability for tracking the CO2 plume and/or associated pressure response in the subsurface and monitoring out-of-zone migration, and 3) compliance with UIC Class VI program requirements. The research activities proposed for the overall project include 1) design of an automated, integrated, modular (AIM) monitoring station; 2) time-lapse electromagnetic (EM) field surveys; 3) drone-based surveillance studies; 4) time-lapse monitoring with seismic methods; 5) advanced wellbore-monitoring methods; 6) deployment of an AIM monitoring network; 7) EM monitoring of CO2 with real-time data processing; 8) continued seasonal drone-based surveillance studies; 9) seismic monitoring with passive and active surveys; and 10) wellbore monitoring with nuclear magnetic resonance (NMR) for near-surface characterization. Completion of Activities 1.0–5.0 (baseline activities) are described in this report. Upon authorization of funding by DOE, the EERC will initiate Activities 6.0– 10.0 (operational monitoring activities). Current state-of-the-art (SOA) carbon storage-monitoring techniques require countless labor hours dedicated to the acquisition of data. Once data are gathered, these SOA techniques often rely on commercial facilities to process raw data from the field. However, it is anticipated that next-generation monitoring techniques, such as those being demonstrated, will lower acquisition footprints, be less operationally intensive, and improve data acquisition efficiencies. These new techniques are more conducive to the application of machine learning, artificial intelligence, and automation, thus providing a pathway for integration into active control systems, informing site operability, and improving the integration of data for future CCS projects across the United States. Additionally, reclaimed and active mining lands are present within the project site, creating a unique opportunity to demonstrate the effectiveness of remote sensing and surface-based geophysics monitoring techniques at similar project sites that may include disturbed, unconsolidated, or actively excavated near-surface environments. The efforts included in the overall project will produce necessary designs, learnings, and data acquired during the baseline and operational monitoring periods that are necessary for time-lapse demonstration and validation of the described monitoring techniques. In addition, it is anticipated that the monitoring technologies included in this study will be compliant with UIC Class VI requirements to enable the potential for implementation at other CCS sites across the United States.

42 ENGINEERING↗

Common Information Model for Electromagnetic Transients (CIM for EMT): CRADA 533 [Abstract only}

The control and protection functions of inverter-based resources (IBR) have raised concerns with bulk system reliability. Most of the current interest lies with solar photovoltaic generation but increasing amounts of storage would pose the same risks. Newer North American Electric Reliability Corporation (NERC) guidelines call for electromagnetic transient (EMT) studies of IBR and recommend that transmission operators collect distributed energy resource (DER) data to support such modeling. IEEE Standard P2800.1 is defining tests for model parameterization, so good model data should become available from inverter vendors. (EMT studies also apply to large power transformer reliability, and transformer vendors can provide EMT models.) Utilities don’t currently have the rest of the bulk system represented for EMT studies at large scale. An International Electrotechnical Commission (IEC) standard Common Information Model (CIM) provides a way of supporting these detailed models from physical asset data, e.g., conductors, towers, transformer data sheets, control block diagrams, while avoiding software vendor lock-in. CIM-for-EMT, with proposed schema extensions and open-source converters, provides a way to exchange EMT data between organizations and tools. This project leverages Office of Electricity (OE) funding of CIM-for-EMT code base through the GridAPPS-DTM project, and of GridPACKTM (parallelized transmission solver), for interoperability testing in CIM-for-EMT. The project also leverages partner PGSTech investments in EMTP® interoperability with CIM.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Design of a Multi-Chemistry Battery Pack System for Behind-the-Meter Storage Applications

Battery management systems (BMS) are essential for a battery pack's safe operation and longevity. This paper presents an active balancing method-based BMS for different cell chemistry structures to be used in behind-the-meter storage (BTMS) applications. The proposed system utilizes modular isolated dual active bridge (DAB) DC/DC converters to actively balance the battery pack through a low voltage (LV) bus. A supervisory controller monitors all the cell voltage, current, and state of charge (SOC) values. Based on the estimation of the SOCs, reference currents for the DAB converters are generated by the supervisory controller. Detailed modeling and the control approach of the modular DAB converters are presented in the paper. Moreover, the control strategy of the supervisory control is also analyzed. The proposed method and structure can be extended to any combination of the number of cells to design the battery pack. Simulation results are provided for a system consisting of three cells in parallel to form a cell block and three cell blocks in series to form the battery module. Experimental results are provided for three modular DAB converters operating with a LiFeMnPO4 prismatic cell with 3.2V, 20Ah rated values.

battery management systems↗

A Reliable, Cost-Effective Transformerless Medium-Voltage Inverter for Grid Integration of Combined Solar and Energy Storage

The goal of this project is to utilize an innovative holistic power electronic inverter design approach, which can leverage best-in-class silicon carbide (SiC) power modules, novel multi-level power electronic circuits, high frequency transformers, switching sequence based control and co-designed electro-thermal management methods, to realize a 300 kW transformerless medium-voltage (MV) inverter system. The system cost of the inverter is considered as a primary design objective alongside high power density, efficiency, low electromagnetic interference (EMI) and long lifespan. This design-oriented research activity, especially the proposed multi-objective optimization approach, will have broad impacts in holistic power electronic system design methods and in technologies that can be commercialized into a wide variety of wide bandgap power electronic applications.

14 SOLAR ENERGY↗

Cement and concrete as carbon sinks: Transforming a climate challenge into a carbon storage opportunity

Cement and concrete, while traditionally recognized as the main contributors to anthropogenic CO 2 emissions, also have untapped capacity to serve as substantial and scalable carbon sinks. This perspective examines how engineered mineral carbonation can transform cement-based materials into functional carbon storage systems, generating both environmental and economic value. We review the fundamental mechanisms of CO 2 uptake in cementitious systems, highlighting current limitations in reaction kinetics, phase control, and durability under varying environmental conditions. Emphasis is placed on the utilization of alkaline industrial residues and emerging magnesium-based cements, which offer synergistic pathways for carbon sequestration and circular resource use. We further assess the performance trade-offs associated with CO 2 uptake and the feasibility of deploying these technologies on industrial scales. A strategic roadmap is proposed that integrates scientific innovation, regulatory alignment, and carbon accounting in the life cycle to accelerate the adoption of carbon-storing concrete. This perspective provides a comprehensive framework to advance cement and concrete as engineered carbon sinks and supports the transition to a climate-positive construction industry.

Carbon storage↗

MPC-based double-layer real-time conditional cSelf-restoration for interconnected microgrids

In this report, we propose a novel model predictive control(MPC)-based real-time conditional self-restoration energy management system (CSR-EMS) for interconnected microgrids (IMGs) integrated with renewable energy sources (RESs) and energy storage systems (ESSs). Superior to the existing IMG self-restoration methods, the “conditionality” of the proposed CSR-EMS can economically realize self-restoration and grid-assisted restoration during energy deficiency or faults, in both islanded and grid-connected modes. Cost minimization is implemented as the objective function to judge in real-time which restoration mode is economically preferred. The proposed CSR-EMS comprises two layers–the lower layer operates locally to eliminate electricity fluctuations created by RESs and ensure economic effectiveness within an MG, whereas the upper layer oversees the real-time operational status of the IMG system and determines power exchange among microgrids (MGs) during abnormalities. In detail, when a microgrid inside the IMG system experiences an energy deficiency, the CSR-EMS, on an MPC basis, intelligently optimizes power production from each dispatchable distributed generator (DG), ESS, power imported from the main grid, and power exchange among the IMGs to maintain the demand–supply balance, while considering system recovery cost, state of charge (SoC) of ESSs and operation modes of the IMGs (i.e., grid-connected or islanded mode). Simulation results and comparisons with existing IMG self-healing EMSs demonstrate the economic efficacy of the proposed CSR-EMS strategy during normal and abnormal operations, which can be used as an energy control framework for modern power systems with multiple interconnected microgrids.

24 POWER TRANSMISSION AND DISTRIBUTION↗