Melting or freezing of finite slabs.
Transient temperature distribution for finite slab in phase transformations via single face temperature changes
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Transient temperature distribution for finite slab in phase transformations via single face temperature changes
Asteroidal parent bodies heating by electrical induction during early solar evolution
Experimental and computerized electrochemical measurements in fused sodium aluminum chlorides
Lunar maria igneous rock compositions and magmatic liquid viscosity from samples 12021 and 12022, using microprobe analyses
The deformation behavior of tungsten at temperatures 0.2 T sub m is reviewed, with primary emphasis on the temperature dependence of the yield stress and the ductile-brittle transition temperature. It appears that a model based on the high Peierls stress of tungsten best accounts for the observed mechanical behavior at low temperatures. Recent research is discussed which suggests an important role of electron concentration and bonding on the mechanical behavior of tungsten. It is concluded that future research on tungsten should include studies to define more clearly the correlation between electron concentration and mechanical behavior of tungsten alloys and other transition metal alloys.
A study of molybdenum and three dilute molybdenum-rhenium alloys was undertaken to determine the effects of rhenium on the low temperature ductility and other mechanical properties of molybdenum. Alloys containing 3.9, 5.9, and 7.7 atomic percent rhenium exhibited lower ductile-brittle transition temperatures than did the unalloyed molybdenum. The maximum improvement in the annealed condition was observed for molybdenum - 7.7 rhenium, which had a ductile-brittle transition temperature approximately 200 C (360 F) lower than that for unalloyed molybdenum. Rhenium additions also increased the low and high temperature tensile strengths and the high temperature creep strength of molybdenum. The mechanical behavior of dilute molybdenum-rhenium alloys is similar to that observed for dilute tungsten-rhenium alloys.
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Current results of an experimental study of increasing phase change material thermal diffusivity by means of solid fillers are reported. Aluminum honeycomb appears to offer the best improvement of any of the fillers investigated to date. Details of the experimental method developed in the present study for rapidly determining thermal diffusivities with a precision of about 10 percent are also reported. Further concepts regarding phase change material thermal diffusivity enhancement and of phase change material operation are discussed.
Phase equilibrium experiments at both high and low pressures on lunar samples and synthetic compositions are reported as well as related petrographic studies of lunar rock samples. The objectives were to trace the origins of rocks found on the lunar surface, to characterize the nature of the lunar interior and to locate and identify the sources of lunar magmas.
Study of Mo-Re alloys aimed at examining the effects of small rhenium additions on the low-temperature ductility of molybdenum and determining the mechanical properties of dilute Mo-Re alloys. The results obtained indicate that high-purity Mo-Re alloys have ductile-brittle transition temperatures considerably lower than those for unalloyed molybdenum and that rhenium promotes normal solid-solution strengthening in molybdenum at elevated temperatures.
General facility concepts capable of processing the widest range of possible important containerless processing experiments within reasonable technology constraints are indicated. An important part of the work has been to make an up-to-date summary of these experiment possibilities. An attempt has been made to consider materials based on importance in terms of new scientific data or possible future commercial applications.
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The M553 Sphere Forming Experiment conducted in the M512 Furnace Facility during Skylab II was designed to study the effects of weightlessness on the solidification process. Results indicated that there was an outstanding record of solidification terracing and solute redistribution, and that this record may be better than obtainable terrestrially. The solute redistribution was found to be highly localized to prescribed crystallographic systems. It was also shown that for some experimental conditions in a space environment, the anticipated solid/liquid solidification process was perturbed and a solid/liquid/gas reaction took place during solidification. It is felt that these results will contribute to the understanding of terrestrial solidification and will contribute to future space processing considerations.
The generalized problem of determining the temperature and solute concentration profiles during directional solidification of binary alloys with surface evaporation was mathematically formulated. Realistic initial and boundary conditions were defined, and a computer program was developed and checked out. The programs computes the positions of two moving boundaries, evaporation and solidification, and their velocities. Temperature and solute concentration profiles in the semiinfinite material body at selected instances of time are also computed.
Computer programs are developed and used in the study of the combined effects of evaporation and solidification in space processing. The temperature and solute concentration profiles during directional solidification of binary alloys with surface evaporation were mathematically formulated. Computer results are included along with an econotechnical model of crystal growth. This model allows: prediction of crystal size, quality, and cost; systematic selection of the best growth equipment or alloy system; optimization of growth or material parameters; and a maximization of zero-gravity effects. Segregation in GaAs crystals was examined along with vibration effects on GaAs crystal growth. It was found that a unique segregation pattern and strong convention currents exist in GaAs crystal growth. Some beneficial effects from vibration during GaAs growth were discovered. The implications of the results in space processing are indicated.
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Titanate phase relations at liquidus temperatures are determined for the CaAl2Si2O8-Fe2TiO4-FeTi2O5 system in contact with metallic iron by reflected- and transmitted-light microscopy, electron microprobe, and X-ray diffraction analyses. Results of critical equilibration runs are presented, various primary phase areas and liquidus isotherms are illustrated, and the geometry of the system is described. Three piercing points are determined, and it is noted that the compositional interrelations among coexisting crystalline and liquid phases as well as the sequence of the various titanate phases are indicative of the significant effects of the various cations on the relative stability of these phases. It is found that Al2O3 exerts a strong stabilizing effect on the phase assemblage of ulvospinel plus ferropseudobrookite relative to ilemite.