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At least 1,027 records · Page 57
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Large loop thermal models of solar hard X-ray bursts

Results for small loop thermal models of hard X-ray bursts are extended to large loops. In this model a magnetic arch with a coronal length of 45,000 km has the electrons near the top heated to temperatures above 1 billion K. The resulting conduction fronts which form are dominated by collisionless processes and travel down the arch to the transition region and chromosphere where they evaporate off part of the latter. This relatively cool material travels back up the loop and eventually quenches the source for energy injection times of order 10 sec. Most of the X-ray emission comes from the footpoints of the arch over most of the source lifetime and the spectrum is a power law with a typical spectral index of 3.0. Even though the efficiency gain in this model is only 2.8, it is much easier from the point of view of plasma physics to heat all the electrons in a plasma than to accelerate a substantial fraction of them.

Smith, D. F.↗
NASA NTRS1992

Mars seasonal CO2 ice lifetimes and the angular dependence of albedo

The albedo of the polar caps on Mars brightens appreciably at high solar zenith angle (Warren et al., J. Geophys. Res., 95, 14717, 1990), an effect not included in prior polar-cap energy-balance models. This decreases absorption of sunlight by the polar cap, hence decreasing sublimation of CO2 ice. Lindner (J. Geophys. Res., 95, 1367, 1990) has shown that the radiative effects of clouds and airborne dust will increase sublimation of CO2 ice over that predicted by prior polar-cap energy-balance models. Furthermore, observations hint that more clouds may exist in the Northern Hemisphere, which Lindner (1990) has shown would sublime CO2 ice more quickly in the north than in the south. I show here that the effects of the solar zenith angle dependence of albedo and the radiative effects of clouds and dust offset each other, but act to extend the lifetime of CO2 ice on the south pole more than on the north pole, possibly explaining the observed hemispherical asymmetry in the residual polar caps without the need of a hemispherical asymmetry in polar-cap albedo required by prior models. Another positive aspect of this solution is that neither the inclusion of the solar zenith angle dependence of albedo nor the radiative effects of clouds and dust should appreciably change prior model agreement with observations of the annual cycle of surface pressure and the recession of the polar caps equatorward of 75 degrees latitude.

Lindner, Bernhard Lee↗
DOE OSTI2021

(Invited) Understanding Multi-Component Transport and Reaction Phenomena in Bipolar Membranes Used for Electrosynthesis

Bipolar membranes (BPMs), which have long seen usage in electrodialysis reactors for the generation of acid and base, have recently demonstrated potential to become critical components in electrochemical synthesis devices. Because they can operate under large pH gradients, BPMs enable favorable environments for electrocatalysis at the individual electrodes. Critical to the implementation of BPMs in these devices is understanding the kinetics of water dissociation that occurs within the BPM junction as well as the co- and counter-ion crossover through the BPM, which both present significant obstacles to developing efficient and stable BPM-devices for electrosynthesis applications. Prior work has modeled ion transport in bipolar membranes in neutral salt solutions for electrodialysis. However, no model exists for the BPM under the harsh applied pH gradients that would be present in electrosynthesis, and there is significant need to explore the effects of the internal hydration on the lifetime and performance of BPMs in such environments. Additionally, a mechanistic understanding of water dissociation catalysis will be required to develop interfacial catalysts that enable the high current density operation required for scalable electrosynthesis of fuels. In this talk, we discuss modeling methodologies and physics inherent in BPMs and present our recent model of ion transport and water dissociation catalysis in BPMs across the pH scale. Specifically, we simulate multi-ion transport for a BPM with various electrolyte combinations on each side of the membrane, demonstrating the significance of co- and counter-ion crossover in BPMs operating under harsh pH gradients. We then investigate effects caused by hydration gradients that occur due to internal ion-exchange and examine potential methods for improving performance and mitigating crossover. Finally, we examine the impact of the interfacial water dissociation catalyst and perform sensitivity analysis on the key properties (catalyst point of zero charge and pKa) that dictate catalyst performance. These results provide information that is critical to developing a comprehensive understanding of multi-component phenomena in BPMs and to informing the design and implementation of BPMs in next-generation devices for the numerous electrosynthesis chemistries that benefit from operation under an applied pH gradient.

Bui, Justin C↗
DOE OSTI2020

Measurement of properties of B$^0_\mathrm{s}\to\mu^+\mu^-$ decays and search for B$^0\to\mu^+\mu^-$ with the CMS experiment

Results are reported for the $ {\mathrm{B}}_{\mathrm{s}}^0 $→ μ$^{+}$μ$^{−}$ branching fraction and effective lifetime and from a search for the decay B$^{0}$→ μ$^{+}$μ$^{−}$. The analysis uses a data sample of proton-proton collisions accumulated by the CMS experiment in 2011, 2012, and 2016, with center-of-mass energies (integrated luminosities) of 7 TeV (5 fb$^{−1}$), 8 TeV (20 fb$^{−1}$), and 13 TeV (36 fb$^{−1}$). The branching fractions are determined by measuring event yields relative to B$^{+}$→ J/ψK$^{+}$ decays (with J/ψ → μ$^{+}$μ$^{−}$), which results in the reduction of many of the systematic uncertainties. The decay $ {\mathrm{B}}_{\mathrm{s}}^0 $→ μ$^{+}$μ$^{−}$ is observed with a significance of 5.6 standard deviations. The branching fraction is measured to be $ \mathrm{\mathcal{B}}\left({\mathrm{B}}_{\mathrm{s}}^0\to {\upmu}^{+}{\upmu}^{-}\right)=\left[2.9\pm 0.7\left(\exp \right)\pm 0.2\left(\mathrm{frag}\right)\right]\times {10}^{-9} $, where the first uncertainty combines the experimental statistical and systematic contributions, and the second is due to the uncertainty in the ratio of the $ {\mathrm{B}}_{\mathrm{s}}^0 $ and the B$^{+}$ fragmentation functions. No significant excess is observed for the decay B$^{0}$→ μ$^{+}$μ$^{−}$, and an upper limit of ℬ(B$^{0}$ → μ$^{+}$μ$^{−}$) < 3.6 × 10$^{−10}$ is obtained at 95% confidence level. The $ {\mathrm{B}}_{\mathrm{s}}^0 $→ μ+μ− effective lifetime is measured to be $ {\tau}_{\upmu^{+}{\upmu}^{-}}={1.70}_{-0.44}^{+0.61} $ ps. These results are consistent with standard model predictions.[graphic not available: see fulltext]

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2025

Multiphase Processing of the Water-Soluble and Insoluble Phases of Biomass Burning Organic Aerosol

Biomass burning is one of the most significant sources of organic aerosol in the atmosphere. Biomass burning organic aerosol (BBOA) has been observed to undergo liquid– liquid phase separation (LLPS) to give core–shell morphology with the hydrophobic phase encapsulating the hydrophilic phase, potentially impacting the evolution of light-absorbing components, i.e., brown carbon (BrC), through multiphase processes. Here, we demonstrate how multiphase processing differs between the watersoluble (i.e., hydrophilic) and insoluble (i.e., hydrophobic) phases of BBOA in terms of reactive uptake of ozone in a coated-wall flow tube. Effects of relative humidity (RH) and ultraviolet (UV) irradiation were investigated. Experimental timeseries were used to inform simulations using multilayer kinetic modeling. Among non-irradiated thin films, the uptake coefficient was greatest for the water-soluble phase at 75% RH (3 × 10 –5 , corresponding to a diffusion coefficient of BrC, D BrC , of 3 × 10 –9 cm 2 s –1 ) and least for the same phase at 0% RH (1 × 10 –5 , corresponding to D BrC of 1 × 10 –10 cm 2 s –1 ). The uptake coefficient for the water-insoluble phase fell between these two (about 1.5 × 10 –5 ), regardless of RH, and the corresponding D BrC increased only slightly (8 × 10 –10 cm 2 s –1 at 0% RH to 9 × 10 –10 cm 2 s –1 at 75% RH). The uptake coefficients of both phases at 0% RH decreased significantly after UV irradiation, consistent with a transition from viscous liquid to solid and supported by qualitative microscopy observations. Modeling multiphase ozone oxidation of primary BrC components in the atmosphere demonstrated, first, that LLPS may extend the lifetime of water-soluble BBOA encapsulated by water-insoluble species by a factor of 1.5 at moderate to high RH and, also, that UV irradiation may extend the lifetime of both phases by more than a factor of 2.5.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Dark dimension and the grand unification of forces

The dark dimension scenario, predicting one extra mesoscopic dimension in the micron range, has emerged by applying various swampland principles to the dark energy. In this note we find that realizing the grand unification of gauge forces is highly constraining in this context. Without actually constructing any grand unified theory (GUT) models, we argue that the mere assumption of grand unification of forces in this scenario, together with the experimental bounds on massive replicas of the Standard Model gauge bosons, predicts an upper bound for the GUT scale, 𝑀 GUT ≲ 10 16 GeV. Combined with the experimental bound on the proton lifetime, this predicts that the 𝑋 gauge boson mediating proton decay is a 5D solitonic string of Planckian tension stretched across a length scale 𝐿 ∼ (1–10 TeV) −1 ending on gauge branes of the same diameter ∼𝐿. This leads to a mass of 𝑀 𝑋 ∼ 10 15 –10 16 GeV. In particular assuming grand unification in the dark dimension scenario results in a tower of Kaluza-Klein excitations of Standard Model gauge bosons on the gauge branes in the 1–10 TeV range. This suggests that the diameter/separation 𝐿 of the gauge branes correlates with both the weak scale ∼1/𝐿 near a TeV and the GUT scale ∼𝑀$^2_5$⁢𝐿 at 10 16 GeV.

branes↗
DOE OSTI2022

High-Octane Gasoline from Lignocellulosic Biomass via Syngas and Methanol/Dimethyl Ether Intermediates (2021 State of Technology)

The 2021 state of technology (SOT) assessment for the indirect liquefaction (IDL) of lignocellulosic biomass to high-octane gasoline (HOG) via methanol and dimethyl ether (DME) intermediates details the techno-economic analysis (TEA) results and technical progress of the pathway since the 2020 SOT report. A detailed process description and collection of underlying assumptions is given the 2015 design report. In 2021, research efforts rigorously quantified the selectivity of DME to aromatic compounds. As a result, the overall carbon selectivity to hydrocarbon products was updated based upon new findings. Additionally, research conducted over the past few years resulted in successful lower temperature regeneration of NREL's Cu/BEA catalyst with favorable implications on catalyst longevity. Discussions with an engineering firm resulted in an update to the excess air requirement for process combustors (including the char combustor, tar reformer combustor, and catalyst regenerator) in which excess air was reduced from 20% excess to 10%. The cumulative effect of the above efforts was used to calculate a minimum fuel selling price for the modeled pathway. Sensitivity cases examining federal carbon tax credits from CO 2 capture, product selectivity and yield, catalyst lifetime, and other key financial and process parameters were also considered in this assessment.

09 BIOMASS FUELS↗
DOE OSTI2023

Carrier Dynamics of Polar, Semipolar, and Nonpolar InGaN/GaN LEDs Measured by Small-Signal Electroluminescence

The carrier dynamics in InGaN/GaN LEDs are directly tied to their efficiency and maximum modulation speed, which are important metrics for solid-state lighting, displays, and optical communication. We measure the carrier dynamics of nonpolar, semipolar, and commercial c-plane InGaN/GaN LEDs using small-signal electroluminescence methods. Rate equations and a small-signal circuit are used to model the carrier dynamics. The model is fit to the optical frequency response and input impedance of the LEDs to extract the carrier lifetimes and the recombination rates. The results offer insight into the underlying causes of efficiency droop and the green gap, and inform device design strategies.

42 ENGINEERING↗
DOE OSTI2022

Important role of stratospheric injection height for the distribution and radiative forcing of smoke aerosol from the 2019–2020 Australian wildfires

More than 1 Tg smoke aerosol was emitted into the atmosphere by the exceptional 2019–2020 southeastern Australian wildfires. Triggered by the extreme fire heat, several deep pyroconvective events carried the smoke directly into the stratosphere. Once there, smoke aerosol remained airborne considerably longer than in lower atmospheric layers. The thick plumes traveled eastward, thereby being distributed across the high and mid-latitudes in the Southern Hemisphere, enhancing the atmospheric opacity. Due to the increased atmospheric lifetime of the smoke plume, its radiative effect increased compared to smoke that remains in lower altitudes. Global models describing aerosol-climate impacts lack adequate descriptions of the emission height of aerosols from intense wildfires. Here, we demonstrate, by a combination of aerosol-climate modeling and lidar observations, the importance of the representation of those high-altitude fire smoke layers for estimating the atmospheric energy budget. Through observation-based input into the simulations, the Australian wildfire emissions by pyroconvection are explicitly prescribed to the lower stratosphere in different scenarios. Based on our simulations, the 2019–2020 Australian fires caused a significant top-of-atmosphere (TOA) hemispheric instantaneous direct radiative forcing signal that reached a magnitude comparable to the radiative forcing induced by anthropogenic absorbing aerosol. Up to +0.50 W m -2 instantaneous direct radiative forcing was modeled at TOA, averaged for the Southern Hemisphere (+0.25 W m -2 globally) from January to March 2020 under all-sky conditions. At the surface, on the other hand, an instantaneous solar radiative forcing of up to -0.81 W m -2 was found for clear-sky conditions, with the respective estimates depending on the model configuration and subject to the model uncertainties in the smoke optical properties. Since extreme wildfires are expected to occur more frequently in the rapidly changing climate, our findings suggest that high-altitude wildfire plumes must be adequately considered in climate projections in order to obtain reasonable estimates of atmospheric energy budget changes.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1974

Dust grains in a hot gas. I - Basic physics. II - Astrophysical applications

The interaction of graphite grains with a hot gas is investigated. Detailed computations, based on experimental data and simple theoretical models are presented of the energy transfer by gas particle collisions and of the sputtering rates and grain lifetimes, as functions of gas temperature and grain radius. The electric charge on the grains is calculated, and the effect of electric forces on mechanical stability is discussed. The rate at which the gas cools by this mechanism is evaluated. The results of the work on gas-grain cooling and sputtering rates are applied to various astrophysical environments where dust and hot gas may coexist. The effect is studied of swept-up interstellar grains on the evolution of young supernova remnants, and the infrared luminosity is computed as a function of the age of the remnant. An interpretation is proposed of far-infrared sources embedded in compact H II regions or dense clouds, in terms of the supernova phenomenon, with specific application to eta Carinae. The question of the existence of dust in intergalactic matter in galaxy clusters is also reexamined.

Burke, J. R.↗
NASA NTRS1984

Temporal and spatial behavior of the ultraviolet emissions of comet IRAS-Araki-Alcock 1983d

The spatial distribution and temporal variation of the ultraviolet emissions from comet IRAS-Araki-Alcock 1983d, observed by IUE near closest approach of the comet to the earth, suggest a model for this comet of a rotating cometary nucleus with a nonuniform distribution of volatile ices. The short lifetime of S2 (about 500 s), a species whose presence was first identified in this comet and is presumed to be present generally in the cometary ice, makes S2 a valuable indicator of short-term nuclear activity. In the case of comet 1983d, the S2 production rate decreased by a factor of 10 over a period of 28 hr.

Feldman, P. D.↗
NASA NTRS1999

Observations of Middle Atmosphere CO from the UARS ISAMS during the Early Northern Winter 1991/92

Structure and kinematics of carbon monoxide in the upper stratosphere and lower mesosphere (10-0.03 hPa) are studied for the early northern winter 1991/92 using the Upper Atmosphere Research Satellite Improved Stratospheric and Mesospheric Sounder (ISAMS) measurements. The study is aided by data from a 6-week parameterized-chemistry run of the Goddard Space Flight Center 3D Chemistry and Transport Model (CTM), initialized on 8 December 1991. Generally, CO mixing ratios increase with height due to the increasing source contribution from CO, photolysis. In the tropical upper stratosphere. however, a local maximum in CO mixing ratio occurs. A simple photochemical model is used to show that this feature results largely from methane oxidation. In the extratropics the photochemical lifetime of CO is long, and therefore its evolution is dictated by large-scale motion of air. evidenced by strong correlation with Ertel potential vorticity. This makes CO one of the few useful observable tracers at the stratopause level and above. Thus CO maps are used to study the synoptic evolution of the polar vortex in early January 1992. Modified Lagrangian mean mixing diagnostics are applied to ISAMS and CTM data to examine the strength of the mixing barrier at the polar vortex edge. It is demonstrated that planetary wave activity weakens the barrier. promoting vortex erosion. The vortex erosion first appears in the lower mesosphere and subsequently descends through the upper stratosphere. and is attributed to effects of planetary wave dissipation. Agreement between ISAMS and CTM is good in the horizontal distribution of CO throughout the examined period, but vertical CO gradients in the CTM weaken with time relative to the ISAMS observations.

Allen, D. R.↗
NASA NTRS2000

Fluorescence Studies of Protein Crystal Nucleation

One of the most powerful and versatile methods for studying molecules in solution is fluorescence. Crystallization typically takes place in a concentrated solution environment, whereas fluorescence typically has an upper concentration limit of approximately 1 x 10(exp -5)M, thus intrinsic fluorescence cannot be employed, but a fluorescent probe must be added to a sub population of the molecules. However the fluorescent species cannot interfere with the self-assembly process. This can be achieved with macromolecules, where fluorescent probes can be covalently attached to a sub population of molecules that are subsequently used to track the system as a whole. We are using fluorescence resonance energy transfer (FRET) to study the initial solution phase self-assembly process of tetragonal lysozyme crystal nucleation, using covalent fluorescent derivatives which crystallize in the characteristic P432121 space group. FRET studies are being carried out between cascade blue (CB-lys, donor, Ex 376 nm, Em 420 nm) and lucifer yellow (LY-lys, acceptor, Ex 425 nm, Em 520 nm) asp101 derivatives. The estimated R0 for this probe pair, the distance where 50% of the donor energy is transferred to the acceptor, is approximately 1.2 nm, compared to 2.2 nm between the side chain carboxyls of adjacent asp101's in the crystalline 43 helix. The short CB-lys lifetime (approximately 5 ns), coupled with the large average distances between the molecules ((sup 3) 50 nm) in solution, ensure that any energy transfer observed is not due to random diffusive interactions. Addition of LY-lys to CB-lys results in the appearance of a second, shorter lifetime (approximately 0.2 ns). Results from these and other ongoing studies will be discussed in conjunction with a model for how tetragonal lysozyme crystals nucleate and grow, and the relevance of that model to microgravity protein crystal growth

Pusey, Marc L.↗
NASA NTRS2005

Entrainment, Drizzle, and the Indirect Effect in Stratiform Clouds

Activation of some fraction of increased concentrations of sub-micron soluble aerosol particles lead to enhanced cloud droplet concentrations and hence smaller droplets, increasing their total cross sectional area and thus reflecting solar radiation more efficiently (the Twomey, or first indirect, effect). However, because of competition during condensational growth, droplet distributions tend to broaden as numbers increase, reducing the sensitivity of cloud albedo to droplet concentration on the order of 10%. Also, smaller droplets less effectively produce drizzle through collisions and coalescence, and it is widely expected (and found in large-scale models) that decreased precipitation leads to clouds with more cloud water on average (the so-called cloud lifetime, or second indirect, effect). Much of the uncertainty regarding the overall indirect aerosol effect stems from inadequate understanding of such changes in cloud water. Detailed simulations based on FIRE-I, ASTEX, and DYCOMS-II conditions show that suppression of precipitation from increased droplet concentrations leads to increased cloud water only when sufficient precipitation reaches the surface, a condition favored when the overlying air is-humid or droplet concentrations are very low. Otherwise, aerosol induced suppression of precipitation enhances entrainment of overlying dry air, thereby reducing cloud water and diminishing the indirect climate forcing.

Ackerman, Andrew↗
NASA NTRS2006

Formation of the giant planets

The observed properties of giant planets, models of their evolution and observations of protoplanetary disks provide constraints on the formation of gas giant planets. The four largest planets in our Solar System contain considerable quantities of hydrogen and helium, which could not have condensed into solid planetesimals within the protoplanetary disk. All three (transiting) extrasolar giant planets with well determined masses and radii also must contain substantial amounts of these light gases. Jupiter and Saturn are mostly hydrogen and helium, but have larger abundances of heavier elements than does the Sun. Neptune and Uranus are primarily composed of heavier elements. HD 149026 b, which is slightly more massive than is Saturn, appears to have comparable quantities of light gases and heavy elements. HD 209458 b and TrES-1 are primarily hydrogen and helium, but may contain supersolar abundances of heavy elements. Spacecraft flybys and observations of satellite orbits provide estimates of the gravitational moments of the giant planets in our Solar System, which in turn provide information on the internal distribution of matter within Jupiter, Saturn, Uranus and Neptune. Atmospheric thermal structure and heat flow measurements constrain the interior temperatures of planets. Internal processes may cause giant planets to become more compositionally differentiated or alternatively more homogeneous; high-pressure laboratory .experiments provide data useful for modeling these processes. The preponderance of evidence supports the core nucleated gas accretion model. According to this model, giant planets begin their growth by the accumulation of small solid bodies, as do terrestrial planets. However, unlike terrestrial planets, the growing giant planet cores become massive enough that they are able to accumulate substantial amounts of gas before the protoplanetary disk dissipates. The primary questions regarding the core nucleated growth model is under what conditions planets with small cores/total heavy element abundances can accrete gaseous envelopes within the lifetimes of gaseous protoplanetary disks.

Lissauer, Jack J.↗
NASA NTRS2018

Application of STARFLEET Velocimetry in the NASA Langley 0.3-Meter Transonic Cryogenic Tunnel

Selective two-photon absorptive resonance femtosecond laser electronic excitation tagging (STARFLEET) velocimetry is demonstrated for the first time in a NASA Langley wind tunnel with high repetition-rate and single-shot imaging. Experiments performed in the 0.3-meter Transonic Cryogenic Tunnel (TCT) allowed for testing at 300 K over a range of pressures (124 to 517 kPa) and Mach numbers (0.2-0.8) for freestream conditions and flow behind a cylindrical model. Measurement precision and accuracy are determined for the current set of experiments, as are signal intensity and lifetime. Precisions of 3-5 m/s (based on one standard deviation) were typical in the experiment; precisions better than 2% of the mean velocity were obtained for some of the highest velocity conditions. Agreement within a mean error of 3 m/s between STARFLEET freestream velocity measurements and facility DAS readings is demonstrated. STARFLEET is also shown to return spatially-resolved velocity profiles, though some binning of the signal is required.

STARFLEET↗
DOE OSTI2023

Defect Characterization of Monocrystalline Silicon Solar Cells with Polysilicon Passivated Contact Using Electrically-Detected Magnetic Resonance (EDMR) Spectroscopy

As the c-Si based solar cell efficiencies are approaching over 26%, it is becoming critical to characterize the low concentrations of the defects – as low as 10^10-10^11 cm-3 (for e.g., iron contamination in high-lifetime Ga-doped wafers3 and n-type wafers), and further reduce them. Also, atomistic level understanding of the mechanisms of the low concentration process-induced-defects and reliability limiting defects (such as light and elevated temperature induced degradation, surface passivation degradation) is needed to design the mitigation strategies. The conventional characterization techniques are limited due to their detection limitations. Some of the techniques based on lifetime spectroscopies can still be used for low concentration characterization however, they are based on estimations and theoretical models and hence, indirect and cannot fully reveal information about the microscopic mechanism of the defects. Thus, we present the application of an ultrasensitive magnetic resonance-based technique for the direct spectroscopic detection of the defects in Si PV - electrically detected magnetic resonance (EDMR). In this work, we aim to focus on establishing a process flow for fabrication of minicells with (miniature replica of the larger-area cells) and setting up the routine for EDMR measurements on them with the EDMR instrumentation capability at NREL. For the EDMR measurements, sample size is limited by the dimensions of sample holder tube (width less than 3.2 mm, active area - 20 mm). Thus, we have designed c-Si based minicells with polysilicon (poly-Si) passivated contacts same as the larger-area cells that we fabricate in our group at NREL. We also modified our minicell process flow for fabricating the textured minicells for preserving the texture during processing and taking care of the laser-ablation edge damage which can significantly affect the performance of such small devices. We have achieved comparable performance on these newly fabricated minicells as that of our 4 cm2 devices with same structure (comparable VOC, JSC, FF). We also conducted EDMR measurements on the minicells and observed a distinct EDMR signal at g-value ~2.005 at temperatures 30K and above, as shown in Fig. 2. We associate this signal to the presence of silicon dangling bonds based on the g-value. We also observed an EDMR signal at g-value ~1.998 at temperature ~5K. The origin of this signal is still being investigated. Thus, we show the proof of concept of minicells and EDMR measurements with which we now aim to study some of the unknown defects in silicon solar cell devices.

EDMR↗
DOE OSTI2023

Long term oxidation of NiCoCrAlY coated Ni-based superalloys: A comparison of observed and simulated interdiffusion

Lifetimes of MCrAlY-type coatings can easily surpass 25 kh when the criteria of ß-depletion is used. To reduce experimental effort, it’s necessary to develop models capable of simulating interdiffusion and oxidation. In the present study, NiCoCrAlY coatings were high velocity oxyfuel deposited on PWA 1483, MARM247, and CMSX-4 substrates, and samples were exposed at 900 °C for 5–20 kh in air+10 vol%H 2 O to study interdiffusion rates. Here, Thermo-Calc/DICTRA was used to reproduce the observed differences, and microstructures were compared. Based on the agreement between calculated and observed rates, simulations were projected past the experimental exposures, utilizing ß-depletion as lifetime criteria.

36 MATERIALS SCIENCE↗