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System for controlled injection of electrons or holes into oxide layer of MOS capacitor can be used to measure oxide trapping parameters. Since trapping mechanisms can cause degradation and ultimate failure of MOS elements exposed to ionizing radiation, system can be helpful in predicting device tolerance.
Integrated sensing circuits were designed, fabricated, and packaged for use in determining the direction and fluence of ionizing radiation passing through a multiwire proportional chamber. CMOS on sapphire was selected because of its high speed and low power capabilities. The design of the proposed circuits is described and the results of computer simulations are presented. The fabrication processes for the CMOS on sapphire sensing circuits and hybrid substrates are outlined. Several design options are described and the cost implications of each discussed. To be most effective, each chip should handle not more than 32 inputs, and should be mounted on its own hybrid substrate.
Measurements on two candidate materials for space flight are reported. The observed optical transmittance of aluminum films vapor deposited on fused quartz showed anomalously high transmittance thru 400 A and 600 A and showed an effective skin depth of 110 A in the latter part of the 1000 A thickness. KAPTON films are shown by their optical transmission spectra to have an energy gap for electron excitation of approximately 2.5 eV, which value depends on the thickness as manufactured. The resistance of KAPTON film to ionizing radiation is described by their optical spectra and their electron spin resonance spectra.
Positive-ion electrical-conductivity measurements, which are now performed with 4-cm diameter meteorological rocket payloads, provide a simple means of monitoring the NO concentration in the mesosphere, as well as the ionization variability. A wavelike dynamical structure is observed at low latitudes. Parachute-borne Gerdien mobility analyzers show, in addition, ion mobility spectra which spread from much greater to much less than that expected for simple gas-phase ions in the mesosphere and also indicate an ion clustering chain in the stratosphere. Large particulate ions apparently form in the daytime and grow very large at night. An instrument combining the mobility analyzer with a flashing source of ionizing radiation could be used as an NO(x) spectrometer.
Variations with the solar cycle of chemical composition, density and temperature of the orbital environment of the Space Shuttle are reviewed; micrometeoroid fluxes, ionizing radiation, photon fluxes and cosmic ray bombardment to which the Shuttle will be subjected are also mentioned. In addition, gases arising from offgassing and outgassing of contaminants (at about 300 K) from the Shuttle are considered, and particulates ejected during rocket firings or from the leakage of pressurized vessels (i.e., the cabin) are taken into account.
Physiological criteria determining the design of the habitat for a space colony with 10,000 people are discussed. Centrifugally generated earth-normal gravity, maximum ionizing radiation dose standards less than or equal to 0.5 rem/year (obtained with passive shielding), and an atmosphere with reduced nitrogen partial pressures were established as design requirements for the habitat. However, further research is needed to determine whether humans experience complete adaptation to weightlessness and whether there are long-term effects of breathing various atmospheric mixtures and pressures.
An investigation has been undertaken to determine whether ionizing radiation might engender racemization of optically active amino acids, along with their usual radiolysis. As prototypes, crystalline Dand L-leucine, as well as aqueous solutions of their sodium salts were exposed to the radiation from a 3000 Ci Co-60 gamma-ray source. Gamma-ray doses which caused about 68% radiolysis of solid leucine left a residue which was about 5% racemized, while racemization proved even greater at lower doses for the dissolved sodium salts. In aqueous solution both percent degradation and percent racemization of the sodium salts were proportional to gamma-ray dosage within the range employed (1,000,000-27,000,000 rads). Implications of these observations for the origin of molecular asymmetry by the beta-decay parity violation mechanism are discussed.
The faint optical filaments in Tycho's supernova remnant appear to be emission from a shock front moving at 5600 km/s. The intensity of the hydrogen lines, the absence of forbidden lines of heavy elements in the spectrum, and the width of the filaments are explained by a model in which a collisionless shock wave is moving into partially neutral gas. The presence of the neutral gas can be used to set an upper limit of approximately 5 x 10 to the 47th power ergs to the energy in ionizing radiation emitted by a Type I supernova. The patchy neutral gas is probably part of the warm neutral component of the interstellar medium. The existing information on the remnant of SN 1006 indicates that its emission is similar in nature to that from Tycho's remnant.
Results are reported for optical, near-IR, and mid-IR spectrophotometry of the compact H II region K3-50A. The emission-line observations imply an electron density of about 100,000 per cu cm; the consistency of density measurements in the optical, IR, and radio sources suggests that the optical counterpart of K3-50A is a reflection nebula. Previous measurements of the anomalous extinction law in K3-50A are confirmed, this law is extended out to B-alpha at 4 microns, and a 9-micron optical depth of about 2.5 is obtained. Elemental abundances are derived from measurements of emission lines of several dominant ions of the same element and found to be in close agreement (50%) with mean cosmic abundances. Individual ionic ratios are compared with model H II region calculations to determine the nature of the ionizing radiation. It is concluded that if nongray UV dust absorption does not modify the spectrum appreciably, the radiation temperature can be associated with a stellar surface temperature of about 37,000 K, corresponding to an O6 supergiant.
Synthesis of several classes of hydrophylic microspheres applied to cell labeling and cell separation is described. Five classes of cross-linked microspheres with functional groups such as carboxyl, hydroxyl, amide and/or pyridine groups were synthesized. These functional groups were used to bind covalently antibodies and other proteins to the surface of the microspheres. To optimize the derivatisation technique, polyglutaraldehyde immunomicrospheres were prepared and utilized. Specific populations of human and murine lymphocytes were labelled with microspheres synthesized by the emulsion of the ionizing radiation technique. The labelling of the cells by means of microspheres containing an iron core produced successful separation of B from T lymphocytes by means of a magnetic field.
A self supporting sheet structure comprising a water soluble, noncrosslinked polymer such as polyvinyl alcohol which is capable of being crosslinked by reaction with hydrogen atom radicals and hydroxyl molecule radicals is contacted with an aqueous solution having a pH of less than 8 and containing a dissolved salt in an amount sufficient to prevent substantial dissolution of the noncrosslinked polymer in the aqueous solution. The aqueous solution is then irradiated with ionizing radiation to form hydrogen atom radicals and hydroxyl molecule radicals and the irradiation is continued for a time sufficient to effect crosslinking of the water soluble polymer to produce a water insoluble polymer sheet structure. The method has particular application in the production of battery separators and electrode envelopes for alkaline batteries.
The optically pure D- and L-enantiomers of isovaline, which cannot be racemized by ordinary chemical mechanisms involving alpha-hydrogen removal and which has been isolated in apparently racemic form from the Murchison meteorite, have been subjected to partial radiolysis by the ionizing radiation from a 3000-Ci Co-60 gamma-ray source. Both in the anhydrous and hydrated solid states and as solid sodium or hydrochloride salts each enantiomer suffered significant radioracemization of the undestroyed residue during its partial radiolysis. The sodium salt of isovaline in 0.1-M aqueous solution suffered extensive radiolysis with relatively small radiation doses, but showed no detectable radioracemization. The significance of these observations with respect to the primordial enantiomeric composition of the isovaline (and other amino acids) indigenous to meteorites is discussed.
The basic effects of ionizing radiation are summarized. The problem of the existence of a true dose rate effect is examined. Consideration is given to the nature of long term annealing, which is sometimes manifested as an 'apparent' dose rate effect. Both analytical and experimental work is considered and the results are related to practical testing requirements.
Physical and chemical considerations permit the division of the near-surface regolith on Mars into at least six zones of distinct microenvironments. The zones are euphotic, duricrust/peds, tempofrost, permafrost, endolithic, and interfacial/transitional. Microenvironments vary significantly in temperature extremes, mean temperature, salt content, relative pressure of water vapor, UV and visible light irradiance, and exposure to ionizing radiation events (100 Mrad) and oxidative molecular species. From what is known of the chemistry of the atmosphere and regolith fines (soil), limits upon the aqueous chemistry of soil pastes may be estimated. Heat of wetting could reach 45 cal/g dry soil; initial pH is indeterminate between 1 and 10; ionic strength and salinity are predicted to be extremely high; freezing point depression is inadequate to provide quantities of liquid water except in special cases. The prospects for biotic survival are grim by terrestrial standards, but the extremes of biological resiliency are inaccessible to evaluation. Second-generation in situ experiments which will better define Martian microenvironments are clearly possible. Antarctic dry valleys are approximations to Martian conditions, but deviate significantly by at least half-a-dozen criteria.
A new hypothesis proposes an explanation for the presence of four prominent spikes in a long time record of the NO3(-) concentration inside the Antarctic ice. This solar flare hypothesis suggests that the ionizing radiation necessary in the spike formation could have come from extremely powerful solar flares. It is proposed that these flares would have occurred during the times of the largest maxima in the solar cycle. The solar flare hypothesis is compared with the supernova hypothesis.
Preflight and postflight chromosomal analyses of space flight crews are presented. Special attention is given to findings suggestive of exposure to ionizing radiation. Information was obtained by study of persons receiving an external body source, such as, therapeutic dosage or those accidentally exposed. Others receiving radiation exposure from an internal source, such as the decay of radioisotopes administered for diagnosis or treatment, were also analyzed.
The detectors were fabricated from a Ge:Ga wafer from Eagle-Pitcher with a room temperature resistivity of approx. 12ohms cm. The wafer is approximately 2 inches in diameter and 0.061 inches thick. The contact material was ion implanted with Boron using 10 to the 14th power ions/sq cm at 25 Kev and 2 x10 to the 14th power ions/sq cm at 50 Kev. The crystal was then sputter-cleaned and metallized first with sputtered Ti and then sputter Au. In addition to the usual infrared measurements of responsivity and noise, measurements were made of the detectors' response to ionizing radiation.
The sums of Meyman type-A and Thomas random variables are shown to retain their form under the constant multiplication parameter constraint. The conditions under which the two random variables converge in distribution to the fixed multiplicative Poisson, and to the Gaussian, are presented. It is shown that the latter result is important, in that it provides a solution to likelihood-ratio detection, estimation and discrimination problems in the presence of many kinds of signal and noise. Among the explicit applications presented are: (1) the photon-counter scintillation detection of nuclear particles when particle flux is low, (2) the photon-counting detection of weak optical signals in the presence of ionizing radiation, and (3) the design of a star-scanner spacecraft guidance system adequate for hostile space environments.