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At least 1,027 records · Page 57

Effect of Support on Iron-Based Catalyst Toward CO2-Free H2 Production From Methane Pyrolysis

The global demand for low-emission hydrogen production is increasing rapidly due to the potential for hydrogen to substitute conventional fossil fuels in energy-related applications. Among practical technologies such as steam reforming of methane (SMR), water electrolysis, and methane pyrolysis, methane pyrolysis has the most potential to produce economical- and near-zero-emission hydrogen. The reaction during methane pyrolysis produces a solid carbon by-product that can be monetized to offset production costs. However, this route is not without research challenges, and the selective formation of high-value carbon remains a critical issue. Supported nickel, iron, and cobalt, have been widely investigated for methane pyrolysis. Although iron-based catalysts are less active than Ni, iron catalysts offer less resistance to coke formation, are inexpensive, and have a longer lifetime. One area not sufficiently explored is the effect of support materials other than Al2O3 for the iron-based catalysts. Therefore, we investigated a detailed variation of support materials to study their influence on the catalytic performance. Moreover, this study offers a fair and direct comparison among all catalytic materials which were synthesized and studied under identical conditions. This direct comparison of the obtained results is important because results reported in different publications are often not comparable due to very different reaction conditions.

Gull, Nathan↗

Validation and Sensitivity Analysis of a 1-D Lake Model Across Global Lakes

Lakes have important influence on weather and climate from local to global scales. However, their prediction using numerical models is notoriously difficult because lakes are highly heterogeneous across the globe, but observations are sparse. In this study, we assessed the performance of a 1-D lake model in simulating the thermal structures of 58 lakes with diverse morphometric and geographic characteristics by following the phase 2a local lake protocol of the Inter-sectoral Impact Model Intercomparison Project (ISIMIP2a). After calibration, the root-mean-square errors (RMSE) were below 2 °C for 70% and 75% of the lakes for epilimnion and full-profile temperature simulations, with an average of 1.71 °C and 1.43 °C, respectively. The model performance mainly depended on lake shape rather than location, supporting the possibility of grouping model parameters by lake shape for global applications. Furthermore, through machine-learning based parameter sensitivity tests, we identified turbulent heat fluxes, wind-driven mixing and water transparency as the major processes controlling lake thermal and mixing regimes. Snow density was also important for modeling the ice phenology of high-latitude lakes. The relative influence of the key processes and the corresponding parameters mainly depended on lake latitude and depth. Turbulent heat fluxes showed a decreasing importance in affecting epilimnion temperature with increasing latitude. Wind-driven mixing was less influential to lake stratification for deeper lakes while the impact of light extinction, on the contrary, showed a positive correlation with depth. Our findings may guide improvements in 1-D lake model parameterizations to achieve higher fidelity in simulating global lake thermal dynamics.

54 ENVIRONMENTAL SCIENCES↗

Accessing files in an Internet: The Jade file system

Jade is a new distribution file system that provides a uniform way to name and access files in an internet environment. It makes two important contributions. First, Jade is a logical system that integrates a heterogeneous collection of existing file systems, where heterogeneous means that the underlying file systems support different file access protocols. Jade is designed under the restriction that the underlying file system may not be modified. Second, rather than providing a global name space, Jade permits each user to define a private name space. These private name spaces support two novel features: they allow multiple file systems to be mounted under one directory, and they allow one logical name space to mount other logical name spaces. A prototype of the Jade File System was implemented on Sun Workstations running Unix. It consists of interfaces to the Unix file system, the Sun Network File System, the Andrew File System, and FTP. This paper motivates Jade's design, highlights several aspects of its implementation, and illustrates applications that can take advantage of its features.

Peterson, Larry L.↗

Laser ranging network performance and routine orbit determination at D-PAF

ERS-1 is now about 8 months in orbit and has been tracked by the global laser network from the very beginning of the mission. The German processing and archiving facility for ERS-1 (D-PAF) is coordinating and supporting the network and performing the different routine orbit determination tasks. This paper presents details about the global network status, the communication to D-PAF and the tracking data and orbit processing system at D-PAF. The quality of the preliminary and precise orbits are shown and some problem areas are identified.

Massmann, Franz-Heinrich↗

Accessing files in an internet - The Jade file system

Jade is a new distribution file system that provides a uniform way to name and access files in an internet environment. It makes two important contributions. First, Jade is a logical system that integrates a heterogeneous collection of existing file systems, where heterogeneous means that the underlying file systems support different file access protocols. Jade is designed under the restriction that the underlying file system may not be modified. Second, rather than providing a global name space, Jade permits each user to define a private name space. These private name spaces support two novel features: they allow multiple file systems to be mounted under one directory, and they allow one logical name space to mount other logical name spaces. A prototype of the Jade File System was implemented on Sun Workstations running Unix. It consists of interfaces to the Unix file system, the Sun Network File System, the Andrew File System, and FTP. This paper motivates Jade's design, highlights several aspects of its implementation, and illustrates applications that can take advantage of its features.

Rao, Herman C.↗

Archiving Space Geodesy Data for 20+ Years at the CDDIS

Since 1982, the Crustal Dynamics Data Information System (CDDIS) has supported the archive and distribution of geodetic data products acquired by NASA programs. These data include GPS (Global Positioning System), GLONASS (GLObal NAvigation Satellite System), SLR (Satellite Laser Ranging), VLBI (Very Long Baseline Interferometry), and DORIS (Doppler Orbitography and Radiolocation Integrated by Satellite). The data archive supports NASA's space geodesy activities through the Solid Earth and Natural Hazards (SENH) program. The CDDIS data system and its archive have become increasingly important to many national and international programs, particularly several of the operational services within the International Association of Geodesy (IAG), including the International GPS Service (IGS), the International Laser Ranging Service (ILRS), the International VLBI Service for Geodesy and Astrometry (IVS), the International DORIS Service (IDS), and the International Earth Rotation Service (IERS). The CDDIS provides easy and ready access to a variety of data sets, products, and information about these data. The specialized nature of the CDDIS lends itself well to enhancement and thus can accommodate diverse data sets and user requirements. All data sets and metadata extracted from these data sets are accessible to scientists through ftp and the web; general information about each data set is accessible via the web. The CDDIS, including background information about the system and its user communities, the computer architecture, archive contents, available metadata, and future plans will be discussed.

Noll, Carey E.↗

Failure Engineering Study and Accelerated Stress Test Results for the Mars Global Surveyor Spacecraft's Power Shunt Assemblies

An Engineering-of-Failure approach to designing and executing an accelerated product qualification test was performed to support a risk assessment of a "work-around" necessitated by an on-orbit failure of another piece of hardware on the Mars Global Surveyor spacecraft. The proposed work-around involved exceeding the previous qualification experience both in terms of extreme cold exposure level and in terms of demonstrated low cycle fatigue life for the power shunt assemblies. An analysis was performed to identify potential failure sites, modes and associated failure mechanisms consistent with the new use conditions. A test was then designed and executed which accelerated the failure mechanisms identified by analysis. Verification of the resulting failure mechanism concluded the effort.

Gibbel, Mark↗

Root anatomy helps to reconcile observed root trait syndromes in tropical tree species

Premise Studying the organization of functional traits in plant leaves and stems has revealed notable patterns linking function and form; however, evidence of similarly robust organization in root tissues remains controversial. We posit that anatomical traits in roots can provide insight on the overall organization of the root system. We hypothesized that size variation in the tissue outside the stele is related in a nonlinear fashion with functional traits associated with direct resource uptake, including a negative relationship with root architectural traits, and that similar relationships detected in tropical areas also hold true in other biomes. Methods We addressed our hypotheses using empirical data from 24 tropical tree species in French Guiana, including anatomical measurements in first order roots and functional trait description for the entire fine root system. In addition, we compiled a global meta‐analysis of root traits for 500+ forest species across tropical, subtropical, and temperate forests. Results Our results supported the expected nonlinear relationships between cortical size and morphological traits and a negative linear trend with architectural traits. We confirmed a global negative relationship among specific root length (SRL), diameter, and tissue density, suggesting similar anatomical constraints in root systems across woody plants. However, the importance of factors varies across biomes, possibly related to the unequal phylogenetic representation across latitudes. Conclusions Our findings imply that the rhizocentric hypothesis can be a valuable approach to understand fine root trait syndromes and the evolution of absorptive roots in vascular plants.

Valverde‐Barrantes, Oscar J.↗

Satellite Observations for Detecting and Tracking Changes in Atmospheric Composition

The satellite observations provide constraints on detailed atmospheric modeling, including emissions inventories, indications of transport, harmonized data over vast areas suitable for trends analysis, and a link between spatial scales ranging from local to global, and temporal scales from diurnal to interannual. 1 The National Oceanic and Atmospheric Administration's (NOAA) long-term commitments help provide these observations in cooperation with international meteorological organizations. NASA s long-term commitments will advance scientifically important observations as part of its Earth Science Program, and will assist the transition of the science measurements to applied analyses through the Applied Science Program. Both NASA and NOAA have begun to provide near realtime data and tools to visualize and analyze satellite data,2 while maintaining data quality, validation, and standards. Consequently, decision-makers can expect satellite data services to support air quality decision making now and in the future. The international scientific community's Integrated Global Atmosphere Chemistry Observation System Report3 outlined a plan for ground-based, airborne and satellite measurements and models to integrate the observations into a four-dimensional representation of the atmosphere (space and time) to support assessment and policy information needs. This plan is being carried out under the Global Earth Observation System of Systems (GEOSS). Demonstrations of such an integrated capability4 provide new understanding of the changing atmosphere and link policy decisions to benefits for society. In this article, we highlight the use of satellite data to constrain biomass burning emissions, to assess oxides of nitrogen (NO(x)) emission reductions, and to contribute to state implementation plans, as examples of the use of satellite observations for detecting and tracking changes in atmospheric composition.

Neil, Doreen O.↗

Assessing the Altitude and Dispersion of Volcanic Plumes Using MISR Multi-angle Imaging from Space: Sixteen Years of Volcanic Activity in the Kamchatka Peninsula, Russia

Volcanic eruptions represent a significant source of atmospheric aerosols and can display local, regional and global effects, impacting earth systems and human populations. In order to assess the relative impacts of these events, accurate plume injection altitude measurements are needed. In this work, volcanic plumes generated from seven Kamchatka Peninsula volcanoes (Shiveluch, Kliuchevskoi, Bezymianny, Tolbachik, Kizimen, Karymsky and Zhupanovsky), were identified using over 16 years of Multi-angle Imaging SpectroRadimeter (MISR) measurements. Eighty-eight volcanic plumes were observed by MISR, capturing 3-25% of reported events at individual volcanoes. Retrievals were most successful where high intensity events persisted over a period of weeks to months. Compared with existing ground and airborne observations, and alternative satellite-based reports compiled by the Global Volcanism Program (GVP), MISR plume height retrievals showed general consistency; the comparison reports appear to be skewed towards the region of highest concentration observed in MISR-constrained vertical plume extent. The report observations display less discrepancy with MISR toward the end of the analysis period, with improvements in the suborbital data likely the result of the deployment of new instrumentation. Conversely, the general consistency of MISR plume heights with conventionally reported observations supports the use of MISR in the ongoing assessment of volcanic activity globally, especially where other types of volcanic plume observations are unavailable. Differences between the northern (Shiveluch, Kliuchevskoi, Bezymianny and Tolbachik) and southern (Kizimen, Karymsky and Zhupanovsky) volcanoes broadly correspond to the Central Kamchatka Depression (CKD) and Eastern Volcanic Front (EVF), respectively, geological sub-regions of Kamchatka distinguished by varying magma composition. For example, by comparison with reanalysis-model simulations of local meteorological conditions, CKD plumes generally were less constrained by mid-tropospheric (< 6 km) layers of vertical stability above the boundary layer, suggesting that these eruptions were more energetic than those in the EVF

Kamchatka↗

The diatom record from beneath the West Antarctic Ice Sheet and the global proxy perspective

Recent glaciological evaluation and modeling of the marine-based West Antarctic Ice Sheet (WAIS) support the possibility that the WAIS disintegrated during one or more Pleistocene interglacial period(s). The magnitude of sea level and oxygen isotope variation during certain late-Pleistocene interglacial periods is also consistent with the possibility of major retreat of the WAIS. Although oxygen isotopes from deep-sea sediments provide the best available proxy record for global ice volume (despite the ambiguities in the record), the source of ice volume changes must be hypothesized. Based on the intensity of interglacial isotopic shifts recorded in Southern Ocean marine sedimentary records, stage 11 (400,000 years ago) is the strongest candidate for WAIS collapse, but the records for stages 9, 7, and 5.5 are all consistent with the possibility of multiple late-Pleistocene collapses. Seismic reflection studies through the WAIS have revealed thick successions of strata with seismic characteristics comparable to upper Tertiary marine sediments. Small samples of glacial diamictons from beneath the ice sheet have been collected via hot-water drilled access holes. These sediments include mixed diatom assemblages of varying ages. Late-Miocene diatoms dominate many samples, probably reflecting marine deposition in West Antarctic basins prior to development of a dominantly glacial phase in West Antarctica. In addition to late-Miocene diatoms, samples from Upstream B (1988/89) contain rare post-Miocene diatoms, many of which imply deposition in the West Antarctic interior during one or more Pleistocene deglaciation periods. Age-diagnostic fossils in glacial sediments beneath ice sheets provide relatively coarse chronostratigraphic control, but they do contain direct evidence of regional deglaciation. Thus, sub-glacial till samples provide the evidence regarding the source of ice sheet variability seen in well-dated proxy records. Combined, these independent data sets can provide a more comprehensive and less speculative interpretation of the history of past glacial minima in currently glaciated polar regions.

Scherer, Reed P.↗

Improving Boundary Layer Data Assimilation in the NASA GEOS System

The Goddard Earth Observing System (GEOS) developed by the NASA Global Modeling and Assimilation Office assimilates a wide range of observations to support various NASA Earth Science missions. As Measurement of planetary boundary layer (PBL) was designated as an incubation program by the 2018 Decadal Survey, we have aimed to improve PBL thermodynamic structure using data from multiple observing systems. In particular, we have developed strategies and infrastructure to assimilate PBL height (PBLH) data derived from radiosondes, GNSS radio occultation, space-based lidar (CALIPSO, CATS, IceSat-2), ground-based lidar (MPLNET) and radar wind profilers to produce global PBL height analyses. We have also explored methods to better represent capping inversions by using PBLH data together with other observations in the GEOS to adjust background error covariance and enhance model PBL parameterization performance.

Y. Zhu↗

The International Global Network of Geodetic Fiducial Stations

Scientific need and technological opportunity require that we move toward implementing a global network of geodetic fiducial stations which feature co-located SLR, VLBI, GNSS, and DORIS instrumentation. Earth science of the next decade will require more accurate global change measurements of sea level topography, sea level change, polar ice mass balance, hydrological and atmospheric mass flux. and topographic deformation, real time mm scale navigation and precision time transfer on a global scale. These scientific requirements have been translated into a goal of mm scale annual stability for the terrestrial reference frame, earth orientation parameters, as well as the orbit and clock determinations tbr the GNSS systems. To meet these challenges, the four geodetic observing systems must be more tightly integrated in technology, location, and analysis. NASA strongly supports the objectives of the IGGOS initiative vis NASA's National Geodetic Observatory and INDIGO programs. The Global networks of GNSS, SLR. and VLBI observatories are for the most part poorly suited for these new demands. These important geodetic networks have evolved with little planning yet these systems are providing essential measurements to a wide swath of society. New signal structures in the GPS and the developing Galileo GNSS will soon require replacement of the GNSS receivers. The SLR network is poorly distributed globally, requires labor intensive observations and analysis, and for the most part relies upon antiquated technology. The VLBI observatories utilize large radio telescopes in remote regions that are poorly distributed globally. Co-location of these networks is sparse and co-location errors contribute significantly to the observing error spectrum. Increasing use of the S and X band by commercial and other government services will also contribute to increased observational errors. The time is upon us for an international effort to develop an optimized global geodetic fiducial network of twelve or more integrated automated geodetic observatories that will provide in near real time high density mea.surements of Earth orientation, geodetic positioning, and GNSS system monitoring. The strategic goal for the optimized global fiducial network should be efficient autonomous operation, real time data streaming to analysis centers with an integrated near real time analysis capability for all four observing systems. These goals are achievable in the next decade given the dramatic technological improvements in all geodetic systems. For VLBI, the BKG TIGO might be viewed as a preliminary prototype of technology for fundamental stations. Mark 5, PC-VSI. e-VLBI broadband development efforts are laying the groundwork to reduce the aperture of the VLBI antennas and to allow for precision mm level co-location of observing systems. Operating costs and enhanced accuracy would accrue from the elimination of hydrogen maser clocks using double differencing, GNSS time transfer technology, GHz broadband recording, real time analysis, and mm wavelength VLBI observations. A global geodetic fiducial network will not be realizable without international efforts and the support of the four services.

LaBrecque, John↗

A Flexible Low-Cost Optical Communications Ground Terminal at NASA Goddard Space Flight Center

We present the status of ongoing work at NASA-Goddard Space Flight Center (GSFC) to build a low-cost flexible ground terminal for optical communication. Previous laser communication missions at NASA have been supported by one-of-a-kind ground terminals built specifically for each mission. If NASA is to build a global network of optical terminals to enable widespread use of optical communications, then a blueprint for an economical ground terminal able to support a variety of missions is needed. With this goal in mind, NASA is constructing a ground terminal in Greenbelt, Maryland to enable testing of new ground terminal technologies from industry to academia.

Robert E Lafon↗

A statistical inference approach for the retrieval of the atmospheric ozone profile from simulated satellite measurements of solar backscattered ultraviolet radiation

NASA's Mission to Planet Earth (MTPE) will address important interdisciplinary and environmental issues such as global warming, ozone depletion, deforestation, acid rain, and the like with its long term satellite observations of the Earth and with its comprehensive Data and Information System. Extensive sets of satellite observations supporting MTPE will be provided by the Earth Observing System (EOS), while more specific process related observations will be provided by smaller Earth Probes. MTPE will use data from ground and airborne scientific investigations to supplement and validate the global observations obtained from satellite imagery, while the EOS satellites will support interdisciplinary research and model development. This is important for understanding the processes that control the global environment and for improving the prediction of events. In this paper we illustrate the potential for powerful artificial intelligence (AI) techniques when used in the analysis of the formidable problems that exist in the NASA Earth Science programs and of those to be encountered in the future MTPE and EOS programs. These techniques, based on the logical and probabilistic reasoning aspects of plausible inference, strongly emphasize the synergetic relation between data and information. As such, they are ideally suited for the analysis of the massive data streams to be provided by both MTPE and EOS. To demonstrate this, we address both the satellite imagery and model enhancement issues for the problem of ozone profile retrieval through a method based on plausible scientific inferencing. Since in the retrieval problem, the atmospheric ozone profile that is consistent with a given set of measured radiances may not be unique, an optimum statistical method is used to estimate a 'best' profile solution from the radiances and from additional a priori information.

Bonavito, N. L.↗

LandScan HD: a high-resolution gridded ambient population methodology for the world

Unwarned population distributions accounting for routine human activities are needed to address many global human security challenges, including disasters, conflict, and infrastructure demand. LandScan High Definition (LSHD) supports this need through gridded ambient population estimates that measure average human presence between daytime and nighttime at a high spatial resolution of 3 arcseconds (approximately 90 m). Although LSHD has traditionally been produced on a country-specific basis, advances in global foundational data and computational resources now enable scaling its methodology to the world. Combining aspects of top-down and bottom-up gridded population methods, LSHD allocates subnational population totals from authoritative statistics to built-up areas based on occupancy estimates for multiple facility types (e.g., residential, commercial) and then reaggregates these estimates to a global population grid. We scale this approach by organizing the LSHD data stack into a 1° resolution tileset of vector analytic features, enabling an efficient and repeatable workflow for all countries worldwide. Examining the Philippines as an output of the global LSHD baseline dataset, we contrast unwarned and residential (WorldPop) population distributions by (1) exploring a practical application of flood risk assessment and (2) evaluating their congruence with outcomes of collective human activities (subnational CO 2 emissions). Finally, we discuss plans to address current LSHD limitations through data/modeling and uncertainty quantification improvements and provide outlook for workflow automation and extending the model to social, demographic and economic population characteristics.

Building morphology↗

On the global circulation and the hurricane system of the Jovian atmosphere

An argument is made to support the proposal that Jupiter's red spot and the white and brown ovals are hurricanes or cyclones. Against the background of a convectively unstable troposphere, the general condition exists for the formation of hurricanes. The energy Jupiter emits must be transported upwards through the troposphere. If that transport is accelerated by the prevailing upward motions in the solar driven multicellular meridional circulation, eastward jets develop such as observed in the l region. But if that vertical transport is impeded by the prevailing downward motions in the meridional circulation, the atmosphere reacts and tends to maintain the process through the development of hurricanes. Dynamically induced by solar differential heating, an ordered latitudinal structure with alternating stability and instability is impressed on the troposphere to form alternating zonal strata where hurricanes are forbidden and permitted, respectively.

Mayr, H. G.↗