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NASA NTRS1972

X-ray fluorescence experiment

The X-ray fluorescence spectrometer, carried in the scientific instrument module bay of the command and service module, was used for orbital mapping of the lunar surface composition and X-ray galactic observations during transearth coast. The lunar surface measurements involved observations of the intensity and characteristic energy distribution of the secondary or fluorescent X-rays produced by the interaction of solar X-rays with the lunar surface. The astronomical observations consisted of relatively long periods of X-ray measurement of preselected galactic sources such as Cygnus (Cyg X-1) and Scorpius (Sco X-1).

Adler, I.↗
NASA NTRS1972

The Apollo 15 X-ray fluorescence experiment.

The prime purpose of the X-ray fluorescence spectrometer carried in the Scientific Instrument Module of the Command-Service Module was to map the lunar surface with respect to its chemical composition. Results are presented for Al, Mg, and Si as Al/Si and Mg/Si ratios for the various features overflow by the spacecraft. The lunar surface measurements involved observations of the intensity and characteristic energy distribution of the secondary or fluorescent X rays produced by the interaction of solar X rays with the lunar surface. The results showed that the highlands and maria are chemically different, with the highlands having considerably more Al and less Mg than the maria. The mare-highland contact is quite sharp and puts a limit on the amount of horizontal transport of material. The X-ray data suggest that the dominant rock type of the lunar highlands is a plagioclase-rich pyroxene bearing rock probably anorthositic gabbro or feldspathic basalt.

Adler, I.↗
NASA NTRS1973

Ultraminiature X-ray fluorescence spectrometer for in-situ geochemical analysis on Mars.

A spectrometer based upon the X-ray fluorescence method of elemental analysis has been developed in an ultraminiature, rugged form suitable for a spacecraft mission to Mars. The instrument employs two radioisotope sources (Fe-55 and Cd-109) which irradiate adjacent areas on a regolith sample. Fluorescent X rays emitted by the sample are detected by four thin-window proportional counters. Using pulse-height discrimination, the energy spectra are determined. Virtually all elements above sodium in the periodic table are detected if present at sufficient levels. Minimum detection limits range from 30 ppm to 2% depending upon the element and the matrix. For most elements, they are below 0.5%. Accuracies also depend upon the matrix, but are generally better than plus or minus 0.5% for all elements of atomic number greater than 14. Elements below sodium are also detected, but as a single group. Ambiguities of identification of the elements producing the observed spectra are minimal.

Clark, B. C.↗
NASA NTRS1973

A search for continuous fluorescence in reflection nebulae

Photometric and spectrophotometric observations were made of the reflection nebulae NGC1435, NGC2068, NGC7023, and IC1287 in an attempt to detect continuous fluorescence by dust grains. Several effects of importance for observations of such faint objects are discussed, including instrumental light scattering, a photographic effect, and a time delay effect which can occur if the illuminating star is a spectrum variable. It is found that continuous fluorescence by interstellar grains is not likely to exist and that it cannot account for more than 10 percent of the total surface brightness of these reflection nebulae. No evidence of diffuse interstellar features is found in the spectra of these nebulae.

Rush, W. F.↗
NASA NTRS1974

Fluorescence and phosphorescence of photomultiplier window materials under electron irradiation

The fluorescence and phosphorescence of photomultiplier window materials under electron irradiation were investigated using a Sr-90/Y-90 beta emitter as the electron source. Spectral emission curves of UV grade, optical grade, and electron-irradiated samples of MGF2 and LiF, CaF2, BaF2, sapphire, fused silica, and UV transmitting glasses were obtained over the spectral range of 200 nm to 650 nm. Fluorescence yields, expressed as the number of counts in a solid angle of 2 pi steradian per 1MeV of incident electron energy deposited, were determined on these materials utilizing photomultiplier tubes with cesium telluride, bialkali, and trialkali (S-20) photocathodes, respectively.

Viehmann, W.↗
NASA NTRS1972

Fluorescent antibody detection of microorganisms in terrestrial environments

The fluorescent antibody technique and its use in direct microscopic examination of the soil is discussed. Feasibility analyses were made to determine if the method could be used to simultaneously observe and recognize microorganisms in the soil. Some data indicate this may be possible. Data are also given on two related problems involving the interaction of soil microorganisms with plant roots to form symbiotic structures. One was concerned with the developmental ecology and biology of the root nodule of alder and the second was concerned with the ectotrophic mycorrhizal structure on forest trees, especially pines. In both, the fluorescent antibody detection of the microbial symbiont both as a free living form in soil, and as a root inhabiting form in the higher plant was emphasized. A third aspect of the research involved the detection of autotrophic ammonia oxidizing microorganisms in soil.

Schmidt, E. L.↗
NASA NTRS1973

Fluorescence of molecular hydrogen excited by solar extreme-ultraviolet radiation

During trans-earth coast, the Apollo 17 ultraviolet spectrometer was scheduled to make observations of the far ultraviolet background in selected regions of the sky. In the course of one of these observations, the spacecraft fuel cells were routinely purged of excess hydrogen and water vapor. The ultraviolet fluorescence spectrum of the purged molecular hydrogen excited by solar extreme ultraviolet radiation is interpreted by absorption of solar L-beta and L-gamma radiation in the nearly resonant (6, 0) and (11, 0) Lyman bands. The results are deemed significant for ultraviolet spectroscopic investigations of the atmospheres of the moon and planets since Lyman-band fluorescence provides an unambiguous means of identification of molecular hydrogen in upper atmospheres.

Feldman, P. D.↗
NASA NTRS1975

Laser-excited fluorescence for measuring atmospheric pollution

System measures amount of given pollutant at specific location. Infrared laser aimed at location has wavelength that will cause molecules of pollutant to fluoresce. Detector separates fluorescence from other radiation and measures its intensity to indicate concentration of pollutant.

Menzies, R. T.↗
NASA NTRS1974

A flash photolysis-resonance fluorescence study of the formation of O(D-1) in the photolysis of water and reaction of O(D-1) with H2, Ar and He

The relative importance of two primary processes in the photolyis of water: (1) H2O + h (nu) yields H + OH, and (2) H2O + h (nu) yields H2 + OD-1 were determined in a direct manner by time resolved detection (via resonance fluorescence) of H and O formed in processes 1 and 2 respectively. The initially formed OD-1 was deactivated to ground state OP-3 prior to detection via resonance fluorescence. The relative quantum yields for processes 1 and 2 are 0.89 and 0.11 for the wavelength interval 105 to 145nm and = to or greater than 0.99, and = to or less than 0.01 for the wavelength interval 145 to 185nm. Rate constants at 300 K for the reactions OD-1 + H2, + Ar, and + He are presented.

Stief, L. J.↗
NASA NTRS1975

LIFES: Laser Induced Fluorescence and Environmental Sensing

A laboratory investigation has been conducted to evaluate the detection and identification capabilities of laser induced fluorescence as a remote sensing technique for the marine environment. The relative merits of fluorescence parameters including emission and excitation profiles, intensity and lifetime measurements are discussed in relation to the identification of specific targets of the marine environment including crude oils, refined petroleum products, fish oils and algae. Temporal profiles displaying the variation of lifetime with emission wavelength have proven to add a new dimension of specificity and simplicity to the technique.

Houston, W. R.↗
NASA NTRS1975

Search for continuous fluorescence in reflection nebulae

Photometric and spectrophotometric observations have been made of the reflection nebulae NGC 1435, NGC 2068, NGC 7023, and IC 1287 in an attempt to detect continuous fluorescence by dust grains. Several effects of importance for observations of such faint objects are discussed, including instrumental light scattering, a photographic effect, and a time-delay effect which can occur if the illuminating star is a spectrum variable. It is found that continuous fluorescence by interstellar grains is not likely to exist and that it cannot account for more than 10% of the total surface brightness of these reflection nebulae. No evidence of diffuse interstellar features is found in the spectra of these nebulae.

Rush, W. F.↗
NASA NTRS1975

Stripping-mechanism dependence of the Ar 2s fluorescence yield

Argon L1 fluorescence yields have been calculated for the individual multiplet states of ions containing from three to six M-shell vacancies. Effective fluorescence yields for these charge states are computed for statistically distributed states and for distributions that would arise in sequential stripping. For Ar L1M6, the latter result is about 430 times smaller than the former.

Chen, M. H.↗
NASA NTRS1976

Argon content of the Martian atmosphere at the Viking 1 landing site - Analysis by X-ray fluorescence spectroscopy

Spectra provided by the Viking 1 X-ray fluorescence spectrometer operating in the calibration mode (without a soil sample in the analysis chamber) were analyzed to determine the argon content of the Martian atmosphere at the landing site. This was found to be less than or equal to 0.15 millibar, or not more than 2% by volume, consistent with data obtained by the entry mass spectrometer and by the mass spectrometer on the lander. It is anticipated that analysis of the K content of surface samples using X-ray fluorescence data will provide information on the evolution of the atmosphere, since most atmospheric argon is apparently produced by decay of K-40.

Clark, B. C.↗
NASA NTRS1976

Palus Somni - Anomalies in the correlation of Al/Si X-ray fluorescence intensity ratios and broad-spectrum visible albedos

The positive correlation between Al/Si X-ray fluorescence intensity ratios determined during the Apollo 15 lunar mission and a broad-spectrum visible albedo of the moon is quantitatively established. Linear regression analysis performed on 246 1 degree geographic cells of X-ray fluorescence intensity and visible albedo data points produced a statistically significant correlation coefficient of .78. Three distinct distributions of data were identified as (1) within one standard deviation of the regression line, (2) greater than one standard deviation below the line, and (3) greater than one standard deviation above the line. The latter two distributions of data were found to occupy distinct geographic areas in the Palus Somni region.

Clark, P. E.↗
NASA NTRS1977

Atomic and molecular fluorescence as a stratospheric species monitor

The results of an investigation are presented evaluating the potential of atomic and molecular fluorescence as a stratospheric monitor of the concentrations of any one of 18 minor species: Cl, Cl2, ClO, ClO2, CO, H2, HCHO, HCl, HNO2, HNO3, H2S, NH3, NO, NO2, N2O, O, OH, and SO2. All spectral regions from the vacuum ultraviolet through the infrared were included. It was found that suitable systems can be constructed for the stratospheric monitoring of CO (5 ppb), NO2 (less than 1 ppb), OH (0.2 ppt), and O (50-200 ppt). The fluorescence sensitivities for Cl (0.5-1.0 ppt), H2 (0.2 ppm at 10 torr) and SO2 (1-10 ppb) are marginally insufficient with current technology.

Schofield, K.↗
NASA NTRS1977

Reevaluation of the Apollo orbital X-ray fluorescence data

A combination of Al/Mg ratios and Al/Si ratios has provided high-quality geochemical and geological information from the Apollo orbital X-ray fluorescence data. The high sensitivity of the characteristic Si X-rays to alterations in the energy spectra of the solar X-ray flux limits the analytical usefulness of the ratios involving Si. A photometric study indicates that the Si concentration in lunar materials varies by less than about + or - 15% of the Si present. In addition, particle size and surface roughness are shown to have small effects on the characteristic fluorescent X-ray radiation of Si.

Hubbard, N. J.↗
NASA NTRS1978

Bowen fluorescence in the solar transition region

In Bowen fluorescence, a 304-A photon of He II is converted into two optical photons and an EUV photon of O III. The fluorescent contribution to the intensity of the O III 374-A line is a measure of the column density of O III in the solar transition region. Division of the column density into the emission measure derived from other lines of O III allows determination of the electron density. The accuracy of this technique is roughly a factor of 2, which is comparable to the accuracy of the density diagnostics for the solar transition region.

Raymond, J. C.↗
NASA NTRS1978

Illumination-dependent changes in the intrinsic fluorescence of bacteriorhodopsin

The paper describes the intrinsic UV fluorescence of bacteriorhodopsin in some detail and determines the changes during the rapid cyclic reaction following light flashes. The results suggest that several tryptophan residues are affected in the protein, among them one or more exposed to aqueous medium. The kinetics of the fluorescence changes coincide closely with events involving the retinal residue during the deprotonation and reprotonation of the Schiff base group.

Bogomolni, R. A.↗