Predicting Localized Pitting Corrosion on Austenitic Stainless Steels Utilized in Spent Nuclear Fuel Storage.
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This development of empirical data to support realistic and science-based input to safety regulations and transportation standards is a critical need for the hazardous material (HM) transportation industry. Current regulations and standards are based on the TNT equivalency model. However, real world experience indicates that use of the TNT equivalency model to predict composite overwrapped pressure vessel (COPV) potential energy release is unrealistically conservative. The purpose of this report is to characterize and quantify rupture events involving damaged COPV’s of the type used in HM transportation regulated by the Department of Transportation (DOT). This was accomplished using a series of five tests; 2 COPV tests for compressed natural gas (CNG), 2 COPV tests for hydrogen, and 1 COPV test for nitrogen. Measured overpressures from these tests were compared to predicted overpressures from a TNT equivalence model and blast curves. Comparison between the measurements and predictions shows that the predictions are generally conservative, and that the extent of conservatism is dominated by predictions of the chemical contribution to overpressure from fuel within the COPVs.
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Energetic ions drive a rich variety of instabilities in the complex multi-species plasma of Earth’s magnetosphere. This experiment exploited the highly flexible, high power particle beam injection capability and sophisticated diagnostic suite of the DIII-D tokamak to advance understanding of two particular instabilities of significant interest to the magnetospheric research community that have closely-related counterparts in beam-heated tokamak plasmas: electromagnetic ion cyclotron waves (EMIC) [1], observed at frequencies somewhat below the ion cyclotron frequencies of bulk ion species, and equatorial noise [2], observed at energetic-ion cyclotron harmonics. In the magnetic fusion energy domain, such waves are called ICE (Ion Cyclotron Emission). Recent substantial advances in diagnostic capability in the ion cyclotron range of frequencies in DIII-D, including measurement of wave polarization, spa)al structure and amplitude created an exciting opportunity to challenge and drive advances in theoretical understanding of these phenomena.
Improved lifetime of high-power broad area laser diodes will enhance their utility for manufacturing, scientific, and medical laser systems. However, factors contributing to gradual degradation of diode laser performance are not fully understood. Here we study the aging mechanisms of ~800 nm aluminum-free laser diodes grown by solid-source MBE. Oxygen was intentionally introduced at three different concentration levels into the quantum well (QW) and waveguide (WG) at concentrations <5×10 15 cm -3 . Diode power, slope efficiency (SE th ), threshold current (I th ), and device parameters such as QW and WG lifetimes were measured at discrete time steps throughout the aging run. The data show that lasing characteristics prior to aging are degraded by oxygen introduction, but the gradual power degradation rate of ~5% over 500 hours at current density 1.74 kA/cm 2 does not change with oxygen concentration. Aging-induced changes in nonradiative lifetimes and threshold were observed for shorter aging times, but stabilized after ~100 hrs. and cannot explain the observed power degradation. This suggests that gradual degradation in these devices is not due to nonradiative recombination at low levels of point defects. The data shows that this degradation results primarily from changes in slope efficiency, and simulation of these results suggests that the power degradation arises from increased intracavity absorption (ICA). Efforts to slow ICA growth, instead of efforts to control low levels of nonradiative recombination centers, may be the most fruitful path forward to improve laser diode lifetime.
Quantitative risk assessment (QRA) is highly dependent on data, leading to more robust models as new and updated data is acquired. The Hydrogen Plus Other Alternative Fuels Risk Assessment (HyRAM+) QRA capabilities include calculations of individual risk from leaks in a gaseous hydrogen facility due to the potential effects of jet fires and explosions. Leak frequencies are acquired through statistical analysis of published data from a variety of sources and industries. The filter leak frequencies in previous versions of the HyRAM+ software are substantially greater than the leak frequencies of other components, leading to QRA results for gaseous hydrogen in which filters consistently dominate the overall risk. Data that were previously used to derive the filter leak frequencies were reevaluated for applicability and additional data points were added to update the filter leak frequencies. The new frequencies are more comparable to leak frequencies for other components.
Liquefied petroleum gas (LPG) is used in heating, cooking, and as a vehicle fuel (called autogas). A safety risk assessment may be needed to assess potential hazard scenarios and inform the regulations, codes, and standards that apply to LPG facilities, such as autogas refueling facilities. The frequency of unintended releases in an LPG system is an important aspect of a system quantitative risk assessment. This report documents estimation of leakage frequencies for individual components of LPG systems. These frequencies are described using uncertainty distributions obtained with Bayesian statistical methods, generic data, and LPG data which were publicly available. There was a lack of LPG data in the literature, so frequencies for most components were developed with generic data and should be used cautiously; without additional information about component leak frequencies in LPG systems, it is not known whether these generic frequencies may be conservative or non-conservative.
This report investigates topics of interest with regard to Nuclear Power Plants (NPPs) utilizing flexible plant operations and generation (FPOG). Previous reports have identified the risk associated with co-located hydrogen generation facilities. This report evaluates special topics with regard to co-location of both hydrogen and syngas production facilities. A literature review was conducted to evaluate overpressure mitigation techniques that may be available to the NPP to reduce the consequence of an overpressure event. Also, the overpressure consequence of a catastrophic hydrogen storage tank failure event was analyzed. A comparison of the similarities and differences between the methodology utilized in HyRAM+ and Regulatory Guide 1.91 (R.G. 1.91) was performed for overpressure analysis. Also, the trinitrotoluene (TNT) equivalency methodology was utilized to evaluate an overpressure event at a Syngas production facility.
Nuclear power plants (NPPs) are considering flexible plant operations to take advantage of excess thermal and electrical energy. One option for NPPs is to pursue hydrogen production through high temperature electrolysis as an alternate revenue stream to remain economically viable. The intent of this study is to investigate the risk of a hydrogen production facility in close proximity to an NPP. A 100 MW, 500 MW, and 1,000 MW facility are evaluated herein. Previous analyses have evaluated preliminary designs of a hydrogen production facility in a conservative manner to determine if it is feasible to co-locate the facility within 1 km of an NPP. This analysis specifically evaluates the risk components of different hydrogen production facility designs, including the likelihood of a leak within the system and the associated consequence to critical NPP targets. This analysis shows that although the likelihood of a leak in an HTEF is not negligible, the consequence to critical NPP targets is not expected to lead to a failure given adequate distance from the plant.
Nuclear power plants (NPPs) are considering flexible plant operations to take advantage of excess thermal and electrical energy. One option for NPPs is to pursue hydrogen production through high temperature electrolysis as an alternate revenue stream to remain economically viable. The intent of this study is to investigate the risk of a 100 MW hydrogen production facility in close proximity to an NPP. Previous analyses have evaluated preliminary designs of a hydrogen production facility in a conservative manner to determine if it is feasible to co-locate the facility within 1 km of an NPP. This analysis specifically evaluates the risk components of a 100 MW hydrogen production facility design, including the likelihood of a leak within the system and the associated consequence to critical NPP targets. This analysis shows that although the likelihood of a leak in an HTEF is not negligible, the consequence to critical NPP targets is not expected to lead to a failure given adequate distance from the plant.
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Typical QRAs provide deterministic estimates and understanding of risks posed but are constructed using significant assumptions and uncertainties due to limited data availability and historical momentum of using nominal estimates. This report presents a hydrogen QRA analysis using HyRAM+ that incorporates uncertainty with Latin hypercube sampling and sensitivity analysis using linear regression.
Blending hydrogen into existing natural gas pipelines is a current initiative for large-scale hydrogen deployment in the United States. Understanding changes in hazards and risk for fuel blends can help inform regulations. A differential risk assessment was conducted to understand how the safety profile of fires and unignited flammable plumes of leaking fuel would change based on blend composition. The area affected by harmful heat fluxes from jet fires was found to be larger for blends with more natural gas in them, while the distance affected by unignited flammable fuel concentrations was found to be larger for blends with more hydrogen in them. Component leak frequencies and ignition probabilities greatly impact both heat flux risk and the flammable plume risk. The collection of additional blend-specific industry data could help understand which assumptions are most valid to make when calculating risk.
The Disposal Research & Development (Disposal R&D) Campaign of the U.S. Department of Energy (DOE) Office of Nuclear Energy (NE), Office of Spent Fuel & High-Level Waste Disposition is conducting research and development (R&D) on geologic disposal of spent nuclear fuel (SNF) and high-level nuclear waste (HLW). A high priority for Disposal R&D is disposal system modeling (Sassani et al. 2023). The Geologic Disposal Safety Assessment (GDSA) work package is charged with developing a disposal system modeling and analysis capability for evaluating generic disposal system performance for nuclear waste in geologic media.