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At least 1,027 records · Page 57

Remote sensing of atmospheric SO2 using the differential absorption LIDAR technique

The paper reports an investigation of the capabilities of a UV differential absorption lidar (DIAL) system for remote measurements of sulfur dioxide emissions. Two features of the present DIAL system are an absorption cell permitting the determination of the difference in SO2 absorption coefficients for the two transmitted wavelengths and a calibration cell permitting the linearity and performance of the system to be evaluated. The DIAL technique is described along with the transmitter, receiver, data-adquisition, and data-processing components of the investigated system. Quantitative measurements of the average SO2 concentration in a region surrounding the exhaust stack of a steam-generating plant are discussed which show that the present system has measurement sensitivities of 10 ppb at a range of 0.8 km and 20 ppb at 1.9 km. Based on performance characteristics obtained during a calibration of this system, it is predicted that a measurement sensitivity of less than 4 ppb over a 1-km path will be attained.

Hoell, J. M., Jr.↗

High temperature reflectance of hyperpure slip cast silica

An experimental program to optically characterize hyperpure slip cast silica at elevated temperatures is described. This sintered ceramic material is being used in the development of a reflective heat shield for the Outer Planet Entry Probe. A unique high temperature integrating sphere reflectometer is described and reflectance data in the spectral range 0.23-2.3 micron are presented at temperatures up to 1427 C in air and helium environments. Kubelka-Munk (K-M) scattering and absorptance coefficients (K and S), using the Reichman extension of the K-M theory, are presented as is a unique method of obtaining K and S from the Reichman equations using only reflectance data. The hyperpure slip cast silica material was found to retain its high diffuse reflectance at temperatures up to 1204 C, with slight degradation occurring at higher temperatures.

Dillow, C. F.↗

Effect of radiant and convective heating on the optical and thermochemical properties of reusable surface insulation

A correlation between the morphology, chemistry, and optical properties of space shuttle candidate reusable surface insulation coatings were made to determine the proper test environment for flight evaluation studies. The optical properties (solar absorption coefficient and total hemispherical emittance) for each coating were obtained as a function of exposure to radiant and convectively heated environments since these parameters define the surface temperature of the material during flight. Results are presented which show these optical properties differ in the two environments and can be related to the coating's surface and bulk chemistry.

Stewart, D. A.↗

9.6 micrometer ozone band /nu sub 3/ intensity

The band intensity of the 9.6 micrometer (nu sub 3) band of ozone was investigated. The nu sub 3 band strength was determined from ultraviolet spectra over the interval 9.36-11.00 micrometers. A set of 34 absorption measurements were made at pressures of about 730 torr and mass paths of 0.002-0.025 atm cm (STP). The ozone amounts were corrected to the Harn (1961) absorption coefficients. The data indicate that the weak-line approximation is valid at least to 0.025 atm cm (STP). A least-squares fit yields a band strength (298 K) of 355/cm/atm cm STP with a standard deviation of 10/cm/atm cm STP, in close agreement with results reported by McCaa and Shaw (1968) and Young and Bunner (1974).

Bartman, F. L.↗

Ethane and acetylene abundances in the Jovian atmosphere

The paper reports spectra of Jupiter in the spectral region from 755 to 850 kaysers, which covers the nu-9 fundamental of ethane and contains lines from the R branch of the nu-5 fundamental of acetylene. The monochromatic absorption coefficient of the central Q branch of the nu-9 fundamental of ethane, which was determined in the laboratory, is applied in a radiative-transfer calculation to evaluate the ethane mixing ratio in the Jovian atmosphere; the present data are also used to place an upper limit on the acetylene mixing ratio. For the radiative-transfer calculation, emission intensity is computed for the region above the 0.02-atm level assuming both an isothermal inversion layer and a previously reported temperature profile. The resulting maximum mixing ratios consistent with the observations are 0.00003 for ethane and 7.5 by 10 to the -8th power for acetylene.

Tokunaga, A.↗

The ionization of a low-density intercloud medium by a single O star

The ionization structure of hydrogen in a cloud-containing low-density gas surrounding an O star is calculated, emphasizing how UV photons cause the ionization of hydrogen in regions which are totally obscured from the star by neutral clouds. Particular consideration is given to the ionization of such obscured regions by diffuse Lyman continuum radiation produced when H(+) recombines directly to the ground state. The assumed physical structure of the cloud-containing neighborhood of an O star is discussed, a method is outlined for expressing the emission and absorption properties of the neutral clouds and their shadows in terms of effective volume emissivities and absorption coefficients on a line of sight, and equations of radiative transfer are derived for diffuse and stellar radiation in a cloud-containing H II region. Reradiation of Lyman continuum photons from the ionized boundary layer of a neutral cloud or shadow is analyzed. The expected emission measure across a large cloud-containing H II region is determined and found to compare well with that obtained from observations of H-alpha emission around runaway O stars. It is shown that the hydrogen in cloud shadows may be completely ionized by diffuse radiation within approximately half the Stroemgren radius, depending on the extent of that radius, the average frequency of the Lyman continuum radiation from the star, and the average cloud size.

Elmegreen, B. G.↗

Stark effect applicable to optically pumped far-infrared laser

Absorption measurements at CO2 laser frequencies were carried out as a function of Stark fields and CH3OH gas pressures to assess the effect of low electric field Stark tuning on methanol absorption at the P(12) 9.4 micron CO2 laser line, in a continuing search for coherent emitters at submillimeter wavelengths (far infrared). The line center absorption coefficient is found to increase five-fold with a 2.3 kV/cm Stark field at the 220 mtorr methanol pressure optimal for methanol far infrared lasing. The low electric field Stark tuning encourages efforts to enhance the pumping efficiency of a methanol far infrared laser at its normal optimum operating pressure, and suggests that significant Stark field induced frequency modulation of the far IR laser output is feasible.

Claspy, P. C.↗

Method and apparatus for background signal reduction in opto-acoustic absorption measurement

The sensitivity of an opto-acoustic absorption detector is increased to make it possible to measure trace amounts of constituent gases. A second beam radiation path is created through the sample cell identical to a first path except as to length, alternating the beam through the two paths and minimizing the detected pressure difference for the two paths while the beam wavelength is tuned away from the absorption lines of the sample. Then with the beam wavelength tuned to the absorption line of any constituent of interest, the pressure difference is a measure of trace amounts of the constituent. The same improved detector may also be used for measuring the absorption coefficient of known concentrations of absorbing gases.

Rosengren, L. G.↗

X-ray topographic observations of magnetic domains in Czochralski-grown nickel single crystals in anomalous transmission geometry

The anomalous transmission effect has been observed in nickel single crystals grown by the Czochralski technique. Sample crystals prepared for X-ray topography are 1.5 to 2.5 cm in diameter and thicker than 0.4 mm; the product of the ordinary linear absorption coefficient and thickness ranges from 17 to 45 for Cu K-alpha radiation. Topographs taken with an asymmetric-crystal-topographic (ACT) camera have revealed extremely straight line images and rectangular arrangements of short line-segment images, along with the images of crystal imperfections. The line images change their arrangement upon application of magnetic fields. These images are attributed to magnetic domains in the interior of crystals. The formation of domain walls near the crystal surface is also observed and distinguished clearly from magnetic domains in the bulk with the use of the ACT camera.

Kuriyama, M.↗

Monitoring complex trace-gas mixtures by long-path laser absorption spectrometry

Laser-based spectrophotometric methods, which have been proposed for the detection of trace concentrations of gaseous contaminants, include Raman and passive radiometry. The paper discusses a simple long-path laser absorption method which is capable of resolving complex mixtures of closely related trace contaminants at ppm levels. A number of species were selected which are most likely to accumulate in closed environments, such as submarines or long-duration manned space flights. Absorption coefficients at CO2 laser wavelengths were measured, accurate to + 3 per cent or better, for each of these species. This data base was then used to determine the presence and concentration of the contaminants in prepared mixtures of 12 to 15 gases. Computer programs have been developed which will permit a real-time analysis of the monitored atmosphere. Minimum detectable concentrations for individual species are generally in the ppm range, and are not seriously degraded by interferences even in complex mixtures. Estimates of the dynamic range of this monitoring technique for various system configurations and comparison with other methods of analysis are discussed

Green, B. D.↗

Spectral band passes for a high precision satellite sounder

Atmospheric temperature soundings with significantly improved vertical resolution can be obtained from carefully chosen narrow band-pass measurements in the 4.3-micron band of CO2 by taking advantage of the variation of the absorption coefficients, and thereby the weighting functions, with pressure and temperature. A set of channels has been found in the 4.2-micron region that is capable of yielding about 2-km vertical resolution in the troposphere. The concept of a complete system is presented for obtaining high resolution retrievals of temperature and water vapor distribution, as well as surface and cloud top temperatures, even in the presence of broken clouds.

Kaplan, L. D.↗

The embedded feature model for the interpretation of chromospheric contrast profiles

Contrast profiles obtained from chromospheric filtergrams and spectra of bright and dark mottles have to date been interpreted almost exclusively in terms of Becker's cloud model. Here we demonstrate the failure of this model to account in a physically consistent way for the observed contrasts. As an alternative, we introduce an embedded-feature model, restricting our discussion in this paper to stationary features. Our model is then characterized by three independent parameters: the density of absorbing atoms, the geometrical depth, and the profile of the absorption coefficient. An analytic approximation to the contrast resulting from such a model reproduces well the observed behavior of all types of contrast profiles.

Steinitz, R.↗

Instrument measures many optical properties in visible and IR

Electro-optical system measures reflectance, reflectance ratio, transmission, absorption, refractive index, and absorption coefficient in both visible and infrared (IR) spectral regions. System effectively combining capabilities of ellisometer, reflectometer, and spectrophotometer is expected to find application in environmental and material composition testing fields.

Batten, C. E.↗

Theoretical simulation of solar spectra in the middle ultraviolet and visible for atmospheric trace constituent measurements

Two balloon flights reaching float altitudes of approximately 30 and 40 km respectively, were used to obtain scans of the ultraviolet and visible solar spectra. Both flights covered the UV (2800-3500A) at approximately 0.3A resolution and the visible at approximately 0.6A. Numerous scans were obtained during ascent and from float for both flights. All spectral scans obtained at float, from high sun to low sun, were calibrated in wavelength by using several standard solar spectra for line position references. Comparisons of low sun scans and high sun scans show significant atmospheric continuum extinction and have the potential of being used to identify atmospheric lines superimposed on the attenuated solar spectrum. The resolution was mathematically degraded to approximately 5A to better see the broad band atmospheric extinction. This low resolution is also appropriate for the available low resolution absorption coefficients of NO2 and O3, allowing the identification of NO2 and O3 features on the sunset spectra.

Goldman, A.↗

Properties of aerosols in the Martian atmosphere, as inferred from Viking Lander imaging data

Three types of aerosol were detected from observations of the Martian sky, Phobos, and the sun with the Viking imaging cameras. Atmospheric optical depths were derived from observations of the objects' brightness. Data on the absorption coefficient, mean size, and shape of aerosols were obtained from studies of the sky brightness, using a multiple-scattering computer code. The aerosol types were water ice ground fog, a higher-level ice cloud (polar hood), and soil particles suspended at heights up to 30 km. The properties of each type of aerosol are discussed. The data are subjected to thorough analysis, and the results are summarized.

Pollack, J. B.↗

Study of the luminosity function for field galaxies

Nine determinations of the luminosity function (LF) for field galaxies are adjusted, analyzed, and compared. Adjustments are made for differences in definitions as well as in assumptions regarding magnitude systems, the Hubble constant, and galactic absorption. Eight of the nine adjusted determinations are found to be in fairly good agreement, and the discrepancy in the ninth is attributed to incompleteness effects. A large-scale normalization of the LF is performed using the method and some integral counts of Gott and Turner (1976); the large-scale mean LF of (mostly field) galaxies is found to be about 2.3 times less than a previously derived 'local' LF. The large-scale luminosity density in space arising from sources within the B(0) isophotes of galaxies is evaluated, and a value of 86 million (H/50) suns per cu Mpc is obtained for a galactic absorption coefficient of 0.25 magnitude. It is noted that the true large-scale luminosity density is probably within a factor of 1.6 of the reported value.

Felten, J. E.↗

Measurements of H-beta, He D3, and Ca/+/ 8542-A line emission in quiescent prominences

Measurements of H-beta, He D3, and Ca(+) 8542-A line emission in 18 quiescent prominences are presented which were performed with a 25-cm coronagraph/coude spectrograph system and an optical multichannel analyzer utilizing a Si-vidicon detector assembly mounted at the single-pass spectrograph port. The data obtained show that the line profiles deviate in the wings from those calculated on the basis of an isothermal atmosphere and a Gaussian absorption coefficient. Both a non-Gaussian microturbulence component and a temperature gradient from prominence-core to coronal values can successfully account for this phenomenon. The line widths from a given line of sight of prominence material are reduced on the basis of a common core emitting region with a temperature of 7500 to 11,600 K and a microturbulent velocity of 4.5 to 7.1 km/s for the isothermal model (these values are 5% to 10% less for the two-temperature model). It is noted that long-period low-amplitude oscillations in the D3 line width and intensity were observed when a specific line of sight in a quiescent prominence was followed. These oscillations are found to remain coherent for as many as 3 or 4 cycles and to be associated with prominence structural activation.

Landman, D. A.↗

An approximate inviscid radiating flow field analysis for outer planet entry probes

An approximate computational technique has been developed for predicting inviscid, radiating flows about blunt probes entering atmospheres consisting of hydrogen and helium. The technique is rapid and versatile and is well suited for performing parametric trade studies for outer planet entries. Details of the computational technique, the thermodynamic correlations, the 58-step absorption coefficient model and the analytic shock shape equations are discussed. Good comparisons of the radiative heating computed by the approximate method and by detailed calculations are obtained.

Zoby, E. V.↗