Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “MOLDING”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,027 records · Page 57

Studies on the Module Structure for the NOvA Liquid Scintillator Neutrino Detector

This thesis contains studies pertinent to the construction of modules for the NOνAexperiment detectors. The tensile strength of acrylic and epoxy adhesives used in construction of the detector was studied over time and with various surface preparations. Sanding and corona discharge surface treatments increased the bond strength of the acrylic by 10-20%; aging in oil did not affect the acrylic bond strength while aging in air at 50°C for 9 months (equivalent to approximately 5 years at room temperature) increased the acrylic bond strength by 25%. For the epoxy, corona discharge treated samples’ strength increased slightly after aging while the strength of sanded samples in air remained consistent and sanded samples in oil decreased by 17% when aged at 50°C for 1.5 years (equivalent to approximately 10 years at room temperature).All materials used in the detector were studied to determine if degrading interaction would occur with the pseudocumene liquid scintillator. Substances such as acrylic adhesive and PTFE paste were found to interact with the scintillator while materials such as a variety of PVCs, epoxy adhesives, and PTFE tape were found to be non-reactive with the scintillator. Following the appearance of cracks on manifold covers in installed modules, studies were carried out to help to determine the cause and mitigation of these cracks. Manifold covers that had been pressure tested at various pressures during the check of the seals during the manufacturing process were examined for the formation of cracks. “Containment units” were used to constrain the swelling of the manifold covers during pressure testing. Internal cracks were visible on the majority of manifold covers tested at 1.4 bar with the original containment units. It was found that reducing the pressure testing of the modules from 1.4 bar to 0.7 bar and increasing the rigidity of the pressure test containment units eliminated the formation of visible cracks in the manifold covers. Stress concentration in small fillet radius injection molded PVC was studied. GeonM3500 PVC has a yield strength 12% greater than Geon M3800 PVC originally used for the manifold covers but increased the stress concentrated failure time by 6600% and was thus chosen to mold new manifold covers after a redesign to eliminate stress concentrating features.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Hexagonal Distributed Embedded Energy Converters (HexDEECs)

The HexDEEC is a small, characteristic length approximating a centimeter, energy transducer that converts the dynamic deformations of its elastomer housing into electricity through a variable capacitance charging-discharging cycle. This device is a type of Distributed Embedded Energy Converter Technology (DEEC-Tec), a new domain for marine renewable energy research that utilizes a conglomeration of small distributed embedded energy converters (DEECs) that, in aggregate, form larger metamaterial frameworks. These resulting DEEC-Tec metamaterials can then, in turn, be used to construct flexible ocean wave energy converters called flexWECs, which can utilize a broad band of ocean wave frequencies and lack highly loaded rigid bodies. These systems also provide new avenues of wave energy harvesting such as actively transforming topologies (e.g., shape and form) and morphologies (e.g., stiffness and damping throughout its entire structure) in real time. Presented, is one specific type of DEEC: the HexDEEC, which is currently being developed by the United States National Renewable Energy Laboratory. This transducer shows promise in aiding the adoption and further development of the DEEC-Tec domain. The following presentation focuses on the promise of this technology and current work being done to analyze the performance of an individual HexDEEC design. The HexDEEC is composed of a hyperelastic hexagonal housing, nominally silicon rubber, with six electrodes on its inner faces. The upper three electrodes share the same charge while the lower three electrodes oppose the upper electrode charges. Externally, the HexDEEC has two arms extending away from the middle vertices of the hexagon. Via principles governing the relationship between electrical capacitance and electrical potential (voltage and charge), electricity is generated when the HexDEEC's arms are dynamically pulled or released under tensile loading, as doing so causes the distance between the upper and lower sets of electrodes to change - varying the energy converter's overall capacitance. Analytical and numerical modeling is being used to evaluate the mechanics and electrical energy generated by the HexDEEC. Equations to describe the capacitance and electrostatic forces acting on this unique system have been developed and implemented into the numerical modeling software STAR-CCM+, along with models to describe its hyperelastic material, such as the Mooney-Rivlin 3-parameter model. So far, an initial design has been analyzed and we plan to further optimize it to increase power production. Individual HexDEECs have been fabricated by drawing uncured liquid silicon rubber into molds via vacuum pressure. To simplify manufacturing, HexDEEC sub-components - e.g., electrodes, wires - can be placed within those molds such that they are directly embedded into the hexagonal housing during the curing process. Furthermore, DEEC-Tec metamaterials can be created by interweaving or sequentially layering multiple HexDEEC strands together. The HexDEEC based metamaterial could then generate electricity through its gross deformations. Ultimately, HexDEECs represent a specific type of energy transducer that can be leveraged, by the DEEC-Tec domain, to create metamaterials used to construct novel flexWECs.

DEEC-Tec↗

Hexagonal Distributed Embedded Energy Converters (HexDEECs)

Distributed Embedded Energy Converter Technologies (DEEC-Tec) is a new domain for marine renewable energy research that utilizes a conglomeration of small distributed embedded energy converters (DEECs) that, in aggregate, form larger metamaterial frameworks. These resulting DEEC-Tec metamaterials can then, in turn, be used to construct flexible ocean wave energy converters called flexWECs. DEEC-Tec enables flexWECs: (i) to be inherently broad-banded ocean wave frequency energy converters and (ii) to have an inherent lack of highly loaded rigid bodies. The DEEC-Tec domain also benefits the marine renewable energy domain by inherently availing ways that marine energy can be harvested and converted that heretofore has not yet been considered possible: real-time execution of transforming topologies (e.g., actively changing a flexWEC's shape and form) and morphologies (e.g., actively changing a flexWEC's stiffness and damping throughout its entire structure). Presented, is one specific type of DEEC, a HexDEEC, that shows promise in aiding the adoption and further development of the DEEC-Tec domain - it is a small energy transducer being developed by the United States National Renewable Energy Laboratory. The HexDEEC is a small (characteristic length approximating a centimeter) energy transducer that converts the dynamic deformations of an elastomer into electricity through a charging-discharging cycle of a capacitor whose capacitance is varied by those elastic deformations. The HexDEEC is composed of a hyperelastic hexagonal housing (nominally silicon rubber) with six electrodes on its inner faces. The upper three electrodes share the same charge while the lower three electrodes oppose the upper electrode charges. Externally, the HexDEEC has two arms extending away from the middle vertices of the hexagon. Via principles governing the relationship between electrical capacitance and electrical potential (voltage and charge), electricity is generated when the HexDEEC's arms are dynamically pulled or released under tensile loading as doing so causes the distance between the upper and lower sets of electrodes to change - varying the energy converter's overall capacitance. Analytical and numerical modeling have already been used to estimate the electrical energy produced by a HexDEEC. The cursory models approximate the HexDEEC as a parallel plate variable capacitor - simplifying from six to two opposing plates with a constant dielectric volume between those two plates. To account for the elastic HexDEEC material properties, software such as SolidWorks and STAR-CCM+ have been used to generate hyperelastic models; notably, Mooney-Rivlin based models. Individual HexDEECs have been fabricated by drawing uncured liquid silicon rubber into molds via vacuum pressure. To simplify manufacturing, HexDEEC sub-components - e.g., electrodes, wires - can be placed within those molds such that they are directly embedded into the hexagonal housing during the curing process. Furthermore, DEEC-Tec metamaterials can be created by interweaving or sequentially layering multiple HexDEEC strands together. The HexDEEC based metamaterial could then generate electricity through its gross deformations. Ultimately, HexDEECs represent a specific type of energy transducer that can be leveraged, by the DEEC-Tec domain, to create metamaterials used to construct novel flexWECs.

DEEC-Tec↗

Composite components and methods of manufacturing composite components using magnetic forces at fiber preform seams

A method of manufacturing a composite component according to various aspects of the present disclosure includes disposing a fiber preform in a mold. The fiber preform includes a first portion having a first edge and a second portion having a second edge. The first edge and the second edge cooperate to at least partially define a gap. One of the first portion or the second portion includes a first ferromagnetic material and the other of the first portion or the second portion includes a first magnetic or magnetizable component. The method further includes closing the gap by generating a magnetic field from the first magnetic or magnetizable component. The method further includes injecting a polymer precursor into the mold. The method further includes forming the composite component by solidifying the polymer precursor to form a polymer. The composite component includes the fiber preform and the polymer.

Aitharaju, Venkateshwar R.↗

Methods of making and using bulk products including fiber-containing particles with dual-tapered shape

Recycled carbon fibers are processed by rotational tumbling in a mixture with binder material to prepare fiber-containing particles having a dual-tapered shape and general alignment of fibers with a longitudinal direction of the particles. Bulk products including such fiber-containing particles are compounded with polymer and pelletized to prepare fiber-reinforced composite pellets, which are useful for applications such as injection molding to prepare molded products of carbon fiber-reinforced composite material with recycled carbon fibers.

Harris, Jordan Gray↗

Dexterity and Worker Comfort in an Ergonomically Designed Glovebox Glove

Gloveboxes are prolifically used in nuclear facilities as the primary means of separation between the hazardous material and operators. Due to extended duration and high repetition of hand tasks in glovebox gloves, improperly fitting gloves can be uncomfortable and increase injury risks. Poor fit can increase time necessary to perform work tasks and stress the glove itself. The Plutonium Facility has the largest inventory of glovebox gloves at Los Alamos National Laboratory (LANL) with approximately 6000 gloves installed. The current glove mold dates back to the 1960's and is not based on the true anatomy of the hand. Design flaws (poor anatomical fit and biomechanics) are directly related to injuries of the elbow (lateral epicondylitis) and thumb (DeQuervain's tenosynovitis) injuries. The current design also contributes to 30% of unplanned glove openings. A new glovebox glove was developed and manufactured, incorporating over forty dimensions to produce the most comprehensive ergonomically sound design. The new design received a LANL patent (patent attorney docket No: LANS 36USD1 'Protective Glove'), one of 20 highest patents awarded by the Richard P. Feynman Center for Innovation. A SolidWorks model was given to the manufacturer for production of the glove mold.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Fiber-containing particles with dual-tapered shape

Recycled carbon fibers are processed by rotational tumbling in a mixture with binder material to prepare fiber-containing particles having a dual-tapered shape and general alignment of fibers with a longitudinal direction of the particles. Bulk products including such fiber-containing particles are compounded with polymer and pelletized to prepare fiber-reinforced composite pellets, which are useful for applications such as injection molding to prepare molded products of carbon fiber-reinforced composite material with recycled carbon fibers.

Harris, Jordan Gray↗

Use of Captured CO2 for Production of Sustainable Polyurethane Foams in Automotive Applications

Captured CO2 has been investigated as a feedstock for the production of polyurethane (PU) foams for automotive applications. Previous work has shown successful incorporation of CO2 into polyols via three distinct reaction pathways. These CO2-derived polyols, as well as several commercially available polyols with varying CO2 content, were used to produce PU foams for automotive seating and NVH (noise, vibration, and harshness) applications. Foam formulations were optimized to maximize sustainable content while maintaining manufacturability constraints and performance requirements for each end use application. PU foams were first formulated at lab scale to confirm free rise and molded foam properties, then scaled up to pilot and industrial scales to evaluate production manufacturing feasibility. Finally, CO2-derived foams were used to produce molded components for end use product validation. Life cycle assessment (LCA) was used to quantify the environmental impact of using captured CO2 and bio-renewable content into polyols and PU foams through the metrics of global warming potential and embodied energy. Tradeoffs among environmental impacts, energy usage, manufacturability, and PU foam performance from the incorporation of CO2 and bio-renewable content will be discussed.

Lee, Ellen [Ford Motor Company]↗

Low Cost, Durable Seal

Seal durability is critical to achieving the 2010 DOE operational life goals for both stationary and transportation PEM fuel cell stacks. The seal material must be chemically and mechanically stable in an environment consisting of aggressive operating temperatures, humidified gases, and acidic membranes. The seal must also be producible at low cost. Currentlyused seal materials do not meet all these requirements. This project developed and demonstrated a high consistency hydrocarbon rubber seal material that was able to meet the DOE technical and cost targets. Significant emphasis was placed on characterization of the material and full scale molding demonstrations.

30 DIRECT ENERGY CONVERSION↗

Effect of Composition Variation on Isothermal Rapid Curing Resins for Aerospace Applications

To meet the projected demand for single-aisle composite aircraft in 2040, the production rate of these aircraft will need to increase by four to six times what is currently achievable. A composite manufacturing process with the potential to enable the targeted rates is isothermal resin infusion where infusion and cure occur at the same temperature. However, presently there is not an accepted aerospace-grade resin that can support this isothermal infusion process and maintain acceptable resin properties. Therefore, resin development initiatives have designed anionic catalyzed epoxy systems capable of isothermal infusion and rapid cure at a temperature below 100 ˚C in one hour. High-performance aerospace properties are achieved after undergoing a freestanding post-cure. The resins facilitate faster, energy efficient production cycles by reducing the time and temperature required for cure and eliminating temperature ramps typically required of materials used in the aerospace industry. This work discusses several of the developed resin systems and the impact of varying composition on rheological, thermal, and mechanical properties. Carbon fiber composites were fabricated for one composition by resin transfer molding to demonstrate the potential of these isothermal, rapid cure systems for meeting industry needs.

resin transfer molding↗

Effect of Multi-Walled Carbon Nanotubes on Viscoelastic Properties of PP/Reed Flour Composites

The objective of this investigation was to evaluate the influence of multi-wall carbon nanotubes (MWCNTs) on the dynamic mechanical properties of polypropylene (PP)/reed flour (RF) composites. The experimental samples were prepared through the melt mixing of PP/RF at 50% weight ratios, with various amounts of MWCNTs (0, 1, 2, 3 and 5 phr) in a twin-screw extruder, then the samples made by injection molding. The amount of maleic anhydride grafted polypropylene (PP-g-MA) as a coupling agent was fixed at 2 phr for all formulations. Dynamic mechanical analysis (DMA) tests were carried out to investigate the viscoelastic behavior of nanocomposites. The dynamic mechanical properties such as storage modulus (Eʹ), loss modulus (Eʺ), and damping coefficient (tan δ) of nanocomposites were investigated in the temperature range of −80 to 160 °C at a step of 5 °C and frequency of 1 Hz. The morphology of the specimens was characterized using field emission scanning electron microscope (FE-SEM) technique. Results indicated that the storage modulus of samples was found to increase with incorporation of MWCNTs while damping properties registered a decrease, owing to the reinforcing effect of CNTs into the composites. Moreover, CNTs addition leads to a positive shift in glass transition temperature (T{sub g}), which is explained on the molecular mobility of the polymer chains behavior. Additionally, the minimum adhesion factor is related to samples containing 2 phr MWCNTs which provides the best interaction between polymer and fibers. FE-SEM micrographs showed a predominantly homogeneous CNTs distribution through the composites; however, some aggregates were observed at higher CNTs fractions.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Multiple Reprocessing Cycles of Corn Starch-Based Biocomposites Reinforced with Curauá Fiber

Biocomposites with a corn starch-based biodegradable polymer as matrix and 10 wt% vegetable curauá fiber were processed by injection molding and were submitted to reprocessing up to ten cycles with or without 3 wt% of maleic anhydride grafted polypropylene as coupling agent. The effect of reprocessing on hardness, impact and tensile properties as well as on the morphology, thermal properties, chemical structure and soil degradation behaviour of the matrix and biocomposites was evaluated. Curauá fibers have increased hardness, impact and tensile strengths as well as increased tensile modulus and decreased elongation at break of the biocomposites with respect to starch-based matrix and these properties slightly decreased or no considerable changes were observed with the reprocessing cycle increase. The addition of coupling agent promoted an increase in all properties and they remained almost constant with the reprocessing cycle increase. Thus, the incorporation of curauá fiber within starch-based matrix can improve the mechanical properties of the biocomposites which showed potential to be recycled despite the weight loss in soil degradation tests reached around 10 wt% after 230 days for biocomposites reprocessed ten cycles.

36 MATERIALS SCIENCE↗

Mechanical and Thermal Oxidation Behavior of Poly(Lactic Acid)/Halloysite Nanotube Nanocomposites Containing N,N′-Ethylenebis(Stearamide) and SEBS-g-MA

Poly(lactic acid) (PLA)/halloysite nanotube (HNT) nanocomposites were prepared using melt compounding followed by compression molding. Maleic anhydride grafted styrene–ethylene/butylene–styrene copolymer (SEBS-g-MA) and N,N′-ethylenebis(stearamide) (EBS) were used to improve the impact properties of PLA nanocomposites. The properties of PLA/HNT nanocomposites were characterized by tensile and impact tests, Fourier transform infrared spectroscopy, thermal analysis (DSC and TGA), and morphological analysis (FESEM and TEM). In addition, the oxidation onset temperature (OOT) was determined using DSC. The PLA/HNT6/EBS5 nanocomposites gives higher impact strength improvement (98%) compared to that of PLA/HNT6/SEBS-g-MA5 (77%). Also, the PLA/HNT6/EBS5 exhibited higher OOT compared to that of PLA/HNT6/SEBS-g-MA5 nanocomposites.

36 MATERIALS SCIENCE↗

Fabrication and Characterization of Poly(lactic acid) Biocomposites Reinforced by Calcium Sulfate Whisker

The biodegradable poly(lactic acid) (PLA) composites filled with calcium sulfate whisker (CSW) were fabricated via melt-blending and subsequent injection molding. Surface organification of γ-aminopropyltriethoxysilane (APTES) on CSW was applied to accelerate the wettability of PLA to CSW. The mechanical properties, morphological structures, crystallization behaviors and thermal stabilities of PLA/CSW composites were investigated in detail. Results showed that modification of APTES changed the surface morphologies and element compositions, helping to form the well bonded interfaces. By adding CSW, the elastic modulus of PLA/CSW composites presented a sustained increment, while tensile strength, elongation at break and impact toughness were increased first and then decreased. The presence of CSW impeded the melt-crystallization but accelerated the cold-crystallization process. On the whole, the actual crystallinity for the composites was suppressed except for the case with 20% CSW. The thermal stability was enhanced by CSW as expected, and all the samples showed the exact same reaction order (n = 1) according to Carrasco method. Nevertheless, the activation energies were declined, indicating CSW was in favor of thermal decomposition of PLA phases. Finally, it was interestingly found that CSW could improve the comprehensive properties of PLA without deteriorating the processibility.

36 MATERIALS SCIENCE↗

On the Solidification and Structure Formation during Casting of Large Inserts in Ferritic Nodular Cast Iron

The graphite nodule count and size distributions for boiling water reactor (BWR) and pressurized water reactor (PWR) inserts were investigated by taking samples at heights of 2160 and 1150 mm, respectively. In each cross section, two locations were taken into consideration for both the microstructural and solidification modeling. The numerical solidification modeling was performed in a two-dimensional model by considering the nucleation and growth in eutectic ductile cast iron. The microstructural results reveal that the nodule size and count distribution along the cross sections are different in each location for both inserts. Finer graphite nodules appear in the thinner sections and close to the mold walls. The coarser nodules are distributed mostly in the last solidified location. The simulation result indicates that the finer nodules are related to a higher cooling rate and a lower degree of microsegregation, whereas the coarser nodules are related to a lower cooling rate and a higher degree of microsegregation. The solidification time interval and the last solidifying locations in the BWR and PWR are also different.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Formation Mechanism of Nanoscale Al{sub 3}Fe Phase in Al-Fe Alloy During Semisolid Forming Process

The formation mechanism of nanoscale Al{sub 3}Fe phase in Al-1Fe (wt pct) alloy during rheo-extrusion was investigated, and the mechanical property of the prepared alloy was also measured. The results show that the average length of Al{sub 3}Fe phase in Al-1Fe alloy prepared by rheo-extrusion is 300 nm, which is much more refined than the needlelike Al{sub 3}Fe phase in as-cast Al-1Fe alloy (50 μm). In rheo-extrusion, Al{sub 3}Fe phase formed by eutectic reaction is bonelike, but it could be continuously refined by the shear deformation in the wheel groove, in equal channel angular flow, and in expansion extrusion mold. The total equivalent strain of the shear deformation is higher than 4.82. The tensile strength and elongation of Al-1Fe alloy prepared by rheo-extrusion are 135 MPa and 30 pct, respectively. The tensile strength of Al-1Fe alloy prepared by rheo-extrusion is 58.8 pct higher than that of as-cast Al-1Fe alloy, and the elongation is 19 pct higher than that of as-cast Al-1Fe alloy. Compared with as-cast Al-1Fe alloy, the improvements of tensile strength and elongation caused by shear deformation in rheo-extrusion are higher than the reported improvements induced by rare earth modification.

36 MATERIALS SCIENCE↗

Three-Dimensional Distribution of Hooks in Al-Killed Low-Carbon Continuous Casting Steel Slabs

In the current study, steel samples were etched and hooks on several successive layers of longitudinal and transverse slab sections were obtained to investigate the three-dimensional (3-D) distribution of hooks in low-carbon continuous casting slabs. The data from industrial trials and numerical calculation were used to explain the variation in the distribution and morphology of hooks. Around the slab perimeter, the mean depth of hooks at the center and edge of the wide face and the edge of the narrow face was larger than that of other locations. The 3-D hook demonstrated a varied characteristic on different layers, as the observed surface changed in the longitudinal direction. By several layers of the transverse section being polished off, hooks in the transverse direction below the slab surface were obtained, in which the truncated hook and the joint hook between the wide face and narrow face were observed at the slab corner. The same oscillation mark could show as hook type and depression type, depending on the occurrence of the overflow between the solidified meniscus and the copper plate. Industrial trials and the numerical calculation illustrated that the transient variation of hooks in the 3-D space was related to the level fluctuation of molten steel in the mold and temperature fluctuation with casting time and the fluid flow and temperature near the meniscus. Finally, the influence area and volume of hooks on the capture of inclusions and bubbles were discussed.

36 MATERIALS SCIENCE↗

Manufacturing and characterization of continuous fiber-reinforced thermoplastic tape overmolded long fiber thermoplastic

Light-weight construction, design freedom, integration of functions, and compelling cost element are desired by Original Equipment Manufacturers (OEMs) and their suppliers. The emergence of overmolding of continuous-discontinuous reinforcement enables design freedom and ability to tailor stiffness, strength, and damage tolerance for structural applications. In this work, long fiber thermoplastics (LFT) are overmolded with continuous fiber-reinforced thermoplastic (CFRTP) tape are combined using extrusion compression molding process to evaluate the structural performance. The CFRTP tape overmolded LFT samples were characterized using nondestructive and destructive techniques to track fiber alignment, fiber distribution, manufacturing defects, interfacial bonding of the tape – LFT and effect of CFRTP tape on LFT. Mode 1 fracture toughness, G 1c for tape overmolded LFT was higher by 25–30% compared to literature reported G 1c . This response was attributed to excellent fiber distribution, good fiber wetting, and absence of voids at the interface. Three-point bend test indicated that CFRTP tape overmolded LFT composites were better able to resist damage under the bending load compared to constituent LFT composite. Flexural strength of the overmolded composite was higher by 119–142%, and modulus higher by 77–65% compared to constituent LFT composite. Simulated flexural results accurately represents the mechanical behavior of composites. Here, the penetration energy of tape overmolded LFT composites determined by LVI test was in the range of 27.66–30.15 J, which is significantly higher than constituent LFT composite, 7.76 J. CFRTP tape overmolded LFT composite exhibits progressive fiber fracture, matrix cracking, and interfacial debonding failure, whereas, constituent LFT composite showed catastrophic fiber fracture.

42 ENGINEERING↗