Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Isotopic abundances”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,027 records · Page 57

Cr-Rich and Al-Rich Oxide Grains With 16O-Rich Compositions in Ryugu Samples

Samples returned from asteroid Ryugu by JAXA’s Hayabusa2 mission are CI-like, with abundant hydrated and secondary phases [1]. Rare anhydrous minerals occur in the matrix of the major lithology and in chemically distinct clasts. Oxygen isotopic analysis of coarse (> 10 µm) anhydrous Mg-rich silicates revealed a bimodal distribution, with some grains having compositions similar to amoeboid olivine aggregates (AOAs) and others having compositions similar to chondrule phenocrysts [2, 3]. We previously analyzed < 2 µm-sized Mg-rich silicates within a clast that also showed a range of O isotopic compositions (δ18O from -38 to +5 ‰) [4]. In this study, we conducted coordinated isotopic and mineralogical analysis of anhydrous oxide grains found in the matrix of Ryugu samples

A. N. Nguyen↗

Probing the possibility of a C-12/C-13 galactic abundance gradient

High S/N (equal to or greater than 500) observations of interstellar CH+ with the 3.0 m telescope were performed at Lick Observatory and with the 4.0 m telescope at CTIO, of the reddened, early-type stars HD 183143, HD 24432, and HD 157038 in an effort to probe the existence of a C-12/C-13 abundance gradient in our Galaxy. Previous very high quality optical observations of interstellar CH+ toward five stars within 1 kpc of the Sun have yielded a precise weighted mean C-12/C-13 isotope ratio of 43 plus or minus 4 (1 sigma) (Hawkins, Jura, and Meyer 1985; Hawkins and Jura 1987). The isotope ratios derived toward four lines of sight in the local ISM are uniform within 12 percent. The similarity among these carbon isotope ratios determined in diffuse clouds possessing different physical conditions precludes the possibility that the CH+ molecule is suffering from isotope selective effects in these regions. The precise C-12/C-13 derivable from high quality observations of (12)CH+ and (13)CH+ provide the unique opportunity to probe the homogeneity of the ISM in a large scale and the history of nucleosynthesis in our Galaxy. Since CH+ seems to be the most sensitive probe of C-12/C-13 in the diffuse ISM, observations toward more distant stars located up to 2.5 kpc from the Sun are the best way to study the possibility of a Galactic (C-12/C-13) abundance gradient. The researcher obtained 4232 angstrom data toward all three of the stars mentioned above, 3957 angstrom data toward HD 183143 and HD 157038, and 3745 angstrom data toward HD 157038. Because of the poorer quality of the HD 24432 spectrum, and its weaker CH+ absorption lines, the satellite (13)CH+ line was not detected, and thus only a lower limit on the C-12/C-13 ratio toward this star was obtained. The results obtained from careful reduction and analysis of the data toward these stars in the Northern and Southern Hemispheres are presented.

Hawkins, Isabel↗

Dense autoencoders, clustering techniques, and semi-supervised learning for HPGe $γ$-spectra

Classifying high-resolution gamma spectra by their isotopic content is an essential task in nuclear forensics and other applications. Traditional analysis methods are often time-intensive, but machine learning (ML) may help analysts quickly process many spectra. Such methods tend to rely on abundant, well-labeled data for training. Historical gamma data exists in various fields but is not uniformly useful for supervised ML due to inconsistent labeling. Here, to address some of these challenges, we present a method to classify and organize unlabeled data from high-purity germanium detectors using an autoencoding neural network (autoencoder). We trained dense autoencoders to compress gamma data into latent representations that enable efficient data characterization. By clustering the encoded spectra or lower-dimensional mappings of them, we identified and removed portions of over-abundant data categories, resulting in a more balanced dataset and improved autoencoder performance. This encoding and clustering pipeline also enabled the organization of spectra into self-consistent categories. Finally, we found that encoded representations showed potential as inputs for semi-supervised learning of nuclide identification (NID) labels, achieving an average F1 score of 0.85 ± 0.03 when mapping encodings to a set of 65 isotope labels.

Autoencoders↗

Coordinated analyses of hydrated Kuiper Belt dust

We report on coordinated mineralogical, chemical, and isotopic analyses of hydrated carbon-rich interplanetary dust particles (IDPs). We focus on hydrated IDPs that contain high solar flare track densities consistent with an origin in outer Solar System bodies such as Edgeworth-Kuiper belt objects (EKBOs) [1]. We are searching for evidence of the heavy water reservoir predicted by self-shielding models [2]. The IDPs were embedded in sulfur and microtome thin sections were obtained for Fourier-transform infrared (FTIR), transmission electron microscopy (TEM), and nanoSIMS analyses. The IDPs were only partly microtomed and the remainder was extracted from the sulfur and pressed into In or Au for high precision O isotopic analyses. The hydrated IDPs in this study are compact low-porosity objects with a mineralogy dominated by fine-grained saponite and lesser serpentine, Fe-Ni sulfides, Mg-Fe carbonates, rare crystaline silicates, and abundant organic matter. The C in the IDPs is abundant (typically >4X CI) and occurs as isolated nanoglobules and finely disseminated within the phyllosilicate matrix of the IDPs. TEM analyses of the nanoglobules show O-rich, S-depleted rims with higher carbonyl functionality than their cores. FTIR spectra show strong aliphatic C-H stretches consistent with the presence of short-chain aliphatic hydrocarbons in these IDPs. The oxygen isotopic compositions measured in 6 IDPs all plot within error of the CCAM line [3]. For several of the IDPs we were able to obtain multiple analyses. The ∆^(17)O values range from -23‰ up to +3.4‰ with most analyses clustering above the terrestrial fractionation line. The O isotopic compositions and the high C contents of these IDPs are distinct from known hydrated carbonaceous chondrites. The track-rich hydrated IDPs record parent body aqueous alteration effects through interactions with 16O-poor H2O on a EKBO parent body. The aqueous alteration activity likely resulted from the heat generated by collisional processes among EKBOs given that these objects are believed to have accreted late after the decay of 26Al [4].

Lindsay P. Keller↗

Selective semihydrogenation of acetylene in ethylene using defect-rich boron nitride catalyst from flux reconstruction

Efficient removal of trace acetylene from ethylene streams is essential for producing polymer-grade ethylene, yet achieving highly selective semihydrogenation without over-hydrogenation remains a long-standing challenge. A key barrier is the lack of a simple, low-cost catalyst that can activate hydrogen effectively while preventing ethylene from reacting further. Here we show that defect-rich boron nitride, prepared through a straightforward flux reconstruction method, serves as a highly selective and metal-free catalyst for acetylene semihydrogenation. The catalyst contains abundant open boron and nitrogen sites that enable efficient hydrogen activation and rapid release of ethylene, thereby avoiding over-hydrogenation. Experiments combined with isotope labeling and theoretical analysis reveal that these defects lower the energy barrier for hydrogen activation while accelerating product desorption. Our findings demonstrate a scalable strategy for defect engineering in boron nitride and highlight its potential as a robust, sustainable alternative to metal-based catalysts in industrial ethylene purification.

Wang, Tao [Oak Ridge National Laboratory (ORNL), O↗

The energetics of molecular clouds. II - The S140 molecular cloud

Techniques of analysis which allow estimates of kinetic temperature, gas density, gas cooling rate, and dust cooling rate are applied to the S140 molecular cloud. Maps of this cloud in various molecular lines are examined which reveal the existence of a strong temperature and density peak near the H-alpha rim and the presence of a strong near-IR source very near that peak. This source is found to have an energy distribution which is very similar to that of the Becklin-Neugebauer object, including the silicate feature at 9.5 microns. The heating and cooling rates for the gas and dust in S140 are estimated, and the predicted cooling rate for dust is shown to be much greater than that for gas. The molecular-line observations are compared with a spherical large-velocity-gradient trapping calculation. An optimum cloud model is developed which indicates that: (1) (C-13)O, HCO(+), and H2CO are about 10 times less abundant in S140 than in dark clouds; (2) the HCN abundance is approximately 4 times the H2CO abundance in S140, compared with roughly equal values in dark clouds; and (3) the (C-13)O/C(O-18) ratio is consistent with terrestrial isotope ratios.

Blair, G. N.↗

Geochronology of high-K aluminous mare basalt clasts from Apollo 14 breccia 14304

Two aluminous mare basalt clasts of high K abundances from Apollo 14 breccia 14304 (the 14304,127 and 14304,128 samples) were characterized with respect to the Rb and Sr concentrations and isotopic compositions, and the Rb-Sr, K-Ar, and Sm-Nd isotopic age determinations were carried out. The results suggest that these high-K basalts were melts derived from mantle material and that they have experienced about ten-fold Rb/Sr and K/La enrichments at approximately the time of crystallization.

Shih, C.-Y.↗

Detection of (C-13)-ethane in Jupiter's atmosphere

High-resolution (C-12)- and (C-13)-ethane spectra of Jupiter were acquired with the Kitt Peak 4 m Fourier spectrometer and the Goddard postdisperser in June 1987. A relative abundance ratio (C-12/C-13) of 94 +/- 12 was derived from the measurements. This nearly terrestrial value indicates little or no fractionation of carbon isotopes when ethane is produced in the photolysis of methane in Jupiter's atmosphere.

Wiedemann, Guenter↗

Thermal Balance in Dense Molecular Clouds: Radiative Cooling Rates and Emission-Line Luminosities

We consider the radiative cooling of fully shielded molecular astrophysical gas over a wide range of temperatures ( 10 K < T < 2500 K) and H2 densities ( 10(exp 3)/cc < n(H2) < 10(exp 10)/cc). Our model for the radiative cooling of molecular gas includes a detailed treatment of the interstellar chemistry that determines the abundances of important coolant molecules, and a detailed treatment of the excitation of the species H2, CO, H2O, HCl, O2, C, O, and their isotopic variants where important. We present results for the total radiative cooling rate and for the cooling rate due to individual coolant species, as a function of the gas temperature, density, and optical depth. We have also computed the individual millimeter, submillimeter, and far-infrared line strengths that contribute to the total radiative cooling rate, and we have obtained example spectra for the submillimeter emission expected from molecular cloud cores. Many of the important cooling lines will be detectable using the Infrared Space Observatory and the Submillimeter Wave Astronomy Satellite.

Neufeld, David A.↗

Planetary Accretion, Oxygen Isotopes and the Central Limit Theorem

The accumulation of presolar dust into increasingly larger aggregates (CAIs and Chondrules, Asteroids, Planets) should result in a very drastic reduction in the numerical spread in oxygen isotopic composition between bodies of similar size, in accord with the Central Limit Theorem. Observed variations in oxygen isotopic composition are many orders of magnitude larger than would be predicted by a simple, random accumulation model that begins in a well-mixed nebula - no matter which size-scale objects are used as the beginning or end points of the calculation. This discrepancy implies either that some as yet unspecified process acted on the solids in the Solar Nebula to increase the spread in oxygen isotopic composition during each and every stage of accumulation or that the nebula was heterogeneous and maintained this heterogeneity throughout most of nebular history. Large-scale nebular heterogeneity would have significant consequences for many areas of cosmochemistry, including the application of some well-known isotopic systems to the dating of nebular events or the prediction of bulk compositions of planetary bodies on the basis of a uniform cosmic abundance.

Nuth, Joseph A., III↗

Excess Ar-40 in the Zagami Shergottite: Does It Reveal Crystallization History?

The Zagami basaltic shergottite has fine- and coarse-grained (FG & CG) areas, which may reflect partial crystallization in a deep, slowly cooled magma chamber to form Mg-rich pyroxene cores, followed by entrainment of these crystals into a magma that rose and crystallized near the surface. Late-stage melt pockets formed mesostasis and feldspar (maskelynite) having a range of compositions, but low water abundance. Higher I(sub Sr) in the FG portion may result from the second stage having incorporated old crustal rocks that failed to reach isotopic equilibrium. Zagami, like other shergottites, contains excess Ar-40(sub xs) beyond that expected from internal decay of K-40 during its Sm-Nd age of 177 Myr. We suggest that at least a portion of this Ar-40(sub xs) in Zagami and some other shergottites was inherited from the magma, much as is the case of MORBs on Earth. We made Ar-39-Ar-40 age determinations on feldspar and pyroxene separates from both the FG and CG portions of Zagami. If Zagami experienced an evolving fractional crystallization history, including possible crustal contamination of the magma, that might be indicated in differing amounts of Ar-40(sub xs) between mineral phases and between FG and CG portions.

Bogard, Donald D.↗

The γ -process nucleosynthesis in core-collapse supernovae

The γ-process nucleosynthesis in core-collapse supernovae is generally accepted as a feasible process for the synthesis of neutron-deficient isotopes beyond iron. However, crucial discrepancies between theory and observations still exist: the average yields of γ-process nucleosynthesis from massive stars are still insufficient to reproduce the solar distribution in galactic chemical evolution calculations, and the yields of the Mo and Ru isotopes are a factor of ten lower than the yields of the other γ-process nuclei. We investigate the γ-process in five sets of core-collapse supernova models published in the literature with initial masses of 15, 20, and 25 M ⊙ at solar metallicity. We compared the γ-process overproduction factors from the different models. To highlight the possible effect of nuclear physics input, we also considered 23 ratios of two isotopes close to each other in mass relative to their solar values. Further, we investigated the contribution of C–O shell mergers in the supernova progenitors as an additional site of the γ-process. Our analysis shows that a large scatter among the different models exists for both the γ-process integrated yields and the isotopic ratios. We find only ten ratios that agree with their solar values, all the others differ by at least a factor of three from the solar values in all the considered sets of models. The γ-process within C–O shell mergers mostly influences the isotopic ratios that involve intermediate and heavy proton-rich isotopes with A > 100. We conclude that there are large discrepancies both among the different data sets and between the model predictions and the solar abundance distribution. More calculations are needed; particularly updating the nuclear network, because the majority of the models considered in this work do not use the latest reaction rates for the γ-process nucleosynthesis. Moreover, the role of C–O shell mergers requires further investigation.

79 ASTRONOMY AND ASTROPHYSICS↗

Theoretical and experimental study of the nitrogen-vacancy center in 4H-SiC.

Using first-principles calculations and magnetic resonance experiments, we investigated the physical properties of the negatively charged nitrogen-vacancy (NV) center in 4H-SiC, a promising spin qubit. Our predictive theoretical model in conjunction with experimental measurements reveals a large sensitivity to strain and symmetry. The measured and computed zero-phonon lines (ZPLs) are in agreement and show a consistent trend as a function of the defect location in the crystal. The computed ZPLs are extremely sensitive to the geometrical configurations of the ground and excited states, and large supercells with more than 2 000 atoms are required to obtain accurate numerical results. We find that the computed decoherence time of the basal NV centers at zero magnetic field is substantially larger than that of the axial configurations. Furthermore, at natural nuclear spin abundance and zero field, the Hahn-echo coherence time of one of the basal configurations is similar to that of the axial divacancy in isotopically purified SiC.

Zhu, Yizhi↗

The supernova trigger for formation of the solar system

It is suggested that the explosion of a Type II supernova triggered the collapse of a nearby interstellar cloud and led to the formation of the solar system. Estimates of the abundances resulting from nuclear processing of the supernova ejecta are presented. It appears promising that nucleosynthesis in this single supernova event can account for most isotopic anomalies and traces of extinct radioactivities in solar-system material.

Cameron, A. G. W.↗

The isotopic composition of cosmic-ray beryllium and its implication for the cosmic ray's age

We report a new measurement of the cosmic-ray isotopic composition of beryllium in the low-energy range from 35 to 113 MeV per nucleon. This measurement was made using the High Energy Telescope of the CRS experiment on the Voyager 1 and 2 spacecraft during the time period from 1977 to 1991. In this overall time period of 14 years the average solar modulation level was about 500 MV. The cosmic-ray beryllium isotopes were completely separated with an average mass resolution sigma of 0.185 amu. The isotope fractions of Be-7, Be-9, and Be-10 obtained are 52.4 +/- 2.9%, 43.3 +/- 3.7%, and 4.3 +/- 1.5%, respectively. The measured cosmic-ray abundances of Be-7 and Be-9 are found to be in agreement with calculations based on standard Leaky-Box model for the interstellar propagation of cosmic-ray nuclei using the recent cross sections of the New Mexico-Saclay collaboration. From our observed ratio Be-10/Be = 4.3 +/- 1.5% we deduce an average interstellar density of about 0.28 (+0.14, -0.11) atoms/cu cm, and acosmic-ray lifetime for escape of 27 (+19, -9) x 10(exp 6) years. The surviving fraction of Be-10 is found to be 0.19 +/- 0.07. Modifications to the conclusions of the Leaky-Box model when a diffusion + convection halo model for propagation is used are also considered.

Lukasiak, A.↗

Elemental composition before, during and after the January 6, 1997, CME event measured by CELIAS/SOHO

Using solar wind particle data from the charge, element and isotope analysis system (CELIAS) experiment on the SOHO mission, densities of the elements O, Ne, Mg, Si, S, Ca, and Fe are derived, and their abundance is analyzed before, during and after the 6 Janaury 1997 coronal mass ejection event (CME). In the interstream and coronal hole regions before and after this event, typical solar wind abundances for the elements investigated were found. However, during the passage of the coronal mass ejection and during the passage of the erupted filament, the elemental composition differed markedly from typical solar wind. For the passage of the CME and for the passage of the erupted filament, a mass-dependent enhancement of the elements was found, with a monotonic increase towards heavier elements. Si/O and Fe/O ratios of the order of one during these time periods were observed.

Wurz, P.↗

Mineralogy, Three Dimensional Structure, and Oxygen Isotope Ratios of Four Crystalline Particles from Comet 81P/Wild 2

Preliminary examinations of small dust particles from comet 82P/Wild 2 revealed many expected and unexpected features. Among them the most striking feature is the presence of abundant crystalline material in the comet. Synchrotron radiation X-ray diffraction and microtomography are the most efficient methods to detect and describe bulk mineralogical features of crystalline cometary particles. In the present study, in addition to these two non-destructive techniques, electron microscopy and ion-probe mass spectrometry were carried out on the four crystalline particles.

Nakamura, T.↗

A Diversity of Calcium-Rich Carbonates in EETA 79001

Carbonate minerals of martian origin are present in several martian meteorites in trace concentrations (less than 1 percent) and possess unique isotopic signatures that suggest that the martian environment and/or isotopic reservoirs are very different from the Earth’s. Carbonates are most common in the older martian meteorites (ALH 84001 and the nakhlites), however, there have been reports of carbonate in the younger shergottites including EETA 79001 (Mars meteorite Elephant Moraine 79001). Acidification studies of Zagami and Shergotty have shown that CO2 is released suggesting that carbonate phases are present in these meteorites, but the origin of these phases is controversial. The young ages of the shergottites makes them important samples for understanding the modern martian environment. The carbonates in EETA 79001 are the best-characterized secondary minerals in a shergottite, but their origin remains controversial. Gooding et al. argued that two types of carbonate occur with-in the glassy parts of the meteorite. One type, nearly pure CaCO3 associated with Ca-sulfate shows textural evidence for being present in the rock prior to it being shocked, suggesting formation on Mars. The second was more abundant and consists of Ca-rich carbonate, possibly with finely intergrown Mg-phosphate, but does not possess any textural relationships indicative of a martian origin. Carbon and oxygen isotopic studies of this carbonate yielded oxygen isotopes that potentially suggest a martian origin as well

Niles, P. B.↗