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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,027 records · Page 57

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DOE OSTI2020

CO as a Probe Molecule to Study Surface Adsorbates during Electrochemical Oxidation of Propene

A major challenge in the electrochemical oxidation of hydrocarbons is understanding the formation of intermediate species, some of which continue to react, while others are non-reactive or poisonous species that block adsorption of further reactants. Herein we investigate the identity and behavior of adsorbates formed during partial oxidation of propene. We employ two techniques: Electrochemistry-Mass Spectrometry (EC-MS) and Attenuated Total Reflection Infrared Spectroscopy (ATR-FTIR). In both cases, we use CO as a probe molecule, to perturb the ad-layer of propene intermediates. In the EC-MS experiments, propene and its intermediates were quantified by triggering their desorption via displacement with CO. We show evidence for at least two distinct classes of propene adsorbates, via CO displacement and electrochemical stripping. A redshift in the ν(C–O) mode was observed, during IR spectroscopy, reflecting the chemical environment arising from strongly bound propene intermediates.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2021

Effect of Carbon Doping on CO 2 –Reduction Activity of Single Cobalt Sites in Graphitic Carbon Nitride

Single atom catalysts have demonstrated interesting activity in a variety of applications. In this study, we prepared single C o2+ sites on graphitic carbon nitride (C 3 N 4 ), which was doped with carbon for enhanced activity in visible-light CO 2 reduction. The synthesized materials were characterized with a variety of techniques, including microscopy, X-ray powder diffraction, UV-vis spectroscopy, infrared spectroscopy, photoluminescence spectroscopy, and X-ray absorption spectroscopy. Here, doping C 3 N 4 with carbon was found to have profound effect on the photocatalytic activity of the single Co 2+ sites. At relatively low levels, carbon doping enhanced the photoresponse of C 3 N 4 in the visible region and improved charge separation upon photoactivation, thereby enhancing the photocatalytic activity. Furthermore, high levels of carbon doping were found to be detrimental to the photocatalytic activity of the single Co 2+ sites by altering the structure of C 3 N 4 and generating defect sites responsible for charge recombination.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2022

High capacity ammonia adsorption in a robust metal–organic framework mediated by reversible host–guest interactions

To understand the exceptional adsorption of ammonia (NH 3 ) in MFM-300(Sc) (19.5 mmol g -1 at 273 K and 1 bar without hysteresis), we report a systematic investigation of the mechanism of adsorption by a combination of in situ neutron powder diffraction, inelastic neutron scattering, synchrotron infrared microspectroscopy, and solid-state 45 Sc NMR spectroscopy. These complementary techniques reveal the formation of reversible host–guest supramolecular interactions, which explains directly the observed excellent reversibility of this material over 90 adsorption–desorption cycles.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2023

Characterization of the Soluble and Insoluble Portions of Solids from the Salt Waste Processing Facility Tank 201 and Tank 202 Samples

The Salt Waste Processing Facility (SWPF) Tank 201 and Tank 202 samples have been characterized using X-ray diffraction (XRD), scanning electron microscope/energy dispersive x-ray (SEM/EDX), particle size analysis (PSA-Microtrac), Fourier transform-infrared (FT-IR) and nuclear magnetic resonance ( 1 H NMR) spectroscopic techniques to characterize and identify organic and inorganic components in Tanks 201 and 202 as part of efforts to understand the problems occurring at SWPF due to the presence of solids in the recovered solvent.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2023

Characterization of the Soluble and Insoluble Portions of Solids from the Salt Waste Processing Facility Tank 201 and Tank 202 Samples

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

NASA NTRS1966

The Mars facsimile camera.

Panoramic facsimile camera providing IR and visible spectrum imagery designed for unmanned space operation, noting construction, weight, etc

FACSIMILE TRANSMISSION↗

NASA NTRS1972

Public health applications of remote sensing of the environment, an evaluation

The available techniques were examined in the field of remote sensing (including aerial photography, infrared detection, radar, etc.) and applications to a number of problems in the wide field of public health determined. The specific areas of public health examined included: air pollution, water pollution, communicable disease, and the combined problems of urban growth and the effect of disasters on human communities. The assessment of the possible applications of remote sensing to these problems was made primarily by examination of the available literature in each field, and by interviews with health authorities, physicists, biologists, and other interested workers. Three types of programs employing remote sensors were outlined in the air pollution field: (1) proving ability of sensors to monitor pollutants at three levels of interest - point source, ambient levels in cities, and global patterns; (2) detection of effects of pollutants on the environment at local and global levels; and (3) routine monitoring.

Source record↗

NASA NTRS1974

A study of the effects of solid phase reactions on the thermal degradation and ballistic properties of solid propellants

The thermal stability of perchlorate composite propellants was studied at 135 and 170 C. The experimental efforts were concentrated on determining the importance of heterogeneous oxidizer-fuel reactions in the thermal degradation process. The experimental approach used to elucidate the mechanisms by which the oxidizer fuel composites thermally degrade was divided into two parts: (1) keeping the fuel constant and varying the nature of the oxidizers, and (2) holding the oxidizer constant and varying the fuel components. The fuel component primarily utilized in the first phase was polyethylene. Oxidizers included KClO4, KClO3, NH4ClO4 and NH4ClO4 doped with materials such as chlorate, phosphate and arsenate. In the second phase the oxidizer used was primarily NH4ClO4 while the fuels included saturated and unsaturated polybutadiene prepolymers and a series of bonding agents. Techniques employed in the current study include thermogravimetric measurements, differential thermal analysis, infrared, mass spectrometry, electron microscopy, and appropriate wet chemical analysis.

Schmidt, W. G.↗

NASA NTRS1973

Thermomechanical behavior of a polynorbornadiene

A high-temperature linear amorphous hydrocarbon polymer synthesized cationically from 2,5-norbornadiene was studied thermomechanically with respect to physical transitions and stability in nitrogen. The glass transition temperature was determined to be 320 C (at less than 1 cps), which is probably the highest known for a linear hydrocarbon addition polymer. The thermomechanical technique of torsional braid analysis, together with thermogravimetric analysis, differential thermal analysis, infrared analysis, and solubility studies, was used to investigate the sequential events of the glass transition and degradation. The polymer is of particular interest since it is a high-temperature plastic which in the bulk form would probably need to be processed at high speeds in the vicinity of the glass transition temperature in an inert atmosphere. The presence of tertiary hydrogen atoms should render it amenable to degradation by the earth's environment.

Roller, M. B.↗

NASA NTRS1979

Remote sensing as a source of land cover information utilized in the universal soil loss equation

In this study, methods for gathering the land use/land cover information required by the USLE were investigated with medium altitude, multi-date color and color infrared 70-mm positive transparencies using human and computer-based interpretation techniques. Successful results, which compare favorably with traditional field study methods, were obtained within the test site watershed with airphoto data sources and human airphoto interpretation techniques. Computer-based interpretation techniques were not capable of identifying soil conservation practices but were successful to varying degrees in gathering other types of desired land use/land cover information.

Morris-Jones, D. R.↗

NASA NTRS1984

The spatial extent of the 3.3 micron emission feature in the Seyfert galaxy NGC 7469

Observations have been made of the 3.3-micron feature and the infrared continuum in the type 1 Seyfert galaxy NGC 7469 using multiaperture techniques. While as much as 10 to the 7th solar luminosities in 3.3-micron line emission may arise from within the nucleus, the data indicate that the 3.3-micron emission-line region is extended, with a significant fraction of the luminosity of the line originating at distances greater than 240 pc from the nucleus. Possible mechanisms for the heating of the dust associated with the extended emission are discussed together with observational tests which can be used to verify the more promising of these mechanisms.

Cutri, R. M.↗

NASA NTRS1985

Resin Characterization in Cured Composite Materials

Molecular-level characterization of polymeric matrix resin in cured graphite-reinforced composite materials now determined through analysis of diffuse reflectance (DR) with Fourier Transform Infrared (FTIR) spectroscopy. Improved analytical method based on diffuse reflectance. DR/ FTIR technique successfully applied to analysis of several different composites and adhesives impossible to analyze by conventional methods.

Young, P. R.↗

NASA NTRS1984

Technology for satellite power conversion

Techniques for satellite electromagnetic energy transfer and power conversion at millimeter and infrared wavelengths are discussed. The design requirements for rectenna receiving elements are reviewed for both coherent radiation sources and Earth thermal infrared emission. Potential power transmitters including gyrotrons, free electron lasers, and CO2 lasers are assessed along with the rectification properties of metal-oxide metal diode power converters.

Campbell, D. P.↗

NASA NTRS1986

Laser heterodyne spectrometer for helioseismology

The technique of laser heterodyne spectroscopy has been applied to the measurement of solar oscillations. Coherent mixing of solar radiation with the output of a frequency-stabilized CO2 laser permits the measurement of fully resolved profiles of solar absorption lines with high spectral purity and excellent frequency stability. This technique has been used to measure OH pure rotation lines in the infrared solar spectrum. Power spectra of these line frequency measurements show the well-known 5-min oscillations as well as significant velocity power at shorter periods.

Glenar, D. A.↗

NASA NTRS1985

Improved satellite retrievals and mesoscale moisture variability

The investigations over the past year have led to the finalization of results from the study of mesoscale atmospheric parameters derived from the visible infrared spin scan radiometer (VISSR) atmospheric sounder (VAS). Soundings from several retrieval techniques for the 6 to 7 March 1982 special observation period were evaluated for mesoscale accuracy. Specific results and comparisons between data from a regression and two physical retrieval schemes are forthcoming in the Journal of Atmospheric and Oceanic Technology (JTech) this year. A generalization of these results is outlined. Large temperature and moisture biases existed in the VAS derived profiles, particularly in layers near inversions. Standard errors ranged from 1 to 3 C and 3 to 6 C for temperature and dewpoint, respectively. Parameters derived from VAS soundings (geopotential height, thickness, and precipitable water) often reflected the temperature and moisture profile biases. VAS derived mesoscale gradients were often weaker than those from corresponding rawinsonde data. Little improvement was made in defining the vertical structure of the atmosphere over the first guess information. VAS soundings were able to improve in the horizontal structure due to the high spatial resolution of the radiance data.

Jedlovec, G. J.↗

NASA NTRS1989

Modelling the dust grains around the peculiar Be star HD 45677

Numerical radiative transfer models are used to study circumstellar dust grains around the peculiar Be star HD 45677. The modeling technique is to fit the observed far-ultraviolet through far-infrared energy distribution with the energy distributions predicted for a spherical dust shell around a luminous hot star. Such a simultaneous multi-wavelength study makes it possible to strengthen constraints on dust-grain properties. It is found that the observations can be fitted with the emergent spectrum of a spherical shell consisting of a graphite-silicate mixture. The grain-size distribution is similar to that for diffuse cloud dust, but the circumstellar dust contains large grains with a maximum size of about 1 micron. This result is consistent with a scenario in which HD 45677 is a young stellar object (100 Myr or less), with the dust shell being a fossil of the molecular cloud left over from star formation.

Sorrell, Wilfred H.↗

NASA NTRS1991

New devices for flow measurements: Hot film and burial wire sensors, infrared imagery, liquid crystal, and piezo-electric model

An experimental program aimed at identifying areas in low speed aerodynamic research where infrared imaging systems can make significant contributions is discussed. Implementing a new technique, a long electrically heated wire was placed across a laminar flow. By measuring the temperature distribution along the wire with the IR imaging camera, the flow behavior was identified.

Mcree, Griffith J., Jr.↗

NASA NTRS1992

A generalized approach to the thermal analysis of the Long Duration Exposure Facility's flight experiments

The generalized method used in the thermal analysis of the LDEF flight experiments is presented. The approach consists of developing a mathematical lumped parameter node representation of the experiment; defining the source and sink temperature boundary conditions; calculating the albedo, infrared, and solar orbital heating fluxes; and solving with a finite difference technique. The temperature predictions can be made either on a per orbit basis or for any length of mission time using a daily averaged calculated composite flux. The thermal analysis of the Ultra Heavy Cosmic Ray Experiment (UHCRE-A0178) is presented as an example of this approach.

Sampair, Thomas R.↗