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All sourcesNASA NTRSDOE OSTI
NASA NTRS2014

Space Radiation and the Challenges Towards Effective Shielding Solutions

The hazards of space radiation and their effective mitigation strategies continue to pose special science and technology challenges to NASA. It is widely accepted now that shielding space vehicles and structures will have to rely on new and innovative materials since aluminum, like all high Z materials, are poor shields against the particulate and highly ionizing nature of space radiation. Shielding solutions, motivated and constrained by power and mass limitations, couple this realization with "multifunctionality," both in design concept as well as in material function and composition. Materials endowed with effective shielding properties as well as with some degree of multi‐functionality may be the kernel of the so‐called "radiation‐smart" structures and designs. This talk will present some of the challenges and potential mitigation ideas towards the realization of such structures and designs.

Barghouty, Abdulnasser↗
NASA NTRS2016

The Near-Earth Meteoroid Flux, Speed Distribution, and Uncertainty

Meteoroids are known to pose a threat to spacecraft; they can puncture components, disturb spacecraft attitude, and possibly create secondary electrical effects. Accurate environment models are therefore critical for mitigating meteoroid-related risks. While there are several meteoroid environment models available for assessing spacecraft risk, the uncertainties associated with these models are not well understood. Because meteoroid properties are derived from indirect observations such as meteors and impact craters, the uncertainty in the meteoroid flux is potentially quite large. We combine existing meteoroid flux measurements with new radar and optical meteor data to improve our characterization of the meteoroid flux onto the Earth and its velocity distribution. We use data extracted from the NASA all-sky network, the Canadian Automated Meteor Observatory, and the Canadian Meteor Orbit Radar. We improve our characterization of the observed meteoroid speed distribution by incorporating modern descriptions of the ionization efficiency (e.g., Thomas et al., 2016). We also present estimates of the uncertainties associated with our meteoroid flux distribution. Finally, we discuss the implications for spacecraft. Our model is constrained by the cratering rate on the space-facing surface of LDEF, and thus the risk posed to spacecraft by meteoroid-induced physical damage is the least uncertain component of our model. Other sources of risk, however, may vary. For instance, a lower average meteoroid speed would require a higher meteoroid mass flux in order to match the LDEF crater counts, leading to higher predicted rates of attitude disturbances.

Moorhead, Althea↗
NASA NTRS2026

Mechanical Properties of Carbon Fiber Reinforced Composites Exposed to Cryogenic Conditions and Space Radiation via Simulation and Testing

As NASA missions extend beyond low Earth orbit, increasing reliance is placed on carbon fiber reinforced polymer (CFRP) composites for spacecraft structures where mass efficiency, durability, and long-term reliability are critical. In service, these materials are subjected to a combination of ultraviolet radiation, vacuum, ionizing radiation, atomic oxygen, and extreme thermal excursions under sustained mechanical loading. Flight systems such as the Boeing Starliner and SpaceX Dragon employ external composite structures that will experience these environments for extended durations. Although prior spaceflight and ground studies have reported limited changes in bulk mechanical properties, the synergistic effects of these environments on composite microstructure, particularly at the fiber matrix interphase, remain insufficiently characterized and represent a potential qualification and reliability risk. This study investigates the effects of short-term cryogenic exposure on a radiation shielding carbon epoxy composite, SC2020, as a ground-based analog for space relevant thermal extremes. The SC2020 material system has previously flown on the International Space Station under the Materials International Space Station Experiment (MISSE) program. Composite specimens were exposed to liquid nitrogen for 6 and 24 hours and evaluated using a multiscale characterization framework that combined ASTM D3039 tensile testing, Atomic Force Microscopy (AFM) based interphase analysis, and helium gas permeability measurements. Tensile testing showed no statistically significant or permanent degradation in global strength or modulus following cryogenic exposure. In contrast, AFM measurements revealed reductions in interphase modulus, weakened adhesion, and increased nanoscale heterogeneity, indicating localized degradation mechanisms not captured by conventional bulk testing. Gas permeability measurements showed a progressive increase in helium diffusion with exposure duration, consistent with micro-void formation or partial interfacial debonding. The results indicate that cryogenic exposure initiates degradation at the fiber matrix interphase while leaving global mechanical properties largely unchanged over short durations. These findings underscore the importance of multiscale diagnostics for identifying early-stage damage mechanisms that may influence long term performance and qualification margins for spaceflight composite structures. The data presented establish a cryogenic baseline for comparison with forthcoming MISSE flight exposure results and support ongoing NASA Established Program to Stimulate Competitive Research (EPSCoR) efforts aimed at improving composite qualification methodologies, risk assessment, and reliability prediction for space environments.

composite reliability↗
NASA NTRS1992

Helium escape from the Earth's atmosphere - The charge exchange mechanism revisited

We have studied the escape of neutral helium from the terrestrial atmosphere through exothermic charge exchange reactions between He(+) ions and the major atmospheric constituents N2, O2 and O. Elastic collisions with the neutral background particles were treated quantitatively using a recently developed kinetic theory approach. An interhemispheric plasma transport model was employed to provide a global distribution of He(+) ions as a function of altitude, latitude and local solar time and for different levels of solar ionization. Combining these ion densities with neutral densities from an MSIS model and best estimates for the reaction rate coefficients of the charge exchange reactions, we computed the global distribution of the neutral He escape flux. The escape rates show large diurnal and latitudinal variations, while the global average does not vary by more than a factor of three over a solar cycle. We find that this escape mechanism is potentially important for the overall balance of helium in the Earth's atmosphere. However, more accurate values for the reaction rate coefficients of the charge exchange reactions are required to make a definitive assessment of its importance.

Lie-Svendsen, O.↗
NASA NTRS2006

Interaction of Ethyl Alcohol Vapor with Sulfuric Acid Solutions

We investigated the uptake of ethyl alcohol (ethanol) vapor by sulfuric acid solutions over the range approx.40 to approx.80 wt % H2SO4 and temperatures of 193-273 K. Laboratory studies used a fast flow-tube reactor coupled to an electron-impact ionization mass spectrometer for detection of ethanol and reaction products. The uptake coefficients ((gamma)) were measured and found to vary from 0.019 to 0.072, depending upon the acid composition and temperature. At concentrations greater than approx.70 wt % and in dilute solutions colder than 220 K, the values approached approx.0.07. We also determined the effective solubility constant of ethanol in approx.40 wt % H2SO4 in the temperature range 203-223 K. The potential implications to the budget of ethanol in the global troposphere are briefly discussed.

sulfate aerosols↗
DOE OSTI2023

Extreme high vacuum for polarized electron sources

Nuclear physics experiments often require highly polarized electron beams to do precise measurements of the structure and size of nucleons and the nucleus, as well as for searches for physics beyond the standard model. Jefferson Lab?s electron source, with polarization near 90%, has been providing polarized electron beams for CEBAF for over two decades. Development is underway for polarized electron sources at MESA at Mainz and the Electron Ion Collider at Brookhaven National Lab, and there is potential for polarized electron beam in the future at facilities including the International Linear Collider, an electron upgrade at CERN, and the SuperKEKB collider in Japan. At Jefferson Lab there are even plans to make use of polarized electrons to make a polarized positron source for experimental nuclear physics. High polarization electron beams are generated using photoemission from strained superlattice GaAs based photocathodes, and photocathode lifetime is limited by the ionization of residual gas in the system, which is then accelerated into the photocathode. Extreme high vacuum (near 1x10-10 Pa) is required to operate the Jefferson Lab polarized electron source with an acceptable lifetime, and the upcoming projects will need various combinations of higher current, higher bunch charge and longer photocathode lifetimes. To meet the vacuum requirements for polarized electron sources, every component for a polarized electron source must be optimized, including chamber materials, pumps, bakeout procedure and the high voltage electrode geometry and processing. Each change in these components must be evaluated offline before being used in the accelerator, and effects on pressure are difficult to evaluate even using XHV-optimized hot filament ionization gauges. In fact, we do not get a final evaluation of system modifications until an electron source is built, installed and lifetime measurements are made over the course of months or years of operation. I will be discussing the evolution of vacuum in the Jefferson Lab polarized source system toward XHV pressures and discuss the characterization and limitations measured for commercially available XHV vacuum gauges. Finally, I?ll present the effect of system pressure on photocathode lifetime and highlight how XHV pressure standards can benefit the ongoing efforts to improve vacuum for the next generation of polarized electron sources.

Stutzman, Marcy↗
DOE OSTI2026

Electron-irradiation induced creep in amorphous alloys

Electron-irradiation induced creep rates in amorphous alloys, a-SiO2, Fe79B16Si5, Cu60Ta40, and Cu50Ti50, were measured at room temperature using a miniaturized beam-bending apparatus within a transmission electron microscope operated at 200 keV. The creep rates of these amorphous samples increased nearly linearly with both e-beam current density and applied stress, while a reference crystalline (c-)SiO2 sample failed to creep under the same conditions. The irradiation induced creep compliance of a-SiO2 was ~ 15 times larger than that of Fe79B16Si5 and over 1,000 times larger than that of the two Cu alloys. Molecular dynamics computer simulations were employed to simulate electron irradiation induced creep using interatomic potentials representing amorphous Cu75Zr25, Ni80P20, and SiO2 as model systems. The irradiation induced creep compliances calculated for Cu75Zr25 during 200 keV electron irradiation provided good quantitative agreement with the two Cu-based alloys, but that for a-SiO2 was ~ 180 times too small. These results indicate that unlike neutron or ion-beam induced creep in a-SiO2, creep under electron irradiation is dominated by the effects of ionization owing largely to the far higher ratio of electronic stopping to nuclear stopping for electrons than for ions.

36 MATERIALS SCIENCE↗
NASA NTRS1988

Ionic rotational branching ratios in resonant enhanced multiphoton ionization of NO via the A2Sigma(+)(3s sigma) and D2Sigma(+)(3p sigma) states

Results are presented for the rotationally resolved photoelectron spectra resulting from a (2 + 1) one-color resonant enhanced multiphoton ionization (REMPI) of NO via the rotationally clean S21(11.5) and mixed S11(15.5) + R21(15.5) branches of the 0-0 transition in the D-X band. The calculations were done in the fixed-nuclei frozen core approximation. The resulting photoionization spectra, convoluted with a Lorentzian detection function, agree qualitatively with experimental results of Viswanathan et al. (1986) and support their conclusion that the nonspherical nature of the molecular potential creates a substantial l-mixing in the continuum, which in turn leads to the intense Delta N = 0 peak. The rather strong photoelectron energy dependence of the rotational branching ratios of the D 2Sigma(+) S21(11.5) line was investigated and compared to the weak energy dependence of the A 2Sigma(+) R22(21.5) line.

Rudolph, H.↗
NASA NTRS1994

Electron-Beam Diagnostic Methods for Hypersonic Flow Diagnostics

The purpose of this work was the evaluation of the use of electron-bean fluorescence for flow measurements during hypersonic flight. Both analytical and numerical models were developed in this investigation to evaluate quantitatively flow field imaging concepts based upon the electron beam fluorescence technique for use in flight research and wind tunnel applications. Specific models were developed for: (1) fluorescence excitation/emission for nitrogen, (2) rotational fluorescence spectrum for nitrogen, (3) single and multiple scattering of electrons in a variable density medium, (4) spatial and spectral distribution of fluorescence, (5) measurement of rotational temperature and density, (6) optical filter design for fluorescence imaging, and (7) temperature accuracy and signal acquisition time requirements. Application of these models to a typical hypersonic wind tunnel flow is presented. In particular, the capability of simulating the fluorescence resulting from electron impact ionization in a variable density nitrogen or air flow provides the capability to evaluate the design of imaging instruments for flow field mapping. The result of this analysis is a recommendation that quantitative measurements of hypersonic flow fields using electron-bean fluorescence is a tractable method with electron beam energies of 100 keV. With lower electron energies, electron scattering increases with significant beam divergence which makes quantitative imaging difficult. The potential application of the analytical and numerical models developed in this work is in the design of a flow field imaging instrument for use in hypersonic wind tunnels or onboard a flight research vehicle.

Source record↗
NASA NTRS2009

The Scientific Capabilities of the James Webb Space Telescope

The scientific capabilities of the James Webb Space Telescope fall into four themes. The End of the Dark Ages: First Light and Reionization theme seeks to identify the first luminous sources to form and to determine the ionization history of the universe. The Assembly of Galaxies theme seeks to determine how galaxies and dark matter, gas, stars, metals morphological structures, and active nuclei within them evolved from the epoch of reionization to the present. The Birth of Stars and Protoplanetary Systems and the Origins of Life theme seeks to determine the physical and chemical properties of planetary systems around nearby stars and of our own, and investigate the potential for life in those systems. A comprehensive, top-level review of JWST sciences was published in the journal Space Science Reviews (Gardner et al. 2006, SSR, 123, 485). That paper gives details of the 4 JWST science themes, and describes the design of the observatory and ground system. Since that paper was published, the JWST Science Working Group, working with members of the astronomical community, has continued to develop the science case for JWST, giving more details in a series of white papers. In this poster, the main science themes and white papers are reviewed.

Gardner, Jonathan P.↗
NASA NTRSDate not supplied

UV Laser Development for In Situ Planetary Lander Instruments

Mass and Raman spectrometers represent progressive analytical platforms for future in situ lander missions to explore the surface chemistry of planetary bodies across the Solar System. Europa, the Moon, and Mars are some of the primary targets for future NASA missions to search for extraterrestrial life and potentially habitable environments beyond Earth, further our understanding of the timing and formation of the Solar System and identify potentially viable economic resources such as water and/or valuable metal assets. The CORALS (Characterization of Ocean Residues And Life Signatures) and CRATER (Characterization of Regolith And Trace Economic Resources) instruments are UV laser-enabled OrbitrapTM mass spectrometers currently under development for prospective lander missions to Europa and the Moon, respectively. The Raman Mass Spectrometer (RAMS) is a dual wavelength (UV and visible) laser enabled hybrid instrument that incorporates laser desorption/ ionization mass spectrometry (LDMS) and micro-Raman microspectroscopy imaging (μRS) into a compact instrument package for multiple planetary missions to the inner and outer Solar System. The Pulse Laser Ablation Sampling and Mass Analysis (PLASMA) instrument combines a multi-wavelength laser (deep-UV to near-IR), plasma source, and collision cell with a heritage quadrupole mass spectrometer (QMS) to enable high precision trace element analyses for a future Lunar lander instrument. We report on the advancement of four compact, robust, and high technology readiness level (TRL) solid state lasers operating at wavelengths 213 nm, 266 nm, 515 nm, 532 nm and 1064 nm that serve as the sampling and ionization sources, for the CRATER, CORALS, RAMS and PLASMA investigations.

Molly Fahey↗
DOE OSTI2025

The bulk motion of gas in the core of the Centaurus galaxy cluster

Galaxy clusters contain vast amounts of hot ionized gas known as the intracluster medium (ICM). In relaxed cluster cores, the radiative cooling time of the ICM is shorter than the age of the cluster. However, the absence of line emission associated with cooling suggests heating mechanisms that offset the cooling, with feedback from active galactic nuclei (AGNs) being the most likely source. Turbulence and bulk motions, such as the oscillating (‘sloshing’) motion of the core gas in the cluster potential well, have also been proposed as mechanisms for heat distribution from the outside of the core. Here we present X-ray spectroscopic observations of the Centaurus galaxy cluster with the X-Ray Imaging and Spectroscopy Mission satellite. We find that the hot gas flows along the line of sight relative to the central galaxy, with velocities from 130 km s −1 to 310 km s −1 within about 30 kpc of the centre. This indicates bulk flow consistent with core gas sloshing. Although the bulk flow may prevent excessive accumulation of cooled gas at the centre, it could distribute the heat injected by the AGN and bring in thermal energy from the surrounding ICM. The velocity dispersion of the gas is found to be only ≲120 km s −1 in the core, even within about 10 kpc of the AGN. This suggests that the influence of the AGN on the surrounding ICM motion is limited in the cluster.

galaxies and clusters↗
DOE OSTI2023

Use of FLOSIC for understanding anion-solvent interactions

An Achille’s heel of lower-rung density-functional approximations is that the highest-occupied-molecular-orbital energy levels of anions, known to be stable or metastable in nature, are often found to be positive in the worst case or above the lowest-unoccupied-molecular-orbital levels on neighboring complexes that are not expected to accept charge. A trianionic example, [Cr(C2O4)3]3−, is of interest for constraining models linking Cr isotope ratios in rock samples to oxygen levels in Earth’s atmosphere over geological timescales. Here we describe how crowd sourcing can be used to carry out self-consistent Fermi–Löwdin–Orbital-Self-Interaction corrected calculations (FLOSIC) on this trianion in solution. The calculations give a physically correct description of the electronic structure of the trianion and water. In contrast, uncorrected local density approximation (LDA) calculations result in approximately half of the anion charge being transferred to the water bath due to the effects of self-interaction error. Use of group-theory and the intrinsic sparsity of the theory enables calculations roughly 125 times faster than our initial implementation in the large N limit reached here. By integrating charge density densities and Coulomb potentials over regions of space and analyzing core-level shifts of the Cr and O atoms as a function of position and functional, we unambiguously show that FLOSIC, relative to LDA, reverses incorrect solute-solvent charge transfer in the trianion-water complex. In comparison to other functionals investigated herein, including Hartree–Fock and the local density approximation, the FLOSIC Cr 1s eigenvalues provide the best agreement with experimental core ionization energies.

Chemistry↗
NASA NTRS1979

Nonequilibrium ionization in solar and stellar winds

Substantial and systematic departures from ionization equilibrium can occur in the solar transition region and corona when mass outflows are present. Modeling calculations illustrate the general characteristics of the ionization balance in such regions. The presence of nonequilibrium conditions suggests a natural explanation for the extended region of EUV line emission that is observed above the solar limb. Comparison with observations of a coronal hole on the disk indicates that outflow may not start until temperatures of about 250,000 K are reached. Additional consequences include a diminution of the density discrepancy between ultraviolet and radio observations of coronal holes, and potential effects on the energy balance in solar and stellar atmospheres undergoing mass loss.

Dupree, A. K.↗
NASA NTRS2000

Heat of Formation of OBrO: An Experiment Photoionization Study

The potential importance of OBrO in atmospheric chemistry has been suggested recently. Although there appear to be no experimental measurements of deltaH(OBrO), estimated values range from 70 to 152 kJ/mol. In the present investigation, the appearance energy (AE) of BrO+ from OBrO was measured by employing a discharge flow-photoionization mass spectrometer that is operated at beamline U-11. The heat of formation was derived from the AE result and the ionization energy of OBrO [IE = 10.29 eV]. The AE experiments yield a threshold at about 98.7 nm that gives, in turn, a value for AH(OBrO) of 180 +/- 10 kJ/mol. The difference with the estimated values mentioned above and the concomitant implications for the atmospheric reactions of OBrO will be discussed.

Klemm, R. Bruce↗
NASA NTRS2000

Elemental, Isotopic, and Organic Analysis on Mars with Laser TOF-MS

The in-depth landed exploration of Mars will require increasingly sophisticated robotic analytical tools for both in situ composition science [1] and reconnaissance for sample return [2]. Beyond dust, rock surfaces, and topsoil, samples must be accessed within rocks and ice, well below surface soil, and possibly in elevated deposit layers. A range of spatial scales will be studied, and for the most information-rich microscopic analyses, samples must be acquired, prepared, and positioned with high precision. In some cases samples must also be brought into a vacuum chamber. After expending such resources, it will be important to apply techniques that provide a wide range of information about the samples. Microscopy, mineralogy, and molecular/organic, elemental, and isotopic analyses are all needed, at a minimum, to begin to address the in situ goals at Mars. These techniques must work as an efficient suite to provide layers of data, each layer helping to determine if further analysis on a given sample is desired. In the spirit of broad-band and efficient data collection, we are developing miniature laser time-of-flight mass spectrometers (TOF-MS) for elemental, isotopic, and molecular/organic microanalysis of unprepared solid samples. Laser TOF-MS uses a pulsed laser to volatilize and ionize material from a small region on the sample. The laser energy and focus can be adjusted for atomic and molecular content, sampling area, and depth. Ions travel through the instrument and are detected at a sequence of times proportional to the square root of their mass-to- charge ratios. Thus, each laser pulse produces a complete mass spectrum (in less than 50 microseconds). These instruments can now be significantly miniaturized (potentially to the size of a soda can) without a loss in performance. This effort is reviewed here with an emphasis on applications to Mars exploration.

Brinckerhoff, W. B.↗
NASA NTRS1990

Physical processes associated with current collection by plasma contactors

Recent flight data confirms laboratory observations that the release of neutral gas increases plasma sheath currents. Plasma contactors are devices which release a partially ionized gas in order to enhance the current flow between a spacecraft and the space plasma. Ionization of the expellant gas and the formation of a double layer between the anode plasma and the space plasma are the dominant physical processes. A theory is presented of the interaction between the contactor plasma and the background plasma. The conditions for formation of a double layer between the two plasmas are derived. Double layer formation is shown to be a consequence of the nonlinear response of the plasmas to changes in potential. Numerical calculations based upon this model are compared with laboratory measurements of current collection by hollow cathode-based plasma contactors.

Katz, Ira↗