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At least 1,027 records · Page 57

Surface properties of the Pettit wind streak on Mars Implications for sediment transport

Satellite imagery of the Pettit streak on Amazonis Planitia are discussed in terms of the details of wind streaks and their associated sediments. Increasingly more detailed blow-ups of the available imagery demonstrate that the Pettit streak holds both a Type I bright streak (at the crater rim) and a Type II dark streak beginning at the dark patch within the crater. The lowest albedos measured, 0.20-0.22, are associated with the highest thermal inertia, indicative of grain diameters similar to medium sand, i.e., ranging from 250-350 microns. The brightest portions of the streak have albedos over 0.26 and a low thermal inertia, in the range 3-4, which implies the presence of fine-grained sand, diameters from 50-100 microns. The particle grains are less than 50 microns diameter in the surrounding plains, which have an approximately uniform albedo (0.27) and a thermal inertia of 2.5, characteristics typical of silt or clay. Current streak models describe the dark streak well, but do not account for the bright streak, which may be optically thick patches of very fine dust.

Zimbelman, J. R.↗

Template-directed oligonucleotide ligation on hydroxylapatite

It has been suggested that the prebiotic synthesis of the precursors of biopolymers could have occurred on a solid surface such as that provided by clay or some other mineral. One such scheme envisages that growing polymers were localized by adsorption to a mineral surface where an activating agent or activated monomers were supplied continuously or cyclically. Here, it is reported that a sequence of reactions in which initially formed oligo(G)s are reactivated by conversion to phosphorimidazolides in the presence of poly(C) and then allowed to ligate is ideal, in that repeated cycles can be carried out on the surface of hydroxylapatite, whereas in the liquid phase the cycle could be achieved only with considerable difficulty.

Acevedo, O. L.↗

Abundance and distribution of mineral components associated with Moses Rock (kimberlite) diatreme

The surface mineralogy in and around Moses Rock diatreme, a kimberlite-bearing dike in SW Utah, was examined using internally calibrated Airborne Imaging Spectrometer (AIS) data. Distinct near-infrared absorption characteristics of clays, gypsum, and serpentine (a key marker for kinberlite concentration) allowed the surface units containing these components to be identified spatially and the relative abundance of each component measured. Within the dike itself, channels and dispersed components of kimberlite and blocks of country rocks were accurately determined.

Mustard, J. F.↗

Identification of hydrothermal alteration assemblages using airborne imaging spectrometer data

Airborne Imaging Spectrometer (AIS) data, field and laboratory spectra and samples for X-ray diffraction analysis were collected in argillically altered Tertiary volcanic rocks in the Hot Creek Range, Nevada. From laboratory and field spectral measurements in the 2.0 to 2.4 micron range and using a spectroradiometer with a 4 nm sampling interval, the absorption band centers for kaolinite were loacted at 2.172 and 2.215 microns, for montmorillonite at 2.214 micron and for illite at 2.205. Based on these values and the criteria for resolution and separtion of spectral features, a spectral sampling interval of less than 4 nm is necessary to separate the clays. With an AIS spectral sampling interval of 9.3 nm, a spectral matching algorithm is more effective for separating kaolinite, montmorillonite, ad illite in Hot Creek Range than using the location of absorption minima alone.

Feldman, S. C.↗

Detection of hydrothermal alteration at Virginia City, Nevada using Airborne Imaging Spectrometry (AIS)

Airborne Imaging Spectrometer (AIS) data were collected over Virginia City, Nevada; an area of gold and silver mineralization with extensive surface exposures of altered volcanic rocks. The data were corrected for atmospheric effects by a flat-field method, and compared to library spectra of various alteration minerals using a spectral analysis program SPAM. Areas of strong clay alteration were identified on the AIS images that were mapped as kaolinitic, illitic, and sericitic alterations zones. Kaolinitic alteration is distinguishable in the 2.1 to 2.4 and 1.2 to 1.5 micrometer wavelength regions. Montmorillonite, illite, and sericite have absorption features similar to each other at 2.2 micrometer wavelength. Montnorillonite and illite also may be present in varying proportions within one Ground Instantaneous Field of View (GIFOV). In general AIS data is useful in identifying alteration zones that are associated with or lie above precious metal mineralization at Virginia City.

Hutsinpiller, A.↗

Use of digital Munsell color space to assist interretation of imaging spectrometer data: Geologic examples from the northern Grapevine Mountains, California and Nevada

Techniques using Munsell color transformations were developed for reducing 128 channels (or less) of Airborne Imaging Spectrometer (AIS) data to a single color-composite-image suitable for both visual interpretation and digital analysis. Using AIS data acquired in 1984 and 1985, limestone and dolomite roof pendants and sericite-illite and other clay minerals related to alteration were mapped in a quartz monzonite stock in the northern Grapevine Mountains of California and Nevada. Field studies and laboratory spectral measurements verify the mineralogical distributions mapped from the AIS data.

Kruse, F. A.↗

Discrimination of soil hydraulic properties by combined thermal infrared and microwave remote sensing

Using the De Vries models for thermal conductivity and heat capacity, thermal inertia was determined as a function of soil moisture for 12 classes of soil types ranging from sand to clay. A coupled heat and moisture balance model was used to describe the thermal behavior of the top soil, while microwave remote sensing was used to estimate the soil moisture content of the same top soil. Soil hydraulic parameters are found to be very highly correlated with the combination of soil moisture content and thermal inertia at the same moisture content. Therefore, a remotely sensed estimate of the thermal behavior of the soil from diurnal soil temperature observations and an independent remotely sensed estimate of soil moisture content gives the possibility of estimating soil hydraulic properties by remote sensing.

Vandegriend, A. A.↗

Non-equilibrium freezing of water-ice in sandy basaltic regoliths and implications for fluidized debris flows on Mars

Many geomorphic features on Mars were attributed to Earth-analogous, cold-climate processes involving movement of water or ice lubricated debris. Clearly, knowledge of the behavior of water in regolith materials under Martian conditions is essential to understanding the postulated geomorphic processes. Experiments were performed with sand-sized samples of natural basaltic regoliths in order to further elucidate how water/regolith interactions depend upon grain size and mineralogy. The data reveal important contrasts with data for clay-mineral substrates and suggest that the microphysics of water/mineral interactions might affect Martian geomorphic processes in ways that are not fully appreciated. Sand and silt sized fractions of two soils from the summit of Mauna Kea were used as Mars-analogous regolith materials. Temperatures were measured for water/ice phase transitions as wet slurries of individual soil fractions which were cooled or heated at controlled rates under a carbon dioxide atmosphere. Freezing and melting of ice was studied as a function of water/soil mass ratio, soil particle size, and thermal-cycle rate. Comparison tests were done under the same conditions with U.S. Geological Survey standard rock powders.

Gooding, J. L.↗

The effect of overburden thickness on tension fracture patterns above an uplifting dome

Four experiments demonstrate that tension-fracture patterns above an uplifting dome depend on the thickness of the overburden layer being deformed. Four layers of increasing thicknesses (4.92 cm, 6.92 cm, 9.05 cm, and 11.12 cm) of a very fine sand (85%) and silt-clay (15%) mixture were updomed by slowly inflating a 1.22 m-diameter circular rubber pillow. The upper 2 cm of each layer was wetted and air dried to make it brittle and susceptible to fracture. The fractures that formed during these experiments exhibited a continuum of patterns from dominantly arcuate to dominantly radial as the overburden thickness increased. However, fracture density remained constant in each case for a given amount of surface deformation.

Pranger, H., II↗

A surface temperature and moisture parameterization for use in mesoscale numerical models

A modified multi-level soil moisture and surface temperature model is presented for use as in defining lower boundary conditions in mesoscale weather models. Account is taken of the hydraulic and thermal diffusion properties of the soil, their variations with soil type, and the mixing ratio at the surface. Techniques are defined for integrating the surface input into the multi-level scheme. Sample simulation runs were performed with the modified model and the original model defined by Pielke, et al. (1977, 1981). The models were applied to regional weather forecasting over soils composed of sand and clay loam. The new form of the model avoided iterations necessary in the earlier version of the model and achieved convergence at reasonable profiles for surface temperature and moisture in regions where the earlier version of the model failed.

Tremback, C. J.↗

Conodont survival and low iridium abundances across the Permian-Triassic boundary in south China

The Permian-Triassic sedimentary sequence of China includes one of the most complete and fossiliferous Paleozoic-Mesozoic boundaries known. Closely spaced sampling across the boundary, which is an important extinction event for most organisms, has produced good conodont faunas that show little diversity change. A drop in conodont abundance is the only apparent response to the extinction event. A low concentration of iridium in the boundary clay (0.002 part per billion + or - 20 percent), as well as in samples immediately below and above, that range from 0.004 to 0.034 part per billion do not support the proposal of an extraterrestrial impact event at this boundary in China.

Clark, D. L.↗

Rb-Sr and Sm-Nd systematics of cherts and other siliceous deposits

An analysis of marine and lacustrine cherts demonstrates that Rb-Sr and Sm-Nd systems may be used in elucidating the origin and evolution of cherts, and that the Rb-Sr system may be used for dating. All samples have high Rb/Sr ratios, and though the site of these elements in cherts was not established, they appear to be correlated with Al content. Sm/Nd ratios were typical of continental sources, and the results show the Rb-Sr system in cherts to be isolated from the associated carbonate, with little Sr exchange. Data suggest that in many cases cherts are formed by dissolved SiO2 nucleating on clay-like material which preserves the isotropic characteristics of the detrital source, while in some cases it is possible that cherts were formed from silica-saturated waters from a nonmarine source.

Weis, D.↗

Effect of adsorbed iron on thermoluminescence and electron spin resonance spectra of Ca-Fe-exchanged montmorillonite

The ESR spectra and the natural and gamma-induced thermoluminescence (TL) glow curves of a series of variably cation-exchanged Fe-Ca-clays prepared from SWy-1 montmorillonite were examined. The ESR signal intensity associated with surface Fe increased linearly with surface Fe content up to a nominal concentration of 50 percent exchangeable Fe. At above 50 percent exchangeable Fe, no appreciable increase in the signal was noted. The TL intensity decreased linearly with increasing surface Fe up to 50 percent nominal exchangeable Fe. At above 50 percent, the signal was not appreciably further diminished. Possible effects of Fe on quenching of TL are considered.

Coyne, Lelia M.↗

The role of minerals in the thermal alteration of organic matter. IV - Generation of n-alkanes, acyclic isoprenoids, and alkenes in laboratory experiments

The effect of common sedimentary minerals (illite, Na-montmorillonite, or calcite) under different water concentrations on the generation and release of n-alkanes, acyclic isoprenoids, and select alkenes from oil-prone kerogens was investigated. Matrices containing Green River Formation kerogen or Monterey Formation kerogen, alone or in the presence of minerals, were heated at 200 or 300 C for periods of up to 1000 hours, and the pyrolysis products were analyzed. The influence of the first two clay minerals was found to be critically dependent on the water content. Under the dry pyrolysis conditions, both minerals significantly reduced alkene formation; the C12+ n-alkanes and acyclic isoprenoids were mostly destroyed by montmorillonite, but underwent only minor alteration with illite. Under hydrous conditions (mineral/water of 2/1), the effects of both minerals were substantially reduced. Calcite had no significant effect on the thermal evolution of the hydrocarbons.

Huizinga, Bradley J.↗

Dunes in the north polar region of Mars - Their possible formation from low-density sedimentary aggregates

Low-density aggregates composed of submicron clay aerosols were formed experimentally as the sublimation residues of masses of dust-nucleated ice. These ice-dust mixtures are considered to be possible analogs of materials of Martian north polar deposits. Low-density (0.002 g/cu cm) spheroidal pellets formed from these materials in wind tunnel experiments are studied as possible candidates for the formation of dunes in the north polar region of Mars. It is shown that these particles move like sand grains under conditions of saltation and, taken in sufficient quantities, can form the dunes observed in the north circumpolar erg.

Saunders, R. S.↗

Spectral characteristics and the extent of paleosols of the Palouse formation

The objective of this study is to test the hypothesis that TM data is adequate in band selection and width and in spatial resolution to distinguish soil organic matter, iron oxide, and lime-silica contents to map several severity classes of erosion in soils of the Palouse region. The methodology used is as follows: (1) To develop spectral relationships from TM data that define the spatial distribution of soil areas by levels of (1) organic matter in the surface soil, (2) iron oxide and clay in exposed paleosol B horizons, and (3) lime-silica accumulations in exposed paleosol B horizons; (2) To compare areas determined by the method outlined in 1 to patterns interpreted from color aerial photos, and to ground observations on bare-soil fields; and (3) To define, on the basis of results of 1 and 2 to the extent possible, where exposed paleosols exist within fields that are not bare, but have a crop cover, and the distribution of desirable and undesirable soil properties in each field.

Frazier, B. E.↗

Weathering of sulfides on Mars

Pyrrhotite-pentlandite assemblages in mafic and ultramafic igneous rocks may have contributed significantly to the chemical weathering reactions that produce degradation products in the Martian regolith. By analogy and terrestrial processes, a model is proposed whereby supergene alteration of these primary Fe-Ni sulfides on Mars has generated secondary sulfides (e.g., pyrite) below the water table and produced acidic groundwater containing high concentrations of dissolved Fe, Ni, and sulfate ions. The low pH solutions also initiated weathering reactions of igneous feldspars and ferromagnesian silicates to form clay silicate and ferric oxyhydroxide phases. Near-surface oxidation and hydrolysis of ferric sulfato-and hydroxo-complex ions and sols formed gossan above the water table consisting of poorly crystalline hydrated ferric sulfates (e.g., jarosite), oxides (ferrihydrite, goethite), and silica (opal). Underlying groundwater, now permafrost contains hydroxo sulfato complexes of Fe, Al, Mg, Ni, which may be stabilized in frozen acidic solutions beneath the surface of Mars. Sublimation of permafrost may replenish colloidal ferric oxides, sulfates, and phyllosilicates during dust storms on Mars.

Burns, Roger G.↗

Chemical interactions between the present-day Martian atmosphere and surface minerals

Thermochemical and photochemical reactions between surface minerals and present-day atmospheric constituents are predicted to produce microscopic effects on the surfaces of mineral grains. Relevant reactions hypothesized in the literature include conversions of silicates and volcanic glasses to clay minerals, conversion of ferrous to ferric compounds, and formation of carbonates, nitrates, and sulfates. These types of surface-atmosphere interactions are important for addressing issues such as chemical weathering of minerals, biological potential of the surface environment, and atmospheric stability in both present and past Martian epochs. It is emphasized that the product of these reactions will be observable and interpretable on the microscopic surface layers of Martian surface rocks using modern techniques with obvious implications for sample return from Mars. Macroscopic products of chemical weathering reactions in past Martian epochs are also expected in Martian surface material. These products are expected not only as a result of reactions similar to those proceeding today but also due to aqueous reactions in past epochs in which liquid water was putatively present. It may prove very difficult or impossible however to determine definitively from the relic macroscopic product alone either the exact weathering process which led to its formation or the identity of its weathered parent mineral. The enormous advantages of studying Martian chemical weathering by investigating the microscopic products of present-day chemical reactions on sample surfaces are very apparent.

Prinn, Ronald↗