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At least 1,009 records · Page 56
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NASA NTRS1987

Ice or liquid water in the Martian regolith. Morphologic indicators from rampart craters

The morphology of ejecta blankets around certain Martian craters carries implications for volatiles in either the Martian crust or the atmosphere or both. The evidence that rampart crater ejecta can be used to infer the physical condition of volatiles in target rocks at the time of impact is reviewed. It was concluded that ice, and not liquid water, was the main volatile state, although rare examples also suggest the presence of liquid water at the time the craters were formed.

Mouginismark, P. J.↗
NASA NTRS1988

Radiation effects on polymeric materials

It is important to study changes in properties of polymeres after irradiation with charged particles, with ultraviolet radiation, and with combinations of both. An apparatus for this purpose has been built at the NASA Langley Research Center. It consists of a chamber 9 inches in diameter and 9 inches high with a port for an electron gun, another port for a mass spectrometer, and a quartz window through which an ultraviolet lamp can be focused. The chamber, including the electron gun and the mass spectrometer, can be evacuated to a pressure of 10 to the 8th power torr. A sample placed in the chamber can be irradiated with electrons and ultraviolet radiation separately, sequentially, or simultaneously, while volatile products can be monitored during all irradiations with the mass spectrometer. The apparatus described above has been used to study three different polymer films: lexan; a polycarbonate; P1700, a polysulfone; and mylar, a polyethylene terephthalate. All three polymers had been studied extensively with both electrons and ultraviolet radiation separately, but not simultaneously. Also, volatile products had not been monitored during irradiation for the materials. A high electron dose rate of 530 Mrads/hr was used so that a sufficient concentration of volatile products would be formed to yield a reasonable mass spectrum.

Kiefer, Richard L.↗
NASA NTRS1988

The record of Martian climatic history in cores and its preservation

Among the questions to be addressed by a Mars Sample Return Mission are the history of the Martian climate and the mechanisms that control the volatile cycles. Unfortunately, the evidence that bears most strongly on those issues lies in the volatile distribution in, and physical configuration of, a very delicate and volatile system: the uppermost Martian regolith. Some useful measurements to be made on returned samples of the regolith are identified, along with the many critical considerations in ensuring the usefulness of returned samples.

Zent, A. P.↗
NASA NTRS1988

Isotopic investigations in the area of the Tunguska catastrophe in 1908 year

The hypotheses of the annihilation and thermonuclear character of the Tunguska explosion have been tested by measuring inductive Ar-39 radioactivity from K and Ca in rocks and soil under the explosion epicentrum. Ar-39 was not detected though its estimated radioactivity was expected to be 100 times higher than the radio-metrical plant sensitivity. These results testify against the nuclear nature of the Tunguska explosion. The contents of 11 elements in the ultrasmall quantity of matter of the silicate microspherules isolated from catastrophe peat layer at the explosion site were measured by method of neutron activation analysis. It was demonstrated that the enrichment of microspherules by light and volatile elements (Al, Na, Zn, Cs) and the impoverishment by more heavy and hard volatile ones (Fe, Co, Sc). It was shown that the microspherules were not the product of differentiation of the terrestrial soil or of an ordinary meteorite material. It was demonstrated that Pb isotopic content in catastrophe peat layer had more Pb-204, Pb-207, Pb-208 than Pb-206 as compared with Pb isotopic content of other peat layers and common Pb in this area. In the peat column taken at the Ostraya hill area in three nearcatastrophe layers, small increases of isotopic C-13 was determined. Isotopic C effect in the peat layer is confirmed also for the North peatbog. Observed isotopic changes are not accounted for by climatic changes or other physico-chemical reasons. They seem to be related to preservation in the peat of matter resembling carbonaceous chrondrites of the Cl type or more probably of cometary matter enriched much more in volatile elements.

Kolesnikov, E. M.↗
NASA NTRS1988

Heat transfer by fluids in granulite metamorphism

The thermal role of fluids in granulite metamorphism was presented. It was shown that for granulites to be formed in the middle crust, heat must be advected by either magma or by volatile fluids, such as water or CO2. Models of channelized fluid flow indicate that there is little thermal difference between channelized and pervasive fluid flow, for the same total fluid flux, unless the channel spacing is of the same order or greater than the thickness of the layer through which the fluids flow. The volumes of volatile fluids required are very large and are only likely to be found associated with dehydration of a subducting slab, if volatile fluids are the sole heat source for granulite metamorphism.

Morgan, Paul↗
NASA NTRS1988

The cosmochemical classification of the elements

The present cosmochemical study divides the elements into four groups: refractory, moderately volatile, highly volatile, and siderophile, with the former three respectively condensing at temperatures higher than 1300-1400 K, between 670 and 1300 K, below 670 K. In the case of siderophiles, the essential condition is their being more easily reduced to metal than Fe. The siderophiles tend to behave as a cohesive group, occurring primarily as alloys in the FeNi-metal phase; their abundance and distribution, however, also appear to depend, in part, on their volatility.

Larimer, John W.↗
NASA NTRS1988

Siderophile element fractionation

The cosmic volatility of the siderophile elements appears to have played an important role in the determination of their chondritic-material abundances, and has led to minor but significant fractionations: (1) the formation and fractionation of a component bearing elements more refractory than Fe, Ni, or Co; (2) the formation of a common FeNiCo component that separated from the common silicates; and (3) the depletion of moderately volatile elements by factors of as much as 5, where abundance decreased with increasing volatility. A refractory siderophile component is noted to be required in order to account for bulk siderophile trends among closely related chondrite groups.

Larimer, John W.↗
NASA NTRS1990

Proceedings of a workshop on Lunar Volcanic Glasses: Scientific and Resource Potential

This workshop on lunar mare volcanism was the first since 1975 to deal with the major scientific advances that have occurred in this general subject, and the first ever to deal specifically with volcanic glasses. Lunar volcanic glasses are increasingly being recognized as the best geochemical and petrologic probes into the lunar mantle. Lunar volcanic glasses, of which 25 compositional varieties are presently known, appear to represent primary magmas that were produced by partial melting of differentiated mantle source regions at depths of perhaps 400 to 500 km. These high-magnesian picritic magmas were erupted onto the lunar surface in fire fountains associated with the release of indigenous lunar volatiles. The cosmic significance of this volatile component, in an otherwise depleted Moon, remains a lingering puzzle. The resource potential, if any, of the surface-correlated volatile sublimates on the volcanic glass spherules had not been systematically addressed prior to this workshop.

Delano, John W.↗
NASA NTRS1989

Ozone trends in Atlanta, Georgia - Have emission controls been effective?

Nine years of summertime ozone data from the Atlanta metropolitan area are analyzed and compared to local emissions of volatile organic carbon and nitrogen oxides. Trends from 1979 to 1987 were studied for the number of days per year ozone exceeded the NAAQS standard, the second-highest ozone level observed per year, and the first quartile summertime average ozone observed, as well as the mean difference between the ozone level observed downwind and upwind of the city. Because this last parameter is sensitive to chemical factors but relatively insensitive to the number of days each year with meteorological conditions conducive to ozone formation, its trend may be best suited for determining how effective emission controls have been in reducing O3 in the Atlanta area. In spite of the fact that sizeable reductions have been claimed for volatile organic carbon emissions over the past several years, the data give no indication that ozone levels have decreased and in fact, imply that summertime ozone production may have increased. The results imply that either emissions have not decreased as much as has been claimed or that ozone is not sensitive to anthropogenic volatile organic carbon emissions.

Lindsay, Ronald W.↗
NASA NTRS1992

Magma ocean: Mechanisms of formation

The thermal state of the Earth at the time relevant to formation of a magma ocean was dominated by the great impact that created the Moon. As shown in computer experiments, the iron in the impacting bodies quickly sank to the core of the proto-Earth, while a significant fraction of silicates was pushed far enough out beyond the geosynchronous limit to constitute the main material of the Moon. Most of any atmosphere would have been pushed aside, rather than being expelled in the impact. However, the energy remaining in the material not going to the core or expelled was still sufficient to raise its temperature some 1000's of degrees, enough to vaporize silicates and to generate a strong 'planetary wind': a hydrodynamic expansion carrying with it virtually all volatiles plus appreciable silicates. This expansion was violent and uneven in its most energetic stage, but probably the resulting magma ocean was global. The duration, until cooling, was sufficient for silicates to condense to melt and the duration was probably short. Comparison of the Earth and Venus indicates that the great impact was extraordinarily effective in removing volatiles from the proto-Earth; in particular, the enormous differences in primordial inert gases between the planets demand a catastrophic difference in origin circumstances. On the other hand, the comparison limits the amount of silicates lost by the Earth to a rather minor fraction; most of that expelled in the wind must have condensed soon enough for the silicate to fall back to Earth or be swept up by the proto-Moon. So the Earth was left with a magma ocean. The question is whether sufficient water was retained to constitute a steam atmosphere. Probably not, but unknowns affecting this question are the efficiencies of outgassing in great impacts and in subsequent convective churnings deep in the mantle. During the stage when mantle convection is turbulent, an appreciable fraction of volatiles were also retained at depth, perhaps in some mineral phases not yet well-defined. We still have primordial helium being outgassed.

Kaula, W. M.↗
NASA NTRS1992

Carbon and oxygen isotope study of carbonates from highly shocked clasts of the polymict breccia of the Haughton Crater (Canada)

It is known that the release of volatiles on impact is an important controlling factor in cratering processes in carbonate terranes and in the mobility of chemical elements. In order to assess the nature and the role of carbon- and oxygen-bearing volatiles during impact-induced metamorphism of sedimentary rocks, the C-13/C-12 and O-18/O-16 ratios and carbonate contents were determined for 30 shocked clasts from the Haughton Crater polymict breccia as well as for some unshocked carbonates from the sedimentary cover adjacent to the crater. Shock-induced CO2 loss during decarbonation of calcite is known to be a function of peak pressure and ambient partial pressure of the volatile species. In our clast samples, shocked from 20 to 60 GPa, we expect about 20 to 100 percent CO2 loss and preferential depletion in C-13 and O-18 in the residual carbonate. Rayleigh model (progressive loss of CO2) and batch model (single-step loss of CO2) curves for this depletion are shown. The magnitudes of the C-13 and O-18 depletions increase with the increase of the CO2 loss. In addition, the isotopic depletions should be correlated with an enrichment in CaO and MgO in the residual solid.

Agrinier, P.↗
NASA NTRS1991

Methods development for total organic carbon accountability

This report describes the efforts completed during the contract period beginning November 1, 1990 and ending April 30, 1991. Samples of product hygiene and potable water from WRT 3A were supplied by NASA/MSFC prior to contract award on July 24, 1990. Humidity condensate samples were supplied on August 3, 1990. During the course of this contract chemical analyses were performed on these samples to qualitatively determine specific components comprising, the measured organic carbon concentration. In addition, these samples and known standard solutions were used to identify and develop methodology useful to future comprehensive characterization of similar samples. Standard analyses including pH, conductivity, and total organic carbon (TOC) were conducted. Colorimetric and enzyme linked assays for total protein, bile acid, B-hydroxybutyric acid, methylene blue active substances (MBAS), urea nitrogen, ammonia, and glucose were also performed. Gas chromatographic procedures for non-volatile fatty acids and EPA priority pollutants were also performed. Liquid chromatography was used to screen for non-volatile, water soluble compounds not amenable to GC techniques. Methods development efforts were initiated to separate and quantitate certain chemical classes not classically analyzed in water and wastewater samples. These included carbohydrates, organic acids, and amino acids. Finally, efforts were initiated to identify useful concentration techniques to enhance detection limits and recovery of non-volatile, water soluble compounds.

Benson, Brian L.↗
NASA NTRS1992

Venus steep-sided domes: Relationships between geological associations and possible petrogenetic models

Venus domes are characterized by steep sides, a circular shape, and a relatively flat summit area. In addition, they are orders of magnitude larger in volume and have a lower height/diameter ratio than terrestrial silicic lava domes. The morphology of the domes is consistent with formation by lava with a high apparent viscosity. Twenty percent of the domes are located in or near tessera (highly deformed highlands), while most other (62 percent) are located in and near coronae (circular deformational features thought to represent local mantle upwelling). These geological associations provide evidence for mechanisms of petrogenesis and several of these models are found to be plausible: remelting of basaltic or evolved crust, differentiation of basaltic melts, and volatile enhancement and eruption of basaltic foams. Hess and Head have shown that the full range of magma compositions existing on the Earth is plausible under various environmental conditions on Venus. Most of the Venera and Vego lander compostional data are consistent with tholeiitic basalt; however, evidence for evolved magmas was provided by Venera 8 data consistent with a quartz monzonite composition. Pieters et al. have examined the color of the Venus surface from Venera lander images and interpret the surface there to be oxidized. Preliminary modeling of dome growth has provided some interpretations of lava rheology. Viscosity values obtained from these models range from 10(exp 14) - 10(exp 17) pa*s, and the yield strength has been calculated to be between 10(exp 4) and 10(exp 6) Pa, consistent with terrestrial silicic rocks. The apparent high viscosity of the dome lavas suggests that the domes have a silicic composition or must augment their viscosity with increased visicularity or crystal content. Sixty-two percent of the Venus domes are associated with coronae, circular features that have been proposed as sites of mantle upwelling, and 20 percent of the domes are located near tessera, relatively high areas of complex deformed terrain. We have investigated several models that are consistent with these geologic associations. The first case involves the differentiation of basalt in a magma reservoir in the crust, perhaps produced by partial melting within a mantle plume. The second case is melting at the base of thickened basaltic crust, and the final case is volatile exsolution and enhancement within a basaltic magma reservoir. The association of domes with tessera might be explained by crustal remelting, while the association with coronae may be consistent with chemical differentiation of a magma reservoir or the exsolution and concentration of volatiles in the reservoir before eruption.

Pavri, B.↗
NASA NTRS1992

Impact glasses from the less than 20-micrometer fraction of Apollo 17 soils 72501 and 78221

The chemical compositions of microscopic glasses produced during meteoroid impacts on the lunar surface provide information regarding the various fractionation processes that accompany these events. To learn more about these fractionation processes, we studied the compositions of submicrometer glass spheres from two Apollo 17 sampling sites using electron microscopy. The majority of the analyzed glasses show evidence for varying degrees of impact-induced chemical fractionation. Among these are HASP glasses (high-Al, Si-poor), which are believed to represent the refractory residuum left after the loss of volatile elements (e.g., Si, Fe, Na) from the precursor material. In addition to HASP-type glasses, we also observed a group of volatile-rich, Al-poor (VRAP) glasses that represent condensates of vaporized volatile constituents, and are complementary to the HASP compositions. High-Ti glasses were also found during the course of this study, and are documented here for the first time.

Norris, John A.↗
NASA NTRS1992

Cometary origin of carbon, nitrogen, and water on the earth

In this paper, two assumptions on the origin of the earth are substantiated: (1) that the earth accreted from fine hot degassed dust particles containing no volatiles; and (2) that, after the accretion was finished, all the volatiles of the biosphere, including the atmosphere and the oceans, were brought to the earth by cometary bombardment. A temperature of more than 1000 K is deduced at the time when the dust that was going to form the earth was separated from the gas phase. This implies grains of anhydrous silicates and of reduced iron, without either water, carbon, or any labile elements, which remained in gas phase; thus, the minor bodies could not produce atmosphere or oceans. The second assumption is based on the evidence that cometary nuclei are formed in the outer space, by accumulation of frosty particles containing large amounts of ice and volatile molecules. It is shown that the icy bodies which hit the earth are more than enough to explain the whole biosphere.

Delsemme, A. H.↗
NASA NTRS1991

A model of the evaporation of binary-fuel clusters of drops

A formulation has been developed to describe the evaporation of dense or dilute clusters of binary-fuel drops. The binary fuel is assumed to be made of a solute and a solvent whose volatility is much lower than that of the solute. Convective flow effects, inducing a circulatory motion inside the drops, are taken into account, as well as turbulence external to the cluster volume. Results obtained with this model show that, similar to the conclusions for single isolated drops, the evaporation of the volatile is controlled by liquid mass diffusion when the cluster is dilute. In contrast, when the cluster is dense, the evaporation of the volatile is controlled by surface layer stripping, that is, by the regression rate of the drop, which is in fact controlled by the evaporation rate of the solvent. These conclusions are in agreement with existing experimental observations. Parametric studies show that these conclusions remain valid with changes in ambient temperature, initial slip velocity between drops and gas, initial drop size, initial cluster size, initial liquid mass fraction of the solute, and various combinations of solvent and solute. The implications of these results for computationally intensive combustor calculations are discussed.

Harstad, K.↗
NASA NTRS1993

Vaporization by shock loading of albite, jadeite, and pyrex glass: Experimental study

Produced by shock experiments impact melts of albite, jadeite, and Pyrex glass demonstrate a loss of both Na and Al relative to Si, which can be due to selective vaporization. It is suggested that the high volatility of Al is related to volatility of a Na-Al compound of proposed NaAlO2 composition. The similar loss of Al and Na seems to be possible during tektite-forming processes. A degree of selective vaporization and modification of a melt chemical composition during impact processes is still poorly understood. The selective vaporization of some elements has been shown by shock experiments. The vaporization and condensation processes can take place in the lunar regolith. On this basis, there are hypotheses explaining differentiation of planetary bodies through the impact vaporization. On the other hand, studies of tektites, impact glasses, and lunar soils show that bulk compositions of impact melts are not modified significantly. In order to estimate degree of the vaporization during shock fusion, chemical compositions of experimentally produced impact melts were studied. We chose Al-containing compositions, because a high volatilization of Al during unequlibrated evaporization had been demonstrated.

Badjukov, D. D.↗
NASA NTRS1993

SXRF determination of trace elements in chondrule rims in the unequilibrated CO3 chondrite, ALH A77307

The concentrations of Ni, Cu, Zn, Ga, Ge, and Se in five chondrule rims in the CO3 chondrite ALH A77307 (3.0) using the synchrotron x-ray fluorescence (SXRF) microprobe at Brookhaven National Laboratory were determined. The data show that the trace element chemistry of rims on different chondrules is remarkably similar, consistent with data obtained for the major elements by electron microprobe. These results support the idea that rims are not genetically related to individual chondrules, but all sampled the same reservoir of homogeneously mixed dust. Of the trace elements analyzed Zn and Ga show depletions relative to CI chondrite values, but in comparison with bulk CO chondrites all the elements are enriched by approximately 1.5 to 3.5 x CO. The high concentrations of the highly volatile elements Se and Ga and moderately volatile Zn (1.5 to 2 x CO) in rims show that matrix is the major reservoir of volatile elements in ALH A77307.

Brearley, Adrian J.↗