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At least 1,009 records · Page 56

Characterization of Infrequent Samples from the Concentration, Storage, and Transfer Facility: H-Area Diversion Box 1 (HDB-1) Sump Sample: January 25, 2022 Sample

Savannah River Remediation Engineering (SRR-E) requested that the Savannah River National Laboratory (SRNL) analyze the Concentration, Storage, and Transfer Facility (CSTF) samples from the following Tank Farm areas: the sump encasement, catch tank, drain cell, and waste tank annulus. In general, these CSTF samples will be analyzed on an infrequent basis and analyses will include detection for total beta/gamma, total alpha activities, density, free hydroxide, and pH measurements. This report presents characterization results for the H-Area diversion box 1 sump (HDB-1) January 2022 sample. The sample was slightly brown with a small amount of suspended fine particulates visually estimated to be less than 1% by volume. The results are measurements for total gamma, total alpha, total beta, density, free hydroxide, and pH.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Predictive Contaminant Transport Simulation with P2R Model for the Composite Analysis Limited Source Sensitivity Case.

The Plateau to River (P2R) is a groundwater flow and contaminant fate and transport (F&T) simulation model used to support remedial activities conducted by the Central Plateau Cleanup Company at the Hanford Site in Washington State. Figure 1 illustrates the P2R Model extents, discretization, and boundary conditions. The P2R Model is utilized in the Composite Analysis (CA) for the Hanford Site as the computational engine for computing F&T predictions as described in CP-60406, Hanford Site Composite Analysis Technical Approach Description: Groundwater. The model simulates contaminants of concern within the saturated zone of the uppermost aquifer beneath the Central Plateau and downgradient to the Columbia River. CP-57037, Model Package Report for the Plateau to River Model Version 8.3 documents the current version of the P2R Model including a description of the conceptual site model, model development and calibration, and limitations to the model application. Simulations conducted to support the dose calculations required by the CA are documented in ECF-HANFORD-19-0119, Predictive Flow Simulation with the P2R Model for the Composite Analysis Base Case and ECF-HANFORD-19-0120, Contaminant Transport Simulation with the P2R Model for the Composite Analysis Base Case.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Consent Order Site Presentation For LANL Supplier Forum [Slides]

Consent Order Sites are contaminated and potentially contaminated sites in and around LANL that require further investigation and/or remediation. They are referred to as Solid Waste Management Units (SWMUs) and Areas of Concern (AOCs).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Summary of Results from Batch 1 Qualification Samples for Tank Closure Cesium Removal 1A (TCCR 1A)

Savannah River Remediation (SRR) is currently operating the Tank Closure Cesium Removal 1A (TCCR 1A) process to remove 137 Cs from tank waste supernate using an ion exchange process. As part of that process, Savannah River National Laboratory (SRNL) receives and analyzes samples in support of the qualification of each waste supernate batch to be processed. SRNL recently received supernate samples retrieved from Tank 10H as well as in-tank batch contact samples for characterization in support of qualifying Batch 1 for processing through the TCCR 1A unit.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The Future Role of Hydropower in the Northeastern United States: May 2020-May 2022

This paper explores the future role of hydropower in the Northeastern US and beyond. The intent is to provide experience-based insights into how hydropower can best support the reliable and economic evolution of the New England power system and, more broadly, all US grids. Many of the challenges facing New England are driven by the potential integration of 10s of GWs of variable energy resources. Hydro can assist in remediating several issues, and the paper explores how Hydro might hit above its weight in a future low carbon New England system. Hydro can assist in handling periods of over generation, reduce the risk of curtailment of zero carbon resources, improve market efficiency, and provide valuable essential reliability services.

13 HYDRO ENERGY↗

What is Water's Role in a Carbon Neutral Future? A Summary of Findings from a Webinar Series

There has been ever-growing interest and engagement regarding net-zero and carbon neutrality goals, with many nations committing to steep emissions reductions by mid-century. Although water plays critical roles in various sectors, there has been a distinct gap in discussions to date about the role of water in the transition to a carbon neutral future. To address this need, a webinar was convened in April 2022 to gain insights into how water can support or influence active strategies for addressing emissions activities across energy, industrial, and carbon sectors. The webinar presentations and discussions highlighted various nuances of direct and indirect water use both within and across technology sectors (Figure ES-1). For example, hydrogen and concrete production, water for mining, and inland waterways transportation are all heavily influenced by the energy sources used (fossil fuels vs. renewable sources) as well as local resource availabilities. Algal biomass, on the other hand, can be produced across diverse geographies (terrestrial to sea) in a range of source water qualities, including wastewater and could also support pollution remediation through nutrient and metals recovery. Finally, water also influences carbon dynamics and cycling within natural systems across terrestrial, aquatic, and geologic systems. These dynamics underscore not only the critical role of water within the energy-water nexus, but also the extension into the energy-watercarbon nexus.

54 ENVIRONMENTAL SCIENCES↗

Big Hill Geomechanical Analysis Using M-D Viscoplastic Material Model

The integrity of wellbores at the interbed between the caprock and salt is a serious concern in the Big Hill site. For the remediation and life extension of wellbores, more accurate predictions from the global model are needed. The Big Hill global model is improved using the M-D viscoplastic contact surface model and the mesh containing the interbed layer with contact surfaces between the salt and caprock layers, and fault blocks in overburden and caprock layers. The model calibration has been performed based on the cavern volumetric closures obtained from the Caveman calculations. The results agree well from 1991 to the early 2000s. The difference starts to widen after that, it might be because of frequent fluid movement and raw water injection. Therefore, the predictions from this improved model could be used to examine the structural integrity of caverns in Big Hill salt dome.

42 ENGINEERING↗

A Comprehensive Survey of Coal Ash Law and Commercialization: Its Environmental Risks, Disposal Regulation, and Beneficial Use Markets

This white paper was commissioned by the National Association of Regulatory Utility Commissioners (NARUC) under a grant from the U.S. Department of Energy (DOE), in response to a major rule, Hazardous and Solid Waste Management System; Disposal of Coal Combustion Residuals From Electric Utilities; Final Rule (Final Rule) issued by the U.S. Environmental Protection Agency (EPA) on April 17, 2015, on coal ash disposal and remediation of disposal sites, which has significant implications to states. It subjects state environmental agencies and public utility commissions to regulatory responsibilities to implement federal regulations under the Final Rule and oversee the cost implications on electric customers. To better evaluate the regulatory issues underlying the choices facing utilities and independent power producers (IPPs) regarding coal ash management options under the Final Rule, an overview of coal ash production and disposal practices is helpful. This comprehensive survey provides background information on the following topics: (a) coal ash production by a coal combustion generation plant, (b) the historical practices of utility waste management practices, (c) coal ash toxicity and related constituents, (d) further understanding of potential impacts to groundwater, and (e) the aging structures and outdated designs of coal ash surface impoundments and landfills.

01 COAL, LIGNITE, AND PEAT↗

Analysis of Defense Waste Processing Facility Sample: Recycle Collection Tank Sample Batch 4945

The Savannah River National Laboratory (SRNL) was requested by Savannah River Remediation (now Savannah River Mission Completion (SRMC)), through a Technical Task Request, to characterization the “as-received” Recycle Collection Tank (RCT) Sample identified as sample batch 4945 [Sludge Receipt and Adjustment Tank (SRAT) batch 796)], which was delivered to SRNL Shielded Cells on January 28, 2021. The RCT characterization data will be used as input to the Defense Waste Processing Facility (DWPF) Recycle Diversion Project. This RCT report is the first of three sample characterization reports that will be used for this DWPF Project. The other DWPF reports will involve the characterization of the Off-Gas Condensate Tank (OGCT) and the Slurry Mix Evaporator Condensate Tank (SMECT) samples.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Analysis of Defense Waste Processing Facility Sample: Off-Gas Condensate Tank Sample Batch 27862

The Savannah River National Laboratory (SRNL) was requested by Savannah River Remediation (now Savannah River Mission Completion (SRMC)), through a Technical Task Request (X-TTR-H-00107), to characterize the “as-received” Off-Gas Condensate Tank (OGCT) Sample identified as sample batch 27862, which was delivered to SRNL Shielded Cells on April 30, 2021. This OGCT report is the third of three sample characterization reports dealing with this Defense Waste Processing Facility (DWPF) Recycle Diversion Project. The other two recycling stream characterization reports are the Recycle Collection Tank (RCT) and the Slurry Mix Evaporator Condensate Tank (SMECT) sample report.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Analysis of Defense Waste Processing Facility Sample: Slurry Mix Evaporator Condensate Tank Sample Batch 4638

The Savannah River National Laboratory (SRNL) was requested by Savannah River Remediation (SRR, now Savannah River Mission Completion (SRMC)), through a Technical Task Request, to characterization the “as-received” Slurry Mix Evaporator Condensate Tank (SMECT) sample identified as sample batch 4638, which was delivered to SRNL Shielded Cells on March 19, 2021. The SMECT characterization data will be used as input to the Defense Waste Processing Facility (DWPF) Recycle Diversion Project. This SMECT report is the second of three sample characterization reports that will be used for this DWPF Project. The other two DWPF characterization reports involve the characterization of the Recycle Collection Tank (RCT) sample and the future Off-Gas Condensate Tank (OGCT) characterization report.

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Floating Island International PHASE I FINAL TECHNICAL REPORT (Advancing the Development of Floating Solar-Powered Nanobubble Aeration Systems for Use with Floating Treatment Wetlands in Natural and Man-Made Waterbodies)

More and more freshwater lakes are suffering from algae blooms, which deprive water of oxygen and lead to widespread loss of aquatic life and production of dangerous toxins. When oxygen is lacking, methane is generated in the sediments as algae is decomposed; it has been calculated that more than half of global methane emissions come from nutrient-impaired freshwater systems (Beaulieu, 2021). Nutrients, mainly from agricultural run-off, feed algae blooms and are exacerbated by warming related to climate change. Artificial aeration is frequently used to restore oxygen to a waterbody. But diffuser aeration is inefficient and expensive, needs on-site grid power, and is failing to keep pace with the demands of water as it gets warmer with climate change. In the last five years, nanobubble aeration has been introduced into freshwater applications and shows promise for rapidly increasing dissolved oxygen effectively throughout the water column. Nanobubbles deliver oxygen in bubbles that have no buoyancy, so they stay in water longer and release their oxygen more fully, compared to large bubbles that rise and burst at the surface. The prospect of this new technology answering the deficiencies of diffuser aeration drove us to initiate the current project. During our Phase I period, we have successfully tested a nanobubble aeration system that can super-saturate oxygen levels. It is operated on solar power, and both the nanobubbler and solar array are mounted on a proprietary floating island platform, that also performs biological nutrient recycling. A rudimentary system was assembled and tested on a 6.5-acre research lake at our headquarters in Montana, where it was subjected to a summer drought that reduced water levels significantly, periods of severe cold in winter, and spring conditions that included heavy rainfall and violent thunderstorms. Our twice-weekly sampling throughout the project showed that dissolved oxygen levels rose rapidly and were maintained throughout winter and spring, well into June. The nanobubbler was able to run on solar power for long periods. Methane levels were tested periodically and found to decrease as oxygen increased. The nanobubbles appeared to have no adverse impact on fish or other aquatic life exposed to them. The stability of the installation survived the weather conditions. The many problems we encountered taught us what we need to improve in the next iteration. Towards the end of our Phase I, we were awarded a supplementary state grant that enabled us to acquire a new nanobubble system for testing that runs on DC, is extremely efficient and has few moving parts. We plan to team this with low-profile solar panels, lithium batteries and a controller that provides real-time data. The ultimate goal of this project is to commercialize an affordable and scalable lake management system that will oxygenate water from the surface down to the sludge. It will enliven fisheries, prevent toxic algae blooms and – most importantly for the fate of our planet - inhibit the production and release of methane from the sediments. We anticipate that as carbon credits expand to include methane, the cost of remediating waterbodies that produce methane will be offset. We firmly believe that this is a practical technology that works and will make a big difference when fully implemented.

14 SOLAR ENERGY↗

Harnessing Condorcet Methods to Improve Decision-making Based on Ranked Data

Decision-makers must often choose between multiple alternatives based on their relative merits across a variety of criteria. These multiple-criteria decision-making (MCDM) problems must be approached in an objective, measurable, and transparent fashion to obtain well-supported outcomes. The challenge of using sets of ranked data to identify the optimal choice is not unlike the challenge of using ranked ballots to identify the winner of an election in a preference voting system. As such, the methods of rank aggregation used in elections can be applied to help resolve MCDM problems. Previous research into the design of elections and ballots has yielded many algorithms with well-understood properties. A subset of these, called Condorcet methods, reliably identify the “Condorcet winner,” if it exists, giving the result that would defeat any other in a pairwise comparison. That, in addition to several other desirable qualities, makes Condorcet methods like the Schulze method, Ranked Pairs, and Copeland’s method, effective and scalable means for tackling MCDM problems. These rank aggregation methods have been implemented in JavaScript functions for incorporation into a web-based MCDM decision tool. These algorithms can be applied in a wide variety of contexts (for example, determining the “best” environmental remediation method or selecting a subcontractor) to facilitate effective decision-making. The performance of the JavaScript Condorcet prototype tool was compared across the implemented algorithms and with both a non-Condorcet rank aggregation method as well as an implementation of the Simple Multi-Attribute Rating Technique (SMART) algorithm.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Multi-pronged approach to improving carbon utilization by cyanobacterial cultures

The goal of this project was to increase the efficiency of carbon utilization by a Synechocystis biofuel production strain in a photobioreactor system by at least 50% using a multi-pronged approach that combined the best features of both biological and physicochemical CO 2 capture technologies to: 1) increase rates and extent of CO 2 absorption into the culture medium by addition of biocompatible amine solvents and a nanobubble gas delivery system, and 2) increase cellular rates of inorganic carbon uptake and carbon fixation through genetic engineering. In addition, the project plan included evaluating the use of fermentation effluent gases as a CO 2 source and demonstrating performance under outdoor conditions in closed-pond photobioreactor systems. These combined efforts would be guided by integrated technoeconomic and life-cycle analyses. Both physicochemical CO 2 capture technologies explored proved to be successful. The amine solvent monoethanolamine (MEA) was found to be biocompatible with a Synechocystis laurate production strain. Using an adaptive evolution strategy, an MEA-tolerant laurate production strain was developed that showed significantly increased carbon utilization over the parent strain. To our knowledge this was the first time nanobubble (NB) technology had been used as a carbon delivery system for algae production and it also proved quite successful as a proof of concept. Solutions containing CO 2 nanobubbles (Nano-BG11) at concentrations significantly higher than the aqueous CO 2 concentrations achieved with gas sparging were successfully generated and characterized with regard to bubble size (nm), concentration (NB/L), and pH stability as per project plan. Growth studies proved challenging. However, once the source of a puzzling growth defect was found and remedied Synechocystis was able to grow somewhat better in Nano-BG11 than in standard BG11 medium.

09 BIOMASS FUELS↗

Fundamental U235 Nuclear Resonance Spectroscopy (FY2022 LDRD End of Year Report)

Enriched uranium (U-235) is ubiquitous in the nuclear industry yet many of its fundamental properties have never been studied using magnetic resonance. To remedy this we built a high frequency nuclear quadrupole resonance spectrometer that is capable of measuring the very high quadruple resonance signals of U-235.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Summary of Savannah River Site FY21 Salt Waste Qualification Data and Characterization Data from Salt Waste Batches Processed Since 2008

The Savannah River National Laboratory analyzed samples from Savannah River Site Waste Tank 41H and 21H to support qualification of Salt Waste Processing Facility Waste Batches 3 and 4 (the FY21 Salt Batch Qualification samples) for processing. Neither of the samples displayed any unusual or unexpected characteristics such as large amounts of solids, floating solids, or unusual color. Characterization of these samples confirmed similar chemical composition and characteristics to previous salt waste batches. These results were initially provided to Savannah River Remediation (Liquid Waste Operations Sub-contractor) as External Sample Results LIMS Reports. The analytical results (both expedited and routine) are now summarized and discussed in this technical report.

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SCALE Calculations Replicating ARH-600 Data

This report documents Standardized Computer Analyses for Licensing Evaluation (SCALE) calculations replicating data from the ARH-600 criticality handbook. These calculations complement those reproduced with MCNP in PRC-NS-00009. Calculations were performed with SCALE version 6.1, using the v7-238 cross section library. The original ARH-600 data were calculated by the Atlantic Richfield Hanford (ARH) Company starting in the 1960s, and Monte Carlo N-Particle (MCNP) calculations were performed by the Hanford Plateau Remediation Company in 2010. This report is not intended to replace final analysis of fissile systems by qualified criticality personnel.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

2021 Annual Site Environmental Report

This report provides the U.S. Department of Energy (DOE) and the public with information on the level of radioactive and non-radioactive pollutants (if any) that are added to the environment as a result of Princeton Plasma Physics Laboratory’s (PPPL) operations. The results of PPPL’s 2021 environmental surveillance and monitoring program are presented and discussed. The report also summarizes environmental initiatives, assessments, and community involvement programs that were undertaken in 2021. PPPL’s on-site operations were significantly curtailed in 2021 due to the global coronavirus pandemic. PPPL has engaged in fusion energy research since 1951. The Laboratory’s mission is to develop the scientific knowledge and advanced engineering to enable fusion to power the U.S. and the world, and to developing the understanding of plasmas from the nano- to the astrophysical scale. PPPL’s primary experiment, the National Spherical Torus Experiment-Upgrade (NSTX-U) is a collaboration among national laboratories, universities, and national and international research institutions and is a major element in the US Fusion Energy Sciences Program. Its design tests the physics principles of spherical torus (ST) plasmas, playing an important role in the development of smaller, more economical fusion reactors. Due to previous operational issues, NSTX-U did not operate in 2021. PPPL is engaged in a project to replace key NSTX-U components and systems to enable operation of this international fusion user facility. In 2021, PPPL’s radiological environmental monitoring program measured tritium in the air at the NSTX-U Stack and at onsite sampling stations. Using highly sensitive air monitors, PPPL is capable of detecting small changes in the ambient levels of tritium. The operation of an in-stack monitor located on D-site is used to demonstrate compliance with the National Emission Standard for Hazardous Air Pollutants (NESHAPs) regulations. Also included in PPPL’s radiological environmental monitoring program, are water monitoring – ground, surface, and waste waters. PPPL’s radiological monitoring program characterized the background levels of tritium in the environment and those data are presented in this report. Ground water monitoring continued under New Jersey Department of Environmental Protection’s (NJDEP) Site Remediation Program regulations. PPPL monitored for non-radiological contaminants, mainly volatile organic compounds (components of common degreasing solvents). In 2021, PPPL complied with permit limits for surface and sanitary discharges. PPPL was honored with awards for EPEAT-certified electronics purchasing and use of peracetic acid as an alternative water treatment chemical in its non-potable process water systems an NJDEP recycling award.

54 ENVIRONMENTAL SCIENCES↗