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Radiation Characteristics of Reflectarray Antennas: Methodology and Applications to Dual Configurations

Reflectarrays combines key features of large reflectors and phased array elements to generate a collimated beam as required in high gain antennas. In reflectarrays, a large flat reflecting surface with many resonant patch elements is illuminated by a feed (or by a feed/subreflector in dual reflector configuration). In many space applications, reflectarrays applications can be advantageous because their large surface can be folded or rolled as a part of spacecraft payload before being deployed. Consequently, a reflectarray can significantly reduce both volume and mass requirements in space deployment. To optimize reflectarray antenna performance, a phase correction mechanism must be applied to its individual array elements some of which are well documented in the literatures. In this study, we attempt to extend analytical techniques in reflector analysis to reflectarrays by introducing a number of approaches to estimate the reflectarray antenna performance independent of its phase compensation mechanism. In one approach, a Physical Optics (PO) current will be assigned to the surface of individual reflectarray elements upon which a phase correction will be applied. In the second approach, a transmit/receive (TX/RX) radiation characteristics will be assigned to individual reflectarray elements from which coupling coefficients will be calculated and assigned as the excitation coefficient of individual elements. PO approach is modeled in the UCLA reflector code while coupling (TX/RX) method is implemented in both UCLA code as well as TICRA (GRASP) software. Results are presented for single and dual configurations with the main reflector as a reflectarray. The approach described is used to design a 3-m Cassegrain offset-fed configuration for dual X/Ka-bands application.

reflectors↗

Ten Years of SNPP VIIRS Reflective Solar Bands On-Orbit Calibration and Performance

The Visible Infrared Imaging Radiometer Suite (VIIRS) onboard the Suomi National Polar-orbiting Partnership (SNPP) has successfully operated on-orbit for nearly ten years since its launch in October 2011, continuously making global observations and improving studies of changes in the Earth’s climate and environment. VIIRS has 22 spectral bands, among which 14 are reflective solar bands (RSBs) covering a spectral range from 0.41 to 2.25 μm. The SNPP VIIRS RSBs are primarily calibrated by the onboard solar diffuser (SD), with its on-orbit degradation tracked by an onboard SD stability monitor (SDSM). The near-monthly scheduled lunar observations, together with the sensor responses over stable ground targets, have contributed to the sensor’s mission-long on-orbit calibration and characterization. Numerous improvements have been made in the RSB calibration methodology since SNPP VIIRS was launched, and the RSB calibration has reached a mature stage after almost ten years of on-orbit operation. SNPP is a joint NASA/NOAA mission and there are two teams, the NASA VIIRS Calibration Support Team (VCST) and the NOAA VIIRS Sensor Data Record Team, which are dedicated to SNPP VIIRS on-orbit calibration. In this paper, we focus on the calibration performed by the NASA VCST. The SNPP VIIRS RSB calibration methodologies used to produce the calibration coefficient look up tables for the latest NASA Level 1B Collection 2 products are reviewed and the calibration improvements incorporated in this collection are described. Recent calibration changes include the removal of image striping caused by non-uniform degradation of the SD, improvements to the method for combining lunar and SD data, mitigation of the effects due a recent anomaly in the SD measurements, estimation of the SD degradation beyond 935 nm, and fitting strategy improvements for look-up table delivery. Overall, the SNPP VIIRS RSBs have performed well since its launch and continue to meet design specifications.

SNPP↗

Tropospheric Delay Signal in SAR Interferogram and its Correction for Precise Surface Change Detection

Synthetic Aperture Radar (SAR) interferometry has become an important tool for measuring the surface deformation and mapping topography. The largest error source of the SAR interferometry measurements is differential atmospheric delay of water vapor. It reflects detailed distribution of water vapor in troposphere at data acquisition. We found phase difference associated with atmospheric waves and severe local atmospheric phenomena in interferograms. To distinguish phase difference associated with surface deformation from tropospheric effect, we need several SAR interferograms including the time period of the deformation. Averaging the interferograms is an effective way to reduce the tropospheric delay from horizontal inhomogeneity of the water vapor distribution. Apart from the tropospheric delay of the horizontal water vapor inhomogeneity, we often find the differential phase correlated to the topography (elevation) in interferograms, which might cause error in interpretation of surface deformation. This phase is due to the differential tropospheric delay caused by the topography and vertical change of water vapor between two images in different atmospheric condition. Theoretical calculation shows that the phase difference can be approximated by linear expression of the elevation. We applied a simple and effective correction method that the error is removed by subtracting the DEM (Digital Elevation Model) multiplied a coefficient.

Fujiwara, Satoshi↗

Predicting Cell Death and Mutation Frequency for a Wide Spectrum of LET by Assuming DNA Break Clustering Inside Repair Domains

The high relative biological effectiveness (RBE) of high charged and energy (HZE) particles for cell death, DNA mutations and cancer remain based on experimental data. In this work, we propose that the existence of DNA repair domains is sufficient to predict both cell death and mutation frequencies for any LET by only taking into account experimental data from low-LET, offering one mechanism for RBE across LET. We hypothesize that whenever multiple DNA double-strand breaks (DSBs) are generated within the same DNA repair domain, DSBs are actively regrouped for more efficient repair [1]. This hypothesis has been supported by the low-LET sublinear dose response observed at doses greater than ~1Gy for 53BP1 radiation-induced foci (RIF) reflecting increasing DSB/RIF with dose [2]. Previously, we modeled radiation-induced cell death of human breast cells by first inferring the size of these domains from the dose dependence of low-LET RIF, and by associating a lethality factor to the number of pairs of DSBs in each RIF [1]. In this work, we first integrate the new NASA computer models RITCARD (Relativistic Ion Tracks, Chromosome Aberrations, Repair, and Damage) [3] and BDSTracks (Biological Damage by Stochastic Tracks) for a more accurate microdosimetry and a better model of the nuclear organization to predict the location of DSBs. A large array of particles and energy are simulated, covering more than three orders of magnitude for LET (~1-1000 keV/µm). Next, we extend our previous model to predict mutation frequencies by assuming that clustered DSBs increase mutation probability, which is formalized by the mutation frequency being linearly dependent on both the number of DSBs and the number of pairs of DSBs inside individual RIF. Linear coefficients are estimated so that simulations predict accurately mutation frequencies observed in Chinese hamster cells exposed to low-LET. Keeping these coefficients unchanged, we then predict mutation frequencies induced by HZE by simulating DSBs and obtain RBEs for mutations and cell death following the expected experimental bell shape for LET dependence. We also observe an orientation effect that needs to be confirmed, showing different RBE depending on the angle of the HZE beam hitting the main axis of the cell.

Plante, Ianik↗

Spectral Emittance and Reflectance Measurements at the Jet Propulsion Laboratory

In late 1959 a spectrophotometer laboratory was established at JPL to be used as a support for temperature-control programs. The immediate task was spectroradiometric measurements of light sources to be used in a simulated-deep-space environment chamber. It was also necessary to have permanent provisions for measuring reflectances of surfaces for the calculation of solar absorptance alpha, and thermal emittance epsilon. The spectral distribution of an unknown source, in this case a Ventarc carbon-arc lamp, was derived from the ratio of detector outputs (with monochromatic light) of the arc lamp and a tungsten lamp, and the spectral intensity of the tungsten lamp. The tungsten lamp is a ribbonfilament lamp calibrated from 0.25 to 2.6 microns. A recording of pen deflection (linearly proportional to detector output) of each source over the visible and near infrared range is made with all parameters (slit width, amplifier gain, and source focusing) identical; then the ratios are computed at discrete wavelengths from these recordings. Because the spectral intensities of the tungsten lamp and a solar simulator are very different in most of the range, an adjustable slit is placed immediately in front of the detector to obtain comparable pen deflections for the two sources. This slit is set by means of a feeler gage, and the attenuation coefficient is evaluated by a transmission measurement.

Maclay, James E.↗

Characterization of Damage Progression in SCS-6/timetal 21S (0)4 Under Thermomechanical Fatigue Loadings

A detailed experimental investigation was performed at a single maximum cyclic stress (sigma max) level to physically characterize the progression of thermomechanical fatigue (lW) damage in continuously reinforced (0 deg) SCS-6/Timetal 21S, a titanium matrix composite. In-phase (IP) and out of-phase (OP) loadings were investigated at sigma max = 1000 MPa with a temperature cycle from 150 to 6500 C. Damage progression, in terms of macroscopic property degradation, was experimentally quantified through an advanced TMF test methodology which incorporates explicit measurements of the isothermal static moduli at the TMF temperature extremes and the coefficient of thermal expansion (CTE) as functions of the TMF cycles. Detailed characterization of the physical damage progression at the microstructural level was performed by interrupting multiple TMF tests at various stages of mechanical property degradation and analyzing the microstructure through extensive destructive metallography. Further, the extent of damage was also quantified through residual static strength measurements. Results indicated that damage initiation occurred very early in cyclic life (N less than 0.1Nf) for both the IP and OP TMF loadings. IP TMF damage was found to be dominated by fiber breakage with a physical damage progression in the microstructure which was difficult to quantify. OP TMF loadings produced matrix cracking exclusively associated with surface initiations. Here, damage progression was easily distinguished in terms of both the number of cracks and their relative inward progressions toward the outer fiber rows with increased cycling. The point at which the leading cracks reached the outer fiber rows (when localized fiber/matrix de-bonding and matrix crack bridging occurred) appeared to be reflected in the macroscopic property degradation curves.

Castelli, Michael G.↗

The stability of hibonite and other aluminous phases in silicate melts: Implications for the origin of hibonite-bearing inclusions

Phase fields in which hibonite (Hib) and silicate melt coexist with spinel (Sp), CaAl4O7 (CA2), gehlenitic melilite (Mel), anorthite (An), or corundum (Cor) in the system CaO-MgO-Al203-SiO2-TiO2 (CMAST) were determined and activity models developed for Mel and Hib solid solutions. Experimentally determined partition coefficients for Ti between Hib and coexisting melt, D sub t, vary from 0.8 to 2.1 and generally decrease with increasing TiO2 content in the liquid (L). Based on Ti partioning between Hib and melt, bulk inclusion compositions and Hib-saturated liquid use phase diagrams, the Hib in Fluffy Type A inclusions (FTA's) from Allende and at least some of the Hib from Hib-rich inclusions is relict; much of the Hib from Hib-glass spherules probably crystallized from a melt under nonequilibrium conditions. Bulk compositions for all of these Ca-Al-rich inclusions (CAI's) are consistent with an origin as Mel + Hib + Sp + perovskite (Pv) proto-inclusions in which Mel was partially altered. In some cases, the proto-inclusion was partially or completely melted with vaporization occurring over a period of time sufficient to remove any Na introduced by the alteration process but frequently insufficient to dissolve all of the original hibonite. If equilibration temperatures based on Hib-bearing CAI's reflect condensation in a cooling gas of solar composition, then Hib + Cor condensed at approximately 1260 C (referenced to 10 exp -3 atm) and Hib + Sp + Mel at approximately 1215 +/- 10 C. Simple thermochemical models for the substitution of trace elements into the Ca-site of meteoritic Hib suggest that virtually all Eu is divalent in early condensate Hibs but that Eu(2+)/Eu(3+) decreases by a factor of 20 or more during the course of condensation, primarily because the ratio is proportional to the partial pressure of Al, which decreases dramatically as aluminous phases condense. The relative sizes of Eu and Yb anomalies in meteoritic Hibs and CAI's may be influenced by this effect.

Beckett, J. R.↗

Parameterization of the Vertical Variability of Tropical Cirrus Cloud Microphysical and Optical Properties

Cloud Integrating Nephelometers (CIN) were flown on the U. North Dakota Citation aircraft and the NASA WB-57 aircraft for the purpose of measuring in-situ the optical extinction coefficient and the asymmetry parameter (g) at a wavelength of 635 nm of primarily ice particles encountered during the NASA CRYSTAL-FACE study of large cumulus clouds (Cu) and their anvils found in the southern Florida region. The probes performance was largely successful and produced archived data for vertical profiles of extinction, asymmetry parameter, and effective radius (Re), the latter being obtained by combining CIN and CVI (total water; Oregon State U.) measurements. Composites of the CIN and CVI data describing the average microphysical and optical behavior of the Cu and their anvils showed the following: The extinction increases with height as a result of the size of the particles also decreasing with height as shown by the Re measurements; near the top of anvils the size of the primary ice particles is about 10-um radius; and the value of g does not vary significantly with height and has a mean value of about 0.73 consistent with the idea that ambient ice crystals are primarily of complex shape and reflect solar radiation more efficiently than particles of pristine crystal shape. Other observations include: The g measurements were found to be an indicator of the phase of the cloud permitting identification of the clouds with water droplets, rain, and ice; visual ranges as small as several tens of meters were occasionally found in "extinction cores" that coincided with strong updraft cores; and comparison of the cloud probes on the Citation showed significant disagreement.

Gerber, Hermann E.↗

Damage accumulation in closed cross-section, laminated, composite structures

The need for safe, lightweight, less expensive, and more reliable launch vehicle components is being driven by the competitiveness of the commercial launch market. The United States has lost 2/3 of the commercial lunch market to Europe. As low cost Russian and Chinese vehicles become available, the US market share could be reduced even further. This international climate is driving the Single Stage To Orbit (SSTO) program at NASA. The goal of the SSTO program is to radically reduce the cost of safe, routine transportation to and from space with a totally reusable launch vehicle designed for low-cost aircraft-like operations. Achieving this goal will require more efficient uses of materials. Composite materials can provide this program with the material and structural efficiencies needed to stay competitive in the international launch market place. In satellite systems the high specific properties, design flexibility, improved corrosion and wear resistance, increased fatigue life, and low coefficient of thermal expansion that are characteristic of composite materials can all be used to improve the overall satellite performance. Some of the satellites that may be able to take advantage of these performance characteristics are the Tethered Satellite Systems (TOSCIFER, AIRSEDS, TSS2, SEDS1, and SEDS2), AXAF, GRO, and the next generation Hubble Space Telescope. These materials can also be utilized in projects at the NASAIMSFC Space Optics Technology and System Center of Excellence. The successful implementation of composite materials requires accurate performance characterization. Materials characterization data for composite materials is typically generated using flat coupons of finite width. At the free edge of these coupons the stress state is exacerbated by the presence of stiffness and geometric discontinuities. The exacerbated stress state has been shown to dominate the damage accumulation in these materials and to have a profound affect on the material constants. Space structures typically have closed cross-sections, absent of free edges. As a result, composite material characterization data generated using finite width flat specimens does not accurately reflect the performance of the composite materials used in a closed cross-section structural configuration. Several investigators have recognized the need to develop characterization techniques for composite materials in closed cross-sectioned structures. In these investigations test methods were developed and cylindrical specimens were evaluated. The behavior of the cylindrical specimens were observed to depart from behavior typical of flat coupons. However, no attempts were made to identify and monitor the progression of damage in these cylindrical specimens during loading. The identification and monitoring of damage is fundamental to the characterization of composite materials in closed cross-section configurations. In the study reported here, a closed cross-sectioned test method was developed to monitor damage progression in 2 in. diameter cylindrical specimens and 1.5 in. finite width flat coupons subjected to quasi-static, tensile loading conditions. Damage in these specimen configurations was monitored using pulse echo ultrasonic, acoustic emission, and X-ray techniques.

Bucinell, Ronald B.↗

Laser Time-of-Flight Mass Spectrometry for Space

A miniature reflection time-of-flight mass spectrometer for in situ planetary surface analysis is described. The laser ablation mass spectrometer (LAMS) measures the regolith's elemental and isotopic composition without high-voltage source extraction or sample preparation. The compact size (< 2 x 10(exp 3) cubic cm) and low mass (approximately 2 kg) of LAMS, due to its fully coaxial design and two-stage reflectron, fall within the strict resource limitations of landed science missions to solar system bodies. A short-pulse laser focused to a spot with a diameter approximately 30-50 micrometers is used to obtain microscopic surface samples. Assisted by a microimager, LAMS can interactively select and analyze a range of compositional regions (with lateral motion) and with repeated pulses can access unweathered, subsurface materials. The mass resolution is calibrated to distinguish isotopic peaks at unit masses, and detection limits are on resolved to a few ppm. The design and calibration method of a prototype LAMS device is described, which include the development of preliminary relative sensitivity coefficients for major element bulk abundance measurements.

Brinckerhoff, W. B.↗

Effects of Natural Variability on the Use of Standard Deviation to Represent Measurement Uncertainties in Atmospheric Composition Studies

Measurement uncertainty is defined as a “non-negative parameter characterizing the dispersion of the quantity values being attributed to a measurand”. It is most common that the uncertainties of GAW hourly measurements, such as greenhouse gas measurements, are reported as standard deviations derived from individual sampling at a higher time resolution (e.g., 1 min). In contrast, the uncertainties of GAW measurements of reactive gases and aerosol properties are reported in percentiles covering the same probability. A quick look at hourly CO 2 data from Cape Grim, Australia yielded some interesting findings: the hourly standard deviation is, on average, more than a factor of 10 higher for the measurements under non-background conditions (over 50% observations), while the difference in average CO 2 amount fraction was less than 2 ppm. The dramatic contrast cannot be explained by the difference in measurement uncertainties, but can largely be attributed the natural variability, or episodic ambient CO 2 variation reflecting changes in meteorological conditions or emissions. These initial findings motivated a more in-depth analysis of the ground-based measurements of trace gases and aerosol properties. This analysis will be using continuous 1 min ground site observations to construct time averaged statistical indicators to evaluate whether the standard deviation is adequate to represent the dispersion, especially under marked influence by natural variability. The suitability of this representation can be determined by examining the difference between the standard deviation and percentiles encompassing the same probability. We will examine time intervals of 1 hour, 3 hours, and 24 hours, with the latter time intervals chosen to match those commonly used in model assessments. We will also investigate how natural variability can alter the probability distribution of the measurands and how adequate the quadrature propagation of uncertainties is under these conditions. The results will include several trace gases (e.g., CO 2 , CO, O 3 , and NO 2 ) with a range of measurement techniques (e.g., PANDORA, in situ), atmospheric lifetimes, and aerosol properties (e.g. scattering coefficient). The findings from this analysis should provide some useful feedback on the best practices for uncertainty reporting.

Measurement Uncertainty↗

Measured microwave emission and scattering in vegetation canopies

Reflecting metal screens were placed beneath vegetation of three types to allow measurement of the brightness temperature of the vegetation cover alone. A two-frequency radiometer (wavelengths: 11.1 and 5.88 cm) was used to measure the emission from the vegetation, and a theoretical model involving a loss term and a scattering albedo was fitted to the measured temperatures. Passive and active microwave measurements were also made on fields immediately adjacent to the 'screened' fields. Emission and backscattering were measured for these fields under two conditions: with full vegetation cover, and with vegetation removed. Using the same theoretical model and the calculated values for absorption and scattering derived from the screened fields, the effect of the vegetation cover on the soil emission was predicted. The predicted full-canopy temperatures were then compared to those measured. The values for loss and scattering in the vegetation canopy were used in another model to predict the effect of vegetation on backscattering from the soil surface. Again, the predicted backscattering from the vegetation canopy was compared with the measured values of the backscattering coefficient.

Brunfeldt, D. R.↗

The Analysis of Using Satellite Soil Moisture Observations for Flood Detection, Evaluating Over the Thailand’s Great Flood of 2011

A flood monitoring and warning system provides critical information that can protect property and save lives. A basin-scale flood monitoring system requires an effective observation platform that offers extensive ground coverage of flood conditions, low latency, and high spatiotemporal resolution. While satellite imagery offers substantial spatial flood extent in detail due to its high spatial resolution, the coarse temporal resolution and cloud obstruction limit its near real-time application. Daily soil moisture data derived from satellite sensors at a scale of a few km can be used to monitor extreme wet surface conditions arising in flood occurrences. This study analyses the flood detection capabilities of several sources of soil moisture information, including the Soil Moisture and Ocean Salinity mission (SMOS), the Advanced Microwave Scanning Radiometer on EOS (AMSR-E), the Advanced SCATterometer (ASCAT) on MetOp, the Global Land Data Assimilation System (GLDAS), and the WaterGAP Global Hydrology Model (WGHM). In addition to soil moisture, the analysis includes measurements of surface reflectance from the Moderate Resolution Imaging Spectroradiometer (MODIS), precipitation measurements from the Tropical Rainfall Measuring Mission (TRMM), and terrestrial water storage estimates from the Gravity Recovery And Climate Experiment (GRACE) as proxies for flood inundations. The analysis was conducted over the Chao Phraya River Basin (CPB) in Thailand, where the Great Flood of 2011 led to one of the most significant economic losses in the country's history. Satellite-derived soil moisture exhibits a stronger correlation with the flood inundations than the precipitation, model-derived soil moisture, and terrestrial water storage data. SMOS soil moisture observation agrees best with the MODIS-derived flood extent/occurrence, both in terms of spatial distribution and timing, and providing approximated flood lead-time of one week or longer. A neural network constructed from SMOS and MODIS data is used to predict flood intensity/occurrence (given soil moisture input) with a predicted time window from eight days to thirty-two days. The short-term prediction (e.g., eight days) achieves the highest accuracy with an averaged recovery rate of approximately 60% (correlation coefficient). This study's results suggest a potential application of satellite soil moisture data in assisting flood monitoring and warning systems.

Satellite soil moisture↗

Improving Satellite Global Chlorophyll a [alpha] Data Products Through Algorithm Refinement and Data Recovery

A recently developed algorithm to estimate surface ocean chlorophyll a concentrations (Chl in milligrams per cubic meter), namely, the ocean color index (OCI) algorithm, has been adopted by the U.S. National Aeronautics and Space Administration to apply to all satellite ocean color sensors to produce global Chl maps. The algorithm is a hybrid between a band‐difference color index algorithm for low‐Chl waters and the traditional band‐ratio algorithms (OCx) for higher‐Chl waters. In this study, the OCI algorithm is revisited for its algorithm coefficients and for its algorithm transition between color index and OCx using a merged data set of high‐performance liquid chromatography and fluorometric Chl. Results suggest that the new OCI algorithm (OCI2) leads to lower Chl estimates than the original OCI (OCI1) for Chl less than 0.05 milligrams per cubic meter, but smoother algorithm transition for Chl between 0.25 and 0.40 milligrams per cubic meter. Evaluation using in situ data suggests that similar to OCI1, OCI2 has significantly improved image quality and cross‐sensor consistency between SeaWiFS (Sea-viewing Wide Field-of-view Sensor), MODISA (Moderate Resolution Imaging Spectroradiometer on Aqua), and VIIRS (Visible Infrared Imaging Radiometer Suite) over the OCx algorithms for oligotrophic oceans. Mean cross‐sensor difference in monthly Chl data products over global oligotrophic oceans reduced from approximately 10 percent for OCx to 1-2 percent for OCI2. More importantly, data statistics suggest that the current straylight masking scheme used to generate global Chl maps can be relaxed from 7 by 5 to 3 by 3 pixels without losing data quality in either Chl or spectral remote sensing reflectance (R (sub rs) by lambda (sensor wavelength), per steradian (sr (sup −1)) for not just oligotrophic oceans but also more productive waters. Such a relaxed masking scheme yields an average relative increase of 39 percent in data quantity for global oceans, thus making it possible to reduce data product uncertainties and fill data gaps.

Hu, Chuanmin↗

Improved Lunar Irradiance Model Using Multiyear MODIS Lunar Observations

The Moderate Resolution Imaging Spectroradiometer (MODIS) instruments on board the Terra and Aqua spacecrafts were launched on December 18, 1999, and May 4, 2002, respectively. One of the features of the MODIS instruments is the ability to perform observations of the lunar surface from its space view (SV) port. This event is scheduled approximately once a month via a spacecraft roll maneuver, which enables the lunar phase to be confined to within 1° for each instrument. The Moon is considered to be an extremely stable reference to monitor the long-term radiometric stability of the reflective solar bands (RSB). Each MODIS instrument can also view the Moon for about four months in a year without a roll maneuver. This is caused by the intrusion of the Moon in the SV. The lunar phase angles of these unscheduled lunar observations are distributed over a wide range varying from approximately 50° to 80° for Terra MODIS and from about -80° to -50° for Aqua MODIS, where the positive phase angle refers to a waning Moon, while the negative phase angle corresponds to a waxing Moon. Together, the scheduled and unscheduled lunar observations are used to monitor the long-term radiometric stability of the RSB. Of the several challenges involved in the modeling of the lunar optical properties, such as its absolute brightness, a number of optical and view geometry effects need to be considered. These effects are much easier to characterize for the scheduled observations due to confinement of the lunar phase angles compared to those for the unscheduled intrusions of the Moon in the SV. Nevertheless, it is still a challenge to remove the view geometry effect in the calibration coefficients derived from the scheduled lunar observations and even more challenging for the unscheduled lunar intrusions. In this work, the lunar absolute irradiance is modeled using known attributes and from the lunar observations by the two MODIS instruments from the time period between the years 2005 and 2012.

Calibration↗

The stability of hibonite, melilite and other aluminous phases in silicate melts: Implications for the origin of hibonite-bearing inclusions from carbonaceous chondrites

Phase fields in which hibonite and silicate melt coexist with spinel CaAl4O7, gehlenitic melilite, anorthite or corundum at 1 bar in the system CaO-MgO-Al2O3-SiO2-TiO2 were determined. The hibonites contain up to 1.7 wt% SiO2. For TiO2, the experimentally determined partition coefficients between hibonite and coexisting melt D(sub i)(sup Hib/L), vary from 0.8 to 2.1 and generally decrease with increasing TiO2 in the liquid. Based on Ti partitioning between hibonite and melt, bulk inclusion compositions and hibonite-saturated liquidus phase diagrams, the hibonite in hibonite-poor fluffy Type A inclusions from Allende and at least some hibonite from hibonite-rich inclusions is relict, although much of the hibonite from hibonite-glass spherules probably crystallized metasably from a melt. Bulk compositions for all of these CAIs are consistent with an origin as melite + hibonite + spinel + perovskite phase assembalges that were partially altered and in some cases partially or completely melted. The duration of the melting event was sufficient to remove any Na introduced by the alteration process but frequently insufficient to dissolve all of the original hibonite. Simple thermochemical models developed for meteoritic melilite and hibonite solid solutions were used to obtain equilibration temperatures of hibonite-bearing phase assemblages with vapor. Referenced to 10(exp -3) atm, hibonite + corundum + vapor equilibrated at approximately 1260 C and hibonite + spinel +/- melilite + vapor at 1215 +/- 10 C. If these temperatures reflect condensation in a cooling gas of solar composition, then hibonite +/- corundum condensed first, followed by spinel and then melilite. The position of perovskite within this sequence is uncertain, but it probably began to condense before spinel. This sequence of phase appearances and relative temperatures is generally consistent with observed textures but differs from expectations based on classical condensation calculations in that equilibration temperatures are generally lower than predicted and melilite initially condenses with or even after spinel. Simple thermochemical modes for the substitution of trace elements into the Ca site of meteoritic hibonites suggest that virtually all Eu is divalent in early condensate hibonites but that Eu(2+)/Eu(#+) decreases by a factor of 20 or more during the course of condensation primarily because the ratio is proportional to the partial pressure of Al, which decreases dramatically as aluminous phase condense. The relative sizes of Eu and Yb anomalies in meteoritic hibonites and inclusions may be partly due to this effect.

Beckett, J. R.↗

High Resolution Aerosol Data from MODIS Satellite for Urban Air Quality Studies

The Moderate Resolution Imaging Spectroradiometer (MODIS) provides daily global coverage, but the 10 km resolution of its aerosol optical depth (AOD) product is not suitable for studying spatial variability of aerosols in urban areas. Recently, a new Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm was developed for MODIS which provides AOD at 1 km resolution. Using MAIAC data, the relationship between MAIAC AOD and PM(sub 2.5) as measured by the 27 EPA ground monitoring stations was investigated. These results were also compared to conventional MODIS 10 km AOD retrievals (MOD04) for the same days and locations. The coefficients of determination for MOD04 and for MAIAC are R(exp 2) =0.45 and 0.50 respectively, suggested that AOD is a reasonably good proxy for PM(sub 2.5) ground concentrations. Finally, we studied the relationship between PM(sub 2.5) and AOD at the intra-urban scale (10 km) in Boston. The fine resolution results indicated spatial variability in particle concentration at a sub-10 kilometer scale. A local analysis for the Boston area showed that the AOD-PM(sub 2.5) relationship does not depend on relative humidity and air temperatures below approximately 7 C. The correlation improves for temperatures above 7 - 16 C. We found no dependence on the boundary layer height except when the former was in the range 250-500 m. Finally, we apply a mixed effects model approach to MAIAC aerosol optical depth (AOD) retrievals from MODIS to predict PM(sub 2.5) concentrations within the greater Boston area. With this approach we can control for the inherent day-to-day variability in the AOD-PM(sub 2.5) relationship, which depends on time-varying parameters such as particle optical properties, vertical and diurnal concentration profiles and ground surface reflectance. Our results show that the model-predicted PM(sub 2.5) mass concentrations are highly correlated with the actual observations (out-of-sample R(exp 2) of 0.86). Therefore, adjustment for the daily variability in the AOD-PM(sub 2.5) relationship provides a means for obtaining spatially-resolved PM(sub 2.5) concentrations.

remote sensing↗

High Energy Particle Excitations as a Measure of Electronic Crosstalk in MODIS and VIIRS VIS/NIR Bands

The MODIS instruments aboard the Terra and Aqua satellites and the VIIRS instruments aboard the SNPP and NOAA-20 satellites each contain several arrays of Si detectors that measure Earth-reflected radiance in the visible and near-infrared spectral range. Even in the absence of incident light, the Si detectors are occasionally excited by high energy charged particles that pass through the spacecraft. These particle radiation events are, fortunately, infrequent enough that they do not lead to significant degradation of the detectors and they do not have a significant impact on the Earth scene radiance images. On the other hand, they are frequent enough that the cumulative data from many years on orbit may provide valuable diagnostic information about the sensors. In this paper, we provide some basic statistics on the frequency and magnitude of the particle excitation events for MODIS and VIIRS and explore the usefulness of this data as a measure of electronic crosstalk. Large amounts of crosstalk can degrade the quality of the Earth images, so it is crucial to have methods to characterize and correct for it on-orbit, which has previously been done for MODIS using lunar image analysis. The particle excitations can manifest as single-pixel spikes in the otherwise dark space view background, which may be an ideal source for evaluating crosstalk. We derive crosstalk coefficients between the NIR band detectors of Terra MODIS, and compare them to coefficients previously derived from lunar observations. The same approach is applied to SNPP VIIRS, which does not show any significant electronic crosstalk. While the HgCdTe detectors used in the MODIS and VIIRS infrared bands can also be excited by particle radiation, the magnitudes of the excitations are much smaller compared to the Si detectors and in general are not large enough to be useful for examining crosstalk.

MODIS↗