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At least 1,009 records · Page 56

Over 11% Efficient Eco-Friendly Kesterite Solar Cell: Effects of S-Enriched Surface of Cu2ZnSn(S,Se)4 Absorber and Band Gap Controlled (Zn,Sn)O Buffer

For high efficiency kesterite Cu2ZnSn(S,Se)4 (CZTSSe) solar cell, CdS thin film was usually used as a buffer layer. However, due to the toxicity of Cd and pollution problems involved from the solution-based chemical bath deposition, eco-friendly high efficiency CZTSSe solar cell with Cd-free buffer is necessary. As an Cd-free buffer layer, we investigated (Zn,Sn)O (ZTO) film deposited by sputtering method. In order to achieve high power conversion efficiency, we controlled energy band gaps of CZTSSe absorber as well as ZTO buffer, which was required to optimize conduction band offset (CBO) between the absorber and the buffer and to increase open circuit voltage (Voc) and fill factor (FF). The CBO was optimized by controlling the band gap of ZTO. By varying the Sn/(Zn + Sn) ratio and its deposition temperature, band gap of ZTO was successfully adjusted. Experimental and computational calculation results showed that solar cell performance was strongly affected by the CBO between absorber and buffer. Besides CBO matching, larger band gap of ZTO improved short circuit current density (Jsc) with enhanced external quantum efficiency value in blue photon spectrum range. As an additional way to improve power conversion efficiency of solar cell, band graded CZTSSe absorber was developed by using spray-based two-step process. The sprayed CZTSSe film was engineered to have S-enriched surface, which makes surface band gap widened and surface passivated, and resultantly increases Voc, Jsc and fill factor (FF). By controlling band gaps of both CZTSSe absorber and ZTO buffer, we obtained 11.22% environment-friendly CZTSSe solar cell without MgF2 anti-reflection coating.

(Zn↗

Proposal of a gigawatt-class L/Ku dual-band magnetically insulated transmission line oscillator

We present a gigawatt (GW)-class magnetically insulated transmission line oscillator (MILO) which is capable of generating dual-band high power microwaves (HPMs). The proposed device, deriving from previously studied complex MILO and dual-frequency MILO, is designed to produce two HPMs in L-band and Ku-band, respectively. It is found in particle-in-cell (PIC) simulation that when the diode voltage is 610 kV, HPMs with frequencies of 1.72 GHz and 14.6 GHz can be achieved with powers of 3.3 GW and 2.4 GW, respectively. The corresponding total power conversion efficiency is approximately 12.8%. Power difference of the two generated HPMs is approximately 1.4 dB, and frequency difference of them reaches a level as high as ∼10 dB.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Characterization of advanced electric propulsion systems

Characteristics of several advanced electric propulsion systems are evaluated and compared. The propulsion systems studied are mass driver, rail gun, MPD thruster, hydrogen free radical thruster and mercury electron bombardment ion engine. These are characterized by specific impulse, overall efficiency, input power, average thrust, power to average thrust ratio and average thrust to dry weight ratio. Several important physical characteristics such as dry system mass, accelerator length, bore size and current pulse requirement are also evaluated in appropriate cases. Only the ion engine can operate at a specific impulse beyond 2000 sec. Rail gun, MPD thruster and free radical thruster are currently characterized by low efficiencies. Mass drivers have the best performance characteristics in terms of overall efficiency, power to average thrust ratio and average thrust to dry weight ratio. But, they can only operate at low specific impulses due to large power requirements and are extremely long due to limitations of driving current. Mercury ion engines have the next best performance characteristics while operating at higher specific impulses. It is concluded that, overall, ion engines have somewhat better characteristics as compared to the other electric propulsion systems.

Ray, P. K.↗

High Efficiency Fiber-Coupled Diode Lasers for Resonant Pumping of Fiber Lasers

In this program, we have been developing high power, high efficiency laser diodes in InP, operating at 1532 nm and 1910 nm. These lasers have applications in resonant pumping eye-safe laser gain media, such as Erbium or Thulium doped fiber lasers, emitting in the ranges of 1600 nm and 1800-2000 nm, respectively. While such fiber lasers may be pumped with shorter wavelength diode lasers (e.g. 790 nm or 976 nm GaAs didoes), there are advantages to pumping with diode laser light that is closer in wavelength to the fiber laser emission, a technique known as resonant pumping. These advantages include lower quantum defect (the energy lost due to pump and emission at different wavelengths), increased eye-safety of system, decreased waste heat, and potential for lower overall system efficiency. We have achieved diode laser performance with peak electrical-to-optical (EO) efficiency of 39% at 15xx nm and 13% at 19xx nm, a significant advancement over current state-of-the-art. The rated output power and efficiency for these lasers are 4.0 W at 34% EO for 15xx nm, and 1.1 W at 11% EO for 19xx nm. We have designed and built a fiber-coupled-module at 15xx nm. There are many improvements to be made to increase the output power and efficiency of the module, but in our preliminary demonstration, we have achieved a fiber coupling efficiency of 85%.

99 GENERAL AND MISCELLANEOUS↗

Deep Absorbing Porphyrin Small Molecule for High-Performance Organic Solar Cells with Very Low Energy Losses

In this work, we designed and synthesized the DPPEZnP-TEH molecule, with a porphyrin ring linked to two diketopyrrolopyrrole units by ethynylene bridges. The resulting material exhibits a very low energy band gap of 1.37 eV and a broad light absorption to 907 nm. An open-circuit voltage of 0.78 V was obtained in bulk heterojunction (BHJ) organic solar cells, showing a low energy loss of only 0.59 eV, which is the first report that small molecule solar cells show energy losses <0.6 eV. The optimized solar cells show remarkable external quantum efficiency, short circuit current, and power conversion efficiency up to 65%, 16.76 mA/cm 2 , and 8.08%, respectively, which are the best values for BHJ solar cells with very low energy losses. Additionally, the morphology of DPPEZnP-TEH neat and blend films with PC61BM was studied thoroughly by grazing incidence X-ray diffraction, resonant soft X-ray scattering, and transmission electron microscopy under different fabrication conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Chance-Constrained AC Optimal Power Flow: Reformulations and Efficient Algorithms

Higher levels of renewable electricity generation increase uncertainty in power system operation. To ensure secure system operation, new tools that account for this uncertainty are required. Here, in this paper, we adopt a chance-constrained AC optimal power flow formulation, which guarantees that generation, power flows and voltages remain within their bounds with a pre-defined probability. We then discuss different chance-constraint reformulations and solution approaches for the problem. Additionally, we first discuss an analytical reformulation based on partial linearization, which enables us to obtain a tractable representation of the optimization problem. We then provide an efficient algorithm based on an iterative solution scheme which alternates between solving a deterministic AC OPF problem and assessing the impact of uncertainty. This more flexible computational framework enables not only scalable implementations, but also alternative chance-constraint reformulations. In particular, we suggest two sample based reformulations that do not require any approximation or relaxation of the AC power flow equations.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Techno-economic analysis of DC power distribution in commercial buildings

Improvements in building end-use efficiency have significantly reduced the energy intensity of new buildings, but diminishing returns make it a challenge to build very-low energy buildings cost-effectively. A largely untapped efficiency strategy is to improve the efficiency of power distribution within buildings. Direct current (DC) distribution with modern power electronics has the potential to eliminate much of the power conversion loss in alternating current (AC) building distribution networks that include photovoltaics and DC end uses. Previous literature suggests up to 15% energy savings from DC power distribution in very energy efficient buildings with onsite generation and battery storage. This paper extends prior energy modeling of DC versus AC distribution in buildings, to consider the cost of implementing DC systems on a life-cycle basis. A techno-economic analysis framework based on commercially available products that evaluates the cost-effectiveness of DC systems is presented. The analysis is conducted for three commercial building types in two California climate zones and for various PV and battery storage capacities. Monte Carlo simulation is used to compute the payback period and lifecycle cost savings of DC versus AC distribution systems. A future-market scenario is also examined, which evaluates how future efficiency improvements in power converters and changes in electricity tariffs may affect cost savings. This analysis shows that DC systems can be cost-effective in all scenarios that include large capacities of battery storage and onsite solar, whereas for systems without storage, DC distribution is generally not cost-effective.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Grid Resilient, Self-Powered, Fuel Flexible, High Efficiency Heating System (Final Report)

The Grid Independent High Efficiency System (GIHES) delivers a heating system that operates free from the power grid and provides ultra-low emissions and high efficiency heating for residential and commercial buildings. The project demonstrated two weeks of continuous grid independent operation of a storage water heater equipped with a powered damper. The Thermoelectric Generator (TEG) integrated GIHES technology revolutionizes heating systems to provide grid resilient hot water production, while delivering significant value to the end user by eliminating impacts of power interruption and enhancing comfort, convenience and productivity. The system maximizes the thermal-to-electric conversion efficiency by optimizing location and orientation of the TEGs and durability while lowering system costs. The TEGs generate enough power to charge a battery and run the storage water heater unit with a powered damper uninterrupted by providing the required parasitic electrical power for start-up, shutdown and during idling. Several TEGs were analytically and experimentally evaluated based on the size, surface area and the power being generated before designing and fabricating a complete multi-TEG assembly for integration with the water heater. The GIHES technology can be extended to boilers, furnaces and tankless water heaters and integrated with heat pump to further increase the overall equipment efficiency. The technology has the potential to reduce the amount of dispatch power and peak power plant operation. An advanced burner was designed, developed and 3D printed for fuel flexible operation. The burner was designed to enable tighter integration with TEGs for potentially higher TEG output, should this be necessary. A bench-scale test rig to perform testing of a 200,000 Btu/h burner and capable of handling up to 10% H2 (by volume) was setup at GTI’s laboratory with appropriate safety and controls to ensure smooth and safe operation. Testing of the 3D burner showed < 5 ppm NOx emissions can be achieved for the entire firing range and with different levels of hydrogen blends with natural gas. The burner will enable a more integrated TEG-burner module design for improved system performance, should this be required in the future. Techno-economic analysis (TEA) of the TEG integrated with the water heaters was performed. The testing data and the power output were used to develop the TEA. The analysis for the storage unit with damper showed that the TEG integrated system costs $95. This is much lower than a one-time charge needed to wire and install dedicated power. Discussions with TEG manufacturers and OEM’s will provide more detailed information and methods to further lower these costs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

High efficiency low cost solar cell power

A concept for generating high-efficiency, low-cost, solar-cell power is outlined with reference to solar cell parameters, optical concentrators, and thermal control procedures. A design for a 12.5-kw power module for space operation is discussed noting the optical system, spectrum splitter, light conversion system, cell cooling, power conditioner, and tracking mechanism. It is found that for an unconcentrated array, efficiency approaches 60% when ten or more bandgaps are used. For a 12-band system, a computer program distributed bandgaps for maximum efficiency and equal cell currents. Rigid materials and thin films have been proposed for optical components and prisms, gratings, and dichroic mirrors have been recommended for spectrum splitting. Various radiator concepts are noted including that of Weatherston and Smith (1960) and Hedgepeth and Knapp (1978). The concept may be suitable for the Solar Power Satellite.

Bekey, I.↗

Analysis of a Mars-stationary orbiting microwave power transmission system

To determine the feasibility of providing efficient RF power transmission from a Mars-stationary orbit to the surface of the planet, an assessment was made focussing on RF propagation in the 2.45- to 300-GHz range. The proposed orbiting system configuration provides for power generation by either photovoltaic array or nuclear reactor, the conversion of the dc output to RF, and subsequent propagation of RF energy from the orbiting array to the Martian surface. On the planet, a rectenna array will convert RF to dc power to be distributed for planetary power needs. Total efficiency of the energy conversion chain from dc to RF in orbit through RF to dc on the planetary surface was derived for several representative frequencies in the range of study. Tradeoffs between component efficiency and transmitting antenna requirements were considered for each of these frequencies. Rectenna element power density thresholds and desired received power levels were used to determine receiving antenna criteria. Recommendations are presented for research into developing technologies which may afford enhanced viability of the proposed microwave power transmission system.

Long, Kenwyn J.↗

A Copula-Based Conditional Probabilistic Forecast Model for Wind Power Ramps

Efficient management of wind ramping characteristics can significantly reduce wind integration costs for balancing authorities. By considering the stochastic dependence of wind power ramp (WPR) features, this paper develops a conditional probabilistic wind power ramp forecast (cp-WPRF) model based on Copula theory. The WPRs dataset is constructed by extracting ramps from a large dataset of historical wind power. Each WPR feature (e.g., rate, magnitude, duration, and start-time) is separately forecasted by considering the coupling effects among different ramp features. To accurately model the marginal distributions with a copula, a Gaussian mixture model (GMM) is adopted to characterize the WPR uncertainty and features. The Canonical Maximum Likelihood (CML) method is used to estimate parameters of the multivariable copula. The optimal copula model is chosen based on the Bayesian information criterion (BIC) from each copula family. Finally, the best conditions based cp-WPRF model is determined by predictive interval (PI) based evaluation metrics. Numerical simulations on publicly available wind power data show that the developed copula-based cp-WPRF model can predict WPRs with a high level of reliability and sharpness.

17 WIND ENERGY↗

Conversion of residual organics in corn stover-derived biorefinery stream to bioenergy via microbial fuel cell

A biorefinery process typically uses about 4-10 times as much water as the amount of biofuel generated. The wastewater produced in a biorefinery process contains residual sugars, 5-furfural, phenolics, and other pretreatment and fermentation byproducts. Treatment of the wastewater can reduce the need for fresh water and potentially add to the environmental benefits of the process. Use of microbial fuel cells (MFCs) for conversion of the various organics present in a post-fermentation biorefinery stream is reported here. The organic loading was varied over a wide range to assess removal efficiency, coulombic efficiency and power production. A coulombic efficiency of 40% was observed for a low loading of 1% (0.66 g/L) and decreased to 1.8% for the undiluted process stream (66.4 g/L organic loading). A maximum power density of 1180 mW/m2 was observed at a loading of 8%. Excessive loading was found to result in poor electrogenic performance. The results indicate that operation of an MFC at an intermediate loading using dilution and recirculation of the process stream can enable effective treatment with bioenergy recovery.

Borole, Abhijeet P↗

Differential Power Processing for Ultra-Efficient Data Storage

Here this paper presents the hardware, software, and power codesign of an ultra-efficient data storage server with differential power processing (DPP). DPP can reduce the power conversion stress, improve the efficiency, and enhance the functionality of modular power electronics systems. The power inputs of a large number of hard disk drives (HDDs) were connected in series and supported by a multiport ac-coupled differential power processing (MAC-DPP) converter through a multiwinding transformer. Methods for controlling the multi-input multi-output power flow in the multiwinding transformer while avoiding core saturation were investigated. A ten-port MAC-DPP prototype with 700-W/in 3 power density was built to support a 450-W HDD storage system with ten series-stacked voltage domains. The prototype was tested on a 50-HDD server testbench, and the overall system loss is below 1 W (99.77% system efficiency). The server was able to maintain high-speed reading and writing operation of all 50 HDDs against the worst hot-swapping scenarios. A variety of hardware/software configurations and many cloud storage techniques were tested on the fully functioning server. Experimental results show that the energy efficiency of large-scale information systems (CPU/GPU clusters, memory banks, HDD arrays, etc.) can be greatly improved by software, hardware, and power codesign.

42 ENGINEERING↗

K-Band Power Enbedded Transmission Line (ETL) MMIC Amplifiers for Satellite Communication Applications

The design, fabrication, and performance of K-band high-efficiency, linear power pHEMT amplifiers implemented in Embedded Transmission Line (ETL) MMIC configuration with unthinned GaAs substrate and topside grounding are reported. A three-stage amplifier achieved a power-added efficiency of 40.5% with 264 mW output at 20.2 GHz. The linear gain is 28.5 dB with 1-dB gain compression output power of 200 mW and 31% power-added efficiency. The carrier-to-third-order intermodulation ratio is approx. 20 dBc at the 1-dB compression point. A RF functional yield of more than 90% has been achieved.

Tserng, Hua-Quen↗

Fabrication and Evaluation of a High Performance SiC Inverter for Wireless Power Transfer Applications

In this study, a high power density SiC high efficiency wireless power transfer converter system via inductive coupling has been designed and developed. The detailed power module design, cooling system design and power stage development are presented. The successful operation of rated power converter system demonstrates the feasible wireless charging plan. One of the most important part of this study is the wind bandgap devices packaged at the Oak Ridge National Laboratory (ORNL) using the in-house packaging technologies by employing the bare SiC dies acquired from CREE, which are rated at 50 A / 1200 V each. These packaged devices are also inhouse tested and characterized using ORNL s Device Characterization Facility. The successful operation of the proposed inverter is experimentally verified and the efficiency and operational characteristics of the inverter are also revealed.

Onar, Omer C↗

High-power generation in IMPATT devices in the 100-200-GHz range

A silicon double-drift IMPATT diode with high uniform doping levels was simulated. Simulation results show that it is possible for silicon IMPATT diodes to generate extremely high pulsed output power for frequencies above 100 GHz under high current-density operation. The highest output power matched to a 1-ohm load resistance obtained at 150 GHz is 37.7 W, with a dc current density of 200 kA/sq cm, although the calculated power conversion efficiency is low. It is also shown that the low-power conversion efficiency limits the diode's continuous wave power operation.

Chen, Chien-Chung↗

Highly efficient organic solar cells with improved vertical donor-acceptor compositional gradient via an inverted off-center spinning method

A novel, yet simple solution fabrication technique to address the trade-off between photocurrent and fill factor in thick bulk heterojunction organic solar cells is described. Lastly, the inverted off-center spinning technique promotes a vertical gradient of the donor–acceptor phase-separated morphology, enabling devices with near 100% internal quantum efficiency and a high power conversion efficiency of 10.95%.

14 SOLAR ENERGY↗

Scintillator based nuclear photovoltaic batteries for power generation at microwatts level

A nuclear photovoltaic battery uses scintillator to convert radiation into visible light, which is then collected by a photovoltaic (PV) cell to generate electricity. If the radiation is gamma-rays emitted from external sources, the battery may also be referred as gammavoltaic battery. In this study, a polycrystalline CdTe solar cell was optically coupled with a 2.0 cm × 2.0 cm × 1.0 cm Gadolinium Aluminum Gallium Garnet (GAGG) scintillator, and the resulting device was tested using intense gamma radiation fields from a Cs-137 (1.5 kRad/h) and a Co-60 (10 kRad/h) irradiator. Measurements with Cs-137 provided a maximum power output (P max ) of ~288 nW, with a short-circuit current density (J sc ) of ~1.22 μA/cm 2 and an open-circuit voltage (V oc ) of ~0.34 V. In contrast, Co-60 irradiator gave a P max of 1.5 μW, with a J sc of ~4.73 μA/cm 2 and a V oc of ~0.38 V. The CdTe was also paired with a Lutetium-Yttrium Oxyorthosilicate (LYSO) crystal and tested with the Cs-137 source. The experiment presents a scalable option to reach to higher power outputs by harvesting gamma radiation fields in many cases where high radiation field demands heavy shielding and is often regarded as unwanted waste.

25 ENERGY STORAGE↗