Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “orientational order”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,009 records · Page 56

Application of IRTAM to Support ISS Program Safety

The International Space Station (ISS) orbits near the F-peak of the ionosphere (approximately 400 km altitude). Generally, satellites orbiting at this altitude would have a floating potential (FP) of approximately -1 V due to the electron temperature (Te). However, the ISS has 8 large negatively grounded 160 V solar array wings (SAW) that collect a significant electron current from the ionosphere. This current drives the ISS FP much more negative during insolation and is highly dependent on the electron density (Ne). Also, due to the size of the ISS, magnetic inductance caused by the geomagnetic field produces a delta potential up to 40 V across the truss, possibly producing positive potentials. During Extravehicular Activity (EVA) the negative FP can lead to an arcing hazard when it exceeds -45.5 V, and the positive FP can produce a DC current high enough to stimulate the astronaut's muscles and also cause a hazard. Data collected from the Floating Potential Monitoring Unit (FPMU) have shown that the probability of either of these hazards occurring during times with quiet to moderately disturbed geomagnetic activity is low enough to no longer be considered a risk. However, a study of the ionosphere Ne during severe geomagnetic storm activity has shown that the Ne can be enhanced by a factor of 6 in the ISS orbit. As a result, the ISS Safety Review Panel (SRP) requires that ionospheric conditions be monitored using the FPMU in conjunction with the ISS Plasma Interaction Model (PIM) to determine if a severe geomagnetic storm could result in a plasma environment that could produce a hazard. A 'Real-Time' plasma hazard assessment process was developed to support ISS Program real-time decision making providing constraint relief information for EVAs planning and operations. This process incorporates 'real time' ionospheric conditions, ISS solar arrays' orientation, ISS flight attitude, and where the EVA will be performed on the ISS. This assessment requires real time data that is presently provided by the FPMU including ISS floating potential, along with ionospheric Ne and Te, in order to determine the present environment. Once the present environment conditions are known to be either above, below, or near the current IRI values, the IRI is used to forecast what the environment could become in the event of a severe geomagnetic storm. If the FPMU should fail, the Space Environments team needs another source of data which is utilized to support a short-term forecast for EVAs. The IRI Real-Time Assimilative Mapping (IRTAM) model is an ionospheric model that uses real time measurements from approximately 70 digisondes to produce foF2 and hmF2 global maps in 15 minute cadence. The Boeing Space Environments team has used the IRI coefficients produced in IRTAM to calculate the Ne along the ISS orbital track. The results of the IRTAM model have been compared to FPMU measurements and show excellent agreement (figure 1). IRTAM has been identified as a potential FPMU back-up system will be used as a backup for the FPMU to support the ISS Program following completion of an FPMU/IRTAM validation campaign.

Hartman, William A.↗

Reconfiguring COSSIR for the Next Generation of Cloud and Precipitation Science

NASA originally developed the Compact Scanning Sub-millimeter Imaging Radiometer (CoSSIR) in the early 2000s, where it was own in the CRYSTAL-FACE and TC4 field experiments. With renewed interest in sub-millimeter remote sensing motivated by the upcoming launch of the EUMETSAT-sponsored Ice Cloud Imager (ICI), along with its potential for inclusion as part of the NASA Decadal Survey Aerosols, CLouds, Convection, and Precipitation (ACCP) observing architecture, CoSSIR is being refurbished to prepare for routine suborbital submillimeter measurements this decade. Upgrades include hardware (procurement of shared parts so that CoSMIR and CoSSIR can fly concurrently) and a change to the channels, with a focus on differential scattering and polarization at eight frequencies ranging from 170 to 640 GHz. As part of the refurbishment, the instrument name has been changed to Configurable Scanning Sub-millimeter Instrument/Radiometer, retaining the same acronym, in order to emphasize the science objectives that are enabled by CoSSIR's unique scanning geometry and channel set. These anticipated capabilities include two-dimensional pro ling of clouds and precipitation and characterization of the geometry (shape and orientation) of large cloud and precipitating ice particles.

Radiometry↗

Attitude Control System for a Balloon Based Telescope

The Balloon Experimental Twin Telescope for Infrared Interferometry (BETTII) is an 8-meter interferometer which operates on a high-altitude balloon. BETTII had its first successful engineering flight in June 2017. In this paper we discuss the design of the control system for BETTII, which includes the coarse pointing loop and the estimator controls algorithm (Extended Kalman Filter) implemented in FPGA. We will also discuss the different system modes that we defined in the controls system loop, which are used in different phases of the flight and are activated in order to acquire a target star in the science detector. The pointing loop uses different sensors and actuators in each phase to keep pointing at the desired target. The main sensors aregyroscopes, star cameras, and auxiliary sensors such as high-altitude GPS and magnetometers. The azimuth control is achieved with Compensated Controlled Moment Gyros (CCMG) and a Momentum Dump motor. For the elevation control, high-precision motors are used, which change the elevation of the siderostat mirrors. The combination of these instruments keep the baseline oriented within few arcseconds from the target star.In this paper, we will also present the software architecture relevant to the control system. This includes the description of the two flight computers present on the payload and the different control loops that are executed on them. Similarly, we will explain the importance of synchronization between all the sensors and actuators, which have to be referenced to a single master clock in order to obtain science data.

Vila Hernandez De Lorenzo, Jordi↗

Above-threshold multiphoton photoemission from noble metal surfaces

Exciting solids with intense femtosecond laser pulses prompts electrons of the interrogated material to respond in a highly nonlinear manner, as is evident in the emission of high-order harmonic radiation and photoelectrons with kinetic energies well above that of the driving photons. Such high-field interactions can be resolved, for example, in above-threshold multiphoton photoemission (ATP) spectroscopy. In this work, we interrogate the nonlinear photoelectric responses of the pristine copper, silver, and gold noble metal surfaces in (111) and (100) crystal orientations in the perturbative regime. Using multiphoton photoemission spectroscopy (mPP) excited by finely tuned optical fields, we characterize enhancement of the mPP and ATP yields from (111) surfaces in selected k||-momentum ranges when the occupied Shockley surface (SS) states are (near-)resonantly coupled by multiphoton transitions to image potential (IP) intermediate states in the excitation process. The ATP signal from the IP states of (111) surfaces is largely defined by their formation through polarization of SS electrons; this observation is contrasted with ATP experiments from the Ag(100) surface, for which the SS becomes an unoccupied resonance and the IP states can only be excited from bands with significantly more bulk character. In addition, based on the optical power and nonlinear order-dependent mPP spectra, we provide evidence for ATP being a one-step, rather than a sequential process, as previously postulated.

74 ATOMIC AND MOLECULAR PHYSICS↗

Resilience of electric utilities during the COVID-19 pandemic in the framework of the CIGRE definition of Power System Resilience

Resilience is a vital concept in engineering, business, and natural sciences, and is a measure of the ability of an entity to withstand High Impact Low Probability (HILP) events. During the COVID-19 pandemic, which started in late 2019/early 2020, power system utilities around the globe have responded in effective and efficient ways to enhance the resilience of their organisations, both in terms of real-time operations and prudent management of its infrastructure, in order to continue their mandate in providing reliable supply to meet customer demands. Here, this paper presents the CIGRE definition for power system resilience, established by the C4.47 Working Group in 2018, and demonstrates the application of resilience-oriented thinking within the electrical sector. The response and recovery efforts are described, with respect to the key actionable measures integral to the power system resilience definition, taken before, during and after the COVID-19 pandemic. A practical conceptual framework is also presented for thinking about resilience in terms of three key components of resilience strategies: organisational, infrastructure and operational resilience. The paper also discusses the different strategies adopted in response to COVID-19, based on the C4.47 members’ experiences during the pandemic. Finally, a case study is presented, which proves the effectiveness of a set of response measures, using graph theory and the characteristics of the staff-asset interactions.

42 ENGINEERING↗

Detailed mixing measurements from single-hole converging ECN injectors using Rayleigh scattering

Time resolved liquid and vapor fields of dodecane and oxymethylene ethers are measured from Spray A-3 and Spray D using high speed Rayleigh scattering and diffuse back illumination at the Engine Combustion Network (ECN) Spray A condition of 900 K and 22.8 kg/m 3 . Global quantities including mixture fraction, vapor and liquid penetration, as well as spreading angle are measured. The mixture fraction fields and vapor penetration profiles are well predicted by the 1-D Musculus-Kattke model. The mixture fraction field and vapor penetration from Spray A-3 are similar to those measured from Spray A in previous works. Spray D exhibits higher mixture fraction fields and vapor penetration due to its larger nozzle diameter. The quasi-steady mixture fraction fields from these injectors scale well when distance from the injector is normalized by the nozzle diameter. The turbulent dissipation structures were also analyzed based on the orientation, thickness, and magnitude of the mixing layers. Furthermore, the orientation and thickness are similar to other measurements in atmospheric gas jets, while the magnitude is lower. The thickness and magnitude are subject to uncertainties due to limitations in the imaging resolution of the system but still provide an order of magnitude as a useful reference for comparison against computational fluid dynamic simulations.

33 ADVANCED PROPULSION SYSTEMS↗

Energy based fracture initiation criterion for strain-crystallizing rubber-like materials with pre-existing cracks

Fracture prediction is indispensable for polymers, like rubbers, which have a broad range of applications mainly due to their high extensibility. The phenomenon known as strain-induced crystallization further contributes to the fracture toughness of certain rubbers. Here in this study, a criterion based on internal bond energy, incorporating the effects of crystallization, is proposed to predict fracture initiation in rubber-like materials with pre-existing cracks. First, a multi-scale mechanical model is developed for characterizing the behavior of rubber when subjected to both uniaxial and biaxial deformation states. At the microscale, both the amorphous and crystalline chain segments are modeled as elastic in order to consider the energy contribution by the molecular bond distortions. This internal energy is considered along with the entropic and crystalline free energy for each chain. In the chain model, the effects of loading condition and the relative orientation of a chain on its crystallinity are taken into account. At the macroscopic scale, an existing crystallinity distribution function is adapted and a mixed finite element formulation with an augmented Lagrangian multiplier is utilized to impose the incompressibility constraint. A non-affine maximal advance path constraint based homogenization model is utilized for bridging the two scales. Its potential to account for anisotropy in the stretched network compels the model to be preferable due to its physical significance, for the purpose of fracture modeling. The rigidity of the crystallites is accounted for by proposing a crystallite distortion energy in addition to the critical bond dissociation energy, for fracture initiation to occur. The model is validated by comparison with existing experimental results for both crystallizing and non-crystallizing rubbers. In addition to its potential to predict the material behavior when subjected to uniaxial and biaxial loading, the capability of the model to quantitatively estimate the effect of crystallization on fracture initiation is also verified.

36 MATERIALS SCIENCE↗

Epitaxial Stabilization and Oxygen Evolution Reaction Activity of Metastable Columbite Iridium Oxide

Non-rutile polymorphs of binary iridium oxide such as columbite IrO 2 (α-IrO 2 ) are promising candidates for highly active acid-stable oxygen evolution reaction (OER) catalysts, yet their synthesis has been challenging due to the dominant thermodynamic stability of rutile IrO 2 (R-IrO 2 ). Here, we report the growth of α-IrO 2 via epitaxial thin films using pulsed laser deposition. We observe that, in competition with R-IrO 2 (100), the films can be optimized to be predominantly (100)-oriented α-IrO 2 . Surprisingly, the activity of α-IrO 2 shows a large discrepancy of ~0.2 V in the overpotential compared to its predicted activity, which is resolved via theoretical calculations to be a crystal orientation effect. This demonstrates that the electrocatalytic activity can be significantly varied upon crystal orientation, a parameter that is difficult to control in conventional polycrystalline systems but accessible in epitaxial thin films. In total, this study demonstrates epitaxial thin film growth as a powerful technique, which can overcome large energetic instabilities on the order of ~300 meV to stabilize metastable material structures inaccessible by bulk synthesis. As a result, this provides unique opportunities to effectively identify the atomic structure of active catalysts by combining investigations of metastable materials with theoretical predictions.

36 MATERIALS SCIENCE↗

Repository scale classification and decomposition of tandem mass spectral data

Various studies have shown associations between molecular features and phenotypes of biological samples. These studies, however, focus on a single phenotype per study and are not applicable to repository scale metabolomics data. Here we report MetSummarizer, a method for predicting (i) the biological phenotypes of environmental and host-oriented samples, and (ii) the raw ingredient composition of complex mixtures. We show that the aggregation of various metabolomic datasets can improve the accuracy of predictions. Since these datasets have been collected using different standards at various laboratories, in order to get unbiased results it is crucial to detect and discard standard-specific features during the classification step. We further report high accuracy in prediction of the raw ingredient composition of complex foods from the Global Foodomics Project.

59 BASIC BIOLOGICAL SCIENCES↗

Morphogenesis of spin cycloids in a noncollinear antiferromagnet

Pattern formation in spin systems with continuous-rotational symmetry (CRS) provides a powerful platform to study emergent complex magnetic phases and topological defects in condensed-matter physics. However, its understanding and correlation with unconventional magnetic order along with high-resolution nanoscale imaging are challenging. Here, we employ scanning nitrogen vacancy (NV) magnetometry to unveil the morphogenesis of spin cycloids at both the local and global scales within a single ferroelectric domain of (111)-oriented BiFeO 3 , which is a noncollinear antiferromagnet, resulting in formation of a glassy labyrinthine pattern. We find that the domains of locally oriented cycloids are interconnected by an array of topological defects and exhibit isotropic energy landscape predicted by first-principles calculations. We propose that the CRS of spin-cycloid propagation directions within the (111) drives the formation of the labyrinthine pattern and the associated topological defects such as antiferromagnetic skyrmions. Unexpectedly, reversing the as-grown ferroelectric polarization from [$\overline{1}$ $\overline{1}$ $\overline{1}$] to [111] produces a noncycloidal NV image contrast which ¯ could be attributed to either the emergence of a uniformly magnetized state or a reversal of the cycloid polarity. These findings highlight that (111)-oriented BiFeO 3 is not only important for studying the fascinating subject of pattern formation but could also be utilized as an ideal platform for integrating novel topological defects in the field of antiferromagnetic spintronics.

magnetoelectric↗

Magnetic states of graphene proximitized Kitaev materials

Single-layer α-ruthenium trichloride (α–RuCl 3 ) has been proposed as a potential quantum spin liquid. Graphene/RuCl 3 heterobilayers have been extensively studied with a focus on the large interlayer electron transfer that dopes both materials. Here we examine the interplay between the competing magnetic state of RuCl 3 layer and graphene electronic properties. We perform self-consistent Hartree-Fock calculations on a Hubbard-Kanamori model of the 4d 5 t 2g electrons of α–RuCl 3 and confirm that out-of-plane ferromagnetic and zigzag antiferromagnetic states are energetically competitive. We show that the influence of hybridization between graphene and RuCl 3 bands is strongly sensitive to the magnetic configuration of RuCl 3 and the relative orientations of the two layers. We argue that strong hybridization leads to graphene magnetoresistance and that it may tilt the balance between closely competing magnetic states. Furthermore, Our analysis can be applied to any van der Waals heterobilayer system with weak interlayer hybridization and allows for arbitrary lattice constant mismatch and relative orientation.

36 MATERIALS SCIENCE↗

Optical mass memories

Optical and magnetic variants in the design of trillion-bit read/write memories are compared and tabulated. Components and materials suitable for a random access read/write nonmoving memory system are examined, with preference given to holography and photoplastic materials. Advantages and deficiencies of photoplastics are reviewed. Holographic page composer design, essential features of an optical memory with no moving parts, fiche-oriented random access memory design, and materials suitable for an efficient photoplastic fiche are considered. The optical variants offer advantages in lower volume and weight at data transfer rates near 1 Mbit/sec, but power drain is of the same order as for the magnetic variants (tape memory, disk memory). The mechanical properties of photoplastic film materials still leave much to be desired.

Bailey, G. A.↗

Equations of motion and two-equation turbulence model for plane or axisymmetric turbulent flows in body-oriented orthogonal curvilinear coordinates and mass-averaged dependent variables

The full Navier-Stokes time-dependent, compressible, turbulent, mean-flow equations in mass-averaged variables for plane or axisymmetric flow are presented. The equations are derived in a body-oriented, orthogonal, curvilinear coordinate system. Turbulence is modelled by a system of two equations for mass-averaged turbulent kinetic energy and dissipation rate proposed. These equations are rederived and some new features are discussed. A system of second order boundary layer equations is then derived which includes the effects of longitudinal curvature and the normal pressure gradient. The Wilcox and Chambers approach is used in considering effects of streamline curvature on turbulence phenomena in turbulent boundary layer type flows. Their two-equation turbulence model with curvature terms are rederived for the cases considered in the present report. The derived system equations serves as a basis for an investigation of problems where streamline curvature is of the order of the characteristic length in the longitudinal direction.

Sislian, J. P.↗

Finite elastic-plastic deformation of polycrystalline metals

Applying Hill's self-consistent method to finite elastic-plastic deformations, the overall moduli of polycrystalline solids are estimated. The model predicts a Bauschinger effect, hardening, and formation of vertex or corner on the yield surface for both microscopically non-hardening and hardening crystals. The changes in the instantaneous moduli with deformation are examined, and their asymptotic behavior, especially in relation to possible localization of deformations, is discussed. An interesting conclusion is that small second-order quantities, such as shape changes of grains and residual stresses (measured relative to the crystal elastic moduli), have a first-order effect on the overall response, as they lead to a loss of the overall stability by localized deformation. The predicted incipience of localization for a uniaxial deformation in two dimensions depends on the initial yield strain, but the orientation of localization is slightly less than 45 deg with respect to the tensile direction, although the numerical instability makes it very difficult to estimate this direction accurately.

Iwakuma, T.↗

Temperature dependence of gamma-gamma prime lattice mismatch in nickel-base superalloys

High temperature X-ray diffraction techniques were used to determine the gamma-gamma prime lattice mismatch of three different nickel-base superalloys at temperatures between 18 and 1000 C. The measurements were performed on oriented single-crystal disks which had been aged to produce a semicoherent gamma-gamma prime structure. The thermal expansion of the lattice parameters of the gamma and gamma-prime phases was described by a second-order polynomial expression. The expansion of the gamma-prime phase was consistently smaller than that of the gamma phase, which caused the lattice mismatch to become more negative at higher temperatures. It was also shown that high values of lattice mismatch resulted in increased rates of directional gamma-prime coarsening during elevated temperature creep exposure.

Nathal, M. V.↗

Hypersonic three-dimensional nonequilibrium boundary-layer equations in generalized curvilinear coordinates

The basic governing equations for the second-order three-dimensional hypersonic thermal and chemical nonequilibrium boundary layer are derived by means of an order-of-magnitude analysis. A two-temperature concept is implemented into the system of boundary-layer equations by simplifying the rather complicated general three-temperature thermal gas model. The equations are written in a surface-oriented non-orthogonal curvilinear coordinate system, where two curvilinear coordinates are non-orthogonial and a third coordinate is normal to the surface. The equations are described with minimum use of tensor expressions arising from the coordinate transformation, to avoid unnecessary confusion for readers. The set of equations obtained will be suitable for the development of a three-dimensional nonequilibrium boundary-layer code. Such a code could be used to determine economically the aerodynamic/aerothermodynamic loads to the surfaces of hypersonic vehicles with general configurations. In addition, the basic equations for three-dimensional stagnation flow, of which solution is required as an initial value for space-marching integration of the boundary-layer equations, are given along with the boundary conditions, the boundary-layer parameters, and the inner-outer layer matching procedure. Expressions for the chemical reaction rates and the thermodynamic and transport properties in the thermal nonequilibrium environment are explicitly given.

Lee, Jong-Hun↗

Annealing Effects on the Surface Plasmon of MgO Implanted with Gold

Gold ion implantation was carried out with the energy of 1.1 MeV into (100) oriented MgO single crystal. Implanted doses are 1, 3, 6, 10 x 10(exp 16) ions/sq cm. The gold irradiation results in the formation of gold ion implanted layer with a thickness of 0.2 microns and defect formation. In order to form gold colloids from the as-implanted samples, we annealed the gold implanted MgO samples in three kinds of atmospheres: (1)Ar only, (2)H2 and Ar, and (3)O2 and Ar. The annealing over 1200 C enhanced the gold colloid formation which shows surface plasmon resonance band of gold. The surface plasmon bands of samples annealed in three kinds of atmospheres were found to be at 535 nm (Ar only), 524 nm(H2+Ar), and 560 nm (02+Ar), The band positions of surface plasmon can be reversibly changed by an additional annealing.

Ueda, A.↗