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At least 1,009 records · Page 56

Polarized crystal-field spectra of micro particles of the moon

The instrumentation used in the investigation is considered, giving attention also to a block diagram of the apparatus used for measuring crystal-field spectra. The basic object of the studies was to identify the states of transition elements in lunar crystals in order to obtain information on the chemistry of their crystallization history. After spectral measurements were obtained, the crystals were analyzed for major and minor elements using the electron microprobe. Mineral spectra are considered, giving attention to pyroxene, olivine, plagioclase, and lunar glasses.

Mao, H. K.↗

Uranium concentration and distribution in six peridotite inclusions of probable mantle origin

Fission-track activation was used to investigate uranium concentration and distribution in peridotite inclusions in alkali basalt from six localities. Whole-rock uranium concentrations range from 24 to 82 ng/g. Most of the uranium is uniformly distributed in the major silicate phases - olivine, orthopyroxene, and clinopyroxene. Chromian spinels may be classified into two groups on the basis of their uranium content - those which have less than 10 ng/g and those which have 100 to 150 ng/g U. In one sample accessory hydrous phases, phlogopite and hornblende, contain 130 and 300 ng/g U, respectively. The contact between the inclusion and the host basalt is usually quite sharp. Glassy or microcrystalline veinlets found in some samples contain more than 1 microgram/g. Very little uranium is associated with microcrystals of apatite. These results agree with some earlier investigators, who have concluded that suboceanic peridotites contain too little uranium to account for normal oceanic heat flow by conduction alone.

Haines, E. L.↗

A statistical-chemical and thermodynamic approach to the study of lunar mineralogy

Principal components analysis is used to study the chemical compositions of pyroxenes of five Apollo 12 specimens. Important correlations are recognized in the variation of oxide weight per cent. These correlations indicating substitutional relationships can be interpreted as representative of stable and metastable trends of crystallization by using crystal-chemical and thermodynamic information. The per cent variance of pyroxene groups with characteristic trends in each specimen can be evaluated and interpreted in terms of history of crystallization. Distribution of Fe and Mg in certain pairs of olivine and pyroxene, which are found in contact in the rock and which may have crystallized simultaneously, is useful in recognizing the tendency towards chemical equilibrium in Fe-Mg distribution during a limited interval in the liquidus or subsolidus stages.

Saxena, S. K.↗

Origin of the high-temperature fraction of C2 chondrites

The coarse-grained fraction of C2 chondrites is composed mostly of single crystals and aggregates of crystals of Mg-rich olivine and pyroxene. They do not possess compelling textural evidence of being the solidification products of rapidly-quenched molten droplets. Metal inclusions in the silicates contain 3.82-8.88 mole% Ni, 0.16-0.70% Co, 0.17-1.07% Cr, and up to 5.70% P. Thermodynamic calculations show that alloys of these compositions may be condensates from the solar nebula. The implication is that the high-temperature fraction of C2 chondrites consists mostly of high-temperature condensates.

Grossman, L.↗

Melting relations of the Allende meteorite

The proportions of major oxides in the Allende carbonaceous chondrite after partial reduction are remarkably similar to those in possible mantle material of the earth. When heated, the Allende meteorite generates a sulfide melt, a ferrobasaltic melt, and olivine with or without pyroxene, over a wide pressure range (5 to 25 kilobar). The silicate melt contains more sodium and less titanium than lunar ferrobasalts. An aggregate of the Allende chondrite rich in calcium and aluminum produces silica-undersaturated, calcium-rich melt and spinel over a wide pressure and temperature range. It is suggested that the earth's core contains significant amounts of both nickel and sulfur and that a 3:2 mixture of Allende bulk sample and calcium- and aluminum-rich agregates is closer in major element abundances than either of these components to the average composition of the moon.

Seitz, M. G.↗

Analysis of the ultrafine fraction of the Apollo 14 regolith

Analyses were obtained on more than 2400 randomly selected particles from the sub-37 micron (ultrafine) fraction of ten Apollo 14 regolith samples. The analyses were conducted with an energy dispersive electron microprobe system. The semiquantitative data were used to group the particles into ten categories. The pyroxene/plagioclase and olivine/plagioclase ratios are inconsistent with those ratios in the Apollo 14 breccias and rocks. The data suggest that fragmented basalts similar to Apollo 12 olivine basalts may have made significant contributions to the ultrafine fraction of the Fra Mauro regolith. Among a number of unusual particles encountered are brown, birefringent lath-shaped grains with 60 wt % SiO2 and 34 wt % FeO(FeSi2O5) and a glass with 20 to 25 wt % CaO, 0 to 8 wt % MgO, 40 to 45 wt % Al2O3 and approximately 30 wt % SiO2.

Finkelman, R. B.↗

Sample 67955 - A description and a problem

Clasts in breccia sample 67955 contain relatively coarse olivine and plagioclase in part enveloped by poikilitic hypersthene and diopside. This distinctive texture is concluded to result from high temperature crystallization in the presence of a fluid phase, probably a silicate melt. A problem posed by this rock is whether the bulk chemistry, characterized by a high Mg/Fe ratio but low total Fe + Mg, is the result of primary igneous processes on the moon or whether it is the residual end product of a multiple distillation process resulting from repeated meteorite impacts.

Hollister, L. S.↗

Oxygen fugacity values of Apollo 12, 14, and 15 lunar samples and reduced state of lunar magmas

The oxygen fugacity values of lunar samples were measured directly with an improved solid-electrolyte oxygen cell between 1000 and 1200 C with an accuracy mostly better than 0.2 log f(02) unit. The bulk rock f(02) values of basaltic igneous rocks 12009, 12053, 15058, and 15595 ranged from 10 to -15.4 power to 10 to the -15.7 power at 1000 C and from 10 to the -12.3 power to 10 to the -12.8 power at 1200 C. Those of microbreccia 14321 also fell in this range, but the change of oxygen fugacity with temperature was irregular in the first heating cycle in comparison to the smooth changes observed with the basaltic igneous rocks. Two different samples of rock 14310 also showed similar f(02) values below 1170 C, but exhibited irreversible sudden rise in f(02) at this temperature for reasons yet to be determined. The data on the phenocryst olivine and the groundmass of basalt 12009 do not conclusively indicate progressive reduction of the lunar magma during cooling.

Sato, M.↗

Lunar rock types - The role of plagioclase in non-mare and highland rock types

Some nonmare and highland rock types (14310 type KREEP and very high Al2O3 basalts) have the internal chemical variations expected for a plagioclase-liquid system. The observed Eu variations in these rock types suggest a D(Eu) 1/p of 0.6 to 0.7. The Sr variations suggest a D(Sr) 1/p of about 0.6, with values as low as 0.35 suggested for some materials from sample 14063. Common Apollo 14 KREEP and Apollo 15 KREEP do not show internal Sr, Eu, Al2O3 variations consistent with the D(Eu, Sr) 1/p values derived for 14310 type KREEP. Major element and experimental data indicate that olivine or pyroxene is a large, perhaps dominant, controller of chemical variations within common Apollo 14 KREEP. The application of these distribution coefficients to pure anorthosites like 15415 yields the model dependent conclusion that the silicate liquids with which such anorthosites may have been chemically equilibrated have not yet been analyzed and perhaps not directly sampled.

Hubbard, N. J.↗

Characterization of fines from the Apollo 16 site

We describe the characteristics of Apollo 16 fines samples 61281,8; 65701,13; 66031,6; 67701,26; and 67712,16 observed microscopically during the course of size and magnetic separations. Sample 67712,16 is unique in that almost all grains are rounded and no glass welded aggregates are present. All samples except 67712,16 contained about 0.5 wt.% of metal fragments 45 microns or more in diameter including occasional spheres and large single crystals. Some of this metal showed rust spots. Moessbauer spectra showed all the samples to be high in olivine compared to samples from other Apollo sites and to vary significantly in modal composition from each other. The fine grained Fe metal content and the excess absorption area near zero velocity in the Moessbauer spectra both vary with particle size and regolith maturity in the way one would predict from our model of Fe metal reduction and agglomeration during glass aggregate formation.

Housley, R. M.↗

Magnetic and Moessbauer studies of Apollo 16 rock chips 60315,51 and 62295,27

Analysis of the Moessbauer spectra of two Apollo 16 rocks showed that 60315,51 is much richer in iron metal and troilite, but poorer in olivine, than 62295,27. The values of magnetic parameters, derived from hysteresis loops at 175 and 300 K, indicate the high metal contents and the predominance of coarse multidomain grains in both rocks. These coexist with a superparamagnetic grain fraction in 60315 and with a small single-domain grain fraction in 62295. The high Fe(0)/Fe(2+) ratios, the nonlinear acquisition of laboratory thermoremanence, and the drastic changes in magnetic parameters upon heating support the proposed formation of both rocks from the lunar regolith, with incorporation of shocked meteoritic metal grains during high-temperature impact events and simultaneous acquisition of magnetic remanence. Values estimated for ancient lunar magnetic fields by comparing the natural remanence with laboratory thermoremanence acquired in fields of 0.05 and 0.5 Oe, range from 0.01 to more than 1 Oe.

Brecher, A.↗

The thermal state and internal structure of Mars

The evolution and state of the interior of Mars are studied through the use of theoretically calculated thermal history and density models. Invoking melting of an Fe-FeS mixture permits initial core formation within the first billion years. At the present time the core radius ranges from about 1300 to 1800 km, depending on composition, and the core is liquid even if the composition is varied from the eutectic. Large-scale differentiation of the silicates occurs in the last 2 b.y. When the mean density is 3.96 g/cu cm, the radius is 3389 km, and the moment of inertia factor is 0.377, the density models indicate high mantle densities near 3.74 g/cu cm. Thus an FeO content of about 29% is implied, consistent with the production of a low-viscosity magma. Chemical models of the Martian mantle indicate a composition primarily of olivine with about 56% forsterite.

Johnston, D. H.↗

Petrographic-mineralogical investigation of magmatic rocks from the Sea of Fertility

Petrographic and mineralogical features of fragments of magmatic rock of regolith from the Sea of Fertility are examined. The textures and mineral composition vary in relation to the type of rock. More than 50 X-ray spectral analyses of minerals (olivine, pyroxenes, plagioclases, and ores) were made; their chemical composition varies even within the limits of individual rock fragments.

Tarasov, L. S.↗

X-ray diffraction identification of minerals in lunar regolith returned by Luna 16 automatic station

The methods of powder and monocrystal X-ray diffraction served in identifying the mineral composition of gross samples of regolith from different levels of the drill core and about 80 individual regolith particles returned by the Luna 16 station. It was established that the Sea of Fertility regolith includes pyroxenes of the augite-pigeonite series, anorthites, ilmenite, olivines, spinels, alpha cristobalite, iron particles, glass, and several as yet unidentified particles. Crystallographic and roentgenometric data are given for all the lunar minerals found.

Makarov, Y. S.↗

Electron paramagnetic resonance of several lunar rock samples

The results are presented of investigating lunar rock samples returned by the Luna 16 automatic station, using electron paramagnetic resonance (EPR). The EPR technique makes it possible to detect paramagnetic centers and investigate their nature, with high sensitivity. Regolith (finely dispersed material) and five particles from it, 0.3 mm in size, consisting mostly of olivine, were investigated with EPR.

Marov, P. N.↗

Mossbauer analysis of Luna 16 lunar surface material

Samples of Apollo 11 lunar surface material were studied by the Mossbauer effect. Owing to the small number of other resonant isotopes, all measurements were made with Fe-57 nuclei. The principal constituents of the material were as follows: Iron containing silicates (olivine, pyroxene, and so on), ilmenite (FeTiO3), and metallic iron.

Nady, D. L.↗

Some results of track method of investigating Luna 16 lunar material

Preliminary data from an investigation of tracks in olivine crystals, separated from the five zones of a lunar surface material core, are reported. The gradients of track densities, their lengths, and their angular distribution were measured with an optical microscope. Throughout the core depth (35 cm) crystals bearing traces of exposure to low energy solar cosmic rays were found, indicating the occurrence of mixing processes in the surficial layer of lunar surface material. The age of the occurrence of the samples investigated on the lunar surface, calculated from the track density, is in the interval 0.7 to 16 million years.

Kashkarov, L. L.↗

Study of sample of Sea of Fertility lunar surface material by the track method

Tracks in crystals of feldspars, olivines, pyroxenes, and in several fragments of basalts from a sample of Luna 16 lunar surface material were studied. A high track density, exceeding 10 to the 8th power cm/2 was found. The tracks were produced mainly by iron group nuclei of cosmic galactic and solar rays.

Poupeau, G.↗