Geomechanics of CO 2 Reservoir Seals
Chemically-assisted subcritical fracture growth within overlying shale caprock can threaten seal integrity of CO 2 sequestration reservoirs. Here, we integrate laboratory fracture mechanics testing conducted under a wide range of environmental conditions including dry and wet supercritical CO 2 , dry CO 2 gas, ambient air, deionized water, and aqueous solutions of varying pH and salinity, with numerical simulations of fracture network growth and caprock degradation calculations, to investigate the coupled chemo-mechanical processes associated with potential fracture-controlled leakage from subsurface CO 2 storage. Double torsion tests quantify in detail the influence of aqueous fluid chemistry and temperature on subcritical fracture growth of caprock at atmospheric pressure, while short rod tests derive fracture toughness of caprock under pressurized supercritical CO 2 environments. We find that lowered pH as expected after brine acidification enhances subcritical fracture growth properties in carbonate-rich shale. An increase in salinity that may result from scCO 2 -brine interaction would potentially suppress fracture growth in clay-rich shales. Dehydration by dry supercritical CO 2 significantly strengthens shale lithologies. Through boundary element fracture network models that account for subcritical fracture growth we demonstrate that changes in aqueous fluid composition can affect fracture network geometry and connectivity, and thus potentially degrading caprock efficiency at preventing upward migration of CO 2 . Calculations based on boundary element simulation suggest that caprock degradation rates may increase by 58% following acidification of formation water in contact with carbonate-rich caprock. With spatially and temporally variable CO 2 -brine interaction in storage reservoirs, chemo-mechanical interactions may control the location of potential leakage pathway evolution, with preexisting faults and reservoir heterogeneities providing the preferred locus for environmentally assisted fracture growth and subsequent caprock failure.