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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,009 records · Page 56
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Travel and energy implications of ridesourcing service in Austin, Texas

This paper identifies major aspects of ridesourcing services provided by Transportation Network Companies (TNCs) which influence vehicles miles traveled (VMT) and energy use. Using detailed data on approximately 1.5 million individual rides provided by RideAustin in Austin Texas, we quantify the additional miles TNC drivers travel: before beginning and after ending their shifts, to reach a passenger once a ride has been requested, and between consecutive rides (all of which is referred to as deadheading); and the relative fuel efficiency of the vehicles that RideAustin drivers use compared to the average vehicle registered in Austin. We conservatively estimate that TNC drivers commute to and from their service areas accounts for 19% of the total ridesourcing VMT. In addition, we estimate that TNC drivers drove 55% more miles between ride requests within 60 min of each other, accounting for 26% of total ridesourcing VMT. Vehicles used for ridesourcing are on average two miles per gallon more fuel efficient than comparable light-duty vehicles registered in Austin, with twice as many are hybrid-electric vehicles. New generation battery electric vehicles with 200 miles of range would be able to fulfill 90% of full-time drivers' shifts on a single charge. We estimate that the net effect of ridesourcing on energy use is a 41-90% increase compared to baseline, pre-TNC, personal travel.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2017

Inter-layer coupling induced valence band edge shift in mono- to few-layer MoS 2

In this study, recent progress in the synthesis of monolayer MoS 2 , a two-dimensional direct band-gap semiconductor, is paving new pathways toward atomically thin electronics. Despite the large amount of literature, fundamental gaps remain in understanding electronic properties at the nanoscale. Here,we report a study of highly crystalline islands of MoS 2 grown via a refined chemical vapor deposition synthesis technique. Using high resolution scanning tunneling microscopy and spectroscopy (STM/STS), photoemission electron microscopy/spectroscopy (PEEM) and μ-ARPES we investigate the electronic properties of MoS 2 as a function of the number of layers at the nanoscale and show in-depth how the band gap is affected by a shift of the valence band edge as a function of the layer number. Green’s function based electronic structure calculations were carried out in order to shed light on the mechanism underlying the observed bandgap reduction with increasing thickness, and the role of the interfacial Sulphur atoms is clarified. Our study, which gives new insight into the variation of electronic properties of MoS 2 films with thickness bears directly on junction properties of MoS2, and thus impacts electronics application of MoS 2 .

36 MATERIALS SCIENCE↗
DOE OSTI2014

Low energy electron beam irradiation effect on optical properties of nanopillar MQW InGaN/GaN structures

The low energy electron beam irradiation (LEEBI) effect on optical properties of planar and nanopillar InGaN/GaN muliple quantum well light emitting structures was studied by the cathodoluminescence (CL) method. On the planar structures LEEBI leads to a formation of new InGaN-related emission bands red shifted in comparison with initial one at small irradiation doses and blue shifted at doses higher than 0.5 C/cm{sup 2}. It was observed that after dry etching used for the nanopillar formation the main InGaN-related emission line moves from 2.92 to 2.98 eV that can be explained by a strain relaxation in the quantum wells. The optical properties of nanopilars start to change under LEEBI at a dose of about one order of magnitude lower than that for planar structures. At high irradiation doses the behavior of both structures under LEEBI is similar. The results obtained were explained by the formation and reconstruction of quantum dots inside the quantum wells due to a point defect generation and redistribution stimulated by the electron beam irradiation.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Electrically tunable zero dispersion wavelengths in photonic crystal fibers filled with a dual frequency addressable liquid crystal

We present a liquid crystal (LC) infiltrated photonic crystal fiber, which enables the electrical tuning of the position of zero dispersion wavelengths (ZDWs). A dual frequency addressable liquid crystal is aligned perpendicular on the inclusion walls of a photonic crystal fiber, which results in an escaped radial director field. The orientation of the LC is controlled by applying an external electric field. Due to the high index of the liquid crystal the fiber guides light by the photonic band gap effect. Multiple ZDWs exist in the visible and near infrared. The positions of the ZDWs can be either blue or red shifted depending on the frequency of the applied voltage.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

Zeeman effect of the topological surface states revealed by quantum oscillations up to 91 Tesla

In this paper, we report quantum oscillation studies on the Bi 2 Te 3-x S x topological insulator single crystals in pulsed magnetic fields up to 91 T. For the x = 0.4 sample with the lowest bulk carrier density, the surface and bulk quantum oscillations can be disentangled by combined Shubnikov–de Haas and de Hass–van Alphen oscillations, as well as quantum oscillations in nanometer-thick peeled crystals. At high magnetic fields beyond the bulk quantum limit, our results suggest that the zeroth Landau level of topological surface states is shifted due to the Zeeman effect. The g factor of the topological surface states is estimated to be between 1.8 and 4.5. Lastly, these observations shed new light on the quantum transport phenomena of topological insulators in ultrahigh magnetic fields.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Monochromatic 2D K α Emission Images Revealing Short-Pulse Laser Isochoric Heating Mechanism

The rapid heating of a thin titanium foil by a high intensity, subpicosecond laser is studied by using a 2D narrow-band x-ray imaging and x-ray spectroscopy. Here, a novel monochromatic imaging diagnostic tuned to 4.51 keV Ti Kα was used to successfully visualize a significantly ionized area ( < Z > >17±1) of the solid density plasma to be within a ~35 μm diameter spot in the transverse direction and 2 μm in depth. The measurements and a 2D collisional particle-in-cell simulation reveal that, in the fast isochoric heating of solid foil by an intense laser light, such a high ionization state in solid titanium is achieved by thermal diffusion from the hot preplasma in a few picoseconds after the pulse ends. The shift of Kα and formation of a missing Kα cannot be explained with the present atomic physics model. The measured Kα image is reproduced only when a phenomenological model for the Kα shift with a threshold ionization of < Z > =17 is included. This work reveals how the ionization state and electron temperature of the isochorically heated nonequilibrium plasma are independently increased.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Control of second-harmonic generation in all-dielectric intersubband metasurfaces by controlling the polarity of χ (2)

All-dielectric metasurfaces have recently led to a paradigm shift in nonlinear optics as they allow for circumventing the phase matching constraints of bulk crystals and offer high nonlinear conversion efficiencies when normalized by the light-matter interaction volume. Unlike bulk crystals, in all-dielectric metasurfaces nonlinear conversion efficiencies primarily rely on the material nonlinearity, field enhancements, and the modal overlaps, therefore most efforts to date have only focused on utilizing these degrees of freedom. In this work, we demonstrate that for second-harmonic generation in all-dielectric metasurfaces, an additional degree of freedom is the control of the polarity of the nonlinear susceptibility. We demonstrate that semiconductor heterostructures that support resonant nonlinearities based on quantum-engineered intersubband transitions provide this new degree of freedom. We can flip and control the polarity of the nonlinear susceptibility of the dielectric medium along the growth direction and couple it to the Mie-type photonic modes. Here we demonstrate that engineering the χ (2) polarity in the meta-atom enables the control of the second-harmonic radiation pattern and conversion efficiency. Our results therefore open a new direction for engineering and optimizing second-harmonic generation using all-dielectric intersubband nonlinear metasurfaces.

42 ENGINEERING↗
DOE OSTI2022

Designing linear lattices for round beam in electron storage rings using the solution by linear matrices analysis

For some synchrotron light source beamline applications, a round beam is preferable to a flat one. A conventional method of obtaining round beam in an electron storage ring is to shift its tune close to a linear difference resonance. The linearly coupled beam dynamics is analyzed with perturbation theories, which have certain limitations. In this paper, we adopt the Solution by LInear Matrices (SLIM) analysis to calculate exact beam sizes to design round beam lattices. The SLIM analysis can deal with a generally linearly coupled accelerator lattice. The effects of various coupling sources on beam emittances and sizes can be studied within a self-consistent frame. Both the on- and off-resonance schemes to obtain round beams are explained with examples. The SLIM formalism for two widely used magnet models: combined-function bending magnets, and planar wigglers and undulators, is also derived.

43 PARTICLE ACCELERATORS↗
NASA NTRS1980

Smokestack Monitor

Environmental Protection Agency monitors emissions from industrial smokestacks to obtain such information as how much pollutant material is being discharged into the atmosphere, how rapidly it is being discharged, and how the smoke plume disperses after leaving the stack. Raytheon's invisible laser beam, adapted from NASA's laser doppler technology, measures emission from one of the stacks. Aimed from a van's interior, the beam is projected from the roof mounted scanning pod near the rear of the vehicle. Particles in the smoke coming out of the stack reflect the beam back to light-detecting equipment in the van. The frequency of the returned beam is different from that of outgoing beam; analysis of the difference in frequencies, called "doppler shift" allows determination of the velocity.

Source record↗
NASA NTRS2005

Sub-pixel Spatial Resolution Micro-roughness Measurements with Interlaced Stitching

In this paper we describe a method to increase the spatial resolution of surface micro-roughness measurements. As the surface specifications for precision optics become more demanding, the metrology instruments must cover a broad spatial frequency range. Generally, multiple instruments are used to cover the full range of the specifications. For example, a Fizeau interferometer would be used to test low spatial frequency surface errors, a white light interferometer would be used for mid spatial frequency errors, and an AFM would be used for high spatial frequency errors. For some precision optics, three instruments would be necessary. However, in many applications, an increase in the spatial resolution of a metrology instrument could negate the need for multiple instruments. A solution to increase the spatial resolution of micro-roughness measurements obtained using white light interferometry with "interlaced stitching" will be presented. In "interlaced stitching", multiple interferometric measurements are made as the optic under test (or the CCD array) is laterally shifted at sub-pixel increments. The measurements are then combined to construct a measurement with higher spatial resolution. Initial results obtained while implementing a similar process used to increase the spatial resolution of measurements made with a commercially available Fizeau interferometer will be presented.

Mooney, James T.↗
DOE OSTI2024

Increasing Electric Vehicle Adoption Among Disadvantaged Populations: A Case Study in LA

In the shift towards 100% carbon-free energy, ensuring equitable access to clean energy benefits is crucial. The adoption of electric vehicles (EVs), particularly in the personal light-duty vehicle segment, has gained traction, driven by various incentives at the federal, state, and local levels. However, disadvantaged populations face unique challenges in embracing EVs. This paper, using Los Angeles as a case study, explores EV adoption patterns among disadvantaged population groups in both a business-as-usual scenario and an equity scenario. Modeling reveals that by 2035, over half of EV owners will be from low- to middle income backgrounds with limited access to home charging. Strategies such as increasing incentives for used EV purchase from $2500 to $4000, targeted for disadvantaged communities, can boost EV adoption among low-middle income groups by 2%, while providing a $300 annual voucher to households using public charging can further facilitate equitable EV adoption.

ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2018

Computational Modeling of Exciton-Bath Hamiltonians for Light Harvesting 2 and Light Harvesting 3 Complexes of Purple Photosynthetic Bacteria at Room Temperature

Light harvesting 2 (LH2) complex is the primary component of the photosynthetic unit of purple bacteria that is responsible for harvesting and relaying excitons. The electronic absorption line shape of LH2 contains two major bands at 800 and 850 nm wavelength regions. Under low light conditions, some species of purple bacteria replace LH2 with light harvesting 3 (LH3), a variant form with almost the same structure as the former but with distinctively different spectral features. The major difference between the absorption line shapes of LH2 and LH3 is the shift of the 850 nm band of the former to a new 820 nm region. The microscopic origin of this difference has been the subject of some theoretical/computational investigations. However, the genuine molecular level source of such a difference is not clearly understood yet. This work reports a comprehensive computational study of LH2 and LH3 complexes so as to clarify different molecular level features of LH2 and LH3 complexes and to construct simple exciton-bath models with a common form. All-atomistic molecular dynamics simulations of both LH2 and LH3 complexes provide detailed molecular level structural differences of bacteriochlorophylls (BChls) in the two complexes, in particular, in their patterns of hydrogen bonding (HB) and torsional angles of the acetyl group. Time-dependent density functional theory calculation of the excitation energies of BChls for structures sampled from the MD simulations suggests that the observed differences in the HB and torsional angles cannot fully account for the experimentally observed spectral shift of LH3. Potential sources that can explain the actual spectral shift of LH3 are discussed, and their magnitudes are assessed through fitting of experimental line shapes. Furthermore, these results demonstrate the feasibility of developing simple exciton-bath models for both LH2 and LH3, which can be employed for large-scale exciton quantum dynamics in their aggregates.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Influence of Fuel Properties on Gasoline Direct Injection Particulate Matter Emissions Over First 200 s of World-Harmonized Light-Duty Test Procedure Using an Engine Dynamometer and Novel “Virtual Drivetrain” Software

Abstract The influence of fuel properties on particulate matter (PM) emissions from a catalytic gasoline particulate filter (GPF) equipped gasoline direct injection (GDI) engine was investigated using novel “virtual drivetrain” software and an engine mated to an engine dynamometer. The virtual drivetrain software was developed in labview to operate the engine on an engine dynamometer as if it were in a vehicle undergoing a driving cycle. The software uses a physics-based approach to determine vehicle acceleration and speed based on engine load and a programed “shift” schedule to control engine speed. The software uses a control algorithm to modulate engine load and braking to match a calculated vehicle speed with the prescribed speed trace of the driving cycle of choice. The first 200 s of the World-harmonized Light-duty Test Procedure (WLTP) driving cycle was tested using six different fuel formulations of varying volatility, aromaticity, and ethanol concentration. The first 200 s of the WLTP was chosen as the test condition because it is the most problematic section of the driving cycle for controlling PM emissions due to the cold start and cold drive off. It was found that there was a strong correlation between aromaticity of the fuel and the engine-out PM emissions, with the highest emitting fuel producing more than double the mass emissions of the low PM production fuel. However, the post-GPF PM emissions depended greatly on the soot loading state of the GPF. The fuel with the highest engine-out PM emissions produced comparable post-GPF emissions to the lowest PM producing fuel over the driving cycle when the GPF was loaded over three cycles with the respective fuels. These results demonstrate the importance of GPF loading state when aftertreatment systems are used for PM reduction. It also shows that GPF control may be more important than fuel properties, and that regulatory compliance for PM can be achieved with proper GPF control calibration irrespective of fuel type.

Energy & Fuels↗
DOE OSTI2015

Solar photocatalytic activities of porous Nb-doped TiO{sub 2} microspheres by coupling with tungsten oxide

Highlights: • Nb-TiO{sub 2}/WO{sub 3} was prepared by USP method combined impregnation method. • Nb-doping extend the spectral absorption of TiO{sub 2} into visible spectrum. • Nb-TiO{sub 2}/WO{sub 3} has a similar optical band gap as Nb-TiO{sub 2}. • PL spectra indicate WO{sub 3} can accept the photoexcited electrons from Nb-TiO{sub 2}. • Nb-TiO{sub 2}/WO{sub 3} shows higher activity than TiO{sub 2} and Nb-TiO{sub 2} under solar light. - Abstract: Nb doped TiO{sub 2} microspheres modified with WO{sub 3} (Nb-TiO{sub 2}/WO{sub 3}) was prepared by ultrasonic spray pyrolysis method combined with impregnation method. The microspheres were characterized with SEM, TEM, XRD, BET, photoluminescence and UV–vis absorption spectra. The Nb-doping was observed to extend the spectral absorption of TiO{sub 2} into visible spectrum, and the absorption onset was red-shifted for about 88 nm compared to pristine TiO{sub 2} microspheres. Nb-TiO{sub 2}/WO{sub 3} microspheres do not display a red-shifted absorption edge compared with Nb doped TiO{sub 2} microspheres. Under solar irradiation, Nb-TiO{sub 2}/WO{sub 3} microspheres showed higher photocatalytic activity for methylene blue degradation compared with that of pure TiO{sub 2} microspheres and Nb doped TiO{sub 2} microspheres, which could be ascribed to the extended light absorption range and the suppression of electron-hole pair recombination.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Optimizing spectral and morphological match of nonfullerene acceptors toward efficient indoor organic photovoltaics with enhanced light source adaptability

High-performance indoor organic photovoltaics (IOPV) require large-bandgap material systems to absorb visible light efficiently and reduce energy loss. However, state-of-the-art non-fullerene acceptors (NFAs) have absorptions in the near-infrared region and are thus not suitable for IOPV applications. Herein, we report a series of large-bandgap (>1.70 eV) NFAs named FCC-Cl-C8, FCC-Cl-4Ph and FCC-Cl-6Ph by modifying the alkyl side chains with alkylphenyl chains partially or completely. Results show that the bulky alkylphenyl side chains can finely tune the absorption properties of the NFAs and also affect their morphological properties. Interestingly, the best-performing NFA is the one (named FCC-Cl-4Ph) with partial alkyl and alkylphenyl substitutions, which blue-shift the absorption of the NFAs while minimizing the negative morphological effect of the bulky alkylphenyl chains. As a result, FCC-Cl-4Ph can achieve excellent indoor efficiencies over 29% under a 3000 K LED lamp at 1000 lux and show better solution processability over FCC-Cl-C8. More importantly, FCC-Cl-4Ph can maintain high indoor performance (29.7–26.8% at 1000 lux) under a wide range of indoor lighting spectra (2600, 3000, 4000, and 6500 K LED lamps), which should be due to the blue-shifted spectra of FCC-Cl-4Ph and better matching with various indoor conditions. Finally, this work reveals an interesting structure-property relationship and offers useful strategies for the further design of NFAs toward efficient IOPV devices.

14 SOLAR ENERGY↗
NASA NTRS1977

Cortisol-mediated synchronization of circadian rhythm in urinary potassium excretion

Conscious chair-acclimatized squirrel monkeys (Saimiri sciureus) studied with lights on (600 lx) from 0800 to 2000 hr daily (LD 12:12) display a prominent circadian rhythm in renal potassium excretion. The characteristics of this rhythm were reproduced in adrenalectomized monkeys by infusing 5 mg cortisol and 0.001 mg aldosterone, or 5 mg cortisol alone, between 0800 and 0900 kr daily. When the timing of cortisol administration (with or without aldosterone) was phase-delayed by 8 hr, the urinary potassium rhythm resynchronized by 80% of the cortisol phase shift, but only after a transient response lasting 3-4 days. With the same daily dose of adrenal steroids given as a continuous infusion throughout each 24 hr, urinary potassium excretion showed free-running oscillations no longer synchronized to the light-dark cycle. These results indicate that the circadian rhythm of plasma cortisol concentration acts as an internal mediator in the circadian timing system, synchronizing a potentially autonomous oscillation in renal potassium excretion to environmental time cues and to other circadian rhythms within the animal.

Moore-Ede, M. C.↗