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NASA NTRS1990

The validation and application of a rotor acoustic prediction computer program

An essential prerequisite to reducing the acoustic detectability of military rotorcraft is a better understanding of main rotor noise which is the major contributor to the overall noise. A simple, yet accurate, Rotor Acoustic Prediction Program (RAPP) was developed to advance the understanding of main rotor noise. This prediction program uses the Ffowcs Williams and Hawkings (FW-H) equation. The particular form of the FW-H equation used is well suited for the coupling of the measured blade surface pressure to the prediction of acoustic pressure. The FW-H equation is an inhomogeneous wave equation that is valid in all space and governs acoustic pressure generated by thin moving bodies. The nonhomogeneous terms describe mass displacement due to surface motion and forces due to local surface stresses, such as viscous stress and pressure distribution on the surface. This paper examines two of the four types of main rotor noise: BVI noise and low-frequency noise. Blade-vortex interaction noise occurs when a tip vortex, previously shed by a rotor blade, passes close enough to a rotor blade to cause large variations in the blade surface pressures. This event is most disturbing when it happens on the advancing side of the rotor disk. Low-frequency noise includes hover and low to moderate speed forward flight. For these flight conditions, the low frequency components of the acoustic signal dominate.

Gallman, Judith M.↗

NASA NTRS1994

Problems with Re-Os isochron determinations

We have developed closed-system techniques for the equilibration of Os isotopes and for the calibration of Re and Os tracers using high-purity metals. The results show reproducibility of +/- 0.5% for calibrations of Os using different chunks of the same high-purity Os metal produced by vacuum arc melting. On a Re-Os evolution diagram the analyses of Negrillos and of Tocopilla are displaced along horizontal lines and are not consistent with a well-defined isochron. We conclude that is unclear whether whole-rock samples of irons of individual classes of iron meteorites (including the IIA class) define isochrons.In light of these observations, one must consider the evidence for phases in which Re and Os may become redistributed. We note that the IIA irons are composed of large or single kamacite crystals and do not contain taenite. This may hinder redistribution of Re and Os and may allow the IIA irons to define isochrons in preference to other magmatic iron classes. However, the IIA irons also include ubiquitous rhabdites, up to 20 mm in length, and troilite-daubreelite nodules. It has been observed that rhabdites are extremely rich in Pt-group elements. In addition to these considerations, Negrillos and Tocopilla were found in nitrate deposits and show evidence of corrosion. Therefore, it is possible that different samples of these meteorites have been differentially weathered, although our samples appeared fresh. We conclude that it is important to identify the phases in which Re and the PGEs are located and to address in detail the evidence for Re and Os remobilization.

Papanastassiou, D. A.↗

NASA NTRS1997

Design of a Minimum Surface-Effect Tendon-Based Microactuator for Micromanipulation

A piezoelectric (PZT) stack-based actuator was developed to provide a means of actuation with dynamic characteristics appropriate for small-scale manipulation. In particular, the design incorporates a highly nonlinear, large-ratio transmission that provides approximately two orders of magnitude motion amplification from the PZT stack. In addition to motion amplification, the nonlinear transmission was designed via optimization methods to distort the highly non-uniform properties of a piezoelectric actuator so that the achievable actuation force is nearly constant throughout the actuator workspace. The package also includes sensors that independently measure actuator output force and displacement, so that a manipulator structure need not incorporate sensors nor the associated wires. Specifically, the actuator was designed to output a maximum force of at least one Newton through a stroke of at least one millimeter. For purposes of small-scale precision position and/or force control, the actuator/sensor package was designed to eliminate stick-slip friction and backlash. The overall dimensions of the actuator/sensor package are approximately 40 x 65 x 25 mm.

Goldfarb, Michael↗

DOE OSTI2022

Competitive Adsorption of NH 3 and H 2 O in Metal–Organic Framework Materials: MOF-74

Elucidating the interaction between coadsorbed H 2 O and NH 3 in metal–organic frameworks (MOFs) is of paramount importance to uncover mechanistic details of their competitive coadsorption behavior as well as to guide the design of new materials for enhanced NH 3 adsorption in humid environments. Nevertheless, molecular competition between NH 3 and H 2 O within the confined nanopores of MOFs was rarely explored and is poorly understood due to challenges in characterization. Here, we combine in situ infrared spectroscopy with ab initio calculations to unveil the competition of NH 3 and H 2 O for occupying active adsorption sites in the representative MOF-74 material by analyzing the kinetics and energetics of the molecular exchange process. We find that at a high NH 3 /H 2 O ratio, the incoming NH 3 is capable of displacing metal-bound H 2 O and moving it to secondary adsorption sites due to the stronger binding of NH 3 compared with H 2 O. Interestingly, the reverse process of H 2 O displacing metal-bound NH 3 is also possible upon increasing water concentration. Our calculations show that H 2 O exchanging the preabsorbed NH 3 at the metal site is driven not only by a reduced kinetic barrier but also by a favorable energetical state resulting from the formation of water clusters at metal sites and intermolecular H-bonding between the metal-coordinated H 2 O and displaced NH 3 . Our finding emphasizes that the description of molecular occupation in MOFs at equilibrium cannot simply be established by comparing molecules’ binding energies at their strongest binding sites derived by single-component measurements; rather, intermolecular interactions can greatly affect molecular distribution at equilibrium. Furthermore, we show that vibrational modes of adsorbed NH 3 are markedly perturbed upon contact with water molecules, accompanied by a large frequency shift (>30 cm –1 ) and considerable intensity decrease, which arises from the freezing of NH 3 vibrations by coadsorbed H 2 O. As a result, the mechanistic insight obtained through our study sheds light on molecular coadsorption processes in MOFs and helps to assess NH 3 removal efficiency of MOFs containing open-metal sites under realistic conditions, particularly in the presence of humidity.

36 MATERIALS SCIENCE↗

DOE OSTI2023

Expandable Li Percolation Network: The Effects of Site Distortion in Cation-Disordered Rock-Salt Cathode Material

Cation-disordered rock-salt (DRX) materials receive intensive attention as a new class of cathode candidates for high-capacity lithium-ion batteries (LIBs). Unlike traditional layered cathode materials, DRX materials have a three-dimensional (3D) percolation network for Li + transportation. The disordered structure poses a grand challenge to a thorough understanding of the percolation network due to its multiscale complexity. In this work, we introduce the large supercell modeling for DRX material Li 1.16 Ti 0.37 Ni 0.37 Nb 0.10 O 2 (LTNNO) via the reverse Monte Carlo (RMC) method combined with neutron total scattering. Here, through a quantitative statistical analysis of the material’s local atomic environment, we experimentally verified the existence of short-range ordering (SRO) and uncovered an element-dependent behavior of transition metal (TM) site distortion. A displacement from the original octahedral site for Ti 4+ cations is pervasive throughout the DRX lattice. Density functional theory (DFT) calculations revealed that site distortions quantified by the centroid offsets could alter the migration barrier for Li + diffusion through the tetrahedral channels, which can expand the previously proposed theoretical percolating network of Li. The estimated accessible Li content is highly consistent with the observed charging capacity. The newly developed characterization method here uncovers the expandable nature of the Li percolation network in DRX materials, which may provide valuable guidelines for the design of superior DRX materials.

25 ENERGY STORAGE↗

DOE OSTI2024

SCEC/USGS Community Stress-Drop Validation Study: How Spectral Fitting Approaches Influence Measured Source Parameters

Spectral source parameters used to estimate an earthquake’s stress drop (⁠Δσ⁠) can vary significantly across measurement approaches. The Statewide California Earthquake Center/U.S. Geological Survey Community Stress‐Drop Validation Study was initiated to compare source parameter estimates, focusing initially on a dataset from the 2019 Ridgecrest earthquake sequence. As part of that validation effort, here we focus on one potential source of uncertainty: whether spectral fitting approaches alone, applied to a common set of spectra from the 2019 Ridgecrest sequence result in different source parameter estimates. By using a common set of benchmark spectra analyzed across a consistent frequency band of 1–40 Hz, we eliminate many sources of variability. A subgroup of validation study participants volunteered to estimate the low‐frequency displacement (⁠Ω 0 ⁠) and corner frequency (⁠ƒ c ⁠) by fitting a smooth function to benchmark displacement spectra. Participants used linear‐ or log‐sampled spectra, assumed a Brune or Boatwright spectral model, and applied different misfit criteria. We compare 17 approaches used to estimate ⁠Ω 0 ⁠, ƒ c ⁠, and Δσ for 54 earthquake spectra. Our results reveal that 35% of events have Δσ estimates within a factor of two, whereas others exhibit variations exceeding an order of magnitude. The variability in and can largely be attributed to whether a spectrum is consistent with the smooth function of an idealized simple crack model. The trade‐off between Ω 0 and ƒ c may be more pronounced when using linearly sampled spectra, as higher frequency spectral bumps control the fits. As expected, methods that assumed a Boatwright model tended to have lower Ω 0 and somewhat higher ƒ c compared to those assuming a Brune model, although resulting Δσ estimates are similar. Finally, when compared to the overall validation study results, the fitting approach alone may account for between 5% and 90% (25% on average) of the total variability in spectral Δσ⁠.

58 GEOSCIENCES↗

NASA NTRS1975

Internally supported flexible duct joint

An internally supported, flexible duct joint for use in conducting fluids under relatively high pressures in systems where relatively large deflection angles must be accommodated is presented. The joint includes a flexible tubular bellows and an elongated base disposed within the bellows. The base is connected through radiating struts to the bellows near mid-portion and to each of the opposite end portions of the bellows through a pivotal connecting body. A motion-controlling linkage is provided for linking the connecting bodies, whereby angular displacement of the joint is controlled and uniformity in the instantaneous bend radius of the duct is achieved as deflection is imposed.

Kuhn, R. F., Jr.↗

NASA NTRS1976

Determination of strains in optical windows of a high-pressure chamber by holographic interferometry and finite element analysis

Holographic interferometry and finite element analysis have been applied to determine the strain in a large optical window installed in a high-pressure chamber. Two different shapes of windows were chosen, and the outside and inside surface strains of the windows were followed as a function of internal pressure by taking double exposed holograms at 69-bar intervals up to 483 bars. The results were compared with the values calculated by a standard finite element code with an assumption of no displacement at the load-bearing edge. The agreement between two results was found to be good for both cases.

Soga, N.↗

NASA NTRS1985

Fault Offsets and Lateral Crustal Movement on Europa

Structural evidence is presented for tension cracking associated with strike slip faulting and crustal movement in the bright ice covered Galilean satellite Europa. The structure and morphology of wedge shaped bands argues that they formed as a result of the rotation and lateral displacement of crustal units bounded by near vertical faults penetrating through the brittle crustal layer. The significant rotation and lateral motion of crustal blocks near the anti-jove point on Europa, without graben formation, also argues that the lithosphere in the fractured area is mechanically decoupled from the solid silicate interior, by either warm ice at depth or liquid water. Ice at depth and at a large fraction of its melting temperature is expected to behave as a fluid over geologically short time intervals due to its extremely low viscosity relative to the cold, brittle ice near the surface. One proposed convection mechanism is thus considered unlikely as it would be difficult to transmit internal stress through a decoupling layer to the surface.

Schenk, P. M.↗

NASA NTRS1986

Unified control/structure design and modeling research

To demonstrate the applicability of the control theory for distributed systems to large flexible space structures, research was focused on a model of a space antenna which consists of a rigid hub, flexible ribs, and a mesh reflecting surface. The space antenna model used is discussed along with the finite element approximation of the distributed model. The basic control problem is to design an optimal or near-optimal compensator to suppress the linear vibrations and rigid-body displacements of the structure. The application of an infinite dimensional Linear Quadratic Gaussian (LQG) control theory to flexible structure is discussed. Two basic approaches for robustness enhancement were investigated: loop transfer recovery and sensitivity optimization. A third approach synthesized from elements of these two basic approaches is currently under development. The control driven finite element approximation of flexible structures is discussed. Three sets of finite element basic vectors for computing functional control gains are compared. The possibility of constructing a finite element scheme to approximate the infinite dimensional Hamiltonian system directly, instead of indirectly is discussed.

Mingori, D. L.↗

NASA NTRS1992

Observations of height-dependent pressure-perturbation structure of a strong mesoscale gravity wave

Airborne observations using a downward-looking, dual-frequency, near-infrared, differential absorption lidar system provide the first measurements of the height-dependent pressure-perturbation field associated with a strong mesoscale gravity wave. A pressure-perturbation amplitude of 3.5 mb was measured within the lowest 1.6 km of the atmosphere over a 52-km flight line. Corresponding vertical displacements of 250-500 m were inferred from lidar-observed displacement of aerosol layers. Accounting for probable wave orientation, a horizontal wavelength of about 40 km was estimated. Satellite observations reveal wave structure of a comparable scale in concurrent cirrus cloud fields over an extended area. Smaller-scale waves were also observed. Local meteorological soundings are analyzed to confirm the existence of a suitable wave duct. Potential wave-generation mechanisms are examined and discussed. The large pressure-perturbation wave is attributed to rapid amplification or possible wave breaking of a gravity wave as it propagated offshore and interacted with a very stable marine boundary layer capped by a strong shear layer.

Starr, David O'C.↗

NASA NTRS1992

Response of the ionospheric convection pattern to a rotation of the interplanetary magnetic field on January 14, 1988

Ionospheric convection signatures observed over the polar regions are provided by the DMSP F8 satellite. We consider five passes over the Southern summer Hemisphere during a time when the z component of the interplanetary magnetic field was stable and positive and the y component changed slowly from positive to negative. Large-scale regions of sunward flow are observed at very high latitudes consistent with a strong z component. When By and Bz are positive, but By is greater than Bz, strong evidence exists for dayside merging in a manner similar to that expected when Bz is negative. This signature is diminished as By decreases and becomes smaller than Bz, resulting in a four-cell convection pattern displaced toward the sunward side of the dawn-dusk meridian. In this case the sign of By affects the relative sizes of the two highest-latitude cells. In the Southern Hemisphere the duskside high-latitude cell is dominant for By positive and the dawnside high-latitude cell is dominant for By negative. The relative importance of possible electric field sources in the low-latitude boundary layer, the dayside cusp, and the lobe all need to be considered to adequately explain the observed evolution of the convection pattern.

Cumnock, J. A.↗

NASA NTRS2011

Design, Optimization, and Evaluation of Integrally-Stiffened Al-2139 Panel with Curved Stiffeners

A curvilinear stiffened panel was designed, manufactured, and tested in the Combined Load Test Fixture at NASA Langley Research Center. The panel is representative of a large wing engine pylon rib and was optimized for minimum mass subjected to three combined load cases. The optimization included constraints on web buckling, material yielding, crippling or local stiffener failure, and damage tolerance using a new analysis tool named EBF3PanelOpt. Testing was performed for the critical combined compression-shear loading configuration. The panel was loaded beyond initial buckling, and strains and out-of-plane displacements were extracted from a total of 20 strain gages and 6 linear variable displacement transducers. The VIC-3D system was utilized to obtain full field displacements/strains in the stiffened side of the panel. The experimental data were compared with the strains and out-of-plane deflections from a high fidelity nonlinear finite element analysis. The experimental data were also compared with linear elastic finite element results of the panel/test-fixture assembly. Overall, the panel buckled very near to the predicted load in the web regions.

Havens, David↗

DOE OSTI2022

Numerical and experimental investigation of the flame kernel growth in a methane/air mixture near the lean flammability limit

Lean combustion has the potential to improve the thermal efficiency of spark-ignition engines, but it faces the significant challenge of increased cycle-to-cycle variation due to low mixture reactivity and unstable flame dynamics. Computational fluid dynamics (CFD) employing predictive models can guide engine design and optimize operating strategies for lean combustion. However, ignition and combustion models have rarely been validated at fuel-lean conditions, and a fundamental understanding of the early flame kernel growth process is also lacking for a successful sub-model development. Here, the present study develops a numerical simulation framework used to investigate early flame kernel growth in methane/air mixtures. A nanosecond-pulsed discharge (NPD) approach is employed to effectively decouple the flame kernel growth from the electrical discharge due to their difference in timescales, and equivalence ratios near the experimentally measured lean flammability limit (LFL) are selected to focus on challenging mixture conditions. Three numerical investigations, such as the choice of turbulence modeling, grid size, and grid control strategies, are examined to match both LFL and flame kernel structure measured from experiments. It is demonstrated that a quasi-direct numerical simulation (QDNS) with a fixed grid embedding of 10 μm can predict the LFL as φ CFD =0.61 and match the displacement speed of the kernel’s boundary marked in schlieren images. To predict the LFL and flame kernel shape, a fine grid (Δ≤12.5 μm) is needed to capture the consumption of formaldehyde (CH 2 O) in kernel’s reaction branches attached to the anode, and adaptive mesh refinement is replaced with the fixed embedding due to loss of simulation accuracy. Also, it is found that a large-eddy simulation (LES) using the Dynamic Structure model is not suitable for the NPD-induced flame kernel simulation because artificial sub-grid turbulent kinetic energy induced by shock dynamics alters the flow velocity calculation, resulting in divergence of LES from QDNS. Lastly, the simulation well matches the experimental data for the flame kernel evolution in three mixture conditions (φ = 0.7, 0.61, 0.55), showing toroidal flame kernel expansion and flame kernel growth/extinction.

33 ADVANCED PROPULSION SYSTEMS↗

DOE OSTI2025

Atomic-scale insights into topotactic transformations in an extra-large-pore zeolite using time-resolved 3D electron diffraction

Understanding the atomic-scale structural dynamics of phase transformations is crucial for developing materials and tailoring their properties. However, many materials are obtained as polycrystalline powders with large unit cells and/or complex structures, making it challenging to investigate detailed structural changes using conventional X-ray diffraction techniques. Here we employ time-resolved three-dimensional electron diffraction to reveal the topotactic reactions and transformations that convert the extra-large-pore silicate zeolite ECNU-45 into ECNU-46. ECNU-45 features three-dimensional interconnecting 24 × 10 × 10-ring channels, while ECNU-46 consists of one-dimensional 24-ring channels connected to 10-ring pockets. ECNU-45 and ECNU-46 are both examples of pure silicate zeolites with pore openings larger than 22-ring. Our findings indicate changes at six distinct tetrahedral silicon sites, involving atom displacement, addition and removal of framework atoms through bond breakage and formation. This work presents the synthesis of zeolites and also provides atomic-level insights into the dynamic processes of topotactic reactions. Our results have implications for advancing materials engineering and understanding complex solid-state reactions at an atomic scale.

Inorganic chemistry↗

DOE OSTI2025

Accelerated Fuel Qualification of Fast Modular Reactor Fuel in a Thermal Reactor: Modeling and Simulation Paired with Irradiation Testing

The accelerated fuel qualification (AFQ) methodology is applied by simulating accelerated fuel tests of the General Atomics Electromagnetic Systems’ fuel system for its 44-MW(electric) gas-cooled, fast-spectrum fast modular reactor (FMR). This fuel is comprised of UO 2 pellets in SiGA® cladding, a silicon carbide ceramic matrix composite. Fast reactors, like the FMR, offer many benefits, including high fuel utilization and flexibility, but may require a lengthy material design process if tests are performed using fast neutron irradiation alone. A thermal neutron irradiation can instead be used to rapidly test how well key components of the current material models extend to high burnup. Thermal neutrons produce a different radial power distribution within the pin than fast neutrons. However, the temperature and burnup values for the two neutron types are comparable, and the differences between the simulated fuel responses are relatively small, demonstrating the weak sensitivity of the physics-based fuel model calculations on the neutron type and the irradiation rate. Furthermore, the deformation of the SiGA cladding saturates after about 1 displacement per atom for both neutron spectra. In an accelerated fuel test, the irradiation time required to reach the target fuel burnup can be reduced by a factor of 3 by using a small rodlet with a 45% smaller pellet diameter while maintaining the same linear power. Therefore, the time for data collection up to high burnup can be significantly reduced while maintaining the same temperature profile, which largely determines the material response. Tests of fuel rodlets of standard and compact size will be carried out in the Idaho National Laboratory’s Advanced Test Reactor (ATR), including full size and compact rodlets with varying gap sizes. By applying physics-based mechanistic modeling and simulation in accordance with the AFQ methodology, this type of compact rodlet testing in a thermal test reactor captures the necessary phenomena to test fuel material models up to high burnup and to simulate the expected impact of fast neutron radiation on the fuel in FMR operations. Finally, this approach to testing fast reactor fuels in existing thermal test reactors, paired with advanced physics-based mechanistic modeling and simulation, is expected to be applicable to a range of advanced fuels and will decrease the overall fuel qualification timeframe from decades to years.

Advanced test reactor (ATR)↗

DOE OSTI2021

Dynamic Rupture Modeling of the M7.1, 2019 Ridgecrest, California, Earthquake

An important part of the simulation technique implemented in the strong motion prediction recipe developed in Japan, originally proposed by Irikura and Miyake (2011) is the earthquake rupture characterization that is based on established empirical scaling relationships between source parameters and seismic moment. These scaling relationships and rupture characterization are derived from recorded data and are tested by simulations. Recent analysis of results obtained with the Recipe for the 2016 M7.1 Kumamoto earthquake performed by several researchers, indicate that in order to reproduce near-fault long-period ground motions with permanent displacements, typical for earthquakes with surface rupturing, the recipe needs modifications. In particular, improvements are required in characterizing the rupture kinematics at shallow depths, above the seismogenic zone (Irikura et al., 2019). Modeling of rupture dynamics for recorded earthquakes, and numerical simulations for different rupture scenarios, provides physical constrains on slip evolution in time and space, which can be used in adjustments of empirical source scaling relationships for large crustal earthquakes. In this study we mainly focused on rupture dynamics modeling of the 2019 M7 Ridgecrest, California earthquake. The characterization of the kinematic rupture model derived from the dynamic rupture models of this earthquake can inform further refinements of rupture modeling proposed by the Recipe. Through different rupture scenarios we investigated potential relationships between characteristics of Long Period Ground Motion Generation Area (LMGA), used in the Recipe, and asperity depth and rupture initiation.

58 GEOSCIENCES↗

DOE OSTI2025

Geophysical measurements of a demolition at NRF

On May 31 st , 2025, at approximately 14:40:00 UTC, the former Submarine First Westinghouse (SW1) structure housing a large crane was demolished at the Naval Reactors Facility (NRF) located within the perimeter of the Idaho National Laboratory (INL). Several targeted explosives were used to facilitate this demolition. The INL Seismic Monitoring Program (SMP) installed four temporary seismic instrument suites around the site of the demolition in order to monitor ground motion including measuring peak ground acceleration (PGA), peak ground velocity (PGV), and to calculate peak ground displacement (PGD). The demolition produced three types of waves: body waves, surface waves, and acoustic waves. The acoustic wave represents the largest signal received. The PGA, measured on the eastern component of the instrument located approximately 95m away from the demolition site, was 0.187g. The PGV measured was 0.0004 m/s, and the PGD was approximately 0.000006m. Rayleigh waves incident on an instrument located at the Advanced Test Reactor, about 7.6km away, were used to estimate a magnitude of 0.3 at the ATR, representing a yield of energy equivalent to approximately 3 grams of TNT.

58 - GEOSCIENCES↗