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At least 1,009 records · Page 56

New reactions of paraformaldehyde and formaldehyde with inorganic compounds

Both paraformaldehyde and formaldehyde undergo reactions in the presence of several inorganic compounds to generate a variety of interesting organic products that can be important in chemical evolutionary processes. Some examples are acrolein, acetaldehyde, methyl formate, methanol, glycolaldehyde and formic acid. The organic compounds are produced at temperatures as low as 56 C and in high yield (up to 75%). The quantity produced depends principally on the nature of the inorganic compound, the ratio of the inorganic compound to paraformaldehyde, temperature and reaction time. The percent distribution of product depends on some of the foregoing factors.

Becker, R. S.↗

A flash photolysis-resonance fluorescence study of the formation of O/1D/ in the photolysis of water and the reaction of O/1D/ with H2, Ar, and He

The technique employed in the study utilizes the vacuum ultraviolet flash photolysis of H2O combined with time resolved, simultaneous detection of H and O via resonance fluorescence at 121.6 and 130.2 nm respectively. The measurements were made by means of photon counting and multichannel scaling. The sensitivity of the system for H and O is discussed. Experiments are reported in which signals due to H and O were accumulated from the flash photolysis of a mixture of 0.1 torr H2O and 100 torr Ar. Attention is given to the relative importance of two primary processes in the photolysis of water.

Stief, L. J.↗

Launch Processing System - A system to support the Space Shuttle

Kennedy Space Center (KSC) is designing and acquiring a Launch Processing System (LPS), an important part of Ground Support Equipment (GSE), to Support launch site operations in a more efficient way than was done on previous programs. LPS will provide (1) automatic control of GSE and Shuttle systems for test and operations, (2) real time data analysis and information display, and (3) efficient recall of test data and engineering files to support Shuttle ground operations. Modern automation techniques, off-the-shelf components, and modular design are being employed to the maximum to achieve these goals. The cost of acquisition, operations, and maintenance of LPS is of great importance and is considered with each engineering trade.

Paul, H. C.↗

Applications payloads

The future purposes to which the Space Shuttle will or can be put are examined. In addition to the use of the Space Shuttle as a launch/deployment system, the low-gravity environment of the Space Shuttle will be used to conduct important experiments in material processing and cloud microphysics studies. Other purposes include the development of pollution and hydrologic sensors, and of sets of earth-viewing instruments with which to cross correlate data and speed up information extraction. Much attention is given to the flight hardware.

Mathews, C. W.↗

Structure of the Magnetopause: Observations and Implications for Reconnection

The earth's magnetopause is the boundary between a hot tenuous plasma in the magnetosphere and a cooler denser plasma in the magnetosheath. Both of these plasmas contain magnetic fields whose directions are usually different but whose magnitudes are often comparable. Efforts to understand the structure of the magnetosphere were hampered by the variability and complexity of this boundary. Although conclusive direct evidence for a field component, B sub n across the magnetopause was not found, this lack of evidence may reflect the difficulty in determining B sub n in the presence of magnetopause waves rather than the real absence of this component. Considerable indirect evidence exists for an open magnetosphere, but the importance of the reconnection process thought to produce open field lines was questioned.

Fairfield, D. H.↗

A study of Stormsat interactive data analysis facility

Stormsat, a third generation geosynchronous satellite intended for the investigation and forecasting of severe local storms, tropical cyclones and other mesoscale phenomena, could be launched as early as 1982. The paper outlines the interactive data processing and analysis functions which must be performed and presents a possible configuration capable of achieving the demonstration forecast objectives. Important features of the data processing system include (1) interactive extraction of wind, temperature and moisture profiles, cloud structure and precipitation from Stormsat data, and (2) numerical and statistical modeling necessary to provide demonstration forecasts.

Hasler, A. F.↗

Uniform color space analysis of LACIE image products

The author has identified the following significant results. Analysis and comparison of image products generated by different algorithms show that the scaling and biasing of data channels for control of PFC primaries lead to loss of information (in a probability-of misclassification sense) by two major processes. In order of importance they are: neglecting the input of one channel of data in any one image, and failing to provide sufficient color resolution of the data. The scaling and biasing approach tends to distort distance relationships in data space and provides less than desirable resolution when the data variation is typical of a developed, nonhazy agricultural scene.

Nalepka, R. F.↗

Structure of the magnetopause - Observations and implications for reconnection

The earth's magnetopause is the boundary between a hot tenuous plasma in the magnetosphere and a cooler denser plasma in the magnetosheath. Both of these plasmas contain magnetic fields whose directions are usually different but whose magnitudes are often comparable. Efforts to understand the structure of the magnetosphere have been hampered by the variability and complexity of this boundary. Waves on the magnetopause surface propagate toward the magnetotail and produce the multiple boundary crossings frequently seen by spacecraft. Boundary velocities are poorly known and range anywhere within an order of magnitude of 10 km/s. Typical thicknesses are probably of the order of a few hundred km, which is a few times the gyroradius of a thermal proton. Although conclusive direct evidence for a field component, Bn, across the magnetopause has not been found; this lack of evidence may reflect the difficulty in determining Bn in the presence of magnetopause waves rather than the real absence of this component. Considerable indirect evidence exists for an open magnetosphere, but the importance of the reconnection process thought to produce open field lines has recently been questioned.

Fairfield, D. H.↗

Associative ionization of N/2D/ and O

Recent laboratory measurements have shown that N(2P) atoms, and thus probably hot N(2D) atoms, will recombine with atomic oxygen via an associative ionization process at the gas kinetic rate. In the present paper the likelihood of the associative ionization of N(2D) and O playing a significant role in the normal ionosphere is investigated in the light of several recent studies. It is concluded that the associative ionization process is not an important factor and that a more probable cause for disagreements in the various determinations of the recombination coefficient, is the difference in excited states of the ions in the various experiments.

Torr, M. R.↗

The nature of asteroidal differentiation processes - Implications for primordial heat sources

A review of the geochemical data on basaltic achondrite group meteorites, here defined as diogenites, eucrites, howardites, mesosiderites, main-group pallasites and IIIAB irons, suggests that the following processes and properties were important in determining the compositions of igneous materials on asteroidal sized bodies: (1) inhomogeneities in source rock compositions, (2) variable degrees of partial melting from 5-100%, (3) multiple melt genesis from a single source region, (4) fractional crystallization, and (5) remelting of earlier formed igneous rocks. All of this activity started during or shortly after the major asteroidal accretion phase as suggested by the numerous 4.6 Gyr ages for eucrites and may have lasted for at least 200 m.y. The above properties imply an early, intense heat source that was both spatially and temporally variable. A review of asteroid thermal modeling for various heat sources shows that heating by short-lived Al-26 alone appears to be incapable of supplying the observed geochemical variations.

Mittlefehldt, D. W.↗

Spectra from nuclear-excited plasmas

The paper discusses the spectra taken from He-3(n,p)H-3 nuclear-induced plasmas under high thermal neutron flux, lasing conditions. Also, initial spectra are presented for U-235F6 generated plasmas. From an evaluation of these spectra, important atomic and molecular processes that occur in the plasma can be inferred. The spectra presented are the first to be generated by He-3 and U-235F6 nuclear reactions under high neutron flux, lasing conditions. The U-235(n,ff)FF reaction, which liberates 165 MeV of fission-fragment kinetic energy, creates plasmas that are of great interest, since at sufficiently high densities of U-235F6 the gas becomes self-critical; thus, there is no need for an external driving reactor (source of neutrons). The spectra from mixtures of He-3 and Ar, Xe, Kr, Ne, Cl2, F2 and N2 indicate little difference between high-pressure nuclear-induced plasmas and high-pressure electrically pulsed afterglow plasmas for noble-gas systems

De Young, R. J.↗

Dielectronic recombination rates, ionization equilibrium, and radiative emission rates for calcium and nickel ions in low-density high-temperature plasmas

The total dielectronic recombination rates for Ca and Ni ions were calculated taking into account autoionization to excited states of the recombining ion and stabilizing radiative transitions of the recombining electron. Radiative transitions of the recombining ion are found to be the dominant stabilizing processes, and the relative importance of Delta n = 0 and Delta n not equal to 0 transitions in the relevant temperature region is determined for each ion. The relative importance of the Delta n = 0 and Delta n not equal to 0 contributions is significantly altered for some ions by the inclusion of autoionization to excited levels. The relative abundance of the various ionization stages has been determined by using a corona equilibrium model in which collisional ionization and inner-shell excitation followed by autoionization are balanced by direct radiative and dielectronic recombination.

Jacobs, V. L.↗

Effect of time-dependent flight loads on turbofan engine performance deterioration

An analytic evaluation of the dynamic effects of two flight load conditions of the JT9D-7/747 propulsion system is conducted. Predicted performance changes associated with a once-per-flight vertical gust and a typical revenue service landing are calculated. The predicted dynamic load effects on thrust specific fuel consumption are found to be negligible. The results indicate that the quasi-steady state approach to flight loads modeling is adequate to investigate the factors important to the deterioration process.

Lewis, B. L.↗

Topographic domes on Ganymede - Ice vulcanism or isostatic upwarping

Two formation processes are considered for two gently sloping domeshaped features on the surface of Ganymede, lying on grooved terrain and having diameters of roughly 250 km: (1) water vulcanism, triggered by a major impact, and (2) the isostatic upwarping of a crater formed in a thin crust. Numerical simulations show the volume of the domes to be consistent with eruption through fractures created by an impact that excavates partly through a thin crust. Isostatic upwarp rates calculated as a function of effective crustal temperature indicate that upwarping could also create such a dome if the impact excavated to a depth where the crust was sufficiently warm and mobile. Morphologic evidence suggests that both processes may have been important and, if either of the proposed models is correct, it is strongly implied that grooved terrain formation occurred prior to the thickening and stiffening of Ganymede's crust.

Squyres, S. W.↗

Acceleration of energetic ions at the earth's bow shock

A simple analytical solution is presented which incorporates many of the processes believed to be important in the acceleration of the 'diffuse' component of energetic ions at the earth's bow shock, and which can account for many of the characteristics observed for these events. The solution can account for the observed spectral shape, the observed spatial dependence of the intensity, and the observed magnitude and spatial dependence of the anisotropy.

Lee, M. A.↗

The solar modulation of galactic cosmic rays in the outer heliosphere

The intensity changes of galactic cosmic rays associated with the enhanced solar activity during the onset of cycle 21 were observed by Pioneer 10 and Helios 1 and 2, over an extended range of energy and heliocentric distance that provides new insight into the relative importance of the various processes involved in the long-term modulation. A close correspondence is found between changes at 1 AU and those at 23 AU, for hydrogen and helium in the range of 100-200 MeV per nucleon. The time delay observed corresponds to an outward propagation velocity of some 550 km/sec, suggesting that the recently discovered, moderately long-lived, radially propagating shock waves in the outer heliosphere may play a key role in the long-term modulation.

Mcdonald, F. B.↗

Origin and evolution of the giant planets

A discussion is presented of two major giant planet origin hypotheses: (1) protoplanet formation in the solar nebula in the form of a gravitationally unstable, gaseous subcondensation, subsequently evolving as a chemically homogeneous object until a stage at which a solid core may form; and (2) solid core formation by accumulation of planetesimals, followed by the accretion of solar-composition gas onto the core until it becomes unstable to collapse. Under either of the scenarios, evolution is found to comprise an early, cool phase in hydrostatic equilibrium, a hydrodynamic collapse, and a final phase of hydrostatic contraction and cooling to the present state. Attention is given to the physical processes that are most important in the determination of evolutionary characteristics. A concluding note on the cases of Uranus and Neptune is also given.

Bodenheimer, P.↗

A spectral energetics analysis of atmospheric blocking

The spectral energetics of two blocking case studies from the winter of 1978-79 are calculated. One case occurred over the North Atlantic and the other over the North Pacific. The temporal evolution and geographical distribution of the energetics of the planetary-scale (zonal harmonic wavenumbers 1-4) and the intermediate-scale (wavenumbers 5-10) wave ensembles are examined to identify the physical mechanisms important in the blocking process. The Atlantic block was forced by the nonlinear interaction of intense baroclinic cyclone-scale waves with barotropic, ultralong waves. The Pacific blocking resulted from the baroclinic amplification of planetary-scale waves. In addition, at least two necessary conditions are required for the development of blocking. First, one of the forcing mechanisms must be in operation, and second, the phase of the antecedent planetary-scale waves must be such that the forcing mechanism can amplify them into a blocking pattern. In each of the cases studied, the blocking developed downstream of intense intermediate- or large-scale cyclogenesis.

Hansen, A. R.↗