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At least 1,009 records · Page 56

Analysis of fission product distribution and composition in the TRISO layers of AGR-2 fuel

The Advanced Gas Reactor Fuel Qualification and Development Program's second irradiation experiment focuses on the performance of fuel particles produced in an industrial-scale coating system. Ongoing post-irradiation examination efforts include exploration of tristructural-isotropic (TRISO)-coated particle fuel in the as-irradiated state and subjected to elevated temperatures to simulate accident conditions (safety testing). Scanning electron microscopy (SEM) analysis with energy dispersive x-ray spectroscopy (EDS) was used to show the distribution of fission products within the TRISO layers. The SEM analysis showed a variation of fission product distribution within the TRISO layers based on irradiation temperature, burnup, individual particle fission product inventory retention, safety testing history and kernel composition. Finally, a key observation is that particles which likely experienced higher temperature showed a greater diversity and distribution of fission products and actinides in the IPyC and SiC layers, implying that temperature is a dominant variable influencing the transport of radionuclides in TRISO particles.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Consequence analyses of sabotage-induced radiological releases in sodium-cooled fast microreactors

Analysis of three sodium-cooled fast microreactors (SFMs) with thermal powers of 10, 30, and 50 MWt showed that smaller reactors result in lower radiological consequences during a postulated sabotage-induced event because of their reduced core inventory. All SFMs used U-10Zr metal fuel enriched to 15 wt% high-assay low-enriched uranium and operated until their respective effective multiplication factor (k eff ) reduced to less than 1 or until the end of their operational lifespan. Sabotage scenarios were simulated at this point, when the fuel inventory within the core contains the highest-level of radioactivity. Radionuclide core inventories were calculated using the SCALE code at shutdown and 3 days post-shutdown. Dose consequence analyses were performed for three sabotage scenarios using the RASCAL tool. As microreactor developers plan for minimal on-site or complete off-site emergency response, it remains essential to evaluate their physical protection needs and potential hazards, including assessing postulated sabotage-induced events that could become more relevant. SFM licensees should identify a credible worst-case, major accident, estimate release source terms, and perform dose consequence analyses to evaluate site-specific physical protection measures. In conclusion, this recommendation supports a risk-informed, performance-based approach, aligning with applicable regulatory requirements, i.e., 10 CFR Parts 100 and 53 rulemaking in the United States.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Spatially Patterned Architectures to Modulate CO 2 Reduction Cascade Catalysis Kinetics

Electrochemical CO 2 reduction using renewable sources of electrical energy holds promise for converting CO 2 into fuels and chemicals. The complex interactions among chemical/electrochemical reactions and mass transport make it difficult to analyze the effect of an individual process on electrode performance based only on experimental methods. Here, we developed a generalized steady-state simulation to describe an electrode surface in which sequential cascade catalysts are patterned in a periodic trench design. If appropriately constructed, this trench geometry is hypothesized to be able to yield a higher net current density for a CO 2 reduction (CO 2 R) cascade reaction. We have used realistic experimental reaction kinetics to investigate the role of trench geometry in mass transport, local microenvironments, and selectivity for a model CO 2 R cascade reaction. The model considers local concentration gradients of bicarbonate species at quasi-equilibrium and catalytic surface reactions based on concentration-dependent Butler–Volmer kinetics. Our results suggest that varying the spatial distribution of active sites plays a significant role in facilitating effective mass transport between active sites, modulating selectivity for the cascade reaction, and enhancing the yield of desirable cascade products. Moreover, we observe that this trench geometry significantly alters the cascade reaction rate by affecting the local pH, which can cause inadvertent depletion of available aqueous CO 2 to limit the CO 2 R cascade kinetics and modest suppression of the hydrogen evolution reaction (HER). The results highlight the trade-offs between mass transport, pH, and reaction kinetics that become apparent only when considering the coupled physics of all processes at the electrode surface. Here, this model can thus serve as a primary tool to build more selective and efficient patterned architectures for the CO 2 R cascade catalysis.

CO2 reduction↗

Time-Resolved Fuel Density Profiles of the Stagnation Phase of Indirect-Drive Inertial Confinement Implosions

The implosion efficiency in inertial confinement fusion depends on the degree of stagnated fuel compression, density uniformity, sphericity, and minimum residual kinetic energy achieved. Compton scattering-mediated 50–200 keV x-ray radiographs of indirect-drive cryogenic implosions at the National Ignition Facility capture the dynamic evolution of the fuel as it goes through peak compression, revealing low-mode 3D nonuniformities and thicker fuel with lower peak density than simulated. By differencing two radiographs taken at different times during the same implosion, we also measure the residual kinetic energy not transferred to the hot spot and quantify its impact on the implosion performance.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

BISON Capability to Account for Dopant Sensitivity in Relevant UO 2 Material Models

The U.S. Department of Energy’s Nuclear Energy Advanced Modeling and Simulation program aims to develop predictive capabilities using computational methods for the analysis and design of advanced reactor and fuel cycle systems. This program has been supporting the development of BISON, a high-fidelity and high-resolution fuel performance tool at the engineering scale. Incorporation of more physics-based models in BISON for the accident tolerant fuel applications motivated this study. This document details integration of new modeling capabilities in BISON, including: a tensile strength model for uranium dioxide (UO 2 ) fuel to incorporate the microstructural effects (e.g., grain size, fabrication pore size, and porosity), and atomistic-informed creep model for UO 2 fuel that is developed by Los Alamos National Laboratory. Sensitivity analyses are conducted on these models separately as well as a two-dimensional full rod application under normal operating conditions. Lastly, these new modeling capabilities in BISON are exercised in Halden IFA-677.1 and IFA-716.1 assessment cases.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Dual-pump Coherent anti-Stokes Raman scattering measurements in H 2 /CH 4 Counterflow Flames

Temperature and major species concentration measurements are reported in a Williams Seshadri counterflow burner using dual-pump coherent anti-Stokes Raman scattering (DPCARS). Hencken burner H2/Air flames with equivalence ratio of 0.8-1.4 were used to characterize the accuracy of the system. The mean errors for temperature, XH2/XN2 mole fraction ratio, and XO2/XN2 mole fraction ratio are 1.0%, 14.7%, and 5.5%, respectively. The counterflow burner uses a CH4, H2, and N2 mixture as fuel and synthetic air as oxidizer. Measurements were performed along the counterflow burner central axis for two different fuel compositions: 4% H2/86% CH4/10% N2 and 87%H2/3% CH4/10% N2. The measured temperature and species mole fractions agree well with the 1-D opposed-flow diffusion flame simulation. One observation is that the fuel inlet temperature is higher than 300 K, which suggests the possibility of the stagnation plane residing closer to the fuel side. Lastly, these measurements provide valuable data for testing and validation of advanced 2-D flame models.

Murdock, Benjamin K.↗

Performance and Operational Characteristics of a Python Turbine-propeller Engine at Simulated Altitude Conditions / Carl L. Meyer and Lavern A. Johnson

The performance and operational characteristics of a Python turbine propeller engine have been investigated over a range of engine operating conditions at simulated altitudes from 5000 to 40,000 feet in the NACA Lewis altitude wind tunnel . For the performance phase of the investigation, a single cowl-inlet ram pressure ratio was maintained and independent control of engine speed and fuel flow was used to obtain a range of power at each engine speed. Engine performance data obtained at a given altitude could not be used to predict performance accurately at other altitudes by use of the standard air pressure and temperature generalizing factors. Specific fuel consumption based on shaft horsepower decreased as the shaft horsepower increased at a given engine speed. At a given altitude condition and turbine -inlet total temperature, there was an optimum engine speed at which maximum shaft horsepower was obtained. At a given engine speed and turbine-inlet total temperature, a greater portion of the total available energy was converted to propulsive power as the altitude increased. Windmilling starts were made at altitudes up to 40,000 feet; the minimum true airspeed required for successful windmilling starts increased as the altitude was raised. In general, the engine control prevented large overshoots or undershoots of engine speed during starts, accelerations, and decelerations.

Engines - Armstrong-Siddely Python Turbo-Propeller↗

A Non-Linear Approach to Spacecraft Trajectory Control in the Vicinity of a Libration Point

An expanding interest in mission design strategies that exploit libration point regions demands the continued development of enhanced, efficient, control algorithms for station-keeping and formation maintenance. This paper discusses the development of a non-linear, station-keeping, control algorithm for trajectories in the vicinity of a libration point. The control law guarantees exponential convergence, based on a Lyaponov analysis. Controller performance is evaluated using FreeFlyer(R) and MATLAB(R) for a spacecraft stationed near the L2 libration point in the Earth-Moon system, tracking a pre-defined reference trajectory. Evaluation metrics are fuel usage and tracking accuracy. Simulation results are compared with a linear-based controller for a spacecraft tracking the same reference trajectory. Although the analysis is framed in the context of station-keeping, the control algorithm is equally applicable to a formation flying problem with an appropriate definition of the reference trajectory.

Luquette, Richard J.↗

A Non-Linear Approach to Spacecraft Formation Control in the Vicinity of a Collinear Libration Point

An expanding interest in mission design strategies that exploit libration point regions demands the continued development of enhanced, efficient, control algorithms for station-keeping and formation maintenance. This paper discusses the development of a non-linear, formation maintenance, control algorithm for trajectories in the vicinity of a libration point. However, the formulation holds for any trajectory governed by the equations of motion for the restricted three body problem. The control law guarantees exponential convergence, based on a Lyaponov analysis. FreeFlyer and MATLAB provide the simulation environment for controller performance evaluation. The simulation, modeled after the MAXIM Pathfinder mission, maintains the relative position of a "follower" spacecraft with respect to a "leader" spacecraft, stationed near the L2 libration point in the Sun-Earth system. Evaluation metrics are fuel usage and tracking accuracy.

Luquette, Richard J.↗

Small Spacecraft System-Level Design and Optimization for Interplanetary Trajectories

The feasibility of an interplanetary mission for a CubeSat, a type of miniaturized spacecraft, that uses an emerging technology, the CubeSat Ambipolar Thruster (CAT) is investigated. CAT is a large delta-V propulsion system that uses a high-density plasma source that has been miniaturized for small spacecraft applications. An initial feasibility assessment that demonstrated escaping Low Earth Orbit (LEO) and achieving Earth-escape trajectories with a 3U CubeSat and this thruster technology was demonstrated in previous work. We examine a mission architecture with a trajectory that begins in Earth orbits such as LEO and Geostationary Earth Orbit (GEO) which escapes Earth orbit and travels to Mars, Jupiter, or Saturn. The goal was to minimize travel time to reach the destinations and considering trade-offs between spacecraft dry mass, fuel mass, and solar power array size. Sensitivities to spacecraft dry mass and available power are considered. CubeSats are extremely size, mass, and power constrained, and their subsystems are tightly coupled, limiting their performance potential. System-level modeling, simulation, and optimization approaches are necessary to find feasible and optimal operational solutions to ensure system-level interactions are modeled. Thus, propulsion, power/energy, attitude, and orbit transfer models are integrated to enable systems-level analysis and trades. The CAT technology broadens the possible missions achievable with small satellites. In particular, this technology enables more sophisticated maneuvers by small spacecraft such as polar orbit insertion from an equatorial orbit, LEO to GEO transfers, Earth-escape trajectories, and transfers to other interplanetary bodies. This work lays the groundwork for upcoming CubeSat launch opportunities and supports future development of interplanetary and constellation CubeSat and small satellite mission concepts.

Spangelo, Sara↗

Evaluation of the Controller-Managed Spacing Tools, Flight-Deck Interval Management and Terminal Area Metering Capabilities for the ATM Technology Demonstration #1

NASA has developed a suite of advanced arrival management technologies combining time-based scheduling with controller- and flight deck-based precision spacing capabilities that allow fuel-efficient arrival operations during periods of high throughput. An operational demonstration of these integrated technologies, i.e., the ATM Technology Demonstration #1 (ATD-1), is slated for 2016. Human-in-the-loop simulations were conducted to evaluate the performance of the ATD-1 system and validate operational feasibility. The ATD-1 system was found to be robust to scenarios with saturated demand levels and high levels of system delay. High throughput, 10 above baseline demand levels, and schedule conformance less than 20 seconds at the 75th percentile were achievable. The flight-deck interval management capabilities also improved the median schedule conformance at the final approach fix from 5 to 3 seconds with less variance.

terminal metering↗

Analysis of a 100-W Regenerative Fuel Cell Demonstration

A 100-W regenerative fuel cell (RFC) demonstration was successfully completed at the NASA Glenn Research Center on December 11, 2014. This effort was funded by Advanced Space Power Systems milestone and represented the first demonstration of passive laboratory-scale stacks arranged as an RFC, consisting of a non-flow-through fuel cell and a static-feed electrolyzer. Once developed, these stacks present the potential to minimize system mass, volume, and parasitic power in comparison to existing terrestrial electrochemical systems and nonnuclear power generation options. Testing involved the fuel cell powering a simulated load then recycling fuel cell product water by subsequently electrolyzing it to regenerate hydrogen and oxygen gases for fuel cell operations. A total of five cycles were completed over a 2-week period, yielding cell voltage data for stack performance and quality measures for regenerated reactants. Overall, round-trip efficiency was calculated to be 47.4 percent. Gas crossover was observed in electrolyzer gas products, as residual gas analysis showed 1.1 percent hydrogen in oxygen and 0.4 percent oxygen in hydrogen. Fuel cell product water was determined to be more acidic and conductive and have a higher fluoride content when compared to deionized water.

fuel cell↗

Development of Complexity Science and Technology Tools for NextGen Airspace Research and Applications

The objective of this research by NextGen AeroSciences, LLC is twofold: 1) to deliver an initial "toolbox" of algorithms, agent-based structures, and method descriptions for introducing trajectory agency as a methodology for simulating and analyzing airspace states, including bulk properties of large numbers of heterogeneous 4D aircraft trajectories in a test airspace -- while maintaining or increasing system safety; and 2) to use these tools in a test airspace to identify possible phase transition structure to predict when an airspace will approach the limits of its capacity. These 4D trajectories continuously replan their paths in the presence of noise and uncertainty while optimizing performance measures and performing conflict detection and resolution. In this approach, trajectories are represented as extended objects endowed with pseudopotential, maintaining time and fuel-efficient paths by bending just enough to accommodate separation while remaining inside of performance envelopes. This trajectory-centric approach differs from previous aircraft-centric distributed approaches to deconfliction. The results of this project are the following: 1) we delivered a toolbox of algorithms, agent-based structures and method descriptions as pseudocode; and 2) we corroborated the existence of phase transition structure in simulation with the addition of "early warning" detected prior to "full" airspace. This research suggests that airspace "fullness" can be anticipated and remedied before the airspace becomes unsafe.

Holmes, Bruce J.↗

Performance Analysis of Magnetohydrodynamic Drag Modulation for Actively Controlled Aerocapture at Neptune

Missions to the Ice Giants are a top priority for flagship missions this coming decade. However, a fully propulsive orbital insertion into these planets requires an immense amount of fuel, taking a significant portion of the spacecraft mass and restricting the scientific payload. To mitigate this, aerocapture has been heavily investigated. Although simulations have shown that aerodynamically controlled aerocapture can successfully insert into an orbit around both Ice Giants, the deep atmospheric pass required necessitates a complex, mass expensive, and sometimes prohibitive thermal protection system. Magnetohydrodynamic drag modulation serves as a potential alternative control method for aerocapture which could not only save propellant mass compared to fully propulsive orbital insertion, but also save thermal protection system mass compared to conventional aerocapture methods. Both aerodynamically controlled and magnetohydrodynamically controlled aerocapture methodologies were simulated in NASA Langley’s high-fidelity six degree-of-freedom flight dynamics code, the Program to Optimize Simulated Trajectories II. Each method was simulated to identical missions to Neptune using a numerical predictor-corrector algorithm to optimize the control towards the target orbit. The results concluded that magnetohydrodynamic drag modulation can successfully capture and performs on par with aerodynamic drag modulation while significantly reducing the heatflux and aeroshell complexity.

Danny N Nguyen↗

Modeling ablator defects as a source of mix in high-performance implosions at the National Ignition Facility

Recent indirect drive inertial confinement fusion implosions on the National Ignition Facility (NIF) [Spaeth et al., Fusion Sci. Technol. 69, 25 (2016)] have crossed the threshold of ignition. However, performance has been variable due to several factors. One of the leading sources of variability is the quality of the high-density carbon (HDC) shells used as ablators in these experiments. In particular, these shells can have a number of defects that have been found to correlate with the appearance of ablator mix into the hot spot and a degradation in nuclear yield. These defects include pits on the ablator surface, voids in the ablator bulk, high-Z debris from the Hohlraum wall that adheres to the capsule surface, and finally the inherent granular micro-structure of the crystalline HDC itself. This paper summarizes high-resolution modeling of each of these mix sources in two recent high-performance NIF implosion experiments. The simulated impact from a range of individual capsule defects is found to be broadly consistent with the trends seen in experiment, lending credence to the modeling results and the details of the mixing process that they reveal. Interestingly, modeling of the micro-structure inherent to HDC shows that this perturbation source results in considerable mixing of the deuterium–tritium fuel with ablator material during the implosion. The reduction in fuel compression from this mix results in an approximately factor of two reduction in neutron yield in current implosions and emphasizes the importance of mitigating this significant performance degradation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Techno-economic prospects for producing Fischer-Tropsch jet fuel and electricity from lignite and woody biomass with CO 2 capture for EOR

This work explores the prospective techno-economic performance of facilities that produce low- and net-negative-carbon liquid transportation fuels and electricity with CO 2 capture for enhanced oil recovery. The lignite and biomass-to-jet fuel process is based on KBR’s TRIG gasifier, Rectisol (for sulfur removal and CO 2 capture), fixed-bed low temperature Fischer-Tropsch synthesis of liquid fuels, and Brayton/Rankine combined cycles to convert synthesis/refining off-gases and waste heat to electricity. This work leverages a recent, highly-detailed assessment of a prospective first-of-a-kind (FOAK) demonstration facility to develop highly detailed Aspen Plus process simulations for nine prospective N th -of-a-kind (NOAK) plant equipment configurations. Component-level capital costs from the FOAK study are scaled and adjusted to reflective prospective learning-by-doing to estimate capital costs for the NOAK designs. NOAK plant economic performance is found to be largely insensitive to variations in plant configurations and electricity output fraction, but biomass input fraction significantly affects profitability. Facilities that consume only carbon–neutral biomass, with no lignite co-feed, have significantly net-negative carbon emissions and the most favorable prospective economics when carbon emissions are priced. For these facilities, the crude oil price required for plant economic viability falls rapidly from $\$$100/bbl as carbon emission prices increase above $\$$120/tonne CO 2eq . In general, plants that co-fire lignite with biomass are less profitable (than 100% biomass plants) due to their higher net greenhouse gas emissions.

09 BIOMASS FUELS↗

Hydrothermal Corrosion of Latest Generation of FeCrAl Alloys for Nuclear Fuel Cladding

After the Fukushima nuclear disaster, the nuclear materials community has been vastly investing in accident tolerant fuel (ATF) concepts to modify/replace Zircaloy cladding material. Iron–chromium–aluminum (FeCrAl) alloys are one of the leading contenders in this race. In this study, we investigated FA-SMT (or APMT-2), PM-C26M, and Fe17Cr5.5Al over a time period of 6 months in simulated BWR environments and compared their performance with standard Zirc-2 and SS316 materials. Our results implied that water chemistry along with alloy chemistry has a profound effect on the corrosion rate of FeCrAl alloys. Apart from SS316 and Zirc-2 tube specimens, all FeCrAl alloys showed a mass loss in hydrogen water chemistry (HWC). FA-SMT displayed minimal mass loss compared to PM-C26M and Fe17Cr5.5Al because of its higher Cr content. The mass gain of FeCrAl alloys in normal water chemistry (NWC) is significantly less when compared to Zirc-2.

36 MATERIALS SCIENCE↗