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At least 1,009 records · Page 56

An experimental study on round-trip efficiency of a preheating control with a medium office building

The interactions between building energy efficiency and demand response (DR) with buildings may complicate their impacts on the electricity grid and buildings, yet those interactions are not well understood. This work fills this gap by presenting an experimental study that quantifies the effects of DR on building energy efficiency. Unlike existing studies, this work 1) investigates the uncertainty levels when assessing the effects of DR; 2) studies the impact of rooftop heat pumps with direct expansion refrigerant-to-air coils on the round-trip efficiency. Specifically, we considered a medium office building (~1860 m 2 ), which is served by rooftop units, located in eastern Washington State. We performed preheating control tests during typical heating days in the year 2022 and compared the building’s energy consumption during the testing days to that during normal operation days under similar weather conditions. To understand how well those normal operation days represent the baseline for the assessment, the relationship between the energy performance of this building and weather conditions was also studied. Experimental results reveal that the round-trip efficiency (i.e., the ratio of discharging energy output from the building to charging energy input into the building) was between 0.16 and 0.92. The results show that significant energy loss may occur during the preheating process. Finally, it also suggests a significant correlation between the energy efficiency of the studied building under the preheating control and the outdoor temperature; and a highly nonlinear relationship between the zone temperature changing rate and the weather condition.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Wickability-optimized textured liquid-desiccant air dehumidifiers for independent moisture management in energy-efficient buildings

Liquid-desiccant-based air conditioning systems are envisioned to enable independent humidity management, thereby improving the energy efficiency of future buildings. Existing liquid-desiccant-based air conditioning concepts, however, suffer from a poor liquid flow distribution deteriorating moisture removal rate. They are consequently flooded with the liquid-desiccant solution, which significantly degrades the energy efficiency of the dehumidification process. Here, in this work, the capillary forces and wickability effect of textured air dehumidifier surfaces are altered to minimize the liquid-desiccant flow rate of the fully wetted state, thereby transforming the physics of interfacial desiccant flow distribution. Consequently, the wickability-optimized air dehumidifier surface maximizes both moisture removal rate and dehumidification energy efficiency. It was interestingly found that the length scale of a textured air dehumidifier surface concept is optimized at an intermediate pattern density. Dry solid-air menisci appear at length scales exceeding the optimum pattern distance while the effective liquid–air interfacial area is reduced at smaller length scales, both of which degrade the moisture removal rate. At the optimum pattern density, the effective liquid–air interfacial area increases with the solution flow rate, thereby increasing the dehumidification rate. At a water vapor pressure potential of 3 kPa and a solution flow rate of 2.8 g/s, experimental results indicated a moisture removal rate of 0.16 g/m2-s for a textured surface concept with a capillary length scale of 3 mm, a 28% improvement compared with that of smooth-plate dehumidifier surfaces. A high moisture removal rate of the textured surface at a low desiccant flow rate led to a high thermal efficiency of 0.75 at a water vapor pressure potential of 5.6 kPa and a LiBr flow rate of 2.8 g/s. The insights gained from the present study accelerate the development of advanced textured surface concepts for next-generation liquid-desiccant-based air dehumidification systems offering independent humidity management for future energy-efficient buildings.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Evaluating energy efficiency potential in low-income households: A flexible and granular approach

This study presents a new approach to evaluating energy efficiency potential that provides a more accurate, granular, and flexible estimate of the cost-effective energy efficiency potential in households of various income ranges. Results from this work estimate that in U.S. single-family households with income less than 200% of the federal poverty level, energy efficiency packages tailored to maximize net present value could result in an estimated $13 billion per year in energy cost savings, or $670 per year for an average household, corresponding to about 1 EJ (0.9 quads) of annual primary energy savings. These types of metrics can be estimated for other geographies (regions, states, and counties) and for other ranges of household income. These results can be used by policymakers and program designers to improve the cost-effectiveness of income-qualified programs and to improve the equity of non-income-qualified programs. The results can also be used to understand how energy efficiency opportunities differ between urban and rural areas, as well as how energy efficiency can spur economic development in areas that have had high poverty rates for decades.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Quantifying CO 2 storage efficiency factors in hydrocarbon reservoirs. A detailed look at CO 2 Enhanced Oil Recovery

Carbon dioxide (CO 2 ) enhanced oil recovery (EOR) will likely be the primary means of geologic CO 2 storage during the early stages of commercial-scale carbon capture and storage (CCS) because of the inherent economic incentives as well as the abundant experience and demonstrated success in the United States, where CO 2 EOR has been employed since 1974. The work presented here estimates CO 2 storage efficiency factors in CO 2 EOR operations using a unique industry database of CO 2 EOR sites and 12 different reservoir simulation models. The simulation models encompass fluvial clastic and shallow shelf carbonate depositional environments for reservoir depths of 1219 and 2438 m (4000 and 8000 feet) and 7.6-, 20-, and 64-m (25-, 66-, and 209-foot)-thick pay zones. A novel statistical modeling technique incorporating the Michaelis–Menten function is used to generate empirical percentile estimates of CO 2 storage efficiency factors. West Texas San Andres dolomite water alternating gas (WAG) CO 2 flood performance data were used to derive P10, P50, and P90 CO 2 storage efficiency factors of 0.76, 1.28, and 1.74 Mscf/STB (stock tank barrel) of original oil in place. Median CO 2 storage efficiency factors from continuous CO 2 injection following conventional waterflood varied from 15% to 61% and 8% to 40% for fluvial clastic and shallow shelf carbonate simulation models, respectively, while those from WAG injection varied from 14% to 42% and 8% to 31%, respectively. Variation in the CO 2 storage efficiency factors was largely attributable to reservoir depth (a surrogate for reservoir pressure and temperature) and lithology (clastic versus carbonate). The results of this work provide practical information that can be used to quantify CO 2 storage resource estimates in oil reservoirs during CO 2 EOR operations (as opposed to storage following depletion) and the uncertainty associated with those estimates.

54 ENVIRONMENTAL SCIENCES↗

Assessing hydrogen supply chains: An integrated review of leakage and energy efficiency studies

This paper examines hydrogen leakage and efficiency across the supply chain for liquid, gaseous, and mixed hydrogen systems. These factors are crucial for assessing hydrogen's role in mitigating emissions and facilitating a clean energy transition. Drawing on a comprehensive review of existing literature and model-based analysis, the study compiles leakage rates and efficiency metrics at each stage of the supply chain: production, storage, transmission, distribution, and end-use. These data inform system scenarios that estimate the impact of leakage on overall performance and climate benefits. The analysis also identifies persistent data gaps, particularly for liquid and mixed system configurations, and outlines priorities for future research. A comparison of hydrogen system types shows that gaseous pathways generally achieve the highest efficiencies (28 %–39 %) and the lowest leakage rates (∼4.5 %) across the supply chain. Liquid hydrogen systems, while favorable for long-distance and high-volume transport due to their higher energy density, exhibit lower efficiency (∼28 %) and a greater leakage potential (∼12 %). Mixed systems, which combine gaseous and liquid elements (e.g., pipeline transmission followed by liquefaction and truck distribution), show compounded energy losses and moderate-to-high leakage rates (6.8 %–9.4 %), highlighting trade-offs associated with added system complexity. The study highlights opportunities for technological advancements, including optimizing liquefaction, enhancing insulation for storage and transportation, and refining refueling equipment. These improvements are crucial for maximizing the climate benefits of hydrogen. The results offer actionable insights for researchers, industry, and policymakers working to develop low-leakage, high-efficiency hydrogen infrastructure.

08 HYDROGEN↗

Effect of coaxial nozzle wear on catchment efficiency in direct energy deposition built components

Laser based Direct Energy Deposition (DED) systems using metallic powder feedstock are recognized as a promising manufacturing method for their ability to shorten production cycles and create complex part geometries. Components are built by generating a melt pool with a high-power laser beam while material is coaxially injected and left to solidify. An impediment to large scale use of DED lies in poor powder catchment efficiency, the condition in which a portion of injected powder escapes the melt pool resulting in a ratio of decreased printed material mass to mass of supplied feedstock. The wear state of a coaxial nozzle on a DED system within a hybrid manufacturing machine tool has been observed to decrease catchment efficiency over time. Herein this study investigates this effect by adapting flow visualization techniques to an in-situ process monitoring format, the implementation of a Computational Fluid Dynamics (CFD) simulation, and deposition testing. Nozzle geometric defects due to wear are identified and categorized, and the impact of nozzle tip wear, resulting in axial tip reduction, on powder catchment efficiency is proven by multiple calculation methods. A linear correlation between catchment efficiency and powder stream diameter is identified, causing a 15–20% loss in efficiency sustained over incremental nozzle tip reduction up to − 1 mm. These results provide a foundation for further study of wear effects and Zero defect manufacturing solutions for powder fed DED systems.

42 ENGINEERING↗

Demonstration of a Highly Efficient Solid Oxide Fuel Cell Power System Using Adiabatic Steam Reforming and Anode Gas Recirculation

Solid oxide fuel cells (SOFC) are currently being developed for a wide variety of applications because of their high efficiency at multiple power levels. Applications for SOFCs encompass a large range of power levels including 1-2 kW residential combined heat and power applications, 100-250 kW sized systems for distributed generation and grid extension, and MW-scale power plants utilizing coal. This paper reports on the development of a highly efficient, small-scale SOFC power system operating on methane. The system uses adiabatic steam reforming of methane and anode gas recirculation to achieve high net electrical efficiency. The anode exit gas is recirculated and all of the heat and water required for the endothermic reforming reaction are provided by the anode gas emerging from the SOFC stack. Although the single-pass fuel utilization is only about 55%, because of the anode gas recirculation the overall fuel utilization is up to 93%. The demonstrated system achieved gross power output of 1650 to 2150 watts with a maximum net LHV efficiency of 56.7% at 1720 watts. Overall system efficiency could be further improved to over 60% with use of properly sized blowers.

01 COAL, LIGNITE, AND PEAT↗

Thin-film semiconductor perspective of organometal trihalide perovskite materials for high-efficiency solar cells

Organolead trihalide perovskites (OTPs) are arising as a new generation of low-cost active materials for solar cells with efficiency rocketing from 3.5% to over 20% within only five years. From “dye” in dye sensitized solar cells to “hole conductors” and “electron conductors” in mesoscopic heterojunction solar cells, there has been a dramatic conceptual evolution on the function of OTPs in photovoltaic devices. OTPs were originally used as dyes in Gratzel cells, achieving a high efficiency above 15% which, however, did not manifest the excellent charge transport properties of OTPs. An analogy of OTPs to traditional semiconductors was drawn after the demonstration of highly efficient planar heterojunction structure OTP devices and the observation of their excellent bipolar transport properties with a large diffusion length exceeding 100 nm in CH 3 NH 3 PbI 3 (MAPbI 3 ) polycrystalline thin films. Here, this review aims to provide the most recent advances in the understanding of the origin of the high OTP device efficiency. Specifically we will focus on reviewing the progress in understanding 1) the characterization of fantastic optoelectronic property of OTPs, 2) the unusual defect physics that originate the optoelectronic property; 3) morphology control of the perovskite film from fabrication process and film post-treatment, and 4) device interface and charge transport layers that dramatically impact device efficiency in the OTP thin film devices; 5) photocurrent hysteresis; 6) tandem solar cells; 7) stability of the perovskite materials and solar cell devices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Area-preserving scheme for efficiency enhancement in single-pass tapered free electron lasers

Efficiency enhancement of a single-pass short-wavelength high-gain tapered free electron laser (FEL) has recently been intensively studied. The goal is to sustain the growth of radiation power in the post-saturation regime. Among the various schemes, the undulator tapering is considered an effective route to achieve higher power extraction efficiency. The tapering strategy can be of constant or varying resonant phase along the undulator axis. In this paper we propose an efficiency-enhancement scheme based on preservation of the longitudinal phase space area which ensures trapping of resonant particles in the ponderomotive bucket as long as possible along the undulator axis before significant particle depletion occurs. In the meanwhile such a scheme takes advantage of the increase of the radiation field amplitude to precipitate the particle deceleration process at the middle stage of undulator tapering. We analyze such an area-preserving scheme of undulator tapering by formulating the post-saturation FEL interaction in a one-dimensional (1-D) model via introduction of the particle trapping fraction. The output performance is evaluated through numerical iteration and confirmed with 1-D particle tracking simulations. The results show that the optimal power extraction efficiency based on the proposed scheme, together with a prebunched beam, can be greatly improved within relatively short taper length compared with other schemes before radiation diffraction effect becomes significant. Besides, the undesired sideband effects are found to be effectively suppressed. For the proposed area-preserving taper scheme, we also derive an analytical approximate formula for the resonant phase as a function of undulator axis. In conclusion, we expect that the analysis can shed light on the aim to further enhance the power extraction efficiency in single-pass tapered FELs.

47 OTHER INSTRUMENTATION↗

Surface and bulk effects of K in highly efficient Cu 1-x K x InSe 2 solar cells

To advance knowledge of the beneficial effects of K in Cu(In,Ga)(Se,S) 2 (CIGS) photovoltaic (PV) absorbers, recent Cu-K-In-Se phase growth studies have been extended to PV performance. First, the effect of distributing K throughout bulk Cu 1-x K x InSe 2 absorbers at low K/(K+Cu) compositions (0 = x = 0.30) was studied. Efficiency, open-circuit voltage (VOC), and fill factor (FF) were greatly enhanced for x ~ 0.07, resulting in an officially-measured 15.0%-efficient solar cell, matching the world record CuInSe 2 efficiency. The improvements were a result of reduced interface and bulk recombination, relative to CuInSe 2 (x ~ 0). However, higher x compositions had reduced efficiency, short-circuit current density (J SC ), and FF due to greatly increased interface recombination, relative to the x ~ 0 baseline. Next, the effect of confining K at the absorber/buffer interface at high K/(K+Cu) compositions (0.30 = x = 0.92) was researched. Previous work showed that these surface layer growth conditions produced CuInSe 2 with a large phase fraction of KInSe 2 . After optimization (75 nm surface layer with x ~ 0.41), these KInSe 2 surface samples exhibited increased efficiency (officially 14.9%), VOC, and FF as a result of decreased interface recombination. The KInSe 2 surfaces had features similar to previous reports for KF post-deposition treatments (PDTs) used in world record CIGS solar cells - taken as indirect evidence that KInSe 2 can form during these PDTs. Both the bulk and surface growth processes greatly reduced interface recombination. However, the KInSe 2 surface had higher K levels near the surface, greater lifetimes, and increased inversion near the buffer interface, relative to the champion bulk Cu 1-x K x InSe 2 absorber. These characteristics demonstrate that K may benefit PV performance by different mechanisms at the surface and in the absorber bulk.

14 SOLAR ENERGY↗

Evaluating the efficiency of municipalities in collecting and processing municipal solid waste: A shared input DEA-model

Highlights: Black-Right-Pointing-Pointer Complexity in local waste management calls for more in depth efficiency analysis. Black-Right-Pointing-Pointer Shared-input Data Envelopment Analysis can provide solution. Black-Right-Pointing-Pointer Considerable room for the Flemish municipalities to improve their cost efficiency. - Abstract: This paper proposed an adjusted 'shared-input' version of the popular efficiency measurement technique Data Envelopment Analysis (DEA) that enables evaluating municipality waste collection and processing performances in settings in which one input (waste costs) is shared among treatment efforts of multiple municipal solid waste fractions. The main advantage of this version of DEA is that it not only provides an estimate of the municipalities overall cost efficiency but also estimates of the municipalities' cost efficiency in the treatment of the different fractions of municipal solid waste (MSW). To illustrate the practical usefulness of the shared input DEA-model, we apply the model to data on 293 municipalities in Flanders, Belgium, for the year 2008.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A carbon-efficient bicarbonate electrolyzer

Carbon efficiency is one of the most pressing problems of carbon dioxide electroreduction today. While there have been studies on anion exchange membrane electrolyzers with carbon dioxide (gas) and bipolar membrane electrolyzers with bicarbonate (aqueous) feedstocks, both suffer from low carbon efficiency. In anion exchange membrane electrolyzers, this is due to carbonate anion crossover, whereas in bipolar membrane electrolyzers, the exsolution of carbon dioxide (gas) from the bicarbonate solution is the culprit. Here, we first elucidate the root cause of the low carbon efficiency of liquid bicarbonate electrolyzers with thermodynamic calculations and then achieve carbon-efficient carbon dioxide electroreduction by adopting a near-neutral-pH cation exchange membrane, a glass fiber intermediate layer, and carbon dioxide (gas) partial pressure management. We convert highly concentrated bicarbonate solution to solid formate fuel with a yield (carbon efficiency) of greater than 96%. A device test is demonstrated at 100 mA cm -2 with a full-cell voltage of 3.1 V for over 200 h.

42 ENGINEERING↗

Your Best Single-Junction Solar Cell Does Not Always Make an Efficient Tandem Partner

Tandem solar cells, where multiple single-junction cells are combined optically in series, provide a path to making cells with high areal efficiencies, with multiple material systems capable of achieving greater than 30% efficiency under 1-sun conditions. However, there are many different material combinations and configurations used to make a tandem, and it can be challenging to understand how advances in one material system will impact the performance of a tandem device. Here, we have built an open-source calculator based on the spectral efficiency metric proposed by Yu et al. to easily enable calculation of spectral efficiency for single junctions and predicted maximum efficiency of tandem pairs, accounting for different optical and electrical coupling between the top and bottom junctions.

14 SOLAR ENERGY↗

Onset of the Efficiency Droop in GaInN Quantum Well Light-Emitting Diodes under Photoluminescence and Electroluminescence Excitation

The efficiency of Ga0.87In0.13N/GaN single and multiple quantum well (QW) light-emitting diodes is investigated under photoluminescence (PL) and electroluminescence (EL) excitation. By measuring the laser spot area (knife-edge method) and the absorbance of the GaInN QW (transmittance/reflectance measurements), the PL excitation density can be converted to an equivalent EL excitation density. The EL efficiency droop-onset occurs at an excitation density of 2.08 × 1026 cm–3 s–1 (J = 10 A/cm2), whereas no PL efficiency droop is found for excitation densities as high as 3.11 × 1027 cm–3 s–1 (J = 149 A/cm2). Considering Shockley–Read–Hall, radiative, and Auger recombination and including carrier leakage shows that the EL efficiency droop is consistent with a reduction of injection efficiency.

36 MATERIALS SCIENCE↗

Continental-Scale Geographic Trends in Barometric-Pumping Efficiency Potential: A North American Case Study

Barometric pumping is a gas transport mechanism that has important implications for many applications involving subsurface gas seepage processes. Here, this study provides the first continental-scale analysis of barometric-pumping efficiency potential based on meteorology. We quantified the barometric-pumping efficiency potential at 1,257 locations across the continental US and Canada. The results provide continental-scale geographic dependencies of barometric-pumping efficiency potential, indicating a significant correlation with latitude and a nonlinear dependence on longitude. The analysis also indicates that variability in barometric-pumping efficiency potential decreases with distance from the coast and as elevation increases. Locations far from the coastline are more likely to have upper mid-range potentials, while higher elevation locations are more likely to have low potentials. The highest barometric-pumping efficiency potentials are mostly found around the Gulf of St. Lawrence around 50°N. Locations along the Atlantic coast exhibit large-scale variations in potentials with a clear increasing trend with latitude.

58 GEOSCIENCES↗

How reliable are efficiency measurements of perovskite solar cells? The first inter-comparison, between two accredited and eight non-accredited laboratories

Perovskite materials have generated significant interest from academia and industry as a potential component in next-generation, high-efficiency, low-cost, photovoltaic (PV) devices. The record efficiency reported for perovskite solar cells has risen rapidly, and is now more than 22%. However, due to their complex dynamic behaviour, the process of measuring the efficiency of perovskite solar cells appears to be much more complicated than for other technologies. It has long been acknowledged that this is likely to greatly reduce the reliability of reported efficiency measurements, but the quantitative extent to which this occurs has not been determined. To investigate this, we conduct the first major inter-comparison of this PV technology. The participants included two labs accredited for PV performance measurement (CSIRO and NREL) and eight PV research laboratories. We find that the inter-laboratory measurement variability can be almost ten times larger for a slowly responding perovskite cell than for a control silicon cell. We show that for such a cell, the choice of measurement method, far more so than measurement hardware, is the single-greatest cause for this undesirably large variability. We provide recommendations for identifying the most appropriate method for a given cell, depending on its stabilization and degradation behaviour. Moreover, the results of this study suggest that identifying a consensus technique for accurate and meaningful efficiency measurements of perovskite solar cells will lead to an immediate improvement in reliability. This, in turn, should assist device researchers to correctly evaluate promising new materials and fabrication methods, and further boost the development of this technology.

14 SOLAR ENERGY↗

Simulation Study of Current Drive Efficiency for KSTAR 5 GHz LHCD

Theoretical 5 GHz lower hybrid current drive (LHCD) efficiency using power spectrum given by 0-D Brambilla code and Lower Hybrid Simulation Code (LSC) have been studied for KSTAR. In LSC simulation, RF-driven current and current drive efficiency has been found to be deeply dependent on the profiles of the plasma density and temperature as well as on current profile in order to obtain hollow current profile favorable for advance tokamak operation mode and steady state operation. The peaked density and broad temperature profile control has been found to be efficient in current drive with maximum RF-driven current larger than 400 kA/MW with very high efficiency when the peak plasma density is ranged from 0.2 to 2.0x1020 m-3, and the peak electron temperature range of 2-20 keV together with toroidal field 2-3.5 T and Ip = 0.5-2 MA. The on-/off-axis current profile controllability is also investigated through parametric scan, and small negative magnetic shear is seen at the narrow region of the off-axis for very high temperature regime and for high BT and I{sub p}. In order to achieve the same for lower temperature regime Ip has to be lower and also for higher LH-power compromising with CD efficiency in this case.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Highly efficient photochemical HCOOH production from CO{sub 2} and water using an inorganic system

We have constructed a system that uses solar energy to react CO{sub 2} with water to generate formic acid (HCOOH) at an energy conversion efficiency of 0.15%. It consists of an AlGaN/GaN anode photoelectrode and indium (In) cathode that are electrically connected outside of the reactor cell. High energy conversion efficiency is realized due to a high quantum efficiency of 28% at 300 nm, attributable to efficient electron-hole separation in the semiconductor's heterostructure. The efficiency is close to that of natural photosynthesis in plants, and what is more, the reaction product (HCOOH) can be used as a renewable energy source.

36 MATERIALS SCIENCE↗