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At least 1,009 records · Page 56

Efficient and selective degradation of polyethylenes into liquid fuels and waxes under mild conditions

Polyethylene (PE) is the largest-volume synthetic polymer, and its chemical inertness makes its degradation by low-energy processes a challenging problem. We report a tandem catalytic cross alkane metathesis method for highly efficient degradation of polyethylenes under mild conditions. With the use of widely available, low-value, short alkanes (for example, petroleum ethers) as cross metathesis partners, different types of polyethylenes with various molecular weights undergo complete conversion into useful liquid fuels and waxes. Furthermore, this method shows excellent selectivity for linear alkane formation, and the degradation product distribution (liquid fuels versus waxes) can be controlled by the catalyst structure and reaction time. In addition, the catalysts are compatible with various polyolefin additives; therefore, common plastic wastes, such as post consumer polyethylene bottles, bags, and films could be converted into valuable chemical feedstocks without any pretreatment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Structure of a Deformed Inhomogeneous Material on the Data of Acoustic Emission and X-Ray Computer Microtomography

Accumulation of defects at various stages of the deformation of a structurally inhomogeneous material (granite) has been studied using two nondestructive methods: acoustic emission (AE) and X-ray computer microtomorgaphy (CT). The quasi-static testing of cylindrical samples of a Westerly granite was carried out under uniaxial compression. The control of the defect formation was realized using the real-time monitoring of acoustic emission. For each sample under study, several steps of the loading and tomographic imaging have been performed. We have found that an exponential or power-law function of the energy distribution of the AE signals makes it possible to select a sample region, in which the system of defects has transited into a self-organized criticality state and large cracks have been formed. This result coincides with the data of the X-ray tomography Computer Microtomography.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

System Engineering Analysis For Improved Scout Business Information Systems

The project uses system engineering principles to address the need of Boy Scout leaders for an integrated system to facilitate advancement and awards records, leader training and planning for meetings and activities. Existing products to address needs of Scout leaders and relevant stakeholders function to support record keeping and some communication functions but opportunity exists for a better system to fully integrate these functions with training delivery and recording, activity planning along with feedback and information gathering from stakeholders. Key stakeholders for the sytem include Scouts and their families, leaders, training providers, sellers of supplies and awards, content generators and facilities that serve Scout activities. Key performance parameters for the system are protection of personal information, availability of current information, information accuracy and information content that has depth. Implementation concepts considered for the system include (1) owned and operated by Boy Scouts of America, (2) Contracted out to a vendor (3) distributed system that functions with BSA managed interfaces. The selected concept is to contract out to a vendor to maximize the likelihood of successful integration and take advantage of the best technology. Development of requirements considers three key use cases (1) System facilitates planning a hike with training needed satisfied in advance and advancement recording real time (2) Scheduling and documenting in-person training, (3) Family interested in Scouting receives information and can request follow-up. Non-functional requirements are analyzed with the Quality Function Deployment tool. Requirement addressing frequency of backup, compatibility with legacy and new technology, language support, software update are developed to address system reliability and intuitive interface. System functions analyzed include update of activity database, maintenance of advancement status, archive of documents, and monitoring of content that is accessible. The study examines risks associated with information security, technological change and continued popularity of Scouting. Mitigation is based on system functions that are defined. The approach to developing an improved system for facilitating Boy Scout leader functions was iterative with insights into capabilities coming in the course of working through the used cases and sequence diagrams.

97 MATHEMATICS AND COMPUTING↗

Determination of Stress-Free Lattice Spacing (D₀) for Residual Stress Relaxation Measurement in Ni-based Superalloys by Neutron Diffraction

The residual stress and its relaxation in critical engineering components are key to structural materials reliability. The determination of residual stress in bulk engineering structures like Ni-based superalloys can be conducted by measuring the lattice strain with penetrating neutron diffraction. The state-of-the-art engineering diffraction beamline VULCAN at the Oak Ridge National Laboratory (ORNL) Spallation Neutron Source (SNS) provides the critical capability to evaluate the residual strain/stress relaxation in engineering component thanks to the high flux and event data features. By the means of residual stress/strain calculation, it is critical to accurately determine the stress-free lattice spacing d₀, which can be altered by the change of chemistry, unrelieved stress, and measurement scheme. Here we reported d₀ determination for determining residual stress relaxation and distribution in Alloy 718 superalloys after different quenching treatments. Selection of locations for d₀ measurement was discussed by considering the neutron path, attenuation and sample alignment. A dynamic d₀ that resulted from atom diffusion and chemistry change was estimated as function of time for the in-situ relaxation characterization. It demonstrated how the dynamic d₀ values may influence on the strain calculation in different thermally treated samples. The results highlight the importance of dynamic d₀ for in-situ relaxation involving chemical changes and provide guidance to the dynamic d₀ measurement and simulation.

36 MATERIALS SCIENCE↗

US Fallout Shelter

Being indoors (sheltering) reduces radiation exposures resulting from nuclear fallout or a power-plant accident. However, most US building types, particularly non-residential buildings, lack quantitative estimates. We provide here a high-level modeling analysis of modern US building protection based on a novel radiation protection building attribute taxonomy, a new building protection model, compilation of prior experimental results, and nationally representative building survey data. This approach provides a consistent, quantitative understanding of US building protection and, when combined with the distribution of people among different buildings, can assist in selecting emergency response strategies. We find that indoor radiation protection varies by orders of magnitude. Most people in non-residential buildings are adequately protected, particularly below ground or in the building center. Residential buildings are less protective and those with lighter weight walls lack adequate, above ground protection. This work also highlights key areas where further investigation will improve the current results. These include the improving the understanding of residential basement protection, additional experimental data on non-residential buildings (particularly schools and industrial buildings), and the frequency of brick veneer and stucco exterior residential buildings.

61 RADIATION PROTECTION AND DOSIMETRY↗

Understanding Biases in Sample Preparation Techniques for Coupled Scanning Electron Microscopy and MAMA PuO 2 Morphological Analysis

In this project, the scanning electron microscopy (SEM) sampling method used during the statistical design study (SDS) was investigated to determine if any sampling biases were present in the analyzed data. Using standard particle size distribution powders from the National Institute of Standards and Technology (NIST 1984 standard reference material) with the origin wet dispersion method, it was determined that a bias to smaller particles was present. This was supported by theoretical calculations using Stokes’ law to determine the settling rate of spherical particles of roughly the same size and mass as those found in the SDS. Based on the theoretical calculations, it was determined that the settling rate for each of the 76 powder sets in the SDS could be unique based on specific particle shape and mass distributions, making a universal correction factor/formula not applicable. Therefore, priority shifted to developing an improved wet dispersion method that significantly reduced the particle settling rate for all particle size and shapes. This was achieved by replacing the original solvent (isopropyl alcohol) with a heavy liquid (lithium heteropolytungstates), which dramatically slowed the settling rate and allowed for the capture of a suitable homogeneous aliquot. SEM imaging and Morphological Analysis for Material Attribution (MAMA) software analysis were conducted on the NIST standard, and the SEM/MAMA data were compared to data captured by a dynamic image analysis particle size analyzer. The resulting data confirmed that the new wet dispersion method does indeed deliver an improved representative aliquot to the SEM stub. For instance, in the NIST certificate, the average particle size is ~17.1 µm ± 2.2 µm with a normal distribution. The initial wet dispersion method resulted in a drastically reduced average particle size of 6.1 µm in addition to a non-representative heavy bi-modal distribution whereas the improved LST wet dispersion method resulting in an average particle size that was much closer to the NIST certificate (12.7 µm) with a similar normal distribution. Although the improved method was still short of the NIST certificate average, atomic force microscopy analysis determined that the resulting ~20-25% reduction in size was due to particles sinking into the carbon sticky tape used for SEM imaging. It is believed that that this bias can be calibrated in a much more predicable manner than the original settling rate bias. In addition, the matching normal distribution curves between the NIST certificate and the heavy liquid method indicate a much-improved representative aliquot has been sampled and imaged. A surrogate CeO 2 powder was used to reflect PuO 2 more accurately and to aid in implementing radiological controls and shielding. The resulting data sets from the SEM/MAMA method and the particle size analyzer give almost identical average particle sizes and particle distribution statistics. Future work will re-analyze several select runs from the SDS to determine if morphological signatures can be found with the improved sampling method.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Engineering-Scale Integrated Energy System Data Projection Demonstration via the Dynamic Energy Transport and Integration Laboratory

The objective of this study is to demonstrate and validate the Dynamic Energy Transport and Integration Laboratory (DETAIL) preliminary scaling analysis using Modelica language system-code Dymola. The DETAIL preliminary scaling analysis includes a multisystem integral scaling package between thermal-storage and hydrogen-electrolysis systems. To construct the system of scaled equations, dynamical system scaling (DSS) was applied to all governing laws and closure relations associated with the selected integral system. The existing Dymola thermal-energy distribution system (TEDS) facility and high-temperature steam electrolysis (HTSE) facility models in the Idaho National Laboratory HYBRID repository were used to simulate a test case and a corresponding scaled case for integrated system HYBRID demonstration and validation. The DSS projected data based on the test-case simulations and determined scaling ratios were generated and compared with scaled case simulations. The preliminary scaling analysis performance was evaluated, and scaling distortions were investigated based on data magnitude, sequence, and similarity. The results indicated a necessity to change the normalization method for thermal storage generating optimal operating conditions of 261 kW power and mass flow rate of 6.42 kg/s and the possibility of reselecting governing laws for hydrogen electrolysis to improve scaling predictive properties. To enhance system-scaling similarity for TEDS and HTSE, the requirement for scaling validation via physical-facility demonstration was identified.

08 HYDROGEN↗

A Systematic Review of Quantitative Resilience Measures for Water Infrastructure Systems

Over the past few decades, the concept of resilience has emerged as an important consideration in the planning and management of water infrastructure systems. Accordingly, various resilience measures have been developed for the quantitative evaluation and decision-making of systems. There are, however, numerous considerations and no clear choice of which measure, if any, provides the most appropriate representation of resilience for a given application. This study provides a critical review of quantitative approaches to measure the resilience of water infrastructure systems, with a focus on water resources and distribution systems. A compilation of 11 criteria evaluating 21 selected resilience measures addressing major features of resilience is developed using the Axiomatic Design process. Existing gaps of resilience measures are identified based on the review criteria. The results show that resilience measures have generally paid less attention to cascading damage to interrelated systems, rapid identification of failure, physical damage of system components, and time variation of resilience. Concluding the paper, improvements to resilience measures are recommended. The findings contribute to our understanding of gaps and provide information to help further improve resilience measures of water infrastructure systems.

42 ENGINEERING↗

Remote sensing of permafrost and geological hazards in Alaska

The author has identified the following significant results. The study of the ERTS-1 imagery of Alaska indicates the following: that areas of different topographic expression affecting the distribution and character of permafrost can be distinguished clearly; that on the Arctic North Slope, regional differences in the distribution and character of permafrost-related oriented thaw lakes can be observed; that the distribution of certain types of geologic materials having a significant effect on the character of permafrost can be delineated on a regional scale; and that the resolution of the imagery is adequate to identify large scale geologic hazards such as landslides, glacier-dammed lakes, aufeis fields, etc. The information concerning the distribution and character of permafrost and geologic hazards to the gained in accomplishing the objectives of this project will be an invaluable aid in solving engineering-geologic and environmental problems related to route and site selection for structures such as roads, railroads, pipelines, and large installations; to distribution of natural construction materials; and to construction and maintenance.

Ferrians, O. J., Jr.↗

An empirical analysis of the distribution of overshoots in a stationary Gaussian stochastic process

The frequency distribution of overshoots in a stationary Gaussian stochastic process is analyzed. The primary processes involved in this analysis are computer simulation and statistical estimation. Computer simulation is used to simulate stationary Gaussian stochastic processes that have selected autocorrelation functions. An analysis of the simulation results reveals a frequency distribution for overshoots with a functional dependence on the mean and variance of the process. Statistical estimation is then used to estimate the mean and variance of a process. It is shown that for an autocorrelation function, the mean and the variance for the number of overshoots, a frequency distribution for overshoots can be estimated.

Carter, M. C.↗

GRAVSAT/GEOPAUSE covariance analysis including geopotential aliasing

A conventional covariance analysis for the GRAVSAT/GEOPAUSE mission is described in which the uncertainties of approximately 200 parameters, including the geopotential coefficients to degree and order 12, are estimated over three different tracking intervals. The estimated orbital uncertainties for both GRAVSAT and GEOPAUSE reach levels more accurate than presently available. The adjusted measurement bias errors approach the mission goal. Survey errors in the low centimeter range are achieved after ten days of tracking. The ability of the mission to obtain accuracies of geopotential terms to (12, 12) one to two orders of magnitude superior to present accuracy levels is clearly shown. A unique feature of this report is that the aliasing structure of this (12, 12) field is examined. It is shown that uncertainties for unadjusted terms to (12, 12) still exert a degrading effect upon the adjusted error of an arbitrarily selected term of lower degree and order. Finally, the distribution of the aliasing from the unestimated uncertainty of a particular high degree and order geopotential term upon the errors of all remaining adjusted terms is listed in detail.

Koch, D. W.↗

Selection and development of small solar thermal power applications

The paper discusses the approach of the JPL Point Focusing Thermal and Electric Power Applications Project to selecting and developing applications for point-focusing distributed-receiver solar thermal electric power systems. Six application categories are defined. Results of application studies of U.S. utilities are presented. The economic value of solar thermal power systems was found to range from $900 to $2100/kWe in small community utilities of the Southwest.

Bluhm, S. A.↗

A network control concept for the 30/20 GHz communication system baseband processor

The architecture and system design for a satellite-switched TDMA communication system employing on-board processing was developed by Motorola for NASA's Lewis Research Center. The system design is based on distributed processing techniques that provide extreme flexibility in the selection of a network control protocol without impacting the satellite or ground terminal hardware. A network control concept that includes system synchronization and allows burst synchronization to occur within the system operational requirement is described. This concept integrates the tracking and control links with the communication links via the baseband processor, resulting in an autonomous system operational approach.

Sabourin, D. J.↗

Experimental philosophy leading to a small scale digital data base of the conterminous United States for designing experiments with remotely sensed data

Research using satellite remotely sensed data, even within any single scientific discipline, often lacked a unifying principle or strategy with which to plan or integrate studies conducted over an area so large that exhaustive examination is infeasible, e.g., the U.S.A. However, such a series of studies would seem to be at the heart of what makes satellite remote sensing unique, that is the ability to select for study from among remotely sensed data sets distributed widely over the U.S., over time, where the resources do not exist to examine all of them. Using this philosophical underpinning and the concept of a unifying principle, an operational procedure for developing a sampling strategy and formal testable hypotheses was constructed. The procedure is applicable across disciplines, when the investigator restates the research question in symbolic form, i.e., quantifies it. The procedure is set within the statistical framework of general linear models. The dependent variable is any arbitrary function of remotely sensed data and the independent variables are values or levels of factors which represent regional climatic conditions and/or properties of the Earth's surface. These factors are operationally defined as maps from the U.S. National Atlas (U.S.G.S., 1970). Eighty-five maps from the National Atlas, representing climatic and surface attributes, were automated by point counting at an effective resolution of one observation every 17.6 km (11 miles) yielding 22,505 observations per map. The maps were registered to one another in a two step procedure producing a coarse, then fine scale registration. After registration, the maps were iteratively checked for errors using manual and automated procedures. The error free maps were annotated with identification and legend information and then stored as card images, one map to a file. A sampling design will be accomplished through a regionalization analysis of the National Atlas data base (presently being conducted). From this analysis a map of homogeneous regions of the U.S.A. will be created and samples (LANDSAT scenes) assigned by region.

Labovitz, M. L.↗

IRAS observations of matter around nearby stars

A systematic search of the IRAS point-source catalog has led to the identification of eight new nearby stars that are Vega-like in terms of their large 60-micron excess. These stars are distinguished by the predominance of spectral type A and the absence of double stars in the Vega-like group. Both effects are intuitively consistent with the interpretation that the 60-micron excess radiation is due to a disk of protoplanetary material, suggesting an early phase in the evolution of a planetary system; however, this distribution can also be due to luminosity and brightness selection effects.

Aumann, H. H.↗

Discrete-time entropy formulation of optimal and adaptive control problems

The discrete-time version of the entropy formulation of optimal control of problems developed by G. N. Saridis (1988) is discussed. Given a dynamical system, the uncertainty in the selection of the control is characterized by the probability distribution (density) function which maximizes the total entropy. The equivalence between the optimal control problem and the optimal entropy problem is established, and the total entropy is decomposed into a term associated with the certainty equivalent control law, the entropy of estimation, and the so-called equivocation of the active transmission of information from the controller to the estimator. This provides a useful framework for studying the certainty equivalent and adaptive control laws.

Tsai, Yweting A.↗

Clumpy Langmuir waves in type III radio sources - Comparison of stochastic-growth theory with observations

Detailed comparisons are made between the Langmuir-wave properties predicted by the recently developed stochastic-growth theory of type III sources and those observed by the plasma wave experiment on ISEE 3, after correcting for the main instrumental and selection effects. Analysis of the observed field-strength distribution confirms the theoretically predicted form and implies that wave growth fluctuates both spatially and temporally in sign and magnitude, leading to an extremely clumpy distribution of fields. A cutoff in the field-strength distribution is seen at a few mV/m, corresponding to saturation via nonlinear effects. Analysis of the size distribution of Langmuir clumps yields results in accord with those obtained in earlier work and with the size distribution of ambient density fluctuations in the solar wind. This confirms that the inhomogeneities in the Langmuir growth rate are determined by the density fluctuations and that these fluctuations persist during type III events.

Robinson, P. A.↗

Laboratory studies of fast oxygen atom interactions with materials

A pulsed 8 km/s oxygen atom source was used to perform a number of measurements of material interactions of interest to low Earth orbit applications. A system to measure the scattering distribution resulting from 8 km/s oxygen atoms impinging on selected spacecraft materials was developed. Data for scattering from glass and black and clear anodized aluminum are presented. Results on the fast atom oxidation mechanism for thin silver films, the O-atom velocity dependent erosion rates for selected materials, and the oxidation dependence on material temperature are presented.

Caledonia, George E.↗