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At least 1,009 records · Page 56

Hydrogen Energy Storage System at Borrego Springs Towards an H2 Enabled 100 Renewable Microgrid

San Diego Gas & Electric's Borrego Springs Microgrid is one of the largest microgrids in the USA, serving 2500 residential customers, 300 commercial and industrial customers, and has a peak demand of approximately 14 MW. This microgrid is located at the end of a long transmission line, and is subjected to extreme weather events like storms, wildfires, and flooding, which frequently cause grid outages. The microgrid currently relies on 3.65 MW of diesel-powered generators to provide grid-forming services during these outages, which results in greenhouse gas and criteria pollutant emissions. However, the microgrid has access to approximately 37 MW of installed solar generation and struggles with overgeneration and curtailment. 1.5 MW/4.5 MWh of grid-scale batteries have been installed to capture some the overgeneration and provide resiliency, but a longer-duration low-greenhouse gas emission energy storage solution is needed. In our project, the team will evaluate in the lab and demonstrate in the field a grid-forming fuel cell inverter that can provide grid-forming services while utilizing hydrogen's energy storage scalability. We will first utilize NREL's Renewable Energy Integration and Optimization (REopt) platform to perform analyses on future microgrid scenarios that use hydrogen assets to reduce or eliminate the need for diesel backup generators. We will then evaluate the grid-forming inverter through power hardware-in-the-loop and controller hardware-in-the-loop experiments at ARIES, and de-risk the field deployment and operation of hydrogen assets in the microgrid setting. Finally, this project will demonstrate the operation of the fuel cell inverter and updated microgrid controller by operating in grid-forming mode in the Borrego Springs microgrid.

Borrego Springs↗

Transactive Energy Rationing in Islanded Electric Power Systems

Extreme weather events, many of which are climate change related, are occurring with increasing frequency and intensity and causing catastrophic outages. One of the major modern-day concerns of utilities is dealing with such extreme outages and consequently, its repercussions on the lives of people in society and social aspects. Traditionally, operators have been using rolling blackouts as a contingency plan to serve critical loads during such events when electricity supply is scarce. However, such blackouts practices are executed on a last-minute mandatory basis, depriving customers having low-capacity high priority loads (i.e. refrigeration, water, telecommunication, etc) that should also be serviced if at all possible. Historically, policymakers have often adopted quota-based regulatory actions or rationing for other commodities (such as gasoline, butter, sugar) to handle scarcity situations. Motivated from such quota based systems, our contribution presented in this work is an alternative transactive rationing mechanism that would provide some minimum level of service to all of the customers and serve the critical loads using market-based control during such scarcity-based contingencies. This is in contrast to the state-of-art TE mechanisms that allocate resources to customers solely based on their willingness-to-pay. The effectiveness of the proposed mechanism is demonstrated through simulation-based evaluation on two real-life use cases having feeder-level and microgrid-level configurations respectively. The simulation results clearly demonstrate the capability of the rationing scheme to serve customers’ high-priority loads through prolonged outages even during extreme scarcity scenarios.

42 ENGINEERING↗

Influence of Hybridization on the Capacity Value of PV and Battery Resources

Utility-scale systems that combine solar photovoltaic and battery (PV+battery) technologies are growing in popularity on the U.S. bulk power system. The business case for PV+battery systems depends on both their ability to reduce costs and their ability to generate value synergies associated with the provision of energy, capacity, and ancillary services. Capacity value can constitute a significant portion of the value PV+battery hybrids provide to the grid (e.g., through avoided or deferred capacity) and receive through revenues. Throughout this report, we define capacity value as the monetary value of a plant's contribution towards the planning reserve margin, which ultimately depends on market rules and structures. PV+battery hybrids do not always fit into current market structures because of the interactions between the PV and battery components. Unique considerations for the capacity value of PV+battery hybrids include the disparate nature of participation models for PV and battery technologies in existing market rules and the potential influence of a shared interconnection capacity; limitations imposed by a shared inverter; limited ability to charge the battery in advance of capacity events if charging must be sourced from the coupled PV; and challenges or uncertainties associated with co-optimizing the operations of the PV and battery components. Grid operators are currently considering how market structures can be modified to optimally determine the capacity value provided by PV+battery systems, and the rules of how they are integrated into markets are still being written. As with any resource, poorly designed rules could increase the cost of energy and reduce system reliability, while well-designed rules could allow markets to receive the full benefits hybrid systems can offer without overcompensating them for the services they provide. Well-designed rules for PV+battery systems must consider the unique aspects listed above, while leveraging the commonalities with existing resource types. In this report, we summarize the technical capability and market rules that influence the capacity value of PV+battery systems. We further discuss the potential tradeoffs between computational complexity and accuracy for the various ways in which grid operators can credit PV+battery systems for capacity. Finally, we describe markets for capacity, survey current wholesale market rules applying to PV+battery systems, and provide a snapshot of the current regulatory landscape for PV+battery systems.

14 SOLAR ENERGY↗

Primary Frequency Control Using Motor Drives for Short Term Grid Disturbances

Industrial motor systems make up a quarter of all electric sales in the United States. Variable speed drives (VSDs) can provide energy efficiency savings to the customer by regulating motor speed based on specific and varying needs. In addition to the benefits provided to the customer, VSDs can provide support to the grid through ancillary services. The Center for Ultra-Wide-Area Resilient Electric Energy Transmission Networks (CURENT) developed a power electronics converter-based grid emulator to allow testing of various power system architectures and demonstration of key technologies in monitoring, control, actuation, and visualization. This paper proposes using an active front-end VSD's connected motor load to provide frequency regulation to a large scale power grid. Each part of the emulator is described including motor and power electronics model and control. The proposed frequency regulation is implemented in VSDs and modeled in both a transmission system in EMTDC/PSCAD and verified on CURENT's hardware testbed.

24 POWER TRANSMISSION AND DISTRIBUTION↗

IS BLOCKCHAIN A SUITABLE TECHNOLOGY FOR ENSURING THE INTEGRITY OF DATA SHARED BY LIGHTING AND OTHER BUILDING SYSTEMS?

Increasing amounts of data are available from lighting and other building systems. In commercial buildings, these data can be used to improve system and energy performance, detect and diagnose faults, and facilitate maintenance. Building data are not only of interest to owners and operators of the building systems, however. Owners and operators of similar buildings, manufacturers of building systems, utilities, and city agencies also have interesting use cases. Energy data can, for example, be used to verify the performance of energy-conservation measures, issue renewableenergy certificates, and financially settle grid services. Increased data sharing, however, significantly expands the cyber-attack surface, creating new challenges. In this work, blockchain is explored as an option for ensuring the integrity of data that are shared by lighting and other building systems. Blockchain fundamentals and variants are briefly reviewed, and value propositions relevant to building systems are discussed. A recently developed blockchain applicability framework (BAF) that builds upon and addresses the limitations of previous applicability models is also briefly reviewed. The BAF is used to assess the suitability of blockchain over other technologies or approaches for building-data applications, using emerging connected lighting systems as an example use case.

blockchain, connected lighting system, data integr↗

Resilience Enhancements through Deep Learning Yields

This report documents the Resilience Enhancements through Deep Learning Yields (REDLY) project, a three-year effort to improve electrical grid resilience by developing scalable methods for system operators to protect the grid against threats leading to interrupted service or physical damage. The computational complexity and uncertain nature of current real-world contingency analysis presents significant barriers to automated, real-time monitoring. While there has been a significant push to explore the use of accurate, high-performance machine learning (ML) model surrogates to address this gap, their reliability is unclear when deployed in high-consequence applications such as power grid systems. Contemporary optimization techniques used to validate surrogate performance can exploit ML model prediction errors, which necessitates the verification of worst-case performance for the models.

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SPECs Early-Stage Decision Model: User Manual

The SPECs Early-Stage Decision (ESD) model is central to the SPECs procurement solutions toolkit. The ESD model is an Excel-based spreadsheet model, which provides information about the economic and strategic value of a proposed battery-storage project or solar-plus-storage (solar-plus) project. The model can be used to explore combinations of storage-related project value streams in order to define a potential project, while educating co-op decision-makers about project benefits and costs. A sensitivity analysis function speeds the development of "what-if" scenarios. A gap analysis function solves for top-priority metrics and supports the inclusion of hard-to-monetize strategic values, such as the value of storage to defer costly system upgrades in light of increasing distributed solar and other distributed energy resources (DERs). Model outputs include the utility data, assumptions, and use-case scenarios that are recommended content for the requests for proposals (RFPs). The model may also provide an initial "sanity check" for RFP responses, supporting further discussions among utility staff, vendors and stakeholders. The ESD is not a "finance-grade" modeling tool, and users are cautioned to be mindful of its limitations, but the model has been reviewed by users, who recommend it as a way to drive faster and better project design and planning, as well as to facilitate better communications with vendors, grid partners, and stakeholders.

14 SOLAR ENERGY↗

Environmental Co‐Benefits of Maintaining Native Vegetation With Solar Photovoltaic Infrastructure

Abstract Co‐locating solar photovoltaics with vegetation could provide a sustainable solution to meeting growing food and energy demands. However, studies quantifying multiple co‐benefits resulting from maintaining vegetation at utility‐scale solar power plants are limited. We monitored the microclimate, soil moisture, panel temperature, electricity generation and soil properties at a utility‐scale solar facility in a continental climate with different site management practices. The compounding effect of photovoltaic arrays and vegetation may homogenize soil moisture distribution and provide greater soil temperature buffer against extreme temperatures. The vegetated solar areas had significantly higher soil moisture, carbon, and other nutrients compared to bare solar areas. Agrivoltaics in agricultural areas with carbon debt can be an effective climate mitigation strategy along with revitalizing agricultural soils, generating income streams from fallow land, and providing pollinator habitats. However, the benefits of vegetation cooling effects on electricity generation are rather site‐specific and depend on the background climate and soil properties. Overall, our findings provide foundational data for site preservation along with targeting site‐specific co‐benefits, and for developing climate resilient and resource conserving agrivoltaic systems.

14 SOLAR ENERGY↗

Hydropower Role in a Power Grid with a High Proportion of Variable Renewables

The importance of hydropower increases as the power grid evolves with the higher variable renewable contribution. As conventional thermal power plants are retired, the importance of hydropower contribution increases to balance the variability of solar and wind generation. However, reservoir water resources are constrained by multiple constraints, and variability of water inflow to the reservoirs creates limitations to dam water releases for power grid needs. Coordination of multiple tools, including water resources modeling, ecological modeling, and technical and economic power grid modeling, informs dam water releases. Better representation of ecological constraints and other water use details in the suit of power grid models are required to identify the hydropower flexibility to provide multiple power grid services. Impacts of water planning and hydropower operation changes to a power grid are better understood by production cost model simulations with technical and economic data, including unserved energy, reserve failures, transmission congestion to serve load, and local marginal price increases. Similarly, PCM simulation of current and future projected power grid information, including LMP, and carbon emission rates, informs short-term water release plans and long-term investments for power plant upgrades for technical and ecological needs. Hydropower operations of several case studies are simulated to understand operation patterns, revenue, water release decisions in multiple time scales (month, day, minutes), hydropower contracts scheduling, and water variability impacts.

environmental↗

Accelerated Aging Humidity Chamber for Nuclear Grade HEPA Filter Media

A unique accelerated aging humidity chamber for simulating the natural aging process of nuclear grade high efficiency particulate air (HEPA) filter media is being designed, implemented, and tested. The nuclear industry currently lacks information regarding the shelf life and service life of HEPA filter media. The Department of Energy recommends disposing of HEPA filters 10 years after the manufacture date for filters operated under dry conditions. Studies have shown the tensile strength and water repellency of HEPA filter media diminish with age. The chamber's principal function is to sustain an elevated relative humidity condition for an extended duration specified by the Arrhenius aging model. To accomplish this, various design parameters were established: (1) consistently achieve uniform humidity conditions within the chamber to equally expose media sheets, (2) ensure the chamber is sufficiently sealed to mitigate the uncontrolled infiltration of air, (3) confidently secure the media sheets to avert the introduction of unnecessary stressing/creasing, (4) fabricate the chamber from clear polycarbonate material to allow inspection of the media sheets, (5) provide a safe and ergonomic design for personnel, (6) ensure the chamber design is replicable and relatively easy to fabricate/assemble. A humidity source, fan, PID controller, humidity and temperature transmitters, and data loggers are required for proper operation and control of the chamber. The humidity source must accommodate target values up to 95% relative humidity throughout the chamber. The three humidity and temperature transmitters are strategically spaced throughout the chamber to ensure uniform conditions. The 10 cubic feet per minute (CFM) fan selected intends to accomplish the desired air change rate inside the chamber of approximately 20 air changes per hour (ACH). The 2 plenums on the upper and lower portions of the chamber utilize a perforated design to uniformly distribute air, promote air mixing, and control the air velocity entering the chamber. Industrial blueprint hanging clamps are being retrofitted to be seated within the chamber drawers and firmly secure the nuclear grade filter media. The aged media will be evaluated using autopsy methodology, and the results obtained intend to help clarify the useful life of nuclear grade HEPA filters. Nuclear grade high efficiency particulate air (HEPA) filters are defined as disposable, extended-media, dry-type filters with a rigid casing enclosing the full depth of the pleats and have a minimum particle removal efficiency of 99.97%. [1] - HEPA filters are constantly exposed to stressors and subsequently have been shown to degrade as the filter ages. Properties such as tensile strength and water repellency, along with others, are negatively impacted. [2] - Due to the scarcity of naturally aged HEPA filters available, it is crucial to develop accelerated aging methods which effectively mimic the natural degradation effects. - After accelerated aging, the filters are subject to testing in the Axial Flow Large Scale Test Stand (ALSTS) and other analysis techniques such as the same qualification tests performed directly after being manufactured. - Quality data is necessary for future decisions regarding the lifetime of nuclear grade HEPA filters. - The objective is to develop a prototype accelerated aging humidity chamber for nuclear grade HEPA filter media. The chamber should expose the media to commonly occurring stressors to expedite the degradation process caused by aging. PID yields reliable and reproducible results: - CFD model correlates well with actual performance; - Further analysis is needed to complete characterization; - Future work for the chamber is still to be completed. The data shown in Figure 5 and Table 1 indicate the system is functioning as designed. As can be determined from the system response evaluation in Table 1, the PID controller is yielding reliable and reproducible results at each set point. As the set point increases, the time constant and 20% settling time increase accordingly. From the results in Table 1, it stands to reason that the CFD model correlates well with the actual performance of the system. Each system response parameter for the 90%RH* CFD model is slightly lower than the parameters collected from the physical model tested at an equivalent set point. This is to be expected considering the inlet in the CFD model is a constant supply of water vapor, whereas the physical model uses a PID controller to monitor the amount of water vapor needed and reacts accordingly. More analysis is still to be done on the prototype chamber. A pressure test will be conducted in order to determine the hourly leak rate of the chamber. This test will involve constant air flow into the chamber until the desired pressure is reached. A uniformity test will also be conducted in order to ensure each filter medium is being exposed to equivalent relative humidity levels. This test will involve an array of humidity meters strategically oriented inside the chamber to record any possible gradients. Future work for the chamber includes dehumidification abilities, tests while fully loaded with filters, and temperature control. Once completed, the autopsy team at Institute of Clean Energy Technology will conduct necessary accelerated aging studies as needed.

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Internal defect detection and characterization of samarium-cobalt sintered magnets by ultrasonic testing technique

Excessive quantities of samarium-cobalt (Sm-Co) magnet material are being scrapped needlessly due to a lack of understanding of inhomogeneity distribution and unacceptable internal defects. If there is a way to identify, locate, characterize and when needed separate the defective portions of magnet material, utilization can be increased and product quality improved. Further, the magnets’ magnetic and mechanical performance can be improved by reducing the occurrence of internal defects. This paper reports on a cost-effective and efficient nondestructive evaluation method based on an ultrasonic testing (UT) technique applied for detecting and characterizing internal defects in Sm-Co sintered magnets. Applying the UT technique will allow users to comprehensively analyze internal defects, such as inclusions, porosity, microcracks, and other structural irregularities, check for homogeneity and anomalous regions and give the locations of these internal anomalies and defects within the Sm-Co sintered magnets. The UT technique can also be applied to other rare-earth permanent magnets, such as sintered or die-upset neodymium-iron-boron (Nd-Fe-B) magnets. The UT technique can effectively guide quality control and acceptable product selection, in addition to optimizing the magnet alloy design and production processes. Therefore, it can facilitate the improvement of magnet manufacturing efficiency and machinability, reduce scrap, prolong service life, increase the use of what would be post-production waste, and enhance product reuse and recycling at end-of-life disposition.

36 MATERIALS SCIENCE↗

Addressing Electric Aviation Infrastructure Cybersecurity Implementation

This technical report evaluates key considerations of cybersecurity systems in preparation for the electrification of both legacy and new aviation services. The objectives are to consider the landscape of components and interconnections, review sensitivities and the criticality of data and operations, and aim to understand the applicability of existing best practices or the need for new ones associated with the cybersecurity of electric charging systems for the aviation sector. Given the early stages of electric aviation deployment, developers have the opportunity to plan and integrate cybersecurity strategies into the complete electric aviation system during the initial stages of design and procurement and will benefit from employing a framework for continuous cybersecurity monitoring. This paper presents initial considerations of key cybersecurity strategies and their application to forthcoming electric aviation systems.

airports↗

Nonlinear behavior in high-frequency aggregate control of thermostatically controlled loads

Coordinated control of electric loads can provide valuable grid services, such as frequency regulation. However, due to the nonlinear characteristics of such load ensembles, it is important to systematically analyze their behavior and establish a thorough understanding of undesirable phenomena that can potentially arise. In this paper, we analyze the frequency response of an aggregate control scheme, with the goal of exploring controller performance limits. We show that rapid switching commands can induce oscillations in the power output due to the inherent lockout mechanism of the underlying devices. Here, we demonstrate that highly detailed aggregate models are required to capture such phenomena. Such models enable deeper understanding of the control boundaries and therefore play an important role in avoiding the introduction of undesirable effects on the grid.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Deep Factorization Machine Learning for Disaggregation of Transmission Load Profiles with High Penetration of Behind-The-Meter Solar

The ever-growing integration of distributed energy resources (DERs), especially behind-the-meter (BTM) solar generations, poses imperative operational challenges to system operators such as regional transmission organizations (RTOs). It is important for RTOs to effectively and accurately extract actual load profiles at the transmission level for a single node with significant BTM solar injection. This paper first illustrates the necessity of disaggregating the daily actual load profile of a single node. Furthermore, by segmenting nodes with selected timeseries features, nodes with significant BTM solar generation are identified. Lastly, a bi-level framework is proposed, comprising reference node disaggregation and DeepFM nodal disaggregation, aimed at disaggregating the nodal load profiles from which system operators require more information. By adopting a hybrid Deep Factorization Machine (DeepFM) model, the model achieve accurate results by extracting both linear and nonlinear relations between nodes in the same region and the zonal load and nodal load profile. To overcome the lack of ground truth, this paper segments the load profile into daytime, nighttime, and zero-crossing points and utilizes the latter two for evaluation purposes. The proposed disaggregation procedure is validated using real world, minute-level, normalized, and anonymized nodal data in the PJM service territory.

42 ENGINEERING↗

Grid-scale Energy Storage Hazard Analysis & Design Objectives for System Safety

Battery based energy storage systems are becoming a critical part of a modernized, resilient power system. However, batteries have a unique combination of hazards that can make design and engineering of battery systems difficult. This report presents a systematic hazard analysis of a hypothetical, grid scale lithium-ion battery powerplant to produce sociotechnical "design objectives" for system safety. We applied system's theoretic process analysis (STPA) for the hazard analysis which is broken into four steps: purpose definition, modeling the safety control structure, identifying unsafe control actions, and identifying loss scenarios. The purpose of the analysis was defined as to prevent event outcomes that can result in loss of battery assets due to fires and explosions, loss of health or life due to battery fires and explosions, and loss of energy storage services due to non- operational battery assets. The STPA analysis resulted in identification of six loss scenarios, and their constituent unsafe control actions, which were used to define a series of design objectives that can be applied to reduce the likelihood and severity of thermal events in battery systems. These design objectives, in all or any subset, can be utilized by utilities and other industry stakeholders as "design requirements" in their storage request for proposals (RFPs) and for evaluation of proposals. Further, these design objectives can help to protect firefighters and bring a system back to full functionality after a thermal event. We also comment on the hazards of flow battery technologies.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Cesium Ion Exchange Testing Using Crystalline Silicotitanate with Hanford Tank Waste 241-AP-107

At the time of this testing, the Low-Activity Waste Pretreatment System (LAWPS) was to provide for the initial production of immobilized low-activity waste by feeding Hanford tank supernate from tank farms to the Hanford Tank Waste Treatment and Immobilization Plant (WTP) Low-Activity Waste (LAW) Facility for immobilization. Washington River Protection Solutions requested that Hanford tank waste collected from tank 241-AP-107 (hereafter called AP-107) be processed using conceived pretreatment steps (suspended solids removal by filtration, Cs removal by ion exchange) then vitrified. A small-scale test platform to demonstrate the solids filtration, Cs removal, and LAW vitrification was constructed and installed at Pacific Northwest National Laboratory. Bench-scale ion exchange testing with approximately 9 L of AP-107 supernate was conducted using crystalline silicotitanate (CST) ion exchange media. The IONSIV R9140-B CST was provided by Honeywell UOP, LLC in 2018 (Batch 2081000057). The ion exchange media was first tested with simulant and was previously described. This report describes the Cs ion exchange batch contact and column test results with the AP-107 tank waste. Batch contact testing helps to evaluate CST performance on tank waste supernate prior to processing it in the ion exchange columns. Batch contacts were performed with the waste at four Cs concentrations at a phase ratio of 200 (liquid volume to exchanger mass) with AP-107. The distribution coefficient (K d ) at the equilibrium condition of 8.57 µg Cs/mL (AP-107 feed condition) was determined to be 669 mL AP-107/g CST. With a CST bed density of 1.00 g/mL, this K d corresponded to a predicted 50% Cs breakthrough of 669 bed volumes (BVs). The Cs load capacity at the equilibrium feed condition was determined to be 7.5 mg Cs/g dry CST. The column testing was prototypic to the intended LAWPS operations in a lead-lag column format, although on a small-scale basis with 10-mL CST beds. The feed was processed downflow through the lead column and then through the lag column at ~2.2 BV/h. Loading continued until the lag column reached the WTP waste acceptance criteria (WAC) for receiving supernatant waste for vitrification (a function of the Na and 137 Cs concentrations). For AP-107, the WAC is 0.114% of the influent 137 Cs concentration; this required a Cs decontamination factor of 876. The Cs effluent from the lag column reached the WAC after processing ~410 BVs. To keep the subsequent product effluent below the WAC, a replacement lag column was prepared, the lead column was removed from service (after processing a total of 471 BVs), the lag column was put into the lead column position, and the replacement lag column was installed. Feed processing continued and after another ~290 BVs the Cs effluent from the lag column again exceeded the WAC. In both cases, the lead columns only reached 25% Cs breakthrough before removal. Although 50% Cs breakthrough was not reached, this value was estimated and averaged based on extrapolation of the loading curves (640 BVs) and agreed within 4% of the predicted 50% Cs breakthrough from batch contact test results (669 BVs). Table ES.1 summarizes the observed column performance and relevant Cs loading characteristics.

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Change Agent: Energy Storage as a Driver of Regulatory Evolution

Purpose of Review Dividing the electric grid into the functions of generation, transmission, anddistribution enabled the drawing of jurisdictional lines and the application of the U.S.Constitution’s federalist system to energy regulation. Energy storage technologies,which can be placed throughout the grid to increase flexibility, can provide serviceacross all three of those functions. But the jurisdictional boundaries that have beendrawn around those functions have created barriers that restrict energy storagetechnologies from achieving their full potential. This review analyzes regulatory changes made to reduce barriers to storage deployment and their broader impacts on energy regulation in the U.S. Recent Findings Major energy regulations promulgated at the state and federal levels have generally focused on liberalizing the U.S. electric system through deregulation and increased competition. Paradoxically, however, these efforts have erected strict regulatory barriers that prevent energy storage technologies from providing service across multiple functions. A new wave of regulations in recent years has endeavored to reduce and remove those barriers. Summary Energy regulations adopted in recent years to reduce barriers to energy storage functionality in recent years have had deep and far-reaching impacts on U.S. electric regulation. These impacts go beyond storage and affect all energy technologies. This paper traces the development of energy regulation in U.S., the functional barriers that they created that impede energy storage functionality, recent efforts to remove those barriers, and the broader effects of those efforts. It concludes with a brief discussion of remaining barriers that prevent energy storage from reaching their full potential on the U.S. electric grid.

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Neural Network Enhanced RKPM for Electrochemical-Mechanical Coupled Damage Modeling of Energy Storage Materials

Energy storage materials undergo significant charge cycling, which makes understanding their reliability and durability fundamental in predicting performance and service life. Strong electrochemical-mechanical coupling and highly anisotropic material properties contribute to the formation and propagation of micro-cracking, largely along material interfaces and grain boundaries. For Li-ion batteries, for example, lithium moving between electrodes during charging and discharging process causes expansion and contraction of grains, and the strongly anisotropic and nonlinearly [Li]-dependent grain material properties can cause grains to expand into and contract away from each other, leading to chemo-mechanical cracking. In the first part of this work, a RKPM based computational framework for solving the coupled solid-phase lithium conservation with Fickian diffusion and the lithium concentration dependent anisotropic mechanical problem subjected to a highly nonlinear Butler-Volmer boundary condition is introduced. The choice of RKPM completeness conditions for lithium concentration and mechanical deformation fields, and the variational consistency condition for the domain integration of the coupled problem is first determined. In the second part of this work, a neural network-enhanced reproducing kernel particle method (NN-RKPM) [1] is leveraged to accurately capture damage and crack propagation throughout the material, by learning the location, orientation, and sharpness of discontinuity while allowing for a coarser nodal distribution than that is necessary for capturing sharp solution transitions using traditional mesh-based methods. NN-RKPM is used to inform how crack opening and closure in turn affect the coupled chemical equations and material microstructure.

damage modeling↗