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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,009 records · Page 56
All sourcesNASA NTRSDOE OSTI
DOE OSTI2011

Clinical Outcomes Using Accelerated Partial Breast Irradiation in Patients With Invasive Lobular Carcinoma

Purpose: We compared clinical outcomes of women diagnosed with either invasive lobular carcinoma (ILC) or invasive ductal carcinoma (IDC) treated with accelerated partial breast irradiation (APBI). Methods and Materials: A total of 16 patients with ILC received APBI as part of their breast-conservation therapy (BCT) and were compared with 410 patients with IDC that received APBI as part of their BCT. Clinical, pathologic, and treatment related variables were analyzed including age, tumor size, hormone receptor status, surgical margins, lymph node status, adjuvant hormonal therapy, adjuvant chemotherapy, and APBI modality. Clinical outcomes including local recurrence (LR), regional recurrence (RR), disease-free survival (DFS), cause-specific survival (CSS), and overall survival (OS) were analyzed. Results: Median follow-up was 3.8 years for the ILC patients and 6.0 years for the IDC patients. ILC patients were more likely to have positive margins (20.0% vs. 3.9%, p = 0.006), larger tumors (14.1 mm vs. 10.9 mm, p = 0.03) and less likely to be node positive (0% vs. 9.5%, p < 0.001) when compared with patients diagnosed with IDC. The 5-year rate of LR was 0% for the ILC cohort and 2.5% for the IDC cohort (p = 0.59). No differences were seen in the rates of RR (0% vs. 0.7%, p = 0.80), distant metastases (0% vs. 3.5%, p = 0.54), DFS (100% vs. 94%, p = 0.43), CSS (100% vs. 97%, p = 0.59), or OS (92% vs. 89%, p = 0.88) between the ILC and IDC patients, respectively. Additionally, when node-positive patients were excluded from the IDC cohort, no differences in the rates of LR (0% vs. 2.2%, p = 0.62), RR (0% vs. 0%), DFS (100% vs. 95%, p = 0.46), CSS (100% vs. 98%, p = 0.63), or OS (92% vs. 89%, p = 0.91) were noted between the ILC and IDC patients. Conclusion: Women with ILC had excellent clinical outcomes after APBI. No difference in local control was seen between patients with invasive lobular versus invasive ductal histology.

62 RADIOLOGY AND NUCLEAR MEDICINE↗
DOE OSTI2012

THE TRENDS HIGH-CONTRAST IMAGING SURVEY. I. THREE BENCHMARK M DWARFS ORBITING SOLAR-TYPE STARS

We present initial results from a new high-contrast imaging program dedicated to stars that exhibit long-term Doppler radial velocity accelerations (or ''trends''). The goal of the TRENDS (TaRgetting bENchmark-objects with Doppler Spectroscopy) imaging survey is to directly detect and study the companions responsible for accelerating their host star. In this first paper of the series, we report the discovery of low-mass stellar companions orbiting HD 53665, HD 68017, and HD 71881 using NIRC2 adaptive optics (AO) observations at Keck. Follow-up imaging demonstrates association through common proper motion. These comoving companions have red colors with estimated spectral types of K7-M0, M5, and M3-M4, respectively. We determine a firm lower limit to their mass from Doppler and astrometric measurements. In the near future, it will be possible to construct three-dimensional orbits and calculate the dynamical mass of HD 68017 B and possibly HD 71881 B. We already detect astrometric orbital motion of HD 68017 B, which has a projected separation of 13.0 AU. Each companion is amenable to AO-assisted direct spectroscopy. Further, each companion orbits a solar-type star, making it possible to infer metallicity and age from the primary. Such benchmark objects are essential for testing theoretical models of cool dwarf atmospheres.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

MODELING BRIGHT γ-RAY AND RADIO EMISSION AT FAST CLOUD SHOCKS

Recent observations by the Large Area Telescope on board the Fermi satellite have revealed bright γ-ray emission from middle-aged supernova remnants (SNRs) inside our Galaxy. These remnants, which also possess bright non-thermal radio shells, are often found to be interacting directly with surrounding gas clouds. We explore the non-thermal emission mechanism at these dynamically evolved SNRs by constructing a hydrodynamical model. Two scenarios of particle acceleration, either a re-acceleration of Galactic cosmic rays or an efficient nonlinear diffusive shock acceleration (NLDSA) of particles injected from downstream, are considered. Using parameters inferred from observations, our models are contrasted with the observed spectra of SNR W44. For the re-acceleration case, we predict a significant enhancement of radio and GeV emission as the SNR undergoes a transition into the radiative phase. If sufficiently strong magnetic turbulence is present in the molecular cloud, the re-acceleration scenario can explain the observed broadband spectral properties. The NLDSA scenario also succeeds in explaining the γ-ray spectrum but fails to reproduce the radio spectral index. Efficient NLDSA also results in a significant post-shock non-thermal pressure that limits the compression during cooling and prevents the formation of a prominent dense shell. Some other interesting differences between the two models in hydrodynamical behavior and resulting spectral features are illustrated.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

The Highest Energy HAWC Sources are Likely Leptonic and Powered by Pulsars

The HAWC Collaboration has observed gamma rays at energies above 56 TeV from a collection of nine sources. It has been suggested that this emission could be hadronic in nature, requiring that these systems accelerate cosmic-ray protons or nuclei up to PeV-scale energies. In this paper, we instead show that the spectra of these objects favor a leptonic (inverse Compton) origin for their emission. More specifically, the gamma-ray emission from these objects can be straightforwardly accommodated within a model in which $\sim \mathcal{O}(10\%)$ of the host pulsar's spindown power is transferred into the acceleration of electrons and positrons with a power-law spectrum that extends to several hundred TeV or higher. The spectral break that is observed among these sources is naturally explained within the context of this simple model, and occurs at the energy where the timescale for energy losses matches the age of the pulsar. In contrast, this spectral feature cannot be straightforwardly accommodated in hadronic scenarios. Furthermore, hadronic models predict that these sources should produce more emission at GeV-scale energies than is observed. In light of these considerations, we conclude that HAWC's highest energy sources should be interpreted as TeV halos or pulsar wind nebulae, which produce their emission through inverse Compton scattering, and are powered by the rotational kinetic energy of their host pulsar.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2015

Alteration of forest succession and carbon cycling under elevated CO 2

Abstract Regenerating forests influence the global carbon (C) cycle, and understanding how climate change will affect patterns of regeneration and C storage is necessary to predict the rate of atmospheric carbon dioxide (CO 2 ) increase in future decades. While experimental elevation of CO 2 has revealed that young forests respond with increased productivity, there remains considerable uncertainty as to how the long‐term dynamics of forest regrowth are shaped by elevated CO 2 (eCO 2 ). Here, we use the mechanistic size‐ and age‐ structured Ecosystem Demography model to investigate the effects of CO 2 enrichment on forest regeneration, using data from the Duke Forest Free‐Air Carbon dioxide Enrichment (FACE) experiment, a forest chronosequence, and an eddy‐covariance tower for model parameterization and evaluation. We find that the dynamics of forest regeneration are accelerated, and stands consistently hit a variety of developmental benchmarks earlier under eCO 2 . Because responses to eCO 2 varied by plant functional type, successional pathways, and mature forest composition differed under eCO 2 , with mid‐ and late‐successional hardwood functional types experiencing greater increases in biomass compared to early‐successional functional types and the pine canopy. Over the simulation period, eCO 2 led to an increase in total ecosystem C storage of 9.7 Mg C ha ‐1 . Model predictions of mature forest biomass and ecosystem–atmosphere exchange of CO 2 and H 2 O were sensitive to assumptions about nitrogen limitation; both the magnitude and persistence of the ecosystem response to eCO 2 were reduced under N limitation. In summary, our simulations demonstrate that eCO 2 can result in a general acceleration of forest regeneration while altering the course of successional change and having a lasting impact on forest ecosystems.

Miller, Adam D.↗
DOE OSTI2012

Sylgard® Cure Inhibition Characterization

Silicone elastomers are among the most versatile polymer materials due to their desirable properties, including good thermal and chemical stability, low electrical conductivity, biocompatibility, and good aging characteristics. The properties of silicone elastomers can be tuned giving rise to materials for a variety of applications, such as encapsulants, coatings, medical devices, microfluidic devices, and lithography. Sylgard® is a two-part, liquid silicone-based polymer manufactured by Dow Corning®. Sylgard® can be modified by added cure accelerator and/or filler. Modified formulations of Sylgard® are currently used potting materials at LANL and Pantex.

36 MATERIALS SCIENCE↗
DOE OSTI2025

SCILLA Secondary Aerosol Volume Concentration Airborne Data

This data set contains secondary aerosol volume concentration in cubic micrometers per cubic centimeter (um^3/cm^3). The aerosol was generated in an oxidation flow reactor (OFR) and its volume concentration measured with a scanning mobility particle sizer (SMPS). Both components were designed and built at the University of California Riverside. Ambient particles were removed with a Teflon filter upstream of the OFR and then pure ammonium sulfate particles were added to create a stable aerosol surface area on which low-volatility oxidation products condense. High concentrations of hydroxyl radical (OH) formed inside the OFR accelerate the oxidative chemistry that would typically occur over a period of several days in the atmosphere, resulting in the production of secondary aerosol from precursor gases present in the ambient air. Concentrations of added ozone and water vapor were controlled to produce the desired and approximately constant level of photochemical aging. The reactor temperature was controlled, while the pressure was not, and was always slightly lower than that of the sampled outside air. Sampled air was pulled from above the Naval Postgraduate School’s (NPS) Twin Otter aircraft through a rear-facing, ¼” OD PFA Teflon tube. The sample stream was split between the OFR and several gas analyzers (NOx, CO, O3, and H2O). Though not contained in these files, data from an aerosol mass spectrometer intermittently operated downstream of the OFR are also available.

{"secondary aerosol concentration",aerosol_concent↗
NASA NTRS1966

Histopathology of the Chimpanzee Ear

Four female and two male chimpanzees were secured in various positions on a Daisy Decelerator and subjected to forces ranging from 54 to 180 G. It was found that forces in excess of 54 G may rupture the tympanic membranes and cause subepithelial hemorrhages in the middle ear. The majority of cases showed proteinaceous material, with or without cells in the petrous air spaces. When exposed to forces above 119 G, there was engorgement and often rupture of the pericarotid venous plexus. When supine, distortion of both superior and posterior semicircular canals was found. With forces in excess of 54 G, the cupulae of the cristae ampullaris were either elevated or destroyed. The hair processes were also often broken off. The otolithic membranes, especially of the maculae utriculi were also elevated or otherwise distorted and the saccule was often partially collapsed. In several instances, there was an overabundance of a proteinaceous substance in the lumina of the vestibular apparatus and in the cochlear ducts with their associated scalae. In half the cases, the cochlear duct was narrowed by the depression of the vestibular membrane. Although there seems to be considerable individual variation in ability to withstand these forces, neither age, sex nor weight appear to directly influence the results. The possible sources for the materials found both in the air cells and labyrinth are discussed.

ACCELERATION TOLERANCE↗
NASA NTRS2018

Valentina Tereshkova and Sally Ride - Women Space Pioneers

Soon after the dawn of the Space Age, when the Soviet Union and the United States began plans for launching people into space, the question arose of just exactly who those people should be. It was assumed that the stresses of space flight would require individuals already accustomed to that kind of work - familiar with advanced technology, high accelerations, quick reaction time, cool headed under pressure. Both countries decided that the best qualified people for space flight would be military pilots. In the late 1950's and early 1960's, military pilots were exclusively male, so the first groups selected for space flight, 20 in the Soviet Union and seven in the United States, were comprised of the cream of the crop among their military pilots. But could women also survive the stresses of space flight?

John Uri↗
DOE OSTI2025

The detrimental ratio ( ρ ): A critical metric complementing coulombic loss for long calendar-life silicon-based lithium-ion batteries

Silicon (Si) is a promising high-capacity anode in lithium-ion batteries but suffers from chronic chemical degradation and capacity fading during calendar aging, greatly hindering its automobile applications. Electrolyte engineering currently relies on conventional evaluation criteria of reducing coulombic consumption, which implicitly presume its equivalence to irreversible capacity loss and complicates battery development. Here, we introduce the detrimental ratio p to quantify the fraction of parasitic species that permanently degrades active material. This metric is independent and crucially complements total coulombic consumption for accurate performance evaluation. We systematically investigate multiple electrolyte formulations using high-precision leakage current measurements, open-circuit-voltage experiments, and post-mortem characterizations. Although some electrolytes exhibit similarly low coulombic consumption, they diverge significantly incapacity retention and p. Especially, dimethyl-carbonate-based localized-high concentration electrolyte can synergically achieve low coulombic consumption and detrimental ratio p during calendar aging, owing to its chemically inert and structurally resilient solidelectrolyte interface with minimal isolated Si material. By contrast, increasing fluoroethylene carbonate (FEC) additive content suppresses electrolyte breakdown but suffers aggravated chemical degradation of more LixSi isolation for irreversible capacity loss with arising p. This study critically reveals that the chemistry-characteristic detrimental ratio p establishes physically informed performance evaluation to pave the way for accelerating battery development.

Calendar aging↗
DOE OSTI2022

Detecting Thermally-Induced Spinodal Decomposition with Picosecond Ultrasonics in Cast Austenitic Stainless Steels

Destructive techniques to monitor nuclear reactor component health may not always be available during service, as they are time-consuming and often require pre-installed inspection coupons. Non-destructive evaluation (NDE) techniques can bridge this gap by rapidly identifying the state of mission-critical reactor components, via inference between NDE-measurable material properties and those of ultimate interest, such as ductility and toughness. Here, we demonstrate one such inference about the health of thermally aged cast austenitic stainless steels. Observations of surface acoustic wave peak (SAW) splitting correlate with spinodal decomposition-induced embrittlement as destructively measured by Charpy impact energy. Elastodynamic calculations and molecular dynamics simulations of the effects of spinodal decomposition on elastic moduli support that the new acoustic modes present are due to stiffening in the δ-ferrite domains. Finally, this discovery enables one to probe structure-property relationships in materials in a greatly accelerated manner, suggesting that similar inference methods can be used to determine material fitness-for-service, or to quickly uncover new structure-property relationships.

304-type stainless steel↗
DOE OSTI2023

Increasing atmospheric dryness reduces boreal forest tree growth

Rising atmospheric vapour pressure deficit (VPD) associated with climate change affects boreal forest growth via stomatal closure and soil dryness. However, the relationship between VPD and forest growth depends on the climatic context. Here we assess Canadian boreal forest responses to VPD changes from 1951-2018 using a well-replicated tree-growth increment network with approximately 5,000 species-site combinations. Of the 3,559 successful growth models, we observed a relationship between growth and concurrent summer VPD in one-third of the species-site combinations, and between growth and prior summer VPD in almost half of those combinations. The relationship between previous year VPD and current year growth was almost exclusively negative, while current year VPD also tended to reduce growth. Tree species, age, annual temperature, and soil moisture primarily determined tree VPD responses. Younger trees and species like white spruce and Douglas fir exhibited higher VPD sensitivity, as did areas with high annual temperature and low soil moisture. Since 1951, summer VPD increases in Canada have paralleled tree growth decreases, particularly in spruce species. Accelerating atmospheric dryness in the decades ahead will impair carbon storage and societal-economic services.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2014

Stellar signatures of AGN-jet-triggered star formation

To investigate feedback between relativistic jets emanating from active galactic nuclei and the stellar population of the host galaxy, we analyze the long-term evolution of the orbits of the stars formed in the galaxy-scale simulations by Gaibler et al. of jets in massive, gas-rich galaxies at z ∼ 2-3. We find strong, jet-induced differences in the resulting stellar populations of galaxies that host relativistic jets and galaxies that do not, including correlations in stellar locations, velocities, and ages. Jets are found to generate distributions of increased radial and vertical velocities that persist long enough to effectively augment the stellar structure of the host. The jets cause the formation of bow shocks that move out through the disk, generating rings of star formation within the disk. The bow shock often accelerates pockets of gas in which stars form, yielding populations of stars with significant radial and vertical velocities, some of which have large enough velocities to escape the galaxy. These stellar population signatures can serve to identify past jet activity as well as jet-induced star formation.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Water Temperature, Prey Concentration and Salmonid Density Influence Daily Growth of Wild Juvenile Salmonids in Tributaries of the Upper Salmon River, Idaho ( USA )

ABSTRACT Theory, experiments and field studies indicate that the somatic growth rate of freshwater consumers is shaped by the individual, additive and multiplicative effects of multiple factors, including consumer size and condition, temperature, prey resources and biotic interactions. While our understanding of how these factors affect wild populations of freshwater consumers is improving, the topic remains poorly studied, especially with respect to mobile species. Here, we report on an 8‐year, seven‐stream ( n = 49 stream‐year combinations) observational study examining the individual and interactive effects of invertebrate prey concentration (F, mg/m 3 ), mean daily water temperature (T, °C) and juvenile Chinook salmon ( Oncorhynchus tshawytscha ) density (D, fish/100 m 2 ) on summer daily growth rates (%/d) of mobile, anadromous, juvenile Chinook salmon (age‐0+, n = 382) and sub‐yearling (age‐0+, n = 61) and yearling (age‐1+) steelhead trout ( O. mykiss , n = 70) rearing in cold (mean daily summer: 12.1°C, range: 4.2°C–16.7°C) mountain tributaries of the Salmon River basin in central Idaho (USA). AIC c model selection indicated that daily juvenile salmonid growth positively correlated with water temperature, prey biomass concentration, local juvenile Chinook density and the interaction between water temperature and food but with species and age‐specific differences. Water temperature was a covariate in all top‐ranked models, with daily growth (%/day) rate increasing (0.05%–0.23%/d) linearly with mean daily summer water temperature. In addition to a direct positive relationship with daily growth rate, there was evidence that prey concentration positively interacted with water temperature to accelerate daily growth (F × T). The positive relationship between juvenile salmonid daily growth rate and juvenile Chinook density is difficult to explain and could result from confounding factors. The individual success observed in these streams may contribute to population‐level benefits for the focal consumers, as prey‐rich, warm summers may result in larger individuals with higher energy reserves at the end of the summer/autumn growing season, contributing to improved overwinter survival. Our results, taken in combination with evidence from models, experiments and observational studies, have climate change implications. Current and predicted increases in water temperature will necessitate higher rates of prey consumption by aquatic ectothermic consumers to offset accelerated metabolic demands. Thus, to improve the resilience of mobile freshwater consumers in a warming climate, we suggest that natural resource managers not only consider physical and chemical habitat conditions but also biotic conditions, including the spatiotemporal quantity and quality of prey resources.

Kiffney, Peter. M. [Fish Ecology, Northwest Fisher↗
DOE OSTI2020

Design and feasibility of a novel program of cervical screening in Nigeria: self-sampled HPV testing paired with visual triage

Background: Accelerated global control of cervical cancer would require primary prevention with human papillomavirus (HPV) vaccination in addition to novel screening program strategies that are simple, inexpensive, and effective. We present the feasibility and outcome of a community-based HPV self-sampled screening program. Methods: In Ile Ife, Nigeria, 9406 women aged 30–49 years collected vaginal self-samples, which were tested for HPV in the local study laboratory using Hybrid Capture-2 (HC2) (Qiagen). HPV-positive women were referred to the colposcopy clinic. Gynecologist colposcopic impression dictated immediate management; biopsies were taken when definite acetowhitening was present to produce a histopathologic reference standard of precancer (and to determine final clinical management). Retrospective linkage to the medical records identified 442 of 9406 women living with HIV (WLWH). Results: With self-sampling, it was possible to screen more than 100 women per day per clinic. Following an audio-visual presentation and in-person instructions, overall acceptability of self-sampling was very high (81.2% women preferring self-sampling over clinician collection). HPV positivity was found in 17.3% of women. Intensive follow-up contributed to 85.9% attendance at the colposcopy clinic. Of those referred, 8.2% were initially treated with thermal ablation and 5.6% with large loop excision of transformation zone (LLETZ). Full visibility of the squamocolumnar junction, necessary for optimal visual triage and ablation, declined from 68.5% at age 30 to 35.4% at age 49. CIN2+ and CIN3+ (CIN- Cervical intraepithelial neoplasia), including five cancers, were identified by histology in 5.9 and 3.2% of the HPV-positive women, respectively (0.9 and 0.5% of the total screening population), leading to additional treatment as indicated. The prevalences of HPV infection and CIN2+ were substantially higher (40.5 and 2.5%, respectively) among WLWH. Colposcopic impression led to over- and under-treatment compared to the histopathology reference standard. Conclusion: A cervical cancer screening program using self-sampled HPV testing, with colposcopic immediate management of women positive for HPV, proved feasible in Nigeria. Based on the collected specimens and images, we are now evaluating the use of a combination of partial HPV typing and automated visual evaluation (AVE) of cervical images to improve the accuracy of the screening program.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2017

Impact of a Locally Measured H {sub 0} on the Interpretation of Cosmic-chronometer Data

Many measurements in cosmology depend on the use of integrated distances or time, but galaxies evolving passively on a timescale much longer than their age difference allow us to determine the expansion rate H ( z ) solely as a function of the redshift–time derivative dz / dt . These model-independent “cosmic chronometers” can therefore be powerful discriminators for testing different cosmologies. In previous applications, the available sources strongly disfavored models (such as ΛCDM) predicting a variable acceleration, preferring instead a steady expansion rate over the redshift range 0 ≲ z ≲ 2. A more recent catalog of 30 objects appears to suggest non-steady expansion. In this paper, we show that such a result is entirely due to the inclusion of a high, locally inferred value of the Hubble constant H{sub 0} as an additional datum in a set of otherwise pure cosmic-chronometer measurements. This H {sub 0}, however, is not the same as the background Hubble constant if the local expansion rate is influenced by a Hubble Bubble. Used on their own, the cosmic chronometers completely reverse this conclusion, favoring instead a constant expansion rate out to z∼2.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1985

Visceral predictors of cardiovascular deconditioning in late middle-aged men

A number of visceral and behavioral factors connected with cardiovascular deconditioning were investigated, in order to identify a method for predicting the degree of orthostatic intolerance to spaceflight in several late-middle-aged men (55-65 years). Preliminary measurements were made of: mean arterial blood pressure plasma cortisol levels; and norepinephrine levels. Measurements of core temperature; plasma epinephrine level and subjective arousal from sleep were also obtained. Pairwise correlations were found for each of the variables and the time-to-blackout due centrifugal acceleration of up to +3 Gz. It is shown that the men with relatively low resting blood pressure were at greater risk of developing the clinical signs of cardiovascular deconditioning than were the men with higher basal blood pressure. Some applications of the experimental results to the development of selection criteria for Shuttle crews are discussed.

Goldwater, D. J.↗
DOE OSTI2018

Experimental Technetium Release from Simulated Salt-stone Cementitious Waste Form - 18419

Experiments are being conducted to evaluate the early release of technetium (Tc) from fresh salt-stone waste forms using dynamic flow-through tests. Salt-stone is a chemically reducing, grout-based waste form used by the U.S. Department of Energy (DOE) to dispose of low-activity salt solutions arising from high-level radioactive waste tank closure activities at the Savannah River Site (SRS). A key safety function of salt-stone is maintaining a low-flow, chemically reducing environment that will attenuate the release of redox-sensitive radioelements such as Tc. Salt-stone also provides a physical barrier due to its low intrinsic permeability, which limits both water and oxygen ingress. These release experiments, conducted to support the U.S. Nuclear Regulatory Commission's monitoring role during tank closure, are designed to provide independent information on how well salt-stone will perform its safety function. The dynamic leach tests were conducted in a Hassler-type core-holder permeameter system that allows an accelerated flow rate of simulated SRS groundwater through an intact cylinder of salt-stone spiked with Tc-99 at a concentration of approximately 2,100 Bq/g (3 ppm). The first salt-stone specimen to be tested (Specimen 2) was prepared with Grade 100 ground granulated blast-furnace slag and aged for 119 days in a temperature-controlled, low-oxygen, high-humidity environment. Before test completion, 9.5 pore volumes (PV) of simulated SRS groundwater were passed through the salt-stone cylinder. After a few PV, apparent saturated hydraulic conductivity (K{sub sat}) values calculated from flow data reached a steady-state value of approximately 1.0 x 10{sup -9} cm/s, which is within the range of previously reported data. Tc-99 concentrations in leachate peaked early during the leach test at 2.0 x 10{sup -7} M and then declined to approximately 4 x 10{sup -8} M after 9.5 PV. The leachate Tc-99 concentration after elution of 9.5 PV is broadly consistent with a Tc solution concentration controlled by the solubility of reduced Tc solids. The range of Tc-99 concentrations is similar to the range reported for a column test that was sponsored by DOE, but the time pattern of release differs. The second salt-stone specimen tested (Specimen 3) was aged for 372 days and it further differed from the first specimen in that its Grade 100 slag component had been finely ground using a mortar and pestle in an attempt to make it more reactive. This second test yielded Tc release behavior broadly similar to that observed during the first test, except that the early Tc peak (at 1.2 x 10{sup -6} M) was six times higher and the concentration after 6.7 PV (8.8 x 10{sup -8} M) was approximately two times higher than in the first test. In addition, the steady-state K{sub sat} was an order of magnitude lower than that of the first specimen. During the second test, the injection pump was intentionally turned off for a period of 11 days (i.e., approximate residence time for 1 PV) and a Tc spike was observed when pumping resumed, suggesting that longer residence times may promote higher Tc effluent concentrations. During a second intentional shut-down of the pump for 25 days (approximate residence time for 2 PV), another Tc spike was observed. An unplanned excursion to higher confining pressure physically affected the specimen, temporarily lowering the apparent K{sub sat} followed by a subsequent increase in both K{sub sat} and Tc effluent concentration. One hypothesis is that the transient spike in confining pressure and resulting salt-stone compression and later decompression may have induced Tc release from otherwise inactive pores. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗