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NASA NTRS1993

Prototype Backscatter Moessbauer Spectrometer for Measurement of Martian Surface Mineralogy

We have designed and successfully tested a prototype of a backscatter Moessbauer spectrometer (BaMS) targeted for use on the Martian surface to (1) determine oxidation states of iron, and (2) identify and determine relative abundances of iron-bearing mineralogies. No sample preparation is required to perform measurements; it is only necessary to bring sample and instrument into physical contact. The prototype meets our projected specification for a flight instrument in terms of mass, power, and volume. A Moessbauer spectrometer on the Martian surface would provide wide variety of information about the current state of the Martian surface, and this information is described.

Shelfer, T. D.↗

NASA NTRS1993

Improved real-time imaging spectrometer

An improved AOTF-based imaging spectrometer that offers several advantages over prior art AOTF imaging spectrometers is presented. The ability to electronically set the bandpass wavelength provides observational flexibility. Various improvements in optical architecture provide simplified magnification variability, improved image resolution and light throughput efficiency and reduced sensitivity to ambient light. Two embodiments of the invention are: (1) operation in the visible/near-infrared domain of wavelength range 0.48 to 0.76 microns; and (2) infrared configuration which operates in the wavelength range of 1.2 to 2.5 microns.

Lambert, James L.↗

NASA NTRS1993

Sensitivity of LDEF foil analyses using ultra-low background germanium vs. large NaI(Tl) multidimensional spectrometers

Cobalt foils and stainless steel samples were analyzed for induced Co-60 activity with both an ultra-low background germanium gamma-ray spectrometer and with a large NaI(Tl) multidimensional spectrometer, both of which use electronic anticoincidence shielding to reduce background counts resulting from cosmic rays. Aluminum samples were analyzed for Na-22. The results, in addition to the relative sensitivities and precisions afforded by the two methods, are presented.

Reeves, James H.↗

NASA NTRS1992

Absolute calibration of an ultraviolet spectrometer using a stabilized laser and a cryogenic cavity radiometer

We carry out the calibration of an ultraviolet spectrometer by using a cryogenic electrical-substitution radiometer and intensity-stabilized laser sources. A comparison of the error budgets for the laser-based calibration described here and for a calibration using a type-FEL tungsten spectral-irradiance standard indicates that this technique could provide an improvement of a factor of about three in the uncertainty of the spectrometer calibration, resulting in an absolute accuracy (standard deviation of three) of about 1 percent at 257 nm. The technique described here might significantly improve the accuracy of calibrations on NASA ozone-monitoring and solar ultraviolet-monitoring spectrophotometers when used to complement present procedures that employ lamps and the SURF II synchrotron ultraviolet radiation facility at the National Institute of Standards and Technology.

Jauniskis, L.↗

NASA NTRS1993

An operational method for estimating signal to noise ratios from data acquired with imaging spectrometers

A method, using the concept of local means and local standard deviations of small imaging blocks and using a box counting procedure, has been developed for unsupervised estimation of the average signal to noise ratios of images in which the noise is additive. The method has been applied to simulated images with Gaussian noise, to images acquired with the Airborne Visible Infrared Imaging Spectrometer and with the Geophysical and Environmental Research Imaging Spectrometer. The method is compared with other techniques for estimating signal to noise ratios from imaging data. It is believed that the method is generally applicable to images having many small homogeneous blocks. Because the method does not take into account interband effects, it is not appropriate to use the method to estimate signal to noise ratios from images having nonnegligible interband radiometric calibration errors at spatial scales less than or equal to the size of the small imaging blocks used in the noise estimation.

Gao, Bo-Cai↗

NASA NTRS1991

Optical design of the Moderate Resolution Imaging Spectrometer - Tilt (MODIS-T) for the Earth Observing System (Eos)

The Moderate Resolution Imaging Spectrometer (MODIS) is an Earth viewing sensor that is planned as a facility instrument for the Earth Observing System (Eos) scheduled to begin functioning in the late 1990's. The MODIS is composed of two mutually supporting sensors one of which is MODIS-T, where 'T' signifies a tiltable along-track field of view. MODIS-T is a 32 channel imaging spectrometer with a required 10 nm to 15 nm spectral resolution (FWHM) in the 400 nm to 880 nm spectral range with less than 2.3 percent instrument induced linear polarization. The instrument provides at nadir a 33 km by 1500 km swath with a 1.1 km spatial resolution and an along-track pointing capability of +/- 50 deg about nadir. The heart of the optical design consists of a f/3 grating-type reflecting Schmidt camera.

Maymon, Peter W.↗

NASA NTRS1992

The Diffuse X-ray Spectrometer Experiment

The Diffuse X-ray Spectrometer Experiment, or 'DXS', is designed to measure the spectrum of the low-energy diffuse X-ray background with about 10 eV energy resolution and 15-deg spatial resolution. During a 5-day Space Shuttle mission, DXS is to measure the spectrum of ten 15 x 15 deg regions lying along a single 150-deg-long great circle arc on the sky. DXS carries two large-area X-ray Bragg spectrometers for the 44-84 A wavelength range; these permit measurement of the wavelength spectrum of the cosmic low-energy diffuse X-ray background with good spectral resolution.

Sanders, W. T.↗

NASA NTRS1993

Dynamic interferometer alignment and its utility in UV Fourier transform spectrometer systems

Dynamic alignment has been demonstrated as a practical approach to alignment maintenance for systems in the infrared region of the spectrum. On the basis of work done by OPTRA, this technique was introduced in commercial Fourier transform spectrometer systems in 1982 and in various forms is now available from a number of manufacturers. This paper reports on work by OPTRA to extend the basic technique to systems operating in the ultraviolet. In addition, this paper reports the preliminary results of the development of an alignment system using a laser diode in place of a gas laser normally found in dynamic alignment systems. A unique optical system and spatial heterodyne technique allows for achievement of a metrology system with characteristics that fully satisfy the requirements of an ultraviolet spectrometer system.

Dorval, Rick K.↗

NASA NTRS1992

Low earth orbiting Nadir Etalon Sounding Spectrometer instrument concept for temperature, moisture and trace species, LeoNESS

A concept for a low earth orbiting nadir etalon spectrometer sounder (LeoNESS) is described which can achieve retrieval of temperature, H2O, surface, boundary conditions, cloudiness, and trace species with an accuracy that meets or exceeds the AIRS specifications. Options employing 65-K and 30-K detectors are examined; the former may be implemented via passive radiative cooling. The concept, which is derived from the Cryogenic Limb Array Etalon Spectrometer, has the potential for improving the horizontal and vertical resolution.

Kumer, J. B.↗

NASA NTRS1991

Tropospheric Emission Spectrometer for the Earth Observing System

A Tropospheric Emission Spectrometer (TES) for the Earth Observing System (EOS) series of polar-orbiting platforms is described. TES is aimed at studying tropospheric chemistry, in particular, the exchange of gases between the surface and the atmosphere, urban and regional pollution, acid rain precursors, sources and sinks of greenhouse gases, and the interchange of gases between the troposphere and the stratosphere. TES is a high-resolution (0.025/cm) infrared Fourier transform spectrometer operating in the passive thermal-emission mode in a very wide spectral range (600 to 4350/cm; 2.3 to 16.7 microns). TES has 32 spatial pixels in each of four optically conjugated linear detector arrays, each optimized for a different spectral region.

Glavich, Thomas A.↗

NASA NTRS1992

The Objective Double Crystal Spectrometer

The solar corona, supernova remnants, the hot diffuse interstellar gas in the Galaxy, galactic halos, and the hot intracluster gas in rich clusters of galaxies, are examples of extended astrophysical plasmas which emit line-rich spectra in the X-ray spectral range from 1.5 to 25 A. These phenomena represent a significant fraction of the baryonic matter in the universe. The study of the composition, structure and dynamics of these astrophysical plasmas requires observations with both high spectral and spatial resolution simultaneously. The Objective Double Crystal Spectrometer, coupled with a grazing incidence X-ray telescope, represents a stigmatic instrument which is highly efficient for the study of such sources. We describe the configuration and performance (spatial resolution, spectral resolution and efficiency) of the Objective Double Crystal spectrometer.

Walker, Arthur B. C., Jr.↗

NASA NTRS1990

VLSI corrector chip for space-borne mm-wave radiometer spectrometers

JPL developed a 52-channel 150 MHz bandwidth autocorrelator spectrometer using specially designed ECL gate array correlator chips. The characteristics of the ECL chip and the 52-channel auto-correlator are described. These autocorrelator spectrometers will be used with space-borne mm-wave radiometers for remote sensing of the Earth's atmosphere and astrophysical observations.

Chandra, K.↗

NASA NTRS1992

Development of an advanced spacecraft tandem mass spectrometer

The purpose of this research was to apply current advanced technology in electronics and materials to the development of a miniaturized Tandem Mass Spectrometer that would have the potential for future development into a package suitable for spacecraft use. The mass spectrometer to be used as a basis for the tandem instrument would be a magnetic sector instrument, of Nier-Johnson configuration, as used on the Viking Mars Lander mission. This instrument configuration would then be matched with a suitable second stage MS to provide the benefits of tandem MS operation for rapid identification of unknown organic compounds. This tandem instrument is configured with a newly designed GC system to aid in separation of complex mixtures prior to MS analysis. A number of important results were achieved in the course of this project. Among them were the development of a miniaturized GC subsystem, with a unique desorber-injector, fully temperature feedback controlled oven with powered cooling for rapid reset to ambient conditions, a unique combination inlet system to the MS that provides for both membrane sampling and direct capillary column sample transfer, a compact and ruggedized alignment configuration for the MS, an improved ion source design for increased sensitivity, and a simple, rugged tandem MS configuration that is particularly adaptable to spacecraft use because of its low power and low vacuum pumping requirements. The potential applications of this research include use in manned spacecraft like the space station as a real-time detection and warning device for the presence of potentially harmful trace contaminants of the spacecraft atmosphere, use as an analytical device for evaluating samples collected on the Moon or a planetary surface, or even use in connection with monitoring potentially hazardous conditions that may exist in terrestrial locations such as launch pads, environmental test chambers or other sensitive areas. Commercial development of the technology could lead to a new family of environmental test instruments that would be small and portable, yet would give quick analyses of complex samples.

Drew, Russell C.↗

NASA NTRS1993

A Moessbauer spectrometer for the mineralogical analysis of the Mars surface: First temperature dependent tests of the detector and drive system

Part of the scientific payload of the Mars-96 mission is a Fe-(57)Mossbauer (MB) spectrometer installed on a small rover to be placed on the surface of Mars. The instrument is under development at the University of Darmstadt. This instrument, with some modifications, is also included in the scientific payload of the proposed MARSNET mission of the European Space Agency (ESA). A similar instrument is currently under development in the US. The reason for developing a Mossbauer spectrometer for space applications is the high abundance of the element iron, especially on the surface of Mars. The elemental composition of Martian soil was determined during the Viking mission in 1976 but not it's mineralogical composition. One believes that it is composed mainly of iron-rich clay minerals, with an iron content of about 14 (plus or minus 2) wt-percent, partly magnetic. Of extremely great interest are the oxidation state of the iron, the magnetic phases and the mineral composition of the Mars surface. To these questions MB spectroscopy can provide important information, which are not available by other methods. We report on first tests of the experimental setup in the temperature range plus 20 C to -70 C, roughly corresponding to the temperature range on the surface of Mars. Also questions concerning the signal/noise ratio (S/N) are discussed.

Held, P.↗

NASA NTRS1992

Seasonal and spatial variations in phytoplanktonic chlorophyll in eutrophic Mono Lake, California, measured with the Airborne Visible and Infrared Imaging Spectrometer (AVIRIS)

The principal problem with application of airborne imaging spectrometers to lakes is the weak upwelling signal, especially when narrow spectral bands with high spatial resolution are sought. Furthermore, atmospheric path radiance dominates the signal received from dark targets such as lakes. Once atmospheric effects have been removed from the radiance received at the sensor, semi-empirical relationships can be developed to extract information about phytoplankton pigment concentrations for different underwater optical conditions. In lakes where concentrations of dissolved organics and suspended detritus may not co-vary with phytoplankton pigments, the many spectral channels of an imaging spectrometer such as AVIRIS are likely to be required to distinguish the various aquasols. The objectives of our study are to: (1) estimate the chlorophyll content of a lake with hundred-fold seasonal ranges in chlorophyll concentration using atmospherically corrected upwelling radiances derived from AVIRIS imagery, and (2) to examine spatial patterns in chlorophyll after reduction of the coherent noise in the imagery by filtering techniques.

Melack, John M.↗

NASA NTRS1992

JPL activities on development of acousto-optic tunable filter imaging spectrometer

Recent activities of JPL in the development of a new type of imaging spectrometers for earth observation and planetary exploration are reported. This instrument uses the acousto-optic tunable filter (AOTF) as high resolution and fast programmable bandpass filter. AOTF operates in the principle of acousto-optic interaction in an anisotropic medium. This filter can be tuned in sequential, random, and multiwavelength access modes, providing observational flexibility. The diffraction process in the filter generates two diffracted monochromatic beams with polarization orthogonal to each other, creating a unique capability to measure both polarimetric and spectral properties of the incoming light simultaneously with a single instrument. The device gives wide wavelength operations with reasonably large throughput. In addition, it is in a compact solid-state structure without moving parts, providing system reliability. These attractive features give promising opportunities to develop a new generation of airborne/spaceborne and ground, real-time, imaging spectrometer systems for remote sensing applications.

Cheng, Li-Jen↗

NASA NTRS1993

MinMap: An imaging spectrometer for high resolution compositional mapping of the Moon

MinMap has been selected by the Lunar Scout program to characterize and map the mineral composition of the Moon. The instrument will be built as a collaborative effort between Brown University, SETS Technology Inc., and Ball Aerospace Corp. MinMap is a visible to near-infrared imaging spectrometer that contains 192 spectral channels from 0.35-2.4 microns with signal to noise greater than 200 and 256 cross-track spatial elements. The spectrometer design has a 6 deg field of view (FOV) and utilizes grating dispersive elements and two dimensional detectors (no moving parts). An 'image cube' of data is produced that contains two dimensions of spatial information and one dimension of spectral information. All spectral channels and cross-track spatial elements are recorded simultaneously with spacecraft motion scanning the second spatial dimension. The high spectral resolution and continuous spectral range of MinMap are designed to measure the diagnostic absorption features of principal lunar minerals and their lithologic mixtures. Since the optical properties of lunar materials change in a regular manner upon exposure to the space environment, this spectral range is also quite sensitive to variations in exposure history (soil maturity). Nominal measurement stragegy is to obtain full global data of the Moon at 180 m/pixel from a 450 km polar orbit during the first month or two of operation. A 100 km orbit is anticipated for the remaining part of a 1 year mission allowing higher resolution data (approx. 80 m/pixel) to be obtained for targeted regions. MinMap exceeds LE x SWG's measurement recommendations and will provide the highest spatial resolution compositional map of lunar rocks and soils currently planned for orbital missions. Since all spectral channels are co-registered and obtained simultaneously, 'image cube' data swaths will be available for analysis almost immediately.

Pieters, C. M.↗

NASA NTRS1992

Low power, CMOS digital autocorrelator spectrometer for spaceborne applications

A 128-channel digital autocorrelator spectrometer using four 32 channel low power CMOS correlator chips was built and tested. The CMOS correlator chip uses a 2-bit multiplication algorithm and a full-custom CMOS VLSI design to achieve low DC power consumption. The digital autocorrelator spectrometer has a 20 MHz band width, and the total DC power requirement is 6 Watts.

Chandra, Kumar↗