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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,009 records · Page 56
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DOE OSTI2018

Connected Lighting Systems Efficiency Study: PoE Cable Energy Losses, Part 2

DOE published a report in November 2017 (herein referred to as “Part 1”) summarizing the results of an exploratory study investigating power losses in Ethernet cables used between PoE switches and luminaires in PoE connected lighting systems. Testing was conducted at the Pacific Northwest National Laboratory (PNNL) Connected Lighting Test Bed (CLTB) in September 2017. The results were analyzed to explore the impact of cable selection on PoE lighting system energy efficiency, as well as the effectiveness of guidelines published by the American National Standards Institute (ANSI) C137 Lighting Systems Committee in 2017. The guidance offered in ANSI C137.3-2017 was found to be effective in limiting cable energy losses to 5% in PoE lighting applications, provided that the average cable length on a project does not exceed 50 m. This Part 2 report summarizes the results of a continued investigation of the power losses in Ethernet cables used between PoE switches and luminaires in PoE connected lighting systems. Testing was conducted at the PNNL CLTB in July-August 2018. A test setup comprising a PoE switch, a set of luminaires, and a reference meter was again used to test multiple cable models of varying design. The results were analyzed to explore the impact of cable selection and installation practices (e.g., cable bending, cable bundling, and installation in conduit) on PoE lighting system energy efficiency, as well as the effectiveness of the ANSI C137.3 guidelines. Notably, three cables—two of which were shielded—were previously excluded from the Part 1 study due to compatibility issues. All three cables were included in this Part 2 study, along with a fourth model cable introduced in Part 2. In addition, whereas no patch cords were used in Part 1, patch cords were used in some Part 2 testing. The ANSI C137.3 guidance was again shown to effectively limit power losses to less than 5% in the cables tested (varying in AWG, Category, shielding, fire rating, and manufacturer), and AWG again proved to be the most important cable design variable for energy performance, as expected. However, these findings should not be construed as being representative of all cable models and installation practices. For example, energy losses would be greater when cables are connected to patch cords, bundled in conduit, and loaded with powered devices (PDs) approaching 100 W input power. The other key finding was that with 44 W luminaires as PDs and room ambient temperatures below 30°C, cable energy losses were not substantially increased by cable bending or bundling in uninsulated conduit. However, environments with higher ambient temperatures will have greater energy losses due to increased conductor DCR. In addition, product selection and installation practices will have increased importance as PDs approaching 100 W input power—conveyed by a single Ethernet cable—are introduced following publication of the forthcoming Institute of Electrical and Electronics Engineers (IEEE) Standard 802.3bt. The report also provides recommendations and next steps, which include plans for additional PoE cable energy losses testing with higher-power PDs to more fully explore the potential of PoE lighting systems.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2015

Light emission from conductive paths in nanocrystalline CdSe embedded Zr-doped HfO{sub 2} high-k stack

Electrical and optical properties of the solid state incandescent light emitting devices made of zirconium doped hafnium oxide high-k films with and without an embedded nanocrystalline CdSe layer on the p-type Si wafer have been studied. The broad band white light was emitted from nano sized conductive paths through the thermal excitation mechanism. Conductive paths formed from the dielectric breakdown have been confirmed from scanning electron microscopic and atomic force microscopic images and the secondary ion mass spectrometric elemental profiles. Si was diffused from the wafer to the device surface through the conductive path during the high temperature light emission process. There are many potential applications of this type of device.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Enhanced Light Extraction from OLEDs Fabricated on Patterned Plastic Substrates

A key scientific and technological challenge in organic light-emitting diodes (OLEDs) is enhancing the light outcoupling factor η out , which is typically <20%. This paper reports experimental and modeling results of a promising approach to strongly increase η out by fabricating OLEDs on novel flexible nanopatterned substrates that result in a >2× enhancement in green phosphorescent OLEDs (PhOLEDs) fabricated on corrugated polycarbonate (PC). The external quantum efficiency (EQE) reaches 50% (meaning ηout ≥50%); it increases 2.6x relative to a glass/ITO device and 2× relative to devices on glass/poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) or flat PC/PEDOT:PSS. A significant enhancement is also observed for blue PhOLEDs with EQE 1.7× relative to flat PC. The corrugated PC substrates are fabricated efficiently and cost-effectively by direct room-temperature molding. These substrates successfully reduce photon losses due to trapping/waveguiding in the organic+anode layers and possibly substrate, and losses to plasmons at the metal cathode. Focused ion beam gauged the conformality of the OLEDs. Dome-shaped convex nanopatterns with height of ~280–400 nm and pitch ~750–800 nm were found to be optimal. Lastly, substrate design and layer thickness simulations, reported first for patterned devices, agree with the experimental results that present a promising method to mitigate photon loss paths in OLEDs.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Understanding, Predicting, and Mitigating Catastrophic Shorts for Improved OLED Lighting Panel Reliability (Final Report)

Catastrophic OLED lighting panel failure due to electrical shorting was a significant reliability challenge facing the industry. The goal of this program was to develop a basic scientific understanding of how incipient shorts in an OLED originate and grow to a catastrophic level, and to develop mitigation strategies that enable the industry to reach the DOE target of 0.01% failure rate. We accomplished this goal, identifying the origin of shorts, understanding how the evolve over time, and ultimately identifying a mitigation strategy that was implemented by our industry partner and demonstrated to completely eliminate catastrophic shorts in production OLED panels. We identified two general classes of panel defect, termed bright spots and hot spots, that respectively originate from indium-tin-oxide agglomerations and microscale organic semiconductor dust particles on the substrate. The former are largely benign whereas the latter can lead to local shunts that grow over time and cause catastrophic failure. We understand the growth process as a self-reinforcing cycle, where shunt-induced heating volatilizes the surrounding organic semiconductor, which in turn expands the shunt and leads to even more heating. Based on these results, we identified several practical strategies to arrest the growth of early-stage shorts or prevent them entirely. These results will reduce the cost and improve the reliability of OLED lighting.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Consequences of Optimal Bond Valence on Structural Rigidity and Improved Luminescence Properties in Sr x Ba 2-x SiO 4 :Eu 2+ Orthosilicate Phosphors

The orthosilicate phosphors Sr x Ba 2–x SiO 4 :Eu 2+ have now been known for over four decades and have found extensive recent use in solid-state white lighting. It is well-recognized in the literature and in practice that intermediate compositions in the solid-solutions between the orthosilicates Sr 2 SiO 4 and Ba 2 SiO 4 yield the best phosphor hosts when the thermal stability of luminescence is considered. We employ a combination of synchrotron X-ray diffraction, total scattering measurements, density functional theory calculations, and low-temperature heat capacity measurements, in conjunction with detailed temperature- and time-resolved studies of luminescence properties to understand the origins of the improved luminescence properties. We observe that in the intermediate compositions, the two cation sites in the crystal structure are optimally bonded as determined from bond valence sum calculations. Optimal bonding results in a more rigid lattice, as established by the intermediate compositions possessing the highest Debye temperature, which are determined experimentally from low-temperature heat capacity measurements. Greater rigidity in turn results in the highest luminescence efficiency for intermediate compositions at elevated temperatures.

Denault, Kristin A.↗
DOE OSTI2018

Local protein solvation drives direct down-conversion in phycobiliprotein PC645 via incoherent vibronic transport

Significance To harness sunlight for growth, plants and algae rapidly convey absorbed excitation energy from antennae pigments to a reaction center, where the excitations convert to chemical energy. In deep water environments, cryptophyte algae survive by using the molecular motion of phycobiliprotein antennae to funnel excitations to low-energy pigments. The mechanism of down-conversion in phycobiliproteins remains controversial: Could specific vibrations resonant with pigment energy gaps support coherence between excited states and thereby enhance the rate of transport by transient delocalization? Here, we demonstrate that down-conversion in a specific phycobiliprotein, PC645, is both incoherent and enhanced by a broad range of high-frequency vibrations. We suggest that a similar incoherent mechanism is appropriate across phycobiliproteins.

09 BIOMASS FUELS↗