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At least 1,009 records · Page 56

Quasicubic model for metal halide perovskite nanocrystals

In this work, we present an analysis of quantum confinement of carriers and excitons, and exciton fine structure, in metal halide perovskite (MHP) nanocrystals (NCs). Starting with coupled-band k · P theory, we derive a nonparabolic effective mass model for the exciton energies in MHP NCs valid for the full size range from the strong to the weak confinement limits. We illustrate the application of the model to CsPbBr 3 NCs and compare the theory against published absorption data, finding excellent agreement. We then apply the theory of electron-hole exchange, including both short- and long-range exchange interactions, to develop a model for the exciton fine structure. We develop an analytical quasicubic model for the effect of tetragonal and orthorhombic lattice distortions on the exchange-related exciton fine structure in CsPbBr 3 , as well as some hybrid organic MHPs of recent interest, including formamidinium lead bromide (FAPbBr 3 ) and methylammonium lead iodide (MAPbI3). Testing the predictions of the quasicubic model using hybrid density functional theory (DFT) calculations, we find qualitative agreement in tetragonal MHPs but significant disagreement in the orthorhombic modifications. Moreover, the quasicubic model fails to correctly describe the exciton oscillator strength and with it the long-range exchange corrections in these systems. Introducing the effect of NC shape anisotropy and possible Rashba terms into the model, we illustrate the calculation of the exciton fine structure in CsPbBr 3 NCs based on the results of the DFT calculations and examine the effect of Rashba terms and shape anisotropy on the calculated fine structure.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Nonlinear dynamics of small-scale Alfvén waves

Herein we study the nonlinear evolution of very oblique small-scale Alfvén waves with k ⊥ d i ≳1. At these scales, the waves become significantly compressive, unlike in magnetohydrodynamics, due to the Hall term in the equations. We demonstrate that when frequencies are small compared to the ion gyrofrequency and amplitudes are small compared to unity, no new nonlinear interaction appears due to the Hall term alone at the lowest non-trivial order, even when k ⊥ d i ~1. However, at the second non-trivial order, we discover that the Hall physics leads to a slow but resonant nonlinear interaction between co-propagating Alfvén waves, an inherently three-dimensional effect. Including the effects of finite temperature, finite frequency, and electron inertia, the two-fluid Alfvén wave also becomes dispersive once one or more of k ⊥ ρ s , k ⊥ d e , or k ∥ d i becomes significant: for oblique waves at low β as studied here, this can be at a much smaller scale than d i . We show that the timescale for one-dimensional steepening of two-fluid Alfvén waves is only significant at these smaller dispersive scales, and also derive an expression for the amplitude of driven harmonics of a primary wave. Importantly, both new effects are absent in gyrokinetics and other commonly used reduced two-fluid models. Our calculations have relevance for the interpretation of laboratory Alfvén wave experiments, as well as shedding light on the physics of turbulence in the solar corona and inner solar wind, where the dominant nonlinear interaction between counter-propagating waves is suppressed, allowing these new effects to become important.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Reconfigurable Intelligent Surfaces in Action for Nonterrestrial Networks

Next-generation communication technology will be made possible by cooperation between terrestrial networks with nonterrestrial networks (NTNs) composed of high-altitude platform stations (HAPSs) and satellites. Further, as humanity embarks on the long road to establish new habitats on other planets, the cooperation between NTNs and deep-space networks (DSNs) will be necessary. In this regard, we propose the use of reconfigurable intelligent surfaces (RISs) to improve coordination between these networks given that RISs perfectly match the size, weight, and power (SWaP) restrictions of operating in space. Here, a comprehensive framework of RIS-assisted nonterrestrial and interplanetary communications is presented that pinpoints challenges, use cases, and open issues. Furthermore, the performance of RIS-assisted NTNs under environmental effects, such as solar scintillation and satellite drag, is discussed in light of simulation results.

42 ENGINEERING↗

Control of Energy Transport and Transduction in Photosynthetic Down-Conversion (Final Technical Report)

The research conducted under this contract focused on three areas related to control of energy transport and transduction in natural and synthetic light harvesting systems: (1) experimental and theoretical studies exploring the use of ultrafast laser pulse shaping to manipulate the initially excited states of multi-chromophore biological light harvesting networks and influence the early time energy transfer and electronic and vibrational relaxation pathways, (2) fundamental theoretical developments aimed at computing and analyzing the dynamics of excitations of complex heterogeneous environments and nano structures, and (3) joint experimental and theoretical design studies of artificial light harvesting materials exploring the influence of incorporating different types of organic layers in low dimensional lead halide perovskite materials on their hot carrier relaxation dynamics, and theoretical studies of the design of nano structured light harvesting antenna systems. These research projects supported the training of three theoretical and computational graduate students, one experimental graduate student, and one experimental post-doctoral researcher. The research has been published in seven peer reviewed papers and presented at several international meetings and workshops.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Support for the 32 nd Annual Meeting of the Inter-American Photochemical Society

This award offset the registration and travel costs for researchers from U.S. institutions to attend the 32 nd Inter-American Photochemical Society meeting held on Jan 2-5, 2025, in Miramar Beach, Florida. The Inter-American Photochemical Society (I-APS) is a non-profit organization dedicated to promoting and disseminating knowledge and encouraging the development of fundamental and allied photochemistry throughout the Americas. The I-APS annual meeting is a particularly important tool for fulfilling this goal as it provides a welcoming venue to highlight research progress in theoretical, experimental, and applied aspects of photochemistry and molecular photophysics by researchers in all stages of their careers. The participation of graduate students and postdocs at this conference is particularly important as it aids in training the next generation of scientists in photochemistry. This award provided travel awards to three Assistant Professors and fourteen graduate and two undergraduate students to attend the I-APS Meeting in 2025. A majority of the science presented/discussed at the I-APS meeting is in direct alignment with the mission of the DOE and the Solar Photochemistry program, including studying fundamental phenomena, encompassing light absorption, photoinduced energy/electron transfer, charge separation, and charge and energy transport across mesoscale dimensions, as well as their application in generating electricity and chemical bonds using light.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

In-Situ Measurement of Power Loss for Crystalline Silicon Modules Undergoing Thermal Cycling and Mechanical Loading Stress Testing

An in-situ method is proposed for monitoring and estimating the power degradation of mc-Si photovoltaic (PV) modules undergoing thermo-mechanical degradation tests that primarily manifest through cell cracking, such as mechanical load tests, thermal cycling and humidity freeze tests. The method is based on in-situ measurement of the module’s dark current-voltage (I-V) characteristic curve during the stress test, as well as initial and final module flash testing on a Sun simulator. The method uses superposition of the dark I-V curve with final flash test module short-circuit current to account for shunt and junction recombination losses, as well as series resistance estimation from the in-situ measured dark I-Vs and final flash test measurements. The method is developed based on mc-Si standard modules undergoing several stages of thermo-mechanical stress testing and degradation, for which we investigate the impact of the degradation on the modules light I-V curve parameters, and equivalent solar cell model parameters. Experimental validation of the method on the modules tested shows good agreement between the in-situ estimated power degradation and the flash test measured power loss of the modules, of up to 4.31 % error (RMSE), as the modules experience primarily junction defect recombination and increased series resistance losses. However, the application of the method will be limited for modules experiencing extensive photo-current degradation or delamination, which are not well reflected in the dark I-V characteristic of the PV module.

14 SOLAR ENERGY↗

Facility for testing solar cells

Primary components of facility are test chamber and external solar simulator. Voltage--current performance characteristics of solar cells at various combinations of temperature and light intensity are plotted on X-Y recorder. Data are fed into computer for calculation of maximum power, curve shape factor, cell efficiency, and averages of each parameter.

Yasui, R. K.↗

Neutron-rich isotopes of cosmic rays with Z between 9 and 16

Data are reported on the isotopic composition of cosmic rays with charges between 9 and 16 at a temperature of 450 MeV per amu. The data show the presence of a considerable neutron-rich component of Mg and Ne, the measured mean masses being 24.3 plus or minus 0.1 and 20.8 plus or minus 0.1, respectively. Coupled with a calculation of the evolution of cosmic-ray isotopic abundances during propagation, these masses indicate that there is probably some neutron-rich material in this charge range at the cosmic-ray source. To explain the Ne mass requires more neutron-rich Ne at the source than is observed in solar-system material. This result is discussed in light of recent theories of nucleosynthesis and cosmic-ray propagation.

Maehl, R. C.↗

Inexpensive, portable, integrating solar energy meter

Silicon-cell insolometer automatically measures and totals amount of energy available in sunlight falling on the earth at specific location over selected period of time. Device incorporates single silicon solar cell as sensing element and relies on principle that short-circuit current from solar cell is directly proportional to amount of light that shines on cell.

Masters, R. M.↗

Optimization of solar cells for air mass zero operation and a study of solar cells at high temperatures, phase 3

The etch-back epitaxy process is described for producing thin, graded composition GaAlAs layers. The palladium-aluminum contact system is discussed along with its associated problems. Recent solar cell results under simulated air mass zero light and at elevated temperatures are reported and the growth of thin polycrystalline GaAs films on foreign substrates is developed.

Blakeslee, A. E.↗

Evaluation of silicon-on-ceramic material for low-cost solar cells

The silicon-on-ceramic (SOC) process produces thin layers of silicon on inexpensive ceramic substrates. The layers are produced by unidirectional solidification of molten silicon, and are polycrystalline. Solar cells made from SOC material have performed with a conversion efficiency of 10.5%. In connection with the objective to improve the efficiency of SOC solar cells, an investigation was conducted to assess the relative importance of grain boundaries and impurities. In order to separate the two effects, light-beam-induced current (LBIC) measurements of the short-circuit current were made using a micron-sized light beam from a monochromator. The LBIC measurements are closely related to solar cell performance since the technique identifies the various spatial and spectral contributions to solar cell current. On the basis of the obtained results, it appears that structural defects are more important than chemical defects in limiting the performance of present SOC solar cells.

Zook, J. D.↗

Silicon Nitride Antireflection Coatings for Photovoltaic Cells

Chemical-vapor deposition adapted to yield graded index of refraction. Silicon nitride deposited in layers, refractive index of which decreases with distance away from cell/coating interface. Changing index of refraction allows adjustment of spectral transmittance for wavelengths which cell is most effective at converting light to electric current. Average conversion efficiency of solar cells increased from 8.84 percent to 12.63 percent.

Johnson, C.↗

Venus

The present conference concerning the study of Venus discusses stellar magnitude and albedo data for the planet, radio astronomical studies, results of the Venera 13 and 14 missions, Venus optical properties, topography, surface properties and tectonic evolution, the tectonic implications of the interior of Venus, the thermal structure, photochemistry, composition, general circulation, and electrical activity of the Venus atmosphere, and the thermal balance of the lower, middle and upper atmoshere of Venus. Also discussed are the observation and interpretation of the Venus ionosphere, its model calculation, the interaction of the solar wind with the ionosphere of Venus in light of flow field models, the origin and evolution of the Venus atmosphere, and the problem posed by rare gases in the atmosphere of Venus.

Hunten, D. M.↗

Roughening Surfaces Of Solar Cells

Proposed treatment involving bombardment by ions gives silicon solar cells rough surfaces and increases amount of light absorbed by cells. First step of treatment, wafer of single-crystal silicon held at temperature of 70 degree C or higher while bombarded with argon or hydrogen ions at kinetic energies between 100 and 2,000 eV. This high dose produces damaged layer on surface, consisting of outer polycrystalline sublayer and underlying sublayer containing extended defects. Bombarded wafer then etched chemically. Photovoltaic conversion efficiency increases with number of reflections at surface of silicon cell because large part of light absorbed at each reflection. Deeply textured surface provides opportunities for multiple reflections.

Singh, Ranbir↗

Telecommunications and navigation systems design for manned Mars exploration missions

This paper discusses typical manned Mars exploration needs for telecommunications, including preliminary navigation support functions. It is a brief progress report on an ongoing study program within the current NASA JPL Deep Space Network (DSN) activities. A typical Mars exploration case is defined, and support approaches comparing microwave and optical frequency performance for both local in situ and Mars-earth links are described. Optical telecommunication and navigation technology development opportunities in a Mars exploration program are also identified. A local Mars system telecommunication relay and navigation capability for service support of all Mars missions has been proposed as part of an overall solar system communications network. The effects of light-time delay and occultations on real-time mission decision-making are discussed; the availability of increased local mass data storage may be more important than increasing peak data rates to earth. The long-term frequency use plan will most likely include a mix of microwave, millimeter-wave and optical link capabilities to meet a variety of deep space mission needs.

Hall, Justin R.↗

In situ measurements of scattering from contaminated optics in the Vacuum Ultraviolet

NASA's In Situ Contamination Effects Facility has been used to measure the time dependence of the angular reflectance from molecularly contaminated optical surfaces in the vacuum ultraviolet. The light scattering measurements are accomplished in situ on optical surfaces in real time during deposition of molecular contaminants. The measurements are taken using noncoherent VUV sources with the predominant wavelengths being the krypton resonance lines at 1236 and 1600 angstroms. Detection of the scattered light is accomplished using a set of three solar blind VUV photomultipliers. An in-plane VUV BRDF (bidirectional reflectance distribution function) experiment is described and details of the on-going program to characterize optical materials exposed to the space environment is reported.

Herren, Kenneth A.↗