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At least 1,009 records · Page 56

Apparatus for production, measurement and reaction studies of dissociated gases at elevated temperatures

An apparatus is described which is used for the controlled production, characterization, and study of dissociated gases in a microwave discharge at elevated temperatures. A unique feature is the ability to produce and study a microwave discharge plasma in the heated zone. This allows elevated temperature reactions to be studied in high concentrations of dissociated gases. Further, the system permits weight change measurements of specimens in the plasma, thus facilitating reaction rate determinations. Included is a description of a cavity for use on a 50-mm diameter cylindrical reactor. The effects of flow rate, pressure, temperature, power, metal sample, and sampling position on dissociation percentage of oxygen in the apparatus are described as well as a technique for sample temperature measurements in the plasma which permits determination of high temperature recombination coefficients and reaction rates.

Christian, J. D.↗

A similarity solution of the Navier-Stokes equations with wall catalysis and slip for hypersonic, low Reynolds number flow over spheres

The slip conditions for a multicomponent mixture with diffusion, wall-catalyzed atom recombination and thermal radiation are derived. The more realistic multicomponent species slip conditions are shown to be necessary for accurate merged shock layer solutions on a sphere. These slip conditions are used in a first-order similarity solution of the Navier-Stokes equations with nonequilibrium chemistry for the merged shock layer. Results of this quick numerical solution are compared with a time dependent solution around the sphere and with measured arc jet results at low Reynolds numbers. The similarity solution, unlike the time dependent solution, shows smooth radial profiles of the pressure and smooth variations of velocity slip, skin friction, temperature slip and heat transfer around the body. The present first-order similarity solution is valid up to 25 deg from the stagnation point and takes less than 1% of the computer time to run a time dependent scheme. The smaller stand-off distance obtained from the similarity solution is supported by experimental data. The measured heat flux is closer to the similarity solution than the time dependent method at the stagnation point and shows the proper variation with circumferential angle up to at least 40 deg.

Hendricks, W. L.↗

A theory of the Jovian hydrogen torus

The Jovian hydrogen torus associated with Io, that was observed by Judge and Carlson, has been found by them to be a third of a torus rather than a complete torus. It is shown that the energetic particles observed by Pioneer 10 do not ionize atomic hydrogen sufficiently fast to erode the torus as observed. It is proposed that the reason an incomplete torus exists is the presence of a corotating cold magnetospheric plasma. If this explanation is correct, the angular extent of the fractional torus is a measure of the density of the magnetospheric plasma near Io's orbit, which is found to be about 100 per cu cm. It is shown that such a plasma may provide an adequate input to Io, where it can recombine and escape, to form enough hydrogen atoms to explain the number of observed torus atoms. Thus the magnetospheric plasma may serve as both the source and the sink of the torus.

Mcdonough, T. R.↗

Laser processes in plasmadynamic flows

Radiation emitted from the exhaust flow of a multi-megawatt, quasi-steady magnetoplasmadynamic accelerator has been examined photoelectrically for argon mass flows from 6 to 32 g/sec and arc currents up to 25 kA. Vacuum ultraviolet radiation, indicative of resonance transitions, has been detected photoelectrically at various axial locations downstream of the arc chamber, consistent with a relaxation length calculated using a collisional-radiative recombination model. Photoelectric measurements of particular transitions in the neutral and first ionic state of argon show that populations of excited electronic states of AII are in excess of that which would be expected on the basis of Saha-Boltzmann equilibrium at the local electron temperature and number density. Optical depth measurements indicate that for a current of 4 kA and argon mass flow of 12 g/sec, a population inversion exists between the upper and lower states of the 0.4880 micron argon ion transition.

Campbell, E. M.↗

The chemistry of atmospheric bromine

Bromine may act as a catalyst for recombination of ozone and could be more efficient than either nitric oxide or chlorine. The lower atmosphere contains small concentrations of gaseous bromine produced in part by marine activity and volatilization of particulate material released during the combustion of leaded gasoline, with an additional contribution due to the use of methyl bromide as an agricultural fumigant. Observations by Lazrus et al., (1975) indicate small concentrations of bromine, about 10 to the -11th power (v/v), in the contemporary stratosphere and appear to imply a reduction of approximately 0.3% in the global budget of O3. Estimates are given for future reductions in O3 which might occur if the use of CH3Br as an agricultural fumigant were to continue to grow at present rates.

Wofsy, S. C.↗

On the ionization of the intercloud medium by runaway O-B stars

H II regions around seven high-velocity stars of type O5 to B1 (lambda Cep, xi Per, 68 Cyg, alpha Cam, AE Aur, zeta Oph, mu Col) are investigated assuming 'on-the-spot' reabsorption of the diffuse UV and time-dependent cooling and recombination behind the stars. Ratios of column densities integrated through the H II regions are obtained for stationary and moving stars, and the ionization structure is calculated for an H II region around a runaway star moving perpendicular to the galactic plane. The total volume ionized is found to be practically independent of the star's velocity. Global properties of the intercloud medium are examined; it is found that the presence of clouds may reduce the volume ionized by as much as a factor of 7 and that as much as 30% of the total ionizing radiation from early-type stars may leak out of the galaxy. Copernicus satellite observations are shown to be consistent with lines of sight crossing only the H II regions around the observed stars and a neutral intercloud medium as well as with the existence of a 'hole' in the distribution of O-B5 stars in the vicinity of the sun.

Thuan, T. X.↗

Diffusion length measurement using the scanning electron microscope

The present work describes a measuring technique employing the scanning electron microscope in which values of the true bulk diffusion length are obtained. It is shown that surface recombination effects can be eliminated through application of highly doped surface field layers. The effects of high injection level and low-high junction current generation are investigated. Results obtained with this technique are compared to those obtained by a penetrating radiation (X-ray) method, and a close agreement is found. The SEM technique is limited to cells that contain a back surface field layer.

Weizer, V. G.↗

The 1640.4 A H-alpha line of He II observed from Skylab

Profiles obtained from NRL Skylab solar spectra of the 1640.4 A feature identified as the H-alpha line of He II are discussed and compared with theoretical profiles derived assuming (1) collisional excitation and (2) radiative recombination as the dominant excitation mechanism. Relative intensities of this line as a function of altitude above and below the solar white-light limb are also given for a representative quiet sun region and for a polar coronal hole.

Feldman, U.↗

Wave propagation in a quasi-chemical equilibrium plasma

Wave propagation in a quasi-chemical equilibrium plasma is studied. The plasma is infinite and without external fields. The chemical reactions are assumed to result from the ionization and recombination processes. When the gas is near equilibrium, the dominant role describing the evolution of a reacting plasma is played by the global conservation equations. These equations are first derived and then used to study the small amplitude wave motion for a near-equilibrium situation. Nontrivial damping effects have been obtained by including the conduction current terms.

Fang, T.-M.↗

Energy conversion system

Scheme based on chemical decomposition and recombination converts energy collected at relatively low temperatures (300 C) to higher temperatures required for efficient operation of steam-driven electrical generators. Approach uses one or more cyclical reversible chemical reactions in which compound is made to decompose and absorb thermal energy at low temperature by shifting equilibrium.

Miller, C. G.↗

Studies of silicon PN junction solar cells

Silicon pn junction solar cells made with low-resistivity substrates show poorer performance than traditional theory predicts. The purpose of this research was to identify and characterize the physical mechanisms responsible for the discrepancy. Attention was concentrated on the open circuit voltage in shallow junction cells of 0.1 ohm-cm substrate resistivity. A number of possible mechanisms that can occur in silicon devices were considered. Two mechanisms which are likely to be of main importance in explaining the observed low values of open-circuit voltage were found: (1) recombination losses associated with defects introduced during junction formation, and (2) inhomogeneity of defects and impurities across the area of the cell. To explore these theoretical anticipations, various diode test structures were designed and fabricated and measurement configurations for characterizing the defect properties and the areal inhomogeneity were constructed.

Lindholm, F. A.↗

Pulsed electromagnetic gas acceleration

Terminal voltage measurements with various cathodes and anodes in a high power, quasi-steady magnetoplasmadynamic (MPD) are discussed. The magnitude of the current at the onset of voltage fluctuations is shown to be an increasing function of cathode area and a weaker decreasing function of anode area. Tests with a fluted cathode indicated that the fluctuations originate in the plasma adjacent to the cathode rather than at the cathode surface. Measurements of radiative output from an optical cavity aligned to examine the current-carrying portion of a two-dimensional, 56 kA magnetoplasmadynamic discharge reveal no lasing in that region, consistent with calculations of electron excitation and resonance radiation trapping. A voltage-swept double probe technique allows single-shot determination of electron temperature and electron number density in the recombining MPD exhaust flow. Current distributions within the cavity of MPD hollow cathodes for various static prefills with no injected mass flow are examined.

Jahn, R. G.↗

Statistical equilibrium calculations for silicon in early-type model stellar atmospheres

Line profiles of 36 multiplets of silicon (Si) II, III, and IV were computed for a grid of model atmospheres covering the range from 15,000 to 35,000 K in effective temperature and 2.5 to 4.5 in log (gravity). The computations involved simultaneous solution of the steady-state statistical equilibrium equations for the populations and of the equation of radiative transfer in the lines. The variables were linearized, and successive corrections were computed until a minimal accuracy of 1/1000 in the line intensities was reached. The common assumption of local thermodynamic equilibrium (LTE) was dropped. The model atmospheres used also were computed by non-LTE methods. Some effects that were incorporated into the calculations were the depression of the continuum by free electrons, hydrogen and ionized helium line blocking, and auto-ionization and dielectronic recombination, which later were found to be insignificant. Use of radiation damping and detailed electron (quadratic Stark) damping constants had small but significant effects on the strong resonance lines of Si III and IV. For weak and intermediate-strength lines, large differences with respect to LTE computations, the results of which are also presented, were found in line shapes and strengths. For the strong lines the differences are generally small, except for the models at the hot, low-gravity extreme of our range. These computations should be useful in the interpretation of the spectra of stars in the spectral range B0-B5, luminosity classes III, IV, and V.

Kamp, L. W.↗

Study of plasmasphere dynamics using incoherent scatter data from Chatanika, Alaska radar facility

Results of the study of Chatanika incoherent scatter radar data and Lockheed Palo Alto Research Laboratory satellite data are reported. Specific topics covered include: determination of the effective recombination coefficient in the auroral E region; determination of the location of the auroral oval; auroral boundary characteristics; and the relationship of auroral current systems, particle precipitation, visual aurora, and radar aurora.

Shelley, E. G.↗

Low latitude middle atmosphere ionization studies

Low latitude middle atmosphere ionization was studied with data obtained from three blunt conductivity probes and one Gerdien condenser. An investigation was conducted into the effects of various ionization sources in the 40 to 65 Km altitude range. An observed enhancement of positive ion conductivity taking place during the night can be explained by an atmsopheric effect, with cosmic rays being the only source of ionization only if the ion-ion recombination coefficient (alpha sub i) is small(10 to the -7 power cu cm/s) and varies greatly with altitude. More generally accepted values of alpha sub i ( approximately equal to 3x10 to the -7 power cu cm/s) require an additional source of ionization peaking at about 65 Km, and corresponding approximately to the integrated effect of an X-ray flux measured on a rocket flown in conjunction with the ionization measurements. The reasonable assumption of an alpha sub i which does not vary with altitude in the 50-70 Km range implies an even greater value alpha sub i and a more intense and harder X-ray spectrum.

Bassi, J. P.↗

The electron Boltzmann equation in a plasma generated by fission fragments

A Boltzmann equation formulation is presented for the determination of the electron distribution function in a plasma generated by fission fragments. The formulation takes into consideration ambipolar diffusion, elastic and inelastic collisions, recombination and ionization, and allows for the fact that the primary electrons are not monoenergetic. Calculations for He in a tube coated with fissionable material show that, over a wide pressure and neutron flux range, the distribution function is non-Maxwellian, but the electrons are essentially thermal. Moreover, about a third of the energy of the primary electrons is transferred into the inelastic levels of He. This fraction of energy transfer is almost independent of pressure and neutron flux but increases sharply in the presence of a sustainer electric field.

Hassan, H. A.↗

Radio observations of IC 434

Continuum radio emission and hydrogen recombination-line emission were measured at 2.37 GHz with the 64-m antenna at Goldstone, California. The radio emission has the same general distribution as the optical nebula. The radial velocity of the nebula agrees with that of the adjacent dust cloud L 1630. The electron temperature is estimated to be approximately 7000 K. The excitation of the nebula is compared with current estimates of the ionizing flux from the exciting star, sigma Orionis.

Kuiper, T. B. H.↗

Hydrogen chemistry - Perspective on experiment and theory

A review is presented of the advantages and limitations of various experimental methods for the investigation of the kinetics of hydrogen chemistry, including classic thermal and photochemical methods and the crossed molecular beam method. Special attention is given to the flash photolysis-resonance fluorescence apparatus developed by Braun et al, in which repetitive vacuum UV flashes result in the photolytic generation of the desired species, and to the discharge-flow technique. The use of various theoretical methods for the selection or elimination of kinetic data is considered in a brief discussion of the rate theory of two-body encounters and recombination-dissociation processes in neutral reactions. Recent kinetic studies of a series of OH reactions and of a major loss process for odd H in the stratosphere are summarized.

Kaufman, F.↗