Fast neutron reactivity effects for refractory metallic samples measured in a thermal homogeneous reactor
Fast neutron reactivity effects of reactor materials measured in thermal uranyl fluoride-water-solution reactor
Pierce, C. R.↗
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Results for “REACTIVITY”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Space radiation environmental effects on reactively encapsulated zinc orthotitanates and their paints
Space radiation environmental effects on reactively encapsulated zinc orthotitanates and paints
Ashford, N. A.↗
Comprehensive theory for ion cyclotron resonance power absorption - Application to line shapes for reactive and nonreactive ions
Ion cyclotron resonance power absorption theory application to reactive and nonreactive ions line shapes, using Wobschall-Graham-Malone phenomenological equation of motion
Comisarow, M. B.↗
A model for molecular flow of reactive species through cylindrical reactors
Analytical model for molecular flow of reactive gaseous species through cylindrical reactors with apertures at either end, evaluating surviving flux magnitude
Baker, B. R.↗
Impulsive model for reactive collisions
A simple classical mechanical model of the reactive scattering of a structureless atom A and a quasi-diatomic BC is developed which takes full advantage of energy, linear and angular momentum conservation relations but introduces a minimum of further assumptions. These are as follows: (1) the vibrational degree of freedom of the reactant (BC) and product (AB) molecules is suppressed, so the change in vibrational energy is simply a parameter; (2) straight-line trajectories are assumed outside of a reaction shell; (3) within this zone, momentum transfer occurs impulsively (essentially instantaneously) following mass transfer; (4) the impulse, which may be either positive or negative, is directed along the BC axis, which may, however, assume all orientations with respect to the incident relative velocity. The model yields differential and total cross sections and product rotational energy distributions for a given collision exoergicity Q, or for any known distribution over Q. Numerical results are presented for several prototype reactions whose dynamics have been well-studied.
Marron, M. T.↗
Entropy and chemical change. 1: Characterization of product (and reactant) energy distributions in reactive molecular collisions: Information and enthropy deficiency
Optimal means of characterizing the distribution of product energy states resulting from reactive collisions of molecules with restricted distributions of initial states are considered, along with those for characterizing the particular reactant state distribution which yields a given set of product states at a specified total energy. It is suggested to represent the energy-dependence of global-type results in the form of square-faced bar plots, and of data for specific-type experiments as triangular-faced prismatic plots. The essential parameters defining the internal state distribution are isolated, and the information content of such a distribution is put on a quantitative basis. The relationship between the information content, the surprisal, and the entropy of the continuous distribution is established. The concept of an entropy deficiency, which characterizes the specificity of product state formation, is suggested as a useful measure of the deviance from statistical behavior. The degradation of information by experimental averaging is considered, leading to bounds on the entropy deficiency.
Bernstein, R. B.↗
Chemical reactivity of hydrogen, nitrogen, and oxygen atoms at temperatures below 100 k
The synthesis of unusual compounds by techniques employing cryogenic cooling to retard their very extreme reactivity was investigated. Examples of such species that were studied are diimide (N2H2), cyclobutadiene (C4H4), cyclopropanone (C3H4O), oxirene (C2H2O), and many others. Special purpose cryogenically cooled inlet arrangements were designed such that the analyses incurred no warm-up of the cold, and frequently explosively unstable, compounds. Controlled energy electron impact techniques were used to measure critical potentials and to develop the molecular energetics and thermodynamics of these molecules and to gain some insight into their kinetic characteristics as well. Three and four carbon strained ring molecules were studied. Several reactions of oxygen and hydrogen atoms with simple molecules of H, N, C, and O in hard quench configurations were studied. And the quench stabilization of BH3 was explored as a model system in cryochemistry.
Mcgee, H. A., Jr.↗
Reactivity change in a fast-spectrum space power reactor due to a 328-meter-per-second (1075-ft/sec) impact
Application of nuclear reactors in space will present operational problems. One such problem is the possibility of an earth impact at velocities in excess of 305 m/sec (1000 ft/sec). This report shows the results of an impact against concrete at 328 m/sec (1075 ft/sec) and examines the deformed core to estimate the range of activity inserted as a result of the impact. The results of this examination are that the deformation of the reactor core within the containment vessel left only an estimated 2.7 percent void in the core and that the reactivity inserted due to this impact deformation could be from 4.0 to 10.25 dollars.
Peoples, J. A., Jr.↗
Effects of the space flight environment on man's immune system. II - Lymphocyte counts and reactivity.
The present studies were undertaken to assess the effects of the environment of space flights on the cellular division of the human immune system. Peripheral blood absolute lymphocyte counts were determined at various preflight and postflight intervals for the 21 crewmen of Apollo Missions 7-13. Mean lymphocyte numbers tended to exhibit a delayed significant but fluctuating increase shortly after recovery, although a variety of responses was seen in individual astronauts. The in vitro reactivity of lymphocytes, reflected by RNA and DNA synthesis rates by unstimulated and PHA-stimulated lymphocytes tissue-cultured preflight and postflight from the same participants, was found to remain within previously established normal ranges. These results indicate that functional integrity of cellular immune potential as reflected by in vitro techniques is maintained during this spaceflight experience.
Fischer, G. L.↗
Theoretical study of reactive and nonreactive turbulent coaxial jets
The hydrodynamic properties and the reaction kinetics of axisymmetric coaxial turbulent jets having steady mean quantities are investigated. From the analysis, limited to free turbulent boundary layer mixing of such jets, it is found that the two-equation model of turbulence is adequate for most nonreactive flows. For the reactive flows, where an allowance must be made for second order correlations of concentration fluctuations in the finite rate chemistry for initially inhomogeneous mixture, an equation similar to the concentration fluctuation equation of a related model is suggested. For diffusion limited reactions, the eddy breakup model based on concentration fluctuations is found satisfactory and simple to use. The theoretical results obtained from these various models are compared with some of the available experimental data.
Gupta, R. N.↗
The design of reactive shielded magnet clutches
The design of reactive shielded magnet clutches is considered along with their schematics, design formulas and characteristics of clutches in general. The design method suggested makes it possible to reduce calculation errors to 10%.
Gertsov, S. M.↗
Semiclassical dynamics on multiple electronic surfaces - Three-dimensional treatment of reactive F + H2
The role of electron transitions in collisions is studied for the F + H2 reaction by combining quasi-classical Monte Carlo trajectories with a semiclassical decoupling approximation for the electron transitions. Attention is directed at the reaction of excited state F atoms reacting to form ground state products; the reactants are initiated in either of two spin-orbit states of the atom with the diatom in the ground vibrational state and the lowest four rotational states, at relative translational energies of 0.1, 0.2 and 0.3 eV. Even if the reactants are initiated on the excited state surface, the reactive cross sections (which are classically forbidden) are significant. The major dynamical effects of the excited state reaction are the flow of reactant electronic energy into product internal energy.
Komornicki, A.↗
Evaluation of the effect of elastic joints on the auto-oscillation of spacecraft with gas-reactive direction systems
A mathematical model was obtained, on the basis of the method of mixed coordinates, of a generalized flexible spacecraft at one end of which was appended the directive action of a system of gas reactive nozzles. Various structural forms were obtained functionally describing flexible spacecraft, as systems consisting of a solid central body with flexible structural elements joined to it.
Sasin, G. G.↗
Semiclassical study of reactive scattering in a laser field - F + H2 + barred-h times omega times /1.06 microns/ system
Semiclassical calculations of collinear F+H2(nu = 0) reactive and inelastic scattering in an Nd-glass laser field of various intensities are described. The decoupling approximation developed for the Miller-George theory is used for nonadiabatic transitions between the electronic-field surfaces, and special attention is paid to the choice of a proper coordinate system for applying the decoupling approximation. An increase in the total reaction probability and population ratio of the nu = 3 over nu = 2 vibrational state of HF occurs suddenly as the field intensity increases beyond 10 TW/sq cm. It is found that in a laser field the H2 molecule can be vibrationally excited while the F atom is electronically excited.
Yuan, J.-M.↗
Photographic observation of reactive stream impingement
The theoretical and experimental study described was carried out to gain insight into the physical-chemical mechanism which controls hypergolic propellant reactive stream separation (RSS), with a view toward establishing design criteria. The approach employed was to observe photographically single element injector combustion of N2O4/MMH, N2O4/A-50, and N2O4/N2H4 propellants. Single element injectors were used to provide an unobstructed view of the impingement zone. Hot firings were conducted in a special photographic chamber. High-speed color motion pictures were used to identify the occurrence of RSS. Four conventional unlike doublet injectors, two conventional triplet injectors, and three platelet injectors were used in the tests. A simulation of the Space Shuttle platelet injector was included. The most important design criterion derived from the study states that the element should be designed to avoid transitions between mixed and separated modes within the engine operational envelope.
Lawver, B. R.↗
Reactively evaporated films of copper molybdenum sulfide
Films of superconducting Chevrel-phase copper molybdenum sulfide CuxMo6S8 were deposited on sapphire substrates by reactive evaporation using H2S as the reacting gas. Two superconducting temperatures (10.0 K and 5.0 K) of the films were found, corresponding to two different phases with different copper concentrations. All films were superconducting above 4.2 K and contained Chevrel-phase compound as well as free molybdenum. The critical current was measured as a function of applied field. One sample was found to deviate from the scaling law found for co-evaporated or sputtered samples, which possibly indicates a different pinning mechanism or inhomogeneity of the sample.
Chi, K. C.↗
Skylab reactivation mission report
On July 11, 1979, Skylab impacted the Earth's surface. The debris dispersion area stretched from the South Eastern Indian Ocean across a sparsely populated section of Western Australia. The events leading to the reentry of Skylab are discussed and a final assessment of the Skylab debris impact footprint is presented. Also included are detailed evaluations of the various Skylab systems that were reactivated when control of Skylab was regained in mid-1978 after having been powered down since February 4, 1974.
Chubb, W. B.↗
Reactivity of organism in prolonged space flights
An analysis of published data are presented as well as the results of experiments which show that the state of weightlessness and hypodynamia result in a reduced orthostatic and vestibular resistance, increased sensitivity to infections, decreased endurance of accelerations and physical exercises, and altered reactivity of the organism to drugs. Various consequences of weightlessness on the human body, especially weightlessness combined with other factors linked to long space flights are also considered.
Vasilyev, P. V.↗