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At least 1,009 records · Page 56

Materials Data on K3(PtO2)2 by Materials Project

K3(PtO2)2 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. there are two inequivalent K sites. In the first K site, K is bonded in a 6-coordinate geometry to six equivalent O atoms. There are a spread of K–O bond distances ranging from 2.86–2.91 Å. In the second K site, K is bonded in a 4-coordinate geometry to four equivalent O atoms. All K–O bond lengths are 2.69 Å. There are two inequivalent Pt sites. In the first Pt site, Pt is bonded in a distorted square co-planar geometry to four equivalent O atoms. All Pt–O bond lengths are 2.02 Å. In the second Pt site, Pt is bonded in a distorted square co-planar geometry to four equivalent O atoms. All Pt–O bond lengths are 2.04 Å. O is bonded to four K and two Pt atoms to form a mixture of distorted face, edge, and corner-sharing OK4Pt2 octahedra. The corner-sharing octahedra tilt angles range from 0–70°.

36 MATERIALS SCIENCE↗

Materials Data on KRbS by Materials Project

RbKS crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Rb1+ is bonded in a 5-coordinate geometry to five equivalent S2- atoms. There are a spread of Rb–S bond distances ranging from 3.39–3.72 Å. K1+ is bonded to four equivalent S2- atoms to form a mixture of corner and edge-sharing KS4 tetrahedra. There are a spread of K–S bond distances ranging from 3.17–3.22 Å. S2- is bonded in a 9-coordinate geometry to five equivalent Rb1+ and four equivalent K1+ atoms.

36 MATERIALS SCIENCE↗

Materials Data on K3(PdO2)2 by Materials Project

K3Pd2O4 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. there are two inequivalent K sites. In the first K site, K is bonded in a 6-coordinate geometry to six equivalent O atoms. There are a spread of K–O bond distances ranging from 2.83–2.92 Å. In the second K site, K is bonded in a 4-coordinate geometry to four equivalent O atoms. All K–O bond lengths are 2.67 Å. There are two inequivalent Pd sites. In the first Pd site, Pd is bonded in a distorted square co-planar geometry to four equivalent O atoms. All Pd–O bond lengths are 2.04 Å. In the second Pd site, Pd is bonded in a square co-planar geometry to four equivalent O atoms. All Pd–O bond lengths are 2.02 Å. O is bonded to four K and two Pd atoms to form a mixture of distorted corner, edge, and face-sharing OK4Pd2 octahedra. The corner-sharing octahedra tilt angles range from 0–71°.

36 MATERIALS SCIENCE↗

Materials Data on K4Hg3Ge20 by Materials Project

K4Hg3Ge20 crystallizes in the cubic Pm-3n space group. The structure is three-dimensional. there are two inequivalent K sites. In the first K site, K is bonded in a 12-coordinate geometry to four equivalent Hg and eight equivalent Ge atoms. All K–Hg bond lengths are 3.93 Å. All K–Ge bond lengths are 3.76 Å. In the second K site, K is bonded in a 8-coordinate geometry to twenty Ge atoms. There are eight shorter (3.52 Å) and twelve longer (3.58 Å) K–Ge bond lengths. Hg is bonded to four equivalent K and four equivalent Ge atoms to form a mixture of distorted edge and corner-sharing HgK4Ge4 tetrahedra. All Hg–Ge bond lengths are 2.68 Å. There are two inequivalent Ge sites. In the first Ge site, Ge is bonded in a 5-coordinate geometry to one K and four Ge atoms. There are three shorter (2.54 Å) and one longer (2.58 Å) Ge–Ge bond lengths. In the second Ge site, Ge is bonded in a 7-coordinate geometry to three K, one Hg, and three Ge atoms. The Ge–Ge bond length is 2.52 Å.

36 MATERIALS SCIENCE↗

Asymptotic Expansion of the Impedance Per Unit Length for Rectangular Conductors

An iteration method is introduced to obtain the asymptotic form of the impedance per unit length of a rectangular conductor when the half side lengths are large compared to the skin depth. The first terms of the asymptotic expansion are extracted in closed form. The manner in which the corner corrections fit into the expansion are illustrated. The asymptotic results are compared to a numerical solution in the square limit. The odd corner correction for a right angle edge is also discussed.

42 ENGINEERING↗

The role of jet stability in edgetone generation.

Consideration of the role of stability of the mean jet flow of an edgetone system in the edgetone operation. A brief description of the main features of the edgetone operation and a brief review of the pertinent background are presented. This is followed by a discussion of the inadequacy of parallel flow stability considerations in explaining edgetone features. An analysis is made of the stability characteristics of a slightly nonparallel jet flow, and the role of jet stability based on these considerations in the edgetone operation is discussed. It is shown that the characteristics obtained by considering the nonparallel nature of the jet flowfield lead to a satisfactory description of the phenomenon, including a frequency selection criterion based on the concept of the most amplified disturbance frequency at each edge position.

Woolley, J. P.↗

Trailing edge noise

Shadowgraphic observations of the flow structure of a wall jet downstream of the trailing edge of a flat plate were carried out. Shadowgraphs obtained at jet exit Mach number 0.3 to 0.8 consistently showed an orderly large oscillatory flow structure. It is believed that these large scale disturbances are the result of flow instabilities. It is also believed that these orderly disturbances are responsible for generating the dominant part of trailing edge noise either directly or indirectly. The interaction of sound generated by these coherent oscillatory flow disturbances and the plate was investigated theoretically. It is found that the farfield noise directivity is strongly influenced by diffraction of sound at the leading edge of the plate.

Tam, C. K. W.↗

An experimental investigation of the trailing edge noise mechanism

An experimental investigation has been conducted to understand the physical mechanism of noise generation from a turbulent wall jet discharging over a flat plate and interacting with its sharp trailing edge. An aspect ratio 10 rectangular nozzle was used to provide the wall jet. Measurements made consist of farfield noise, surface pressure fluctuations, turbulent velocity fluctuations, and two-point space-time cross-correlations among these quantities. Results are presented which suggest strongly that the generation mechanism is the interaction of the convecting large scale quasi-orderly disturbance in the upper free shear layer of the wall jet with the trailing edge. The interaction also excites large scale strong vortical motion in the trailing edge wake. The dominant part of the sound field is highly coherent and in phase opposition across the trailing edge.

Yu, J. C.↗

Low-speed aerodynamic characteristics of a 42 deg swept high-wing model having a double-slotted flap system and a supercritical airfoil

A low-speed investigation was conducted over an angle-of-attack range from about -4 deg to 20 deg in the Langley V/STOL tunnel to determine the effects of a double-slotted flap, high-lift system on the aerodynamic characteristics of a 42 deg swept high-wing model having a supercritical airfoil. The wing had an aspect ratio of 6.78 and a taper ratio of 0.36; the double-slotted flap consisted of a 35-percent-chord flap with a 15-percent-chord vane. The model was tested with a 15-percent-chord leading-edge slat.

Fournier, P. G.↗

Measuring Recombination Velocities in Solar Cells

Electron-beam scanning method suggested for determining back-surface recombination velocity, SB, of back-surface-field (BSF) solar photovoltaic cell. Recombination velocity important because smaller value correlated with smaller saturation current and therefore higher cell efficiency. Method involves analyzing short-circuit current measured while electron beam scanned along edge of cell.

Vonroos, O.↗

Space environmental effects on silvered Teflon thermal control surfaces

Cumulative space environment effects on Ag/fluorinated ethylene propylene (FEP) were a function of exposure orientation. Samples from nineteen silvered Teflon (Ag/FEP) thermal control surfaces recovered from the Long Duration Exposure Facility (LDEF) were analyzed to determine changes in this material as a function of position on the spacecraft. Although solar absorptance and infrared emittance of measured thermal blanket specimens are relatively unchanged from control specimen values, significant changes in surface morphology, composition and chemistry were observed. Researchers hypothesize that the FEP surfaces on LDEF were degraded by ultraviolet radiation exposure at all orientations, but that the damaged material had been removed by erosion from the blankets exposed to atomic oxygen flux and that contamination is masking the damage on trays flanking the trailing edge.

Hemminger, C. S.↗

Space environmental effects on silvered Teflon thermal control surfaces

Cumulative space environmental effects on silver/fluorinated ethylene propylene (Ag/FEP) were a function of exposure orientation. Samples from nineteen silvered Teflon (Ag/FEP) thermal control surfaces recovered from the Long Duration Exposure Facility (LDEF) were analyzed to determine changes in this material as a function of position on the spacecraft. Although solar absorptance and infrared emittance of measured thermal blanket specimens are relatively unchanged from control specimen values, significant changes in surface morphology, composition, and chemistry were observed. We hypothesize that the FEP surfaces on the LDEF are degraded by UV radiation at all orientations, but that the damaged material has been removed by erosion from the blankets exposed to atomic oxygen flux and that contamination is masking the damage in some areas on the trays flanking the trailing edge.

Hemminger, C. S.↗

Effects of inclination angle on the spectra of X-ray binaries

Iron emission and absorption features from nine X-ray binaries are compared with a model that predicts characteristics of iron K-shell features corresponding to different viewing angles for the accretion disk. In this model, emission and absorption features arise from an accretion disk corona whose structure is computed under the assumptions of ionization, thermal, and hydrostatic balance of gas illuminated by the central continuum source. Hence the equivalent widths of the emission and absorption features are predicted without the introduction of any free parameters to control the physical conditions in the disk corona. Our data/model comparison suggests an explanation for the equivalent widths of the iron K-alpha emission and the depth of the absorption edge in terms of (1) the angle of inclination between the observer's line of sight and the plane of the accretion disk and (2) the shape of the incident source spectrum.

Vrtilek, S. D.↗

Broad-Band X-Ray Telescope spectroscopy of Xi Puppis

The Broad-Band X-Ray Telescope obtained moderate-resolution (about 90 eV) X-ray spectra of the O4 f star Xi Pup during the STS 35/Astro 1 mission in 1990 December. Despite the shortness of the observation (600 s), the data show a surprising amount of detail. We report the detection of an O absorption edge produced by ionized overlying wind material and K-shell line emission from Mg produced by a thermal plasma of temperature near 6 x 10 exp 6 K. The data are used to place constraints on the location, temperature, and amount of the X-ray-emitting gas, as well as the abundance and ionization of the wind material.

Corcoran, M. F.↗

Solutions of the benchmark problems by the dispersion-relation-preserving scheme

The 7-point stencil Dispersion-Relation-Preserving scheme of Tam and Webb is used to solve all the six categories of the CAA benchmark problems. The purpose is to show that the scheme is capable of solving linear, as well as nonlinear aeroacoustics problems accurately. Nonlinearities, inevitably, lead to the generation of spurious short wave length numerical waves. Often, these spurious waves would overwhelm the entire numerical solution. In this work, the spurious waves are removed by the addition of artificial selective damping terms to the discretized equations. Category 3 problems are for testing radiation and outflow boundary conditions. In solving these problems, the radiation and outflow boundary conditions of Tam and Webb are used. These conditions are derived from the asymptotic solutions of the linearized Euler equations. Category 4 problems involved solid walls. Here, the wall boundary conditions for high-order schemes of Tam and Dong are employed. These conditions require the use of one ghost value per boundary point per physical boundary condition. In the second problem of this category, the governing equations, when written in cylindrical coordinates, are singular along the axis of the radial coordinate. The proper boundary conditions at the axis are derived by applying the limiting process of r approaches 0 to the governing equations. The Category 5 problem deals with the numerical noise issue. In the present approach, the time-independent mean flow solution is computed first. Once the residual drops to the machine noise level, the incident sound wave is turned on gradually. The solution is marched in time until a time-periodic state is reached. No exact solution is known for the Category 6 problem. Because of this, the problem is formulated in two totally different ways, first as a scattering problem then as a direct simulation problem. There is good agreement between the two numerical solutions. This offers confidence in the computed results. Both formulations are solved as initial value problems. As such, no Kutta condition is required at the trailing edge of the airfoil.

Tam, Christopher K. W.↗

Observations of a transverse magnetic field perturbation at two altitudes on the equatorward edge of the magnetospheric cusp

On January 28, 1990, the Dynamic Explorer 1 (DE-1) and Akebono satellites crossed a magnetic field structure at the equatorward edge of the polar cusp at altitudes od 22,000 and 5000 km, respectively, within 6 min of each other. Locally measured plasma particles and fields and magnetometer data from a ground station near the foot of the magnetic field line are more consistent with an interpretation of the structure as that of a standing Alfven wave than that of a quasi-steady field-aligned current sheet. We discuss the observations supporting this conclusion and other related observations of field-aligned currents, Alfven waves, and ion energization near the equatorward edge of the cusp. These observations suggest that Alfven waves are commonly present near the equatorward edge of the cusp.

Peterson, W. K.↗

ATMOS/ATLAS-3 Measurements of Stratospheric Chlorine and Reactive Nitrogen Partitioning Inside and Outside the November 1994 Antarctic Vortex

Partitioning between HCl and ClONO2 and among the main components of the reactive nitrogen family (NO, NO2, HNO3, ClONO2, N2O5, and HO2NO2) has been studied inside and outside the Antarctic stratospheric vortex based on ATMOS profiles measured at sunrise during the 3-12 November 1994 ATLAS-3 Shuttle mission. Elevated mixing ratios of HCl in the lower stratosphere with a peak of approximately 2.9 ppbv (10(exp -9) parts per volume) were measured inside the vortex near 500 K potential temperature (approximately 19 km). Maximum ClONO2 mixing ratios of approximately 1.2, approximately 1.4, and approximately 0.9 ppbv near 700 K (approximately 25 km) were measured inside, at the edge, and outside the vortex, respectively. Model calculations reproduce the higher levels of HCl and NO(x) (NO + NO2) inside the lower stratospheric vortex both driven by photochemical processes initiated by low O3. The high HCl at low O3 results from chemical production of HC1 via the reaction of enhanced Cl with CH4, limited production of ClONO2, and the descent of inorganic chlorine from higher altitudes.

Rinsland, C. P.↗

Observed and Modeled Trends in Southern Ocean Sea Ice

Conceptual models and global climate model (GCM) simulations have both indicated the likelihood of an enhanced sensitivity to climate change in the polar regions, derived from the positive feedbacks brought about by the polar abundance of snow and ice surfaces. Some models further indicate that the changes in the polar regions can have a significant impact globally. For instance, 37% of the temperature sensitivity to a doubling of atmospheric CO2 in simulations with the GCM of the Goddard Institute for Space Studies (GISS) is attributable exclusively to inclusion of sea ice variations in the model calculations. Both sea ice thickness and sea ice extent decrease markedly in the doubled CO, case, thereby allowing the ice feedbacks to occur. Stand-alone sea ice models have shown Southern Ocean hemispherically averaged winter ice-edge retreats of 1.4 deg latitude for each 1 K increase in atmospheric temperatures. Observations, however, show a much more varied Southern Ocean ice cover, both spatially and temporally, than many of the modeled expectations. In fact, the satellite passive-microwave record of Southern Ocean sea ice since late 1978 has revealed overall increases rather than decreases in ice extents, with ice extent trends on the order of 11,000 sq km/year. When broken down spatially, the positive trends are strongest in the Ross Sea, while the trends are negative in the Bellingshausen/Amundsen Seas. Greater spatial detail can be obtained by examining trends in the length of the sea ice season, and those trends show a coherent picture of shortening sea ice seasons throughout almost the entire Bellingshausen and Amundsen Seas to the west of the Antarctic Peninsula and in the far western Weddell Sea immediately to the east of the Peninsula, with lengthening sea ice seasons around much of the rest of the continent. This pattern corresponds well with the spatial pattern of temperature trends, as the Peninsula region is the one region in the Antarctic with a strong record of temperature increases. Still, although the patterns of the temperature and ice changes match fairly well, there is a substantial ways to go before these patterns are understood (and can be modeled) in the full context of global change.

Parkinson, Claire L.↗