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At least 1,009 records · Page 56

An In Situ , Automated High-Explosives Aging Method Utilizing Two-Dimensional Gas Chromatography–Mass Spectrometry

Understanding chemical changes that occur in high explosives as they age is of great importance to the safe employment and storage of these compounds. Traditional methods of aging high explosives even under accelerated aging conditions are time intensive with durations on the order of months to years. The nature of traditional aging analyses reduces each sample to a snapshot data point often separated widely in time, requiring many assumptions as to how the degradation products develop. Further complicating matters, several analytical techniques are typically employed for each sample analysis in order to ascertain an entire picture of the decomposition pathways. To address these shortcomings with existing methods, a new method of accelerated aging of high explosives utilizing comprehensive two-dimensional gas chromatography coupled to high-resolution mass spectrometry (GC × GC-HRMS) was developed using 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) as a model compound for method development. This in situ automated method reduces the time scale of aging to a matter of hours using the inlet of the GC × GC as the aging vessel. GC × GC in combination with HRMS allowed for the collection of both evolved gases and other decomposition products produced during the entire aging process in real time with HRMS providing far greater certainty in identification of explosives aging products. Additionally, this method allowed for a higher throughput of samples with greatly simplified sample preparation. Chemometric analysis of the GC × GC-HRMS data set via the alteration analysis (ALA) enabled discovery of statistically significant chemical changes providing insight into the variation of decomposition pathways with varying aging temperatures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Dynamical Downscaling of Earth System Model Data for Energy System Analysis

Assessing energy resources (e.g., solar, wind, and hydro) under future scenarios requires datasets with sufficient spatial and temporal detail to capture variability and extreme events. While global-scale Earth System Model (ESM) projections are widely used, their coarse resolution limits direct application to regional energy system analyses. Dynamical downscaling offers a robust approach to generate physically consistent, fine-scale datasets that better represent local atmospheric processes impacting energy resources. In this work, we present a two-stage approach for producing high-resolution historical and future projections over the contiguous United States (CONUS). First, we optimize the Weather Research and Forecasting (WRF) model configuration for energy-relevant variables - solar irradiance, wind speed, and precipitation - by conducting ERA5-driven simulations at 8-km and 28-km resolution. Multiple physics schemes and model configurations within the WRF are evaluated against observational datasets including the National Solar Radiation Database (NSRDB), the Parameter-elevation Regressions on Independent Slopes Model (PRISM), and the Stage IV multi-radar/multi-sensor precipitation product for the CONUS domain. Using the best-performing configuration, we dynamically downscale MPI-ESM1-2-HR simulations for 2000-2060 under SSP2-4.5 and SSP5-8.5 scenarios at 4-km spatial and hourly temporal resolution. This presentation will provide a comprehensive analysis of the results from multiple numerical experiments and high-resolution ESM projections. In addition, we will discuss potential applications of our high-resolution datasets within the energy sector and outline future research avenues dedicated to evaluating how extreme weather events influence system performance and resilience.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Satellite-derived cyanobacteria frequency and magnitude in headwaters & near-dam reservoir surface waters of the Southern U.S.

Reservoirs are dominant features of the modern hydrologic landscape and provide vital services. However, the unique morphology of reservoirs can create suitable conditions for excessive algae growth and associated cyanobacteria blooms in shallow in-flow reservoir locations by providing warm water environments with relatively high nutrient inputs, deposition, and nutrient storage. Cyanobacteria harmful algal blooms (cyanoHAB) are costly water management issues and bloom recurrence is associated with economic costs and negative impacts to human, animal, and environmental health. As cyanoHAB occurrence varies substantially within different regions of a water body, understanding in-lake cyanoHAB spatial dynamics is essential to guide reservoir monitoring and mitigate potential public exposure to cyanotoxins. Cloud-based computational processing power and high temporal frequency of satellites enables advanced pixel-based spatial analysis of cyanoHAB frequency and quantitative assessment of reservoir headwater in-flows compared to near-dam surface waters of individual reservoirs. Additionally, extensive spatial coverage of satellite imagery allows for evaluation of spatial trends across many dozens of reservoir sites. Surface water cyanobacteria concentrations for sixty reservoirs in the southern U.S. were estimated using 300m resolution European Space Agency (ESA) Ocean and Land Colour Instrument (OLCI) satellite sensor for a five year period (May 2016–April 2021). Of the reservoirs studied, spatial analysis of OLCI data revealed 98% had more frequent cyanoHAB occurrence above the concentration of >100,000 cells/mL in headwaters compared to near-dam surface waters (P < 0.001). Headwaters exhibited greater seasonal variability with more frequent and higher magnitude cyanoHABs occurring mid-summer to fall. Examination of reservoirs identified extremely high concentration cyanobacteria events (>1,000,000 cells/mL) occurring in 70% of headwater locations while only 30% of near-dam locations exceeded this threshold. Wilcoxon signed-rank tests of cyanoHAB magnitudes using paired-observations (dates with observations in both a reservoir's headwater and near-dam locations) confirmed significantly higher concentrations in headwater versus near-dam locations (p < 0.001).

cyanobacteria↗

Revisiting MOA 2013-BLG-220L: A Solar-type Star with a Cold Super-Jupiter Companion

We present the analysis of high-resolution images of MOA-2013-BLG-220, taken with the Keck adaptive optics system six years after the initial observation, identifying the lens as a solar-type star hosting a super-Jupiter-mass planet. The masses of planets and host stars discovered by microlensing are often not determined from light-curve data, while the star–planet mass ratio and projected separation in units of Einstein ring radius are well measured. High-resolution follow-up observations after the lensing event is complete can resolve the source and lens. This allows direct measurements of flux, and the amplitude and direction of proper motion, giving strong constraints on the system parameters. Due to the high relative proper motion, μ{sub rel,Geo}=12.62±0.11 mas yr{sup −1}, the source and lens were resolved in 2019, with a separation of 77.1 ± 0.5 mas. Thus, we constrain the lens flux to K{sub Keck,lens}=17.92±0.02. By combining constraints from the model and Keck flux, we find the lens mass to be M{sub L}=0.88±0.05 M{sub ⊙} at D{sub L}=6.72±0.59 kpc. With a mass ratio of q=(3.00±0.03)×10{sup −3} the planet’s mass is determined to be M{sub P}=2.74±0.17 M{sub J} at a separation of r{sub ⊥}=3.03±0.27 au. The lens mass is much higher than the prediction made by Bayesian analysis that assumes all stars have an equal probability to host a planet of the measured mass ratio, and suggests that planets with mass ratios of a few times 10{sup −3} are more common orbiting massive stars. This demonstrates the importance of high-resolution follow-up observations for testing theories like these.

79 ASTRONOMY AND ASTROPHYSICS↗

Satellite-derived Cyanobacteria Frequency and Magnitude in Headwaters & Near-dam Reservoir Surface Waters of the Southern U.S.

Reservoirs are dominant features of the modern hydrologic landscape and provide vital services. However, the unique morphology of reservoirs can create suitable conditions for excessive algae growth and associated cyanobacteria blooms in shallow in-flow reservoir locations by providing warm water environments with relatively high nutrient inputs, deposition, and nutrient storage. Cyanobacteria harmful algal blooms (cyanoHAB) are costly water management issues and bloom recurrence is associated with economic costs and negative impacts to human, animal, and environmental health. As cyanoHAB occurrence varies substantially within different regions of a water body, understanding in-lake cyanoHAB spatial dynamics is essential to guide reservoir monitoring and mitigate potential public exposure to cyanotoxins. Cloud-based computational processing power and high temporal frequency of satellites enables advanced pixel-based spatial analysis of cyanoHAB frequency and quantitative assessment of reservoir headwater in-flows compared to near-dam surface waters of individual reservoirs. Additionally, extensive spatial coverage of satellite imagery allows for evaluation of spatial trends across many dozens of reservoir sites. Surface water cyanobacteria concentrations for sixty reservoirs in the southern U.S. were estimated using 300 m resolution European Space Agency (ESA) Ocean and Land Colour Instrument (OLCI) satellite sensor for a five year period (May 2016–April 2021). Of the reservoirs studied, spatial analysis of OLCI data revealed 98% had more frequent cyanoHAB occurrence above the concentration of >100,000 cells/mL in headwaters compared to near-dam surface waters (P < 0.001). Headwaters exhibited greater seasonal variability with more frequent and higher magnitude cyanoHABs occurring mid-summer to fall. Examination of reservoirs identified extremely high concentration cyanobacteria events (>1,000,000 cells/mL) occurring in 70% of headwater locations while only 30% of near-dam locations exceeded this threshold. Wilcoxon signed-rank tests of cyanoHAB magnitudes using paired-observations (dates with observations in both a reservoir's headwater and near-dam locations) confirmed significantly higher concentrations in headwater versus near-dam locations (p < 0.001).

Amber R Ignatius↗

Remote-Sensing Time Series Analysis, a Vegetation Monitoring Tool

The Time Series Product Tool (TSPT) is software, developed in MATLAB , which creates and displays high signal-to- noise Vegetation Indices imagery and other higher-level products derived from remotely sensed data. This tool enables automated, rapid, large-scale regional surveillance of crops, forests, and other vegetation. TSPT temporally processes high-revisit-rate satellite imagery produced by the Moderate Resolution Imaging Spectroradiometer (MODIS) and by other remote-sensing systems. Although MODIS imagery is acquired daily, cloudiness and other sources of noise can greatly reduce the effective temporal resolution. To improve cloud statistics, the TSPT combines MODIS data from multiple satellites (Aqua and Terra). The TSPT produces MODIS products as single time-frame and multitemporal change images, as time-series plots at a selected location, or as temporally processed image videos. Using the TSPT program, MODIS metadata is used to remove and/or correct bad and suspect data. Bad pixel removal, multiple satellite data fusion, and temporal processing techniques create high-quality plots and animated image video sequences that depict changes in vegetation greenness. This tool provides several temporal processing options not found in other comparable imaging software tools. Because the framework to generate and use other algorithms is established, small modifications to this tool will enable the use of a large range of remotely sensed data types. An effective remote-sensing crop monitoring system must be able to detect subtle changes in plant health in the earliest stages, before the effects of a disease outbreak or other adverse environmental conditions can become widespread and devastating. The integration of the time series analysis tool with ground-based information, soil types, crop types, meteorological data, and crop growth models in a Geographic Information System, could provide the foundation for a large-area crop-surveillance system that could identify a variety of plant phenomena and improve monitoring capabilities.

McKellip, Rodney↗

Estimating snow depth using VHRR data from NOAA environmental satellites

The NOAA environmental satellites provide daily coverage of the earth in the visible and thermal spectral bands. The ground resolution of the very high resolution radiometer is 1 km at nadir. This improved resolution in the visible permits more detailed observations of snow features than was possible with previous operational satellites. A densitometer examination of a visible-band image from Feb. 11, 1973, which shows heavy snow cover in considerable detail over areas extending from Alabama to North Carolina, indicates that, in general, there is direct correlation between increasing brightness and increasing snow depths. A power regression analysis of greatest satellite brightness versus greatest snow depth for 201 data pairs produced a correlation coefficient of 0.86. Similar analysis of five late winter and early spring cases resulted in much lower correlations.

Mcginnis, D. F., Jr.↗

Structural investigation of the temperature-stable relaxor dielectric Ba 0.8 Ca 0.2 TiO 3 -Bi(Mg 0.5 Ti 0.5 )O 3

Aberration corrected scanning transmission electron microscopy (STEM) and electron diffraction have been used to disclose local structure and nano-chemistry in a Ca modified BaTiO 3 -Bi(Mg 0.5 Ti 0.5 )O 3 relax or dielectric ceramic which exhibits high and near-invariant relative permittivity over a wide temperature range. High resolution, synchrotron X-ray diffraction indicated a globally cubic structure ($Pm$$\overline{3}$$m$), but direct atomic-scale imaging by STEM revealed local tetragonal distortions. Nanopolar clusters were identified from B-site atomic displacement vectors measured relative to oxygen ion positions along < 100 > and < 110 > zone axes of integrated differential phase contrast (iDPC) STEM images, highlighting cluster sizes of 2–5 nm. Chemical analysis by STEM-energy dispersive X-ray spectroscopy and full pattern refinements of X-ray powder diffraction data each implied high levels of Bi vacancies within the matrix. The possibility that these A-site vacancies modulate the nanopolar structure and promote flattening of the permittivity-temperature response in this class of dielectric is discussed.

36 MATERIALS SCIENCE↗

A Satellite-Derived Upper-Ocean Stratification Data Set for the Tropical North Atlantic With Potential Applications for Hurricane Intensity Prediction

Upper-ocean stratification strongly impacts vertical mixing and the heat flux between the ocean and atmosphere, especially under extreme conditions of tropical cyclones (TCs). Knowledge of prestorm stratification is important for accurate TC intensity prediction. In situ observations of the tropical ocean have significantly increased in the past decade. However, they are still too sparse to resolve ocean stratification variability in near-real time and on small spatial scales. Here, in this study, based on long-term observations and an ocean reanalysis data set from 2004–2017, we investigate the possibility of retrieving upper-ocean stratification from sea surface temperature (SST), sea surface salinity (SSS), and sea surface height (SSH) using a simple regression method. It is found that more than 90% of the mean seasonal cycle and about 30% to 80% of temperature and salinity stratification anomalies can be reconstructed using surface data from either observations or an ocean reanalysis. Simple regression can be used with satellite observations to create a high-resolution, near-real-time-gridded ocean stratification data set that successfully reproduces both the large and mesoscale variability of ocean stratification. When used in a simple expression for TC-induced SST cooling, the satellite-derived stratification shows improvements over an ocean analysis in terms of variance explained of SST cooling, offering promise as a near-real-time indicator of the ocean's impact on TC intensification.

54 ENVIRONMENTAL SCIENCES↗

Can ERA5 Be Used to Study Mesoscale Convective System Climatological Characteristics?

Mesoscale convective systems (MCSs) produce more than half of tropical rainfall and are central to the global hydrologic cycle. As the climate warms, environments favorable for MCSs may become more common; however, limited observational records hamper understanding of how MCSs respond to variations and changes in their environments. Here, we evaluate how well MCSs are represented in ERA5, a widely used global high‐resolution reanalysis product. Using PyFLEXTRKR, which jointly tracks top‐of‐atmosphere infrared brightness temperature and surface precipitation, we identified MCSs in ERA5 and compared them with those identified in satellite observations using the same detection algorithm. This comparison analysis spans 2007–2020 using hourly data at 0.25° horizontal resolution focusing over the tropics. ERA5 reproduces observed brightness‐temperature statistics and captures the geographic distribution and seasonal and diurnal cycles of MCS cold cloud shields. However, ERA5 precipitation exhibits an intensity bias—too much light rain and too little heavy rain—which shifts the rain‐rate distribution and reduces the frequency of MCSs relative to observations. Within MCSs, ERA5 precipitation exhibits the same pattern of bias, yielding a systematic underestimation of MCS precipitation intensity. Consistent with these biases, ERA5 underestimates the contribution of MCS to tropical rainfall by 25%–34% in key regions. Overall, ERA5 is suitable for studying MCS cold cloud‐shield climatology and evolution, but precipitation‐based MCS characteristics (including event‐level precipitation features and the geospatial distribution of MCS precipitation) should be interpreted with caution. These findings clarify which aspects of MCS behavior are robustly represented in ERA5 for climatological applications.

mesoscale convection↗

Isospin mixing and the cubic isobaric multiplet mass equation in the lowest T=2, A=32 quintet

The isobaric multiplet mass equation (IMME) is known to break down in the first T=2,A=32 isospin quintet. In this work we combine high-resolution experimental data with state-of-the-art shell-model calculations to investigate isospin mixing as a possible cause for this violation. The experimental data are used to validate isospin-mixing matrix elements calculated with newly developed shell-model Hamiltonians. Our analysis shows that isospin mixing with nonanalog T=1 states contributes to the IMME breakdown, making the requirement of an anomalous cubic term inevitable for the multiplet.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Simulation Of Satellite Imagery From Aerial Imagery

High-resolution-image data convolved with point-spread function. Report describes use of higher-resolution-image data from aerial photographs or electronic scans of ground to simulate lower resolution images obtained if same area of ground viewed from imaging system in orbit. Simulation technique helpful in analysis of data received from operating satellites and in design of future satellite-borne imaging systems.

Hlavka, Christine A.↗

Faunal and erosional events in the Eastern Tethyan Sea across the K/T boundary

A regional pattern of three closely spaced erosional events at and above the K/T boundary was determined from six Cretaceous/Tertiary boundary sections in the Negev of Israel. The sections were collected from locations throughout the central and northern Negev. All sections are lithologically similar. The Maastrichtian consists of a sequence of limestone beds intercalated with thin marly beds. In some sections, the last limestone bed is followed by 1 to 2 m of calcareous marls grading upwards into several meters of grey shale. In other sections the limestone bed is followed directly by grey shale with the contact containing particles of limestone and marl. A 5 to 20 cm thick dark grey organic-rich clay layer is present about 1.5 to 2.5 m above the base of the grey shale. The grey shale grades upwards into increasingly carbonate rich marls. No unconformities are apparent in field outcrops. During field collection the dark grey clay layer was believed to represent the K/T boundary clay. Microfossil analysis however identified the boundary at the base of the grey shale. The black shale represents a low productivity anoxic event similar to, but younger than, the K/T boundary clay in other K/T boundary sections. High resolution planktic foraminiferal and carbonate analysis of these sections (at 5 to 10 cm intervals) yield surprising results. The K/T boundary is marked by an erosional event which removed part or all of the uppermost Maastrichtian marls above the last limestone bed. Percent carbonate data for four Negev sections are illustrated and show the regional similarities in carbonate sedimentation. Faunal and carbonate data from the Negev sections thus show three closely spaced short erosional events at the K/T boundary and within the first 50,000 to 100,000 years of the Danian. These K/T boundary erosional events may represent global climatic or paleoceanographic events.

Keller, G.↗

Small scale patches of suspended matter and phytoplankton in the Elbe River estuary, German Bight and tidal flats

Landsat 5 TM measurements are found suitable for study of small scale features in coastal waters; three independent factors, namely suspended matter concentration, atmospheric scattering, and sea-surface temperature, were extracted from all seven TM channels on the basis of factor analysis. The distribution of suspended matter in near-surface water layer and sea surface temperature is observable with a spatial resolution of at least 120 x 120 sq m. The high correlation between water depth and suspended matter distribution established by ship-gathered data supports the presently hypothesized control by bottom topography and wind-modified tidal currents of eddy and front formation.

Doerffer, R.↗

Operation and design considerations for unsteady data acquisition with PC-based systems in high Reynolds number hypersonic flowfields

Operation and design considerations for personal-computer-based data acquisition are analyzed, and a system is created that is portable, inexpensive, and capable of high-frequency response. This system performed well when given an extensive analysis of the characteristics of the radio-frequency noise in the test environment. The system architecture is well-suited for support of high-frequency data acquisition from both pressure transducers and high-frequency-response thermocouple gauges. As configured, the system provides a data resolution of approximately 0.09 psia and 0.56 F. Considering the constraints placed upon this design, this data resolution is acceptable. The $5000 budget did require use of an existing PC and rental of signal-conditioning equipment.

Flanagan, M. J., Jr.↗

Geocenter location and variations in earth orientation using global positioning system measurements

We have studied the use of GPS ground and flight tracking data to measure short-period earth orientation variations and changes in geocenter location. Comparisons between GPS-estimated earth rotation variations and those calculated from ocean tide models suggest that observed subdaily variations in earth rotation are dominated by oceanic tidal effects. Our preliminary GPS estimates for geocenter location agree with an independent satellite laser ranging estimates to 10-15 cm. Covariance analysis predicts that temporal resolution of GPS estimates for earth orientation and geocenter improves significantly when data collected from low earth-orbiting satellites as well as from ground sites are combined. The low-earth GPS tracking data enhance the accuracy and resolution for measuring high-frequency global geodynamical signals over time scales less than 1 day.

Malla, R. P.↗

Services, Perspective and Directions of the Space Physics Data Facility

The multi-mission data and orbit services of NASA's Space Physics Data Facility (SPDF) project offer unique capabilities supporting science of the Heliophysics Great Observatory and that are highly complementary to other services now evolving in the international heliophysics data environment. The VSPO (Virtual Space Physics Observatory) service is an active portal to a wide rage of distributed data sources. CDAWeb (Coordinated Data Analysis Web) offers plots, listings and file downloads for current data from many missions across the boundaries of missions and instrument types. CDAWeb now includes extensive new data from STEREO and THEMIS, plus new ROCSAT IPEI data, the latest data from all four TIMED instruments and high-resolution data from all DE-2 experiments. SSCWeb, Helioweb and out 3D Animated Orbit Viewer (TIPSOD) provide position data and identification of spacecraft and ground conjunctions. OMNI Web, with its new extension to 1- and 5-minute resolution, provides interplanetary parameters at the Earth's bow shock. SPDF maintains NASA's CDF (Common Data Format) standard and a range of associated tools including format translation services. These capabilities are all now available through web services based APIs, one element in SPDF's ongoing work to enable heliophysics community development of Virtual discipline Observatories (e.g. VITMO). We will demonstrate out latest data and capabilities, review the lessons we continue to learn in what science users need and value in this class of services, and discuss out current thinking to the future role and appropriate focus of the SPDF effort in the evolving and increasingly distributed heliophysics data environment.

McGuire, Robert E.↗

Astronaut Photography of Coral Reefs

Astronaut photographs of tropical coastal areas may contain information on submerged features, including coral reefs, up to depths of about 15 m in clear waters. Previous research efforts have shown that astronaut photographs can aid in estimating coral reef locations and extent on national, regional and global scales, and allow characterization of major geomorphological rim and lagoon features (Andrefouet et al. 2000, in preparation). They can be combined with traditional satellite data to help distinguish between clouds and lagoon features such as pinnacles (Andrefouet and Robinson, in review). Furthermore, astronaut photographs may provide reef scientists and managers with information on the location and extent of river plumes and sediment run off, or facilitate identification of land cover types, including mangroves (Webb et al., in press). Photographs included in the section were selected based on several criteria. The primary consideration of the editors was that the photographs represent a worldwide distribution of coral reefs, have extremely low visual interference by cloud cover, and display a spatial scale reasonable for examining reef-related features. Once photographs were selected, they were digitized from 2nd generation copies. The color and contrast were hand corrected to an approximation of natural color (required to account for spectral differences between photographs due to the color sensitivities of films used, and differences in sun angle and exposure of the photographs). None of the photographs shown here have been georeferenced to correct them to a map projection and scale. Any distortions in features due to slightly oblique look angles when the photographs were taken through spacecraft windows remain. When feasible, near vertical photographs have been rotated so that north is toward the top. An approximate scale bar and north arrow have added using distinctive features on each photograph with reference to a 1:1,000,000 scale navigation chart. Astronaut photographs provide a unique source of moderate resolution reef remote sensing data because of their global coverage and (immediate) availability in the public domain. The database of photographs can be searched an browsed online and high-resolution digital copies of photographs in this atlas can be accessed via the Website of Earth Science and Image Analysis at NASA's Johnson Space Center:

Robinson, Julie A.↗