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At least 1,009 records · Page 56

Post-irradiation characterization of a high burnup mixed oxide fuel rod with minor actinides

The Advanced Fuels Campaign performed a series of irradiation tests of minor actinide-bearing mixed oxide fuel (MA-MOX), the so-called AFC-2C&D experiments, to investigate the transmutation of long-lived transuranic actinide isotopes contained in spent nuclear fuel via fast reactor technology at burnups exceeding 10 % fission of initial metallic atoms. This manuscript reports the test results derived from one of the five MA-MOX rodlets taken to higher burnup in the AFC-2D irradiation. This includes both non-destructive investigations, such as gamma and neutron spectrometry, and destructive investigations, such as fission gas release, ceramography, and chemical burnup analysis. In addition, the microstructure of the fuel was investigated using advanced electron microscopy techniques including electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM). Here, it was observed with EBSD that the pellet had subdivision of the grains and the TEM observed migration of cladding material into the 5 metal precipitates in the fuel which could have been from the higher than desired oxygen/metal ratio. The TEM also showed an enrichment of Cr in fuel clad chemical interaction (FCCI) layer.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Drop Analysis of a Department of Energy Standard Canister Containing Fort Saint Vrain SNF

DOE manages over 300 types of SNF, many of which are located at the INL site. Managing this large variety of SNF for storage, transportation, and disposal poses a challenge to DOE. The Idaho Cleanup Project and INL are collaborating on the DOE SNF Road-Ready Demonstration (“Road-Ready Demonstration”), which will develop and demonstrate the designs, technology, processes, and regulatory framework for packaging DOE-managed SNF for “road-ready dry storage.” Road-ready dry storage (RRDS) is an SNF management concept in which SNF is packaged into dry, sealed canisters that are then placed in on-site storage in anticipation of later transport and disposition. The forward-looking goal of the Road-Ready Demonstration is to establish the foundation for a large-scale RRDS program at the INL site. One critical aspect of RRDS is the ability to certify the DOE Standard Canister and its associated transportation package in accordance with 10 CFR 71 for offsite transportation. Depending on the SNF type and transportation strategy, DOE Standard Canisters may be required to maintain structural integrity under hypothetical accident scenarios (e.g., drop events). The DOE Standard Canisters have been tested and analyzed under various SNF loading configurations and accident drop events in support of the Idaho Spent Fuel Facility and other DOE programs; however, no analysis has yet been completed in support of the recently initiated Road-Ready Demonstration. This paper presents preliminary results from a finite element analysis of the Ø45.7 cm × 4.6 m (Ø18 in. × 15 ft) DOE Standard Canister under the 9 m drop at 80 degrees off-vertical drop scenario considered in previous INL tests and analyses. It considers the Fort St. Vrain spent nuclear fuel loading configuration proposed for the Road-Ready Demonstration, uses updated material properties, and applies the strain-based acceptance criteria established in ASME Boiler and Pressure Vessel Code’s Section III, Division 3 rules for storage and transportation spent nuclear fuel containments. This updated analysis is compared to previous DOE Standard Canister drop analyses. Preliminary results from the updated analysis show that certain regions of the containment exceed the allowable limits during the accidental drop event. However, these regions are limited to components performing a non-structural function. While further work on this analysis will be pursued, this analysis serves as the foundation for formal calculations used to support applicable certification efforts of the RRDS system at INL.

42 ENGINEERING↗

Drop Analysis of a Department of Energy Standard Canister Containing Fort Saint Vrain SNF– 24138

DOE manages over 300 types of SNF, many of which are located at the INL site. Managing this large variety of SNF for storage, transportation, and disposal poses a challenge to DOE. The Idaho Cleanup Project and INL are collaborating on the DOE SNF Road-Ready Demonstration (“Road-Ready Demonstration”), which will develop and demonstrate the designs, technology, processes, and regulatory framework for packaging DOE-managed SNF for “road-ready dry storage.” Road-ready dry storage (RRDS) is an SNF management concept in which SNF is packaged into dry, sealed canisters that are then placed in on-site storage in anticipation of later transport and disposition. The forward-looking goal of the Road-Ready Demonstration is to establish the foundation for a large-scale RRDS program at the INL site. One critical aspect of RRDS is the ability to certify the DOE Standard Canister and its associated transportation package in accordance with 10 CFR 71 for offsite transportation. Depending on the SNF type and transportation strategy, DOE Standard Canisters may be required to maintain structural integrity under hypothetical accident scenarios (e.g., drop events). The DOE Standard Canisters have been tested and analyzed under various SNF loading configurations and accident drop events in support of the Idaho Spent Fuel Facility and other DOE programs; however, no analysis has yet been completed in support of the recently initiated Road-Ready Demonstration. This paper presents preliminary results from a finite element analysis of the Ø45.7 cm × 4.6 m (Ø18 in. × 15 ft) DOE Standard Canister under the 9 m drop at 80 degrees off-vertical drop scenario considered in previous INL tests and analyses. It considers the Fort St. Vrain spent nuclear fuel loading configuration proposed for the Road-Ready Demonstration, uses updated material properties, and applies the strain-based acceptance criteria established in ASME Boiler and Pressure Vessel Code’s Section III, Division 3 rules for storage and transportation spent nuclear fuel containments. This updated analysis is compared to previous DOE Standard Canister drop analyses. Preliminary results from the updated analysis show that certain regions of the containment exceed the allowable limits during the accidental drop event. However, these regions are limited to components performing a non-structural function. While further work on this analysis will be pursued, this analysis serves as the foundation for formal calculations used to support applicable certification efforts of the RRDS system at INL.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Status Update on NETL Techno-Economic Analysis of Solid Oxide Cells

This is a presentation delivered at the Solid Oxide Fuel Cell Project Review Meeting portion of the 2023 FECM / NETL Spring R&D Project Review Meeting on April 19, 2023. The presentation highlights recently completed techno-economic analysis of solid oxide cell systems including a brief overview of pairing SOFC technology with energy storage, an analysis of the tradeoffs associated with reversible SOC technology versus paired SOFC/SOEC, and highlights of the recently released NGFC and IGFC pathway studies. A more detailed description of analysis conducted on hydrogen fueled SOFC systems is also included.

Hackett, Gregory↗

Examination of the costs, benefits and enery conservation aspects of the NASA aircraft fuel conservation technology program

The costs and benefits of the NASA Aircraft Fuel Conservation Technology Program are discussed. Consideration is given to a present worth analysis of the planned program expenditures, an examination of the fuel savings to be obtained by the year 2005 and the worth of this fuel savings relative to the investment required, a comparison of the program funding with that planned by other Federal agencies for energy conservation, an examination of the private industry aeronautical research and technology financial posture for the period FY 76 - FY 85, and an assessment of the potential impacts on air and noise pollution. To aid in this analysis, a computerized fleet mix forecasting model was developed. This model enables the estimation of fuel consumption and present worth of fuel expenditures for selected commerical aircraft fleet mix scenarios.

Source record↗

Infrared spectroscopy for the determination of hydrocarbon types in jet fuels

The concentration of hydrocarbon types in conventional jet fuels and synfuels can be measured using a computerized infrared spectrophotometer. The computerized spectrophotometer is calibrated using a fuel of known aromatic and olefinic content. Once calibration is completed, other fuels can be rapidly analyzed using an analytical program built into the computer. The concentration of saturates can be calculated as 100 percent minus the sum of the aromatic and olefinic concentrations. The analysis of a number of jet fuels produced an average standard deviation of 1.76 percent for aromatic types and one of 3.99 percent for olefinic types. Other substances such as oils and organic mixtures can be analyzed for their hydrocarbon content.

Buchar, C. S.↗

Economic, Greenhouse Gas, and Resource Assessment for Fuel and Protein Production from Microalgae: 2022 Algae Harmonization Update

This report presents an updated “harmonization study” documenting the collaborative analysis of saline microalgae cultivation and conversion to fuels and products. Four national laboratory modeling teams reconvened to investigate the resource, economic, and environmental sustainability implications of integrated systems encompassing large-scale algae farms and conversion biorefineries. Relative to prior harmonization analyses conducted by these partners, the present effort focuses on more near-term technology potential based on the use of nutrient-replete, high-protein algal biomass compositions (more readily achievable today without sacrificing cultivation productivity) coupled with individual algae farms varying in size but generally smaller at 3,900 acres on average (more realistic in practice than a fixed 5,000-acre farm scale previously considered). Additionally, the present assessment adds further granularity around carbon dioxide (CO 2 ) sourcing and transport via carbon capture of nearby point sources, as well as handling of high-saline cultivation media and resultant blowdown/disposal processing. Finally, this assessment focuses on conversion opportunities to produce both fuel (prioritizing sustainable aviation fuel [SAF], in this case via hydrothermal liquefaction) and protein products for the food and feed markets, recognizing growing needs for such products.

09 BIOMASS FUELS↗

A review of coal heating value correlations with application to coal char, tar, and other fuels

Accurately measuring a fuel’s heating value is one of the first steps in the classification of a new fuel. Heating values are widely used in coal combustion research and are becoming more useful in other fuel types as well. Many different empirical correlations to predict heating values based on primary organic (CHONS) elemental composition are found in the literature, many of which were originally created to predict heating values of parent coal, and some of which have been extended for biomass. However, no correlations exist for heating values of coal chars and tars. Thirteen literature heating value correlations (10 model forms with 13 unique sets of coefficients) were evaluated for their predictive accuracy of a wide variety of fuel types, including 353 coals. This comparative analysis showed that the predictive capabilities of many of these literature models are very similar for coal-based fuels, with good correlation of coal char heating values. Correlation of coal tar heating values was hampered by the lack of heating value data. The choice of which model to use becomes more important for biomass fuels as well as for more unique fuel types like propellants and explosives, municipal solid waste, etc. Finally, the best model forms for each fuel type are suggested based on several statistical measures of fit.

01 COAL, LIGNITE, AND PEAT↗

High Altitude Long Endurance Air Vehicle Analysis of Alternatives and Technology Requirements Development

The objective of this study was to develop a variety of High Altitude Long Endurance (HALE) Unmanned Aerial Vehicle (UAV) conceptual designs for two operationally useful missions (hurricane science and communications relay) and compare their performance and cost characteristics. Sixteen potential HALE UAV configurations were initially developed, including heavier-than-air (HTA) and lighter-than-air (LTA) concepts with both consumable fuel and solar regenerative (SR) propulsion systems. Through an Analysis of Alternatives (AoA) down select process, the two leading consumable fuel configurations (one each from the HTA and LTA alternatives) and an HTA SR configuration were selected for further analysis. Cost effectiveness analysis of the consumable fuel configurations revealed that simply maximizing vehicle endurance can lead to a sub-optimum system solution. An LTA concept with a hybrid propulsion system (solar arrays and a hydrogen-air proton exchange membrane fuel cell) was found to have the best mission performance; however, an HTA diesel-fueled wing-body-tail configuration emerged as the preferred consumable fuel concept because of the large size and technical risk of the LTA concept. The baseline missions could not be performed by even the best HTA SR concept. Mission and SR technology trade studies were conducted to enhance understanding of the potential capabilities of such a vehicle. With near-term technology SR-powered HTA vehicles are limited to operation in favorable solar conditions, such as the long days and short nights of summer at higher latitudes. Energy storage system specific energy and solar cell efficiency were found to be the key technology areas for enhancing HTA SR performance.

Nickol, Craig L.↗

Abatement cost curve analysis of freight rail decarbonization alternatives

This paper investigates decarbonization alternatives for the freight rail industry, considering economic, environmental, and operational aspects. The study compares battery-electric and hydrogen fuel cell locomotives, drop-in fuels including biofuels and e-fuels, and overhead catenary electrification through abatement cost analyses. Scenario analysis identifies the cost-effectiveness of each of the technologies at different stages of decarbonization in the US Class 1 freight railroad network. We show that though battery locomotives offer a lower-cost decarbonization option in the considered scenarios, green hydrogen fuel-powered locomotives become more attractive when battery charging delays are considered. We introduce the concept of the technology margin to cater for uncertainties in battery charging operations and hydrogen fuel production for cases where carbon taxes are imposed on railroad operations. In conclusion, the study provides valuable insights for policymakers and rail operators, contributing to sustainable freight rail operations.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Hydrogen Fuel Cell Vehicles in Tunnels

There are numerous vehicles which utilize alternative fuels, or fuels that differ from typical hydrocarbons such as gasoline and diesel, throughout the world. Alternative vehicles include those running on the combustion of natural gas and propane as well as electrical drive vehicles utilizing batteries or hydrogen as energy storage. Because the number of alternative fuels vehicles is expected to increase significantly, it is important to analyze the hazards and risks involved with these new technologies with respect to the regulations related to specific transport infrastructure, such as bridges and tunnels. This report focuses on hazards presented by hydrogen fuel cell electric vehicles that are different from traditional fuels. There are numerous scientific research and analysis publications on hydrogen hazards in tunnel scenarios; however, compiling the data to make conclusions can be a difficult process for tunnel owners and authorities having jurisdiction over tunnels. This report provides a summary of the available literature characterizing hazards presented by hydrogen fuel cell electric vehicles, including light-duty, medium and heavy-duty, as well as buses. Research characterizing both worst-case and credible scenarios, as well as risk-based analysis, is summarized. Gaps in the research are identified to guide future research efforts to provide a complete analysis of the hazards and recommendations for the safe use of hydrogen fuel cell electric vehicles in tunnels.

33 ADVANCED PROPULSION SYSTEMS↗

Laminar Burning Speed Measurements of Hydrogen/Natural Gas Mixtures

Abstract To address the shortage of fossil fuels and the environmental impact of exhaust emissions, research efforts in combustion seek to identify candidates for sustainable fuels. Hydrogen is an example, from which water is produced as the main combustion product. However, when used as neat hydrogen, it is very difficult to control hydrogen combustion due to its high flame speed, pre-ignition propensity, and flashback characteristics. One method to control hydrogen combustion is to blend it with a well-established fuel. Natural gas is a common fuel for use in engines or gas turbines. Natural gas is characterized by slow flame speeds and poor lean-burn ability; thus, engine power is decreased in the lean-burn region. Consequently, natural gas engines are typically operated at stoichiometric conditions to maximize output. Blending hydrogen to natural gas has several advantages: (i) Control of hydrogen’s ignition characteristics, (ii) extension of Natural gas’s lower flammability limit — making it easier to ignite, and (iii) reduced greenhouse gas emissions. In this study, the laminar burning speed (LBS) for neat natural gas and natural gas/hydrogen mixtures at 5 atm and 296 K were measured. Schlieren optical imaging was utilized to validate laminar flame conditions and further investigate the structure of natural gas/hydrogen flames. Results indicate that replacing 50% of natural gas with hydrogen increases the peak laminar burning velocity by a factor of ∼1.6 times. LBS simulations were conducted with NUI 1.1 and UCF NG/H2 mechanisms; Predictions by both mechanisms were found to be satisfactory for neat NG mixtures. However, for 50% NG/ 50% H2 mixture, the true LBS for fuel-lean conditions was under-predicted by both models, while predictions for fuel-rich conditions were satisfactory. Additionally, a literature review and similar experimental analysis will be performed for methane, ammonia, and hydrogen fuel blends to better understand the combustion phenomena of natural gas fuels.

Yovino, Louis↗

Phosphoric acid fuel cell power plant system performance model and computer program

A FORTRAN computer program was developed for analyzing the performance of phosphoric acid fuel cell power plant systems. Energy mass and electrochemical analysis in the reformer, the shaft converters, the heat exchangers, and the fuel cell stack were combined to develop a mathematical model for the power plant for both atmospheric and pressurized conditions, and for several commercial fuels.

Alkasab, K. A.↗

Integration of Solid Oxide Fuel Cell Systems Into Artificial Intelligence Data Centers

This report presents the results of a techno-economic analysis (TEA) that evaluates the economic benefits of integrating solid oxide fuel cell (SOFC) systems with artificial intelligence (AI) data centers. The analysis was completed in two phases: a scoping-level analysis was performed to identify impactful integration opportunities, followed by a more detailed TEA. Results show that, due to their modularity, SOFC can meet the 99.999% availability requirement of data centers with minimal additional costs. Heat integration via absorption chillers decreases data center electricity consumption at the tradeoff of increased water consumption. Higher SOFC exhaust temperatures are important for achieving larger electricity savings. Finally, power electronics integration with SOFC direct current electricity can reduce electricity consumption by 9 percent and reduce water consumption by 6.4 percent.

20 FOSSIL-FUELED POWER PLANTS↗

Development of the Well-to-Wake Life Cycle Assessment Model for Marine Fuels in R&D GREET 2025

The Marine analysis capabilities in the 2025 Research and Development Greenhouse gases, Regulated Emissions, and Energy use in Technologies (R&D GREET) have been updated to incorporate the latest findings from the Fourth International Maritime Organization (IMO) GHG Study.1 To support these updates and enhance user flexibility, the former single marine module used in previous R&D GREET versions has been split into two workbook tabs: The Marine_Fuel tab, which covers the fuel-cycle, and the Marine_Trip tab, which covers the trip-cycle. In the Marine_Fuel tab, fuel cycle results for 39 marine fuels are available—assuming a slow speed diesel engine—and can be seen in Appendix A. However, there are options for changing feedstocks for multiple fuels, ability to view results with or without pilot fuels for fuels such as methanol and ammonia, and carbon capture options. All these combinations make the number of total possible pathways over one hundred. For each pathway, life cycle emission results are divided into feedstock, conversion, and combustion categories, along with pilot fuel supply chain emissions for fuels used in dual fuel engines. In the newly created Marine_Trip tab, users can view the life cycle emissions of using these fuels from a trip perspective. Compared to R&D GREET 2024, 16 new types of vessels are added in R&D GREET 2025. Examples of results assuming the default size for each vessel type are available in Appendix A. Additional information categories on vessels are included such as vessel size, main propulsion type, engine power rating, combustion cycle, etc. based on the Fourth IMO GHG Study. Operational mode of the trip, fuel consumption, and load calculation were updated based on the report. The fuel consumption calculation also incorporates low-load adjustment, speed–power correction, weather correction, and fouling correction factors. Furthermore, fuel consumption in boilers or steam turbines is also added for the first time, besides fuel use in main propulsion engines and auxiliary engines. This effort makes the R&D GREET Marine capabilities more robust than before. Users will be able to estimate fuel consumption more accurately for more diverse choices of vessel categories, vessel sizes, and energy converters.

09 BIOMASS FUELS↗

Background

An analysis was made of the UF6 fueled gas core reactor as a function of cavity reactor criticality and fluid mechanics tests, investigations of uranium optical emission spectra, and radiant heat transfer power plant studies. Data are also given on nuclear and thermodynamic cycle analysis.

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