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At least 1,009 records · Page 56

Spin transition in Gd{sub 3}N-C{sub 80}, detected by low-temperature on-chip SQUID technique

We present a magnetic study of the Gd{sub 3}N-C{sub 80} molecule, consisting of a Gd-trimer via a nitrogen atom, encapsulated in a C{sub 80} cage. This molecular system can be an efficient contrast agent for magnetic resonance imaging (MRI) applications. We used a low-temperature technique able to detect small magnetic signals by placing the sample in the vicinity of an on-chip SQUID. The technique implemented at the National High Magnetic Field Laboratory has the particularity of being able to operate in high magnetic fields of up to 7 T. The Gd{sub 3}N-C{sub 80} shows a paramagnetic behavior and we find a spin transition of the Gd{sub 3}N structure at 1.2 K. We perform quantum mechanical simulations, which indicate that one of the Gd ions changes from a {sup 8}S{sub 7/2} state (L = 0, S = 7/2) to a {sup 7}F{sub 6} state (L = S = 3, J = 6), likely due to a charge transfer between the C{sub 80} cage and the ion.

36 MATERIALS SCIENCE↗

Experimental observation of left polarized wave absorption near electron cyclotron resonance frequency in helicon antenna produced plasma

Asymmetry in density peaks on either side of an m = +1 half helical antenna is observed both in terms of peak position and its magnitude with respect to magnetic field variation in a linear helicon plasma device [Barada et al., Rev. Sci. Instrum. 83, 063501 (2012)]. The plasma is produced by powering the m = +1 half helical antenna with a 2.5 kW, 13.56 MHz radio frequency source. During low magnetic field (B < 100 G) operation, plasma density peaks are observed at critical magnetic fields on either side of the antenna. However, the density peaks occurred at different critical magnetic fields on both sides of antenna. Depending upon the direction of the magnetic field, in the m = +1 propagation side, the main density peak has been observed around 30 G of magnetic field. On this side, the density peak around 5 G corresponding to electron cyclotron resonance (ECR) is not very pronounced, whereas in the m = -1 propagation side, very pronounced ECR peak has been observed around 5 G. Another prominent density peak around 12 G has also been observed in m = -1 side. However, no peak has been observed around 30 G on this m = -1 side. This asymmetry in the results on both sides is explained on the basis of polarization reversal of left hand polarized waves to right hand polarized waves and vice versa in a bounded plasma system. The density peaking phenomena are likely to be caused by obliquely propagating helicon waves at the resonance cone boundary.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Operational strategies for contamination control of composite materials

Composite materials, used on many instruments, are a potential contamination source for sensitive sensors, especially for sensors or detectors cooled below -80 C. It is a well known fact that composite materials absorb water during fabrication, integration, test, and launch activities and desorb this water under vacuum conditions. Water absorption can be divided into two types: shallow water and deep water. Shallow water is generally about 500 A thick on a clean material surface and is easily desorbed under vacuum conditions. Deep water is a function of the material and is absorbed into the bulk of the material. Deep water can outgas for weeks, months, or years, depending on the vent path, the amount of absorbed water, and the temperature of the material. Several operational strategies have been successfully employed on the Wide Field Planetary Camera. The operational strategies include ultradry gaseous nitrogen purge, dew point of less than -80 C, and vacuum bake-out with verification of outgassing rates. The nitrogen purge is instituted during the fabrication phase and is continued through launch activities. Great care is taken to avoid extended periods of time that the material is exposed to the ambient environment (50 percent relative humidity). On-orbit operational strategies include heat-up and cool-down scenarios which allow the deep water to be sufficiently outgassed before cooling the sensors or detectors.

Hansen, Patricia A.↗

Observables, measurements and phase operators from a Bohmian perspective

Bohmian mechanics is a deterministic theory of point particles in motion. While avoiding all the paradoxes of nonrelativistic quantum mechanics, it yields the quantum formalism itself--especially the role of self-adjoint operators--as a macroscopic measurement formalism. As an 'application' it is shown that much of the confusion connected with the phase operator for the electromagnetic field arises from a misunderstanding of the role of operators in quantum theory.

Daumer, Martin↗

Probabilistic Path Planning of Montgolfier Balloons in Strong, Uncertain Wind Fields

Lighter-than-air vehicles such as hot-air balloons have been proposed for exploring Saturn s moon Titan, as well as other bodies with significant atmospheres. For these vehicles to navigate effectively, it is critical to incorporate the effects of surrounding wind fields, especially as these winds will likely be strong relative to the control authority of the vehicle. Predictive models of these wind fields are available, and previous research has considered problems of planning paths subject to these predicted forces. However, such previous work has considered the wind fields as known a priori, whereas in practical applications, the actual wind vector field is not known exactly and may deviate significantly from the wind velocities estimated by the model. A probabilistic 3D path-planning algorithm was developed for balloons to use uncertain wind models to generate time-efficient paths. The nominal goal of the algorithm is to determine what altitude and what horizontal actuation, if any is available on the vehicle, to use to reach a particular goal location in the least expected time, utilizing advantageous winds. The solution also enables one to quickly evaluate the expected time-to-goal from any other location and to avoid regions of large uncertainty. This method is designed for balloons in wind fields but may be generalized for any buoyant vehicle operating in a vector field. To prepare the planning problem, the uncertainty in the wind field is modeled. Then, the problem of reaching a particular goal location is formulated as a Markov decision process (MDP) using a discretized space approach. Solving the MDP provides a policy of what actuation option (how much buoyancy change and, if applicable, horizontal actuation) should be selected at any given location to minimize the expected time-to-goal. The results provide expected time-to-goal values from any given location on the globe in addition to the action policy. This stochastic approach can also provide insights not accessible by deterministic methods; for example, one can evaluate variability and risk associated with different scenarios, rather than only viewing the expected outcome.

Wolf, Michael↗

Spheres: from Ground Development to ISS Operations

SPHERES (Synchronized Position Hold Engage and Reorient Experimental Satellites) is an internal International Space Station (ISS) Facility that supports multiple investigations for the development of multi-spacecraft and robotic control algorithms. The SPHERES National Lab Facility aboard ISS is managed and operated by NASA Ames Research Center (ARC) at Moffett Field California. The SPHERES Facility on ISS consists of three self-contained eight-inch diameter free-floating satellites which perform the various flight algorithms and serve as a platform to support the integration of experimental hardware. SPHERES has served to mature the adaptability of control algorithms of future formation flight missions in microgravity (6 DOF (Degrees of Freedom) / long duration microgravity), demonstrate key close-proximity formation flight and rendezvous and docking maneuvers, understand fault diagnosis and recovery, improve the field of human telerobotic operation and control, and lessons learned on ISS have significant impact on ground robotics, mapping, localization, and sensing in three-dimensions - among several other areas of study.

SPHERES↗

Operation of the GaSb p-channel metal-oxide-semiconductor field-effect transistors fabricated on (111)A surfaces

We demonstrate the operation of GaSb p-channel metal-oxide-semiconductor field-effect transistors (p-MOSFETs) on (111)A surfaces with Al{sub 2}O{sub 3} gate dielectrics formed by atomic-layer deposition at 150 °C. The p-MOSFETs on (111)A surfaces exhibit higher drain current and lower subthreshold swing than those on (100) surfaces. We find that the interface-state density (D{sub it}) values at the Al{sub 2}O{sub 3}/GaSb MOS interfaces on the (111)A surfaces are lower than those on the (100) surfaces, which can lead to performance enhancement of the GaSb p-MOSFETs on (111)A surfaces. The mobility of the GaSb p-MOSFETs on (111)A surfaces is 80% higher than that on (100) surfaces.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Scale-Up Information for Gas-Phase Ammonia Treatment of Uranium in the Vadose Zone at the Hanford Site Central Plateau

Uranium is present in the vadose zone at the Hanford Central Plateau and is of concern for protection of groundwater. The Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau identified gas-phase treatment and geochemical manipulation as potentially effective treatment approaches for uranium and technetium in the Hanford Central Plateau vadose zone. Based on laboratory evaluation, use of ammonia vapor was selected as the most promising uranium treatment candidate for further development and field testing. While laboratory tests have shown that ammonia treatment effectively reduces the mobility of uranium, additional information is needed to enable deployment of this technology for remediation. Of importance for field applications are aspects of the technology associated with effective distribution of ammonia to a targeted treatment zone, understanding the fate of injected ammonia and its impact on subsurface conditions, and identifying effective monitoring approaches. In addition, information is needed to select equipment and operational parameters for a field design. As part of development efforts for the ammonia technology for remediation of vadose zone uranium contamination, field scale-up issues were identified and have been addressed through a series of laboratory and modeling efforts. This report presents a conceptual description for field application of the ammonia treatment process, engineering calculations to support treatment design, ammonia transport information, field application monitoring approaches, and a discussion of processes affecting the fate of ammonia in the subsurface. The report compiles this information from previous publications and from recent research and development activities. The intent of this report is to provide technical information about these scale-up elements to support the design and operation of a field test for the ammonia treatment technology.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Field Reconstruction from PIV Measurements Employing Bernstein Polynomial Derived Operators

A fluid-dynamic reconstruction algorithm is presented that generates a least-squares best-fit, two-dimensional density field from a prespecified two-dimensional velocity field. This method recasts the mass-conservation equation as a modified Sylvester equation employing high-order operators derived from modified Bernstein polynomial expansions. To demonstrate its practical utility, this analytic methodology is applied to two canonical cases and a Particle Image Velocimetry dataset obtained from a Mach-2, mechanically back-pressured, isolator experiment. This methodology is envisioned to be used in conjunction with hypersonic-diagnostic techniques to aid in the quantification of isolator flow fields. However, also note that this reconstruction technique is well suited to other applications relevant to fluid dynamics, such as obtaining three-dimensional flow field reconstructions.

Bernstein Polynomials↗

Mojave Volatiles Prospector (MVP): Science and Operations Results from a Lunar Polar Rover Analog Field Campaign

The Mojave Volatiles Prospector (MVP) project is a science-driven field program with the goal of producing critical knowledge for conducting robotic exploration of the Moon. MVP feeds science, payload, and operational lessons learned to the development of a real-time, short-duration lunar polar volatiles prospecting mission. MVP achieved these goals through a simulated lunar rover mission to investigate the composition and distribution of surface and subsurface volatiles in a natural and a priori unknown environment within the Mojave Desert, improving our understanding of how to find, characterize, and access volatiles on the Moon.

xGDS real-time science tools↗

Quasi-single-mode hybrid fibre with anomalous dispersion in the 1 μm range

We have proposed and demonstrated an approach for ensuring quasi-single-mode operation of a cylindrically symmetric hybrid fibre having anomalous dispersion at wavelengths around 1 μm. Basic to this approach are distinctions between spatial fibre mode distributions and the use of a high-loss ring layer in the region of a minimum in the electric field of the operating hybrid mode. (optical fibres)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Actively Pumped Optical Filters at 532 nm

The operation of two narrow-band optical filters at 532.33 nm is presented. Both of these filters operate on the 4P(sub 1/2) to 8S(sub 1/2) excited-state transition in potassium vapor. One of the filters is based on excited-state Faraday effect, and requires the application of an external axial magnetic field. The peak transmission of this filter is approximately 3.5% with a linewidth of less than 10 GHz. The second filter does not require a magnetic field for its operation, but readily attains peak transmissions of 25-30%. The 4P(sub 1/2) state is excited by a 769.9 nm light pulse which is linearly polarized for the first scheme and circularly polarized for the second.

Billmers, Richard I.↗

Deployment and Performance of the NASA D3R During the GPM OLYMPEx Field Campaign

The NASA D3R was successfully deployed and operated throughout the NASA OLYMPEx field campaign. A differential phase based attenuation correction technique has been implemented for D3R observations. Hydrometeor classification has been demonstrated for five distinct classes using Ku-band observations of both convection and stratiform rain. The stratiform rain hydrometeor classification is compared against LDR observations and shows good agreement in identification of mixed-phase hydrometeors in the melting layer.

Sea measurements↗

Community-wide Validation of Geospace Model Ground Magnetic Field Perturbation Predictions to Support Model Transition to Operations

In this paper we continue the community-wide rigorous modern space weather model validation efforts carried out within GEM, CEDAR and SHINE programs. In this particular effort, in coordination among the Community Coordinated Modeling Center (CCMC), NOAA Space Weather Prediction Center (SWPC), modelers, and science community, we focus on studying the models' capability to reproduce observed ground magnetic field fluctuations, which are closely related to geomagnetically induced current phenomenon. One of the primary motivations of the work is to support NOAA SWPC in their selection of the next numerical model that will be transitioned into operations. Six geomagnetic events and 12 geomagnetic observatories were selected for validation.While modeled and observed magnetic field time series are available for all 12 stations, the primary metrics analysis is based on six stations that were selected to represent the high-latitude and mid-latitude locations. Events-based analysis and the corresponding contingency tables were built for each event and each station. The elements in the contingency table were then used to calculate Probability of Detection (POD), Probability of False Detection (POFD) and Heidke Skill Score (HSS) for rigorous quantification of the models' performance. In this paper the summary results of the metrics analyses are reported in terms of POD, POFD and HSS. More detailed analyses can be carried out using the event by event contingency tables provided as an online appendix. An online interface built at CCMC and described in the supporting information is also available for more detailed time series analyses.

MAGNETIC↗

Quasi‐2D Perovskite Crystalline Layers for Printable Direct Conversion X‐Ray Imaging

Abstract Polycrystalline perovskite film‐based X‐ray detector is an appealing technology for assembling large scale imager by printing methods. However, thick crystalline layer without trap and solvent residual is challenging to fabricate. Here, the authors report a solution method to produce high quality quasi‐2D perovskite crystalline layers and detectors that are suitable for X‐ray imaging. By introducing n ‐butylamine iodide into methylammonium lead iodide precursor and coating at elevated temperatures, compact and crystalline layers with exceptional uniformity are obtained on both rigid and flexible substrates. Photodiodes built with the quasi‐2D layers exhibit a low dark current and stable operation under constant electrical field over 96 h in dark, and over 15 h under X‐ray irradiation. The detector responds sensitively under X‐ray, delivering a high sensitivity of 1214 µC Gy air −1 cm −2 and a sensitivity gain is observed when operated under higher fields. Finally, high resolution images are demonstrated using a single pixel device that can resolve 80–200 µm features. This work paves the path for printable direct conversion X‐ray imager development.

36 MATERIALS SCIENCE↗

Real-Time Testbed for Smart Grid Recloser Controller

The growing need for a low voltage recloser has become apparent due to the rise in requirements for a smart grid. This includes more detailed management of power flow forward (towards load) and backward (towards generation), source synchronization in real time, more indepth fault responses, and the use of green energy. The SEL-651R-2 relay is a device that can manage these needs, especially in fault response and synchronization, and is commonly used in systems called microgrids. Microgrids are distribution level systems that are able to operate separated from the main grid, are typically installed much closer to the load(s), and are fed by distributed energy resources (DERs), such as wind, solar or diesel generators. The SEL-651R-2 is normally used in the field with presets operative settings, but the Western Michigan University (WMU) Center for Interdisciplinary Research on Secure, Efficient and Sustainable Energy Technology (WMU InterEnergy Center) wished to test this device in its range of capabilities for microgrid application. A Hardware-In-the-Loop (HIL) testbed was implemented and used through the Real Time Digital Simulator (RTDS) using the RSCAD software to test the SEL-651R-2's use cases and functions. The testbed includes a microgrid with interconnection to a larger main grid, and the relay is meant to control the recloser at the point of common coupling (PCC) between the main grid and microgrid. The testbed shows how basic protections, reclosing, and synchronization checks function when handling faults that affect both the microgrid and the main grid.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Geothermal Operational Optimization with Machine Learning

The Geothermal Operational Optimization with Machine Learning (GOOML) project has developed a generic and extensible component-based system modeling framework to study complex geothermal fields using a data-driven approach. Through building a digital twin of a geothermal steam field with the GOOML modeling framework, operators can analyze historical and forecasted power production, explore possible steam field configurations, and optimize real world operations, all in a cost-effective digital environment. The GOOML modeling software is based on a historical data-assimilation framework that uses first-principal thermodynamics to model steam field components using historical data, and a forecast framework that uses machine-learning-driven models of steam field components to predict future operations. This modeling framework creates countless new opportunities for digital exploration of steam field design and operations. To date, digital twins have been developed for several steam fields in New Zealand and the United States. These digital twins have been validated by comparing hindcast predictions against historical production data. Field design and operations have been explored using genetic optimization and reinforcement learning. Initial results show compelling and often surprising opportunities for improved design and operation of fields with 2 to 5 percent improvements in annual energy production. GOOML is driving a step-change in geothermal operations by applying state-of-the-art machine learning algorithms, comprehensive data analytics, and a first-of-its-kind intelligent geothermal systems model.

40 EE - Geothermal Technologies Office (EE-4G)↗