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At least 991 records · Page 55

A comprehensive review on valorization of chestnut processing wastes into bio‐based composites and bioplastics

Abstract This review examines the characterization and utilization of chestnut processing wastes (35%) in the production of bioplastics and biocomposites. In this review, a Web of Science search without any publishing year restriction on the biochemical compositions of all the components of Castanea sativa . The obtaining of bioplastics and biocomposites based on C. sativa was reviewed. First, it highlights the biochemical composition and antioxidant properties of chestnut fruit, shell, burrs, leaves, flowers, and wood focusing on the most important compounds, such as phenolic acids, flavonoids, carbohydrates, Klason lignin, cellulose, and glucan, which can enhance the properties of these materials. Then the review covers using several chestnut extracts and fillers in bioplastics production through solvent casting technique. The mechanical, structural, bioactive properties, and moisture content were optimized through the composition and production. The color, UV absorption, antioxidant, and antimicrobial activity were also discussed. Biocomposites reinforced with chestnut burs, shells, or wood flour increased the intended properties. The enhancements in tensile strength, elastic modulus, and the effects of a pre‐treatment were evaluated. Additionally, it discusses material recovery, recycling, and reuse, particularly how it affects the biodegradability of composites incorporating chestnut waste residues. Highlights Chestnut fruit, shells, and burrs are rich in starch, lignin, and cellulose. The waste of chestnut processing can be used in bioplastics and biocomposites. Chestnut‐based films and biocomposites exhibit promising mechanical properties. The antimicrobial activity, making films, and composites proper for food packaging. New techniques boost performance, offering alternatives to conventional plastics.

Silva, Simão B. [REQUIMTE/LAQV, ISEP, Polytechnic ↗

Modeling of SRS Aluminum-clad Spent Nuclear Fuel in Standard DOE Sealed Canisters

At the Savannah River Site (SRS), approximately 7 MTHM of aluminum-clad spent nuclear fuel is currently in wet storage at L-basin. A significant portion of this fuel is slated to be dried and sealed in DOE standard canisters for long-term storage. This report will focus on a few fuel types, which should bound all other fuel stored at SRS. These consist of the reference fuel assembly, the MURR fuel and the HFIR fuel. These bound a hypothetical maximum scenario for MTR box fuel, a maximum for decay heat in an assembly, and a maximum for the aluminum surface area, respectively. The geometry for the packages were created from DOE specifications for storage of each of the fuels. As long as the minimum time from reactor discharge to sealed storage is 3 years, then the highest temperatures which occur within the sealed canisters do not exceed 100° C for all scenarios considered here. In the geometry considered, while the HFIR fuel has a large surface area, the packaging configuration leaves large void areas, such that the aluminum surface to free volume ratio is about 30% less than an ATR or MURR packaging configuration.

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Permanent Criticality Termination Processes in Disposed DPCs

This report aims at answering what, how, and when spent nuclear fuel (SNF) or dual-purpose canister (DPC) characteristics could be impacted by disposal events and processes, including decay, corrosion, dissolution, and criticality, such that the potential for criticality initiation or continuation in disposed DPCs becomes permanently significantly diminished. This report uses the term "permanent termination of criticality to denote the significant diminishment of criticality potential, not absolute prevention. The occurrence of disposal processes and events is a direct function of disposal time. For fundamental processes (e.g., decay), time is absolute; however, for other processes (e.g., corrosion), time is relative because it is driven by a combination of DPC characteristics (e.g., fuel conditions, basket composition), geologic parameters (e.g., infiltration rate), engineered barrier design, and other processes and events that impact in-package chemistry.

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Analysis of Radioactive 65 Zn Contamination using 3D Position Sensitive CdZnTe Detectors

SRNL NMG Goal: In collaboration with ORNL, the aim is to identify and explore innovative technology opportunities that accelerate disposition, reduce life cycle costs, minimize worker radiation exposure, and improve worker safety and minimize program risks. • This process will include 3 glovebox systems that require personnel to dilute and package the plutonium for safe storage at WIPP. • For holdup monitoring and verification, gamma ray spectroscopy and imaging are the methods employed to achieve real time analysis of the plutonium waste. 2

Nwadeyi, Valerie E.↗

Discovery and Vetting of Exoplanets. I. Benchmarking K2 Vetting Tools

We have adapted the algorithmic tools developed during the Kepler mission to vet the quality of transit-like signals for use on the K2 mission data. Using the four sets of publicly available light curves at MAST, we produced a uniformly vetted catalog of 772 transiting planet candidates from K2 as listed at the NASA Exoplanet Archive in the K2 Table of Candidates. Our analysis marks 676 of these as planet candidates and 96 as false positives. All confirmed planets pass our vetting tests. Sixty of our false positives are new identifications, effectively doubling the overall number of astrophysical signals mimicking planetary transits in K2 data. Most of the targets listed as false positives in our catalog show either prominent secondary eclipses, transit depths suggesting a stellar companion instead of a planet, or significant photocenter shifts during transit. We packaged our tools into the open-source, automated vetting pipeline Discovery and Vetting of Exoplanets (DAVE), designed to streamline follow-up efforts by reducing the time and resources wasted observing targets that are likely false positives. DAVE will also be a valuable tool for analyzing planet candidates from NASA's TESS mission, where several guest-investigator programs will provide independent light-curve sets—and likely many more from the community. We are currently testing DAVE on recently released TESS planet candidates and will present our results in a follow-up paper.

Kostov, Veselin B.↗

Fabrication and Testing of DOE Standard Canister Closure Leak Test Assembly

DOE manages over 300 types of SNF, most of which are located at the INL site. “Road-ready dry storage” is a management concept where SNF is packaged into dry, sealed canisters, which are then placed in on-site storage in anticipation of later removal. The Idaho Cleanup Project and INL are collaborating on the Road-Ready Capability Demonstration Project, which will develop and demonstrate the designs, technology, processes, and regulatory framework for packaging DOE SNF for road-ready dry storage. In support of establishing a large-scale road-ready dry storage program at the INL site, the demonstration will package a select amount of DOE-managed SNF into DOE Standard Canisters. The closure process for the DOE Standard Canisters will include fuel and basket loading, welding, inspection, leak testing, and if needed, repair. As a follow-up to previous discussion on the design of the DOE Closure Leak Test Assembly, this report describes recent fabrication and testing efforts performed at INL. DOE Standard Canisters are sealed by two sequential gas tungsten arc welds. Both are performed by remotely operated and semi-autonomous welding systems. The first weld is a circumferential pipe weld that completes assembly of the canister body and lid assembly. The second and final closure weld connects the vent plug to the vent port with an identical butt joint to the circumferential pipe weld. After the second weld is performed on the vent port, these welds are helium leak tested using an inside-out technique. In addition to the commercially available vacuum and leak detector systems, the DOE Standard Canister Closure Leak Test Assembly was designed for both remote and manual operation. This report describes fabrication and performance testing associated with the inside-out technique. INL staff designed and tested systems to accomplish these tasks. Hardware fabrication occurred at INL facilities. Forthcoming work includes design optimization, integration to existing systems, and implementation to packaging demonstration operations.

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GDSA Repository Systems Analysis Progress Report

The Spent Fuel and Waste Science and Technology (SFWST) Campaign of the U.S. Department of Energy Office of Nuclear Energy, Office of Spent Fuel and Waste Disposition (SFWD), has been conducting research and development on generic deep geologic disposal systems (i.e., geologic repositories). This report describes specific activities in fiscal year (FY) 2019 associated with FY19 Geologic Disposal Safety Assessment (GDSA) Repository Systems Analysis (RSA) work package within the SFWST Campaign. The overall objective of the GDSA RSA work package is to develop generic deep geologic repository concepts and system performance assessment (PA) models in several host-rock environments, and to simulate and analyze these generic repository concepts and models using the GDSA Framework toolkit, and other tools as needed.

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GDSA Repository Systems Analysis Investigations in FY2021

The Spent Fuel and Waste Science and Technology (SFWST) Campaign of the U.S. Department of Energy Office of Nuclear Energy, Office of Spent Fuel and Waste Disposition (SFWD), has been conducting research and development on generic deep geologic disposal systems (i.e., geologic repositories). This report describes specific activities in the Fiscal Year (FY) 2021 associated with the Geologic Disposal Safety Assessment (GDSA) Repository Systems Analysis (RSA) work package within the SFWST Campaign. The overall objective of the GDSA RSA work package is to develop generic deep geologic repository concepts and system performance assessment (PA) models in several host-rock environments, and to simulate and analyze these generic repository concepts and models using the GDSA Framework toolkit, and other tools as needed.

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GDSA Repository Systems Analysis Investigations in FY2022

The Spent Fuel and Waste Science and Technology (SFWST) Campaign of the U.S. Department of Energy Office of Nuclear Energy, Office of Spent Fuel and Waste Disposition (SFWD), has been conducting research and development on generic deep geologic disposal systems (i.e., geologic repositories). This report describes specific activities in the Fiscal Year (FY) 2022 associated with the Geologic Disposal Safety Assessment (GDSA) Repository Systems Analysis (RSA) work package within the SFWST Campaign. The overall objective of the GDSA RSA work package is to develop generic deep geologic repository concepts and system performance assessment (PA) models in several host-rock environments, and to simulate and analyze these generic repository concepts and models using the GDSA Framework toolkit, and other tools as needed.

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Transuranic Waste Facility: Evaluation of Material-at-Risk Limits

The purpose of this analysis was to provide an evaluation and justification of the differences in the safety-basis parameters of Area G and the proposed TRU Waste Facility (TWF) in response to a request from the Los Alamos Field Office. Many of the differences in safety parameters stem from physical attributes such as facility location, size, and updated safety-basis requirements, etc. However, the primary safety-basis parameter that LANL and the Los Alamos Field Office can control for the proposed TWF is the required MAR limit. Based on the following analysis, LANL has proposed to reduce the overall facility MAR from 30,000 PE Ci to 21,400 PE Ci, and the waste storage buildings from 4,550 PE Ci to 3,200 PE Ci. The recommendation balances program requirements, operational considerations, facility construction cost, and container costs. To implement the reduced MAR strategy above, the Los Alamos Field Office and LANL will need to work with WIPP to ensure two characterization/shipment campaigns are scheduled each year. The analysis in this document included a review of historical trends and potential future scenarios in activity for enduring waste containers to define the expected normal operating range. The first part of the MAR analysis resulted in a newly defined range of activity of 10.5-18.0 PE Ci per DE2= expected for the design life of the new TWF. However, for accident scenario analysis, containers will use the WIPP WAC limits because there are no other individual container controls. Specifically, accident scenarios involving less than the building MAR will use the 80-PE Ci WIPP-WAC limit for drums. The accident analyses are intended to bound the potential impacts, and are not intended to be based on normal operational ranges. The Field Office also requested that LANL evaluate a potential reduction of the waste storage building MAR Limit by a factor of two to three. LANL used the newly defined MAR range of 10.5-18.0 PE Ci/DE to define upper and lower MAR boundary requirements using three containerization scenarios. The result of the analysis showed that the most probable scenario of future operations that balances costs, drum packaging efficiency, and shipment efficiency will routinely require the use of one-third to two-thirds of the MAR limit for each building. This result, paired with scenarios that could potentially provide short-term MAR increases, demonstrates that the MAR cannot be reduced by a factor as large as two to three, but can be reduced from 4,550 PE Ci to 3,200 PE Ci for waste storage buildings (a reduction of 30%). The TWF PDSA submittal contained combustibility values for enduring waste that appeared relatively large compared to Area G. The analysis provided the basis for the initial combustibility values established in the PDSA. Although the recent data provided combustibility values that were much lower than the PDSA assumptions (27% versus 80% in PDSA), the analysis shows that there is variability in combustible loading over time. For safety-basis accident scenarios, the material composition distribution for waste containers will be included in the MAR requirement by assuming all waste is combustible instead of applying a control for combustible loading. For operations and programs, it is better to assume 100% combustibles and maintain flexibility for waste generator containerization rather than to maintain a requirement for administrative controls of combustible loading. Controlling MAR through administrative controls is difficult for both the generator and waste management operations.

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System Model Calculations for the Active Trenches of the Low-Level Burial Grounds, Hanford Site, Washington

Two lined trenches (Trench 31 and 34) located within the 200 West Low-Level Burial Ground (LLBG) area of the U.S. Department of Energy’s (DOE) Hanford Site are designated for permanent disposal of low-level radioactive waste (LLW) and mixed low-level radioactive waste (MLLW). In accordance with DOE O 435.1, Radioactive Waste Management, radioactive waste shall be managed and disposed in a manner that is protective of worker, public health and safety, and the environment. DOE O 435.1 requires a site-specific radiological performance assessment (PA) that includes calculations of potential releases and subsequent doses to members of the public for a period of 1,000 years after closure of a low-level waste (LLW) disposal facility. The purpose of this environmental calculation file (ECF) is to document the various dose calculations performed to support DOE’s LLBG PA. The dose assessments are performed to evaluate the potential exposure of an all-pathway representative person to radionuclide contaminants of potential concern (COPCs) that may be released from the LLBG Trenches 31 and 34 to the point of calculation (POC) located at the outer edge of a 100 m buffer zone surrounding the trench boundary. This ECF uses inputs from other ECFs and their associated model package reports (MPRs) supporting the LLBG PA. The five major objectives of this ECF are to present the results of the following: (1) Deterministic dose assessments for both groundwater and atmospheric exposure scenarios; (2) Radon-222 (Rn-222) flux emanating at the surface from the disposed wastes; (3) Uncertainty analyses of the groundwater pathway annual dose due to uncertainty in input parameters; (4) Sensitivity analyses of the input parameters that could potentially impact the fate and transport of the contaminants and doses; (5) Doses arising from inadvertent intruder exposure scenarios.

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Lessons Learned from the Remote Reactor Vessel Internals Segmentation at Barsebaeck 2 - 18231

Westinghouse is performing a decommissioning project at Barsebaeck in Sweden that was awarded in June 2015. Barsebaeck is an ABB-designed boiling water reactor (BWR) plant (2 units of 615 MW) located 30 kilometers from Malmoe. The first reactor, Barsebaeck 1, was permanently shut down on Nov. 30, 1999, and the second one, Barsebaeck 2, ceased operation on May 31, 2005. The scope of work covers the underwater segmentation and packaging of the Reactor Vessel internals at Barsebaeck 1 and 2, including the up-front engineering studies and equipment manufacturing and qualification. The Barsebaeck Unit 2 was selected for starting the site work in August 2016. Cutting was performed with different types of Westinghouse designed cutting equipment (hydraulic shears, band saw, disc saw). All segmentation tools are remotely controlled due to the high radiation levels and ALARA and personal safety is the number one priority during the site work. The cutting equipment proved to be reliable and flexible which is very valuable for the execution of such a challenging project. The Barsebaeck Unit 2 cutting activities have been finished end of October 2018 and its lessons learned will be taken into consideration for the Unit 1 activities. (authors)

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Crush Strengths of Stainless Steel Honeycomb for Packaging

Honeycomb structures are used as energy absorbers to dissipate kinetic energy. Their low density to high axial strength and inexpensive cost make them ideal for the energy absorption application. Mechanical properties of lightweight materials are well known compared to more dense materials like stainless steel. Determines the viability of using 304 Stainless Steel honeycomb in future SRNL radioactive material packages. Using a combination of the material properties and testing procedures both static and dynamic crush strength of stainless steel honeycomb will be determined. Both static and dynamic crush strengths of stainless steel honeycomb need to be quantified because strain rate plays a role in the material strength. The stainless steel honeycomb being tested will be cut into sections of about 2.0 inches in width, 2.3 inches in length and 2.5 inches in height. The cell size of the material is 0.25 in and the ribbon thickness 0.003 in. The material has a yield strength of 48 ksi and an ultimate strength of 103.2 ksi, with an elastic modulus of 29,300 ksi. Compression testing to determine the static crush strength will use an Instron compression test machine. This Instron machine uses a 20 ksi capacity load cell, while recording data at varying low strain rates. Dynamic impact testing will involve dropping a 43.8 lb impactor from a height around 5 feet onto the stainless steel honeycomb. The honeycomb structure will be on a rigid surface and the impactor will be dropped via a quick release hook. Dynamic crush strength is determined from the weight of the impactor, height of the drop and difference in height of the honeycomb after the drop.

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A Conceptual World Information Library (WIL) and Land Use Information System (LUIS) - 16181

The Organization for Economic Co-operation and Development Nuclear Energy Agency initiative on the Preservation of Records, Knowledge and Memory is addressing the topic of communicating with future generations on the location, specific contents, and potential risks associated with deep geologic nuclear waste repositories. At the Waste Isolation Pilot Plant (WIPP) in the United States, the U.S. Department of Energy (DOE) has committed, prior to the facility closure, to develop a Passive Institutional Controls (PICs) program designed to last as long as practicable. A portion of this PICs program includes development of records packages, selection of data storage materials and methods, and a determination of records retention/storage locations. The approved plan for record retention at WIPP includes the storage of information including hard copies of data, figures and maps in multiple libraries and archive record centers. With this in mind, it is easy to envision reams of various paper documents in a robust physical archive record center similar to one of the museums in Washington D.C., or DOE's Legacy Management facility in Morgantown, West Virginia. While some portion of records for nuclear waste burial sites should be maintained in this fashion for near-term retrieval purposes, it is widely accepted that this is not an efficient way to communicate with future generations even 1,000 years from now. Transmitting large detailed volumes of information to the future should be captured in an electronic format; maintained on computers, translated by computers, and perhaps updated by artificial intelligence as machine and human languages change over the centuries. In addition to a physical records development and storage process for transmittal to future generations, a web-based electronic database system should be developed. A World Electronic Library (WEL) database could be funded from various nations and perhaps sanctioned by the United Nations and/or the IAEA. This WEL could contain information regarding several different subjects with the intent of being a one-stop-information-shop for future generations. This database would require updates and maintenance for as long as there is a recipient. One subset of the WEL would be a spatial database containing all the information available to any set of GPS coordinates, anywhere within the world. This Land Use Information System (LUIS) database would contain information on past and present land use, natural resources, known geology, hydrology and atmospheric conditions, potential warnings, and other pertinent information. The LUIS database is where specific electronic information, a subset of all the records data gathered for a nuclear waste repository, could reside. For not only would LUIS provide the information on a nuclear waste repository when specific GPS coordinates were entered; but a search from the LUIS on 'Nuclear Waste Repositories' could bring up information, including data on location of repositories, radionuclides, operations, D and D, maps, and regulations, plus many other details for locations throughout the world. This tool could be used by future generations for a number of land use or resource exploration decisions. So what can we do now? We can agree to the types of information that should be captured into an electronic database for nuclear waste repositories. We can agree to the levels of detail, the file names and the formats, for ease of combining information sets in the future. Perhaps we can agree to a central electronic data storage site, or sites, where this information will reside for import into a centralized electronic record system, if one is ever developed. (authors)

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Full-Scale Cask Testing and Public Acceptance of Spent Nuclear Fuel Shipments - 12254

Full-scale physical testing of spent fuel shipping casks has been proposed by the National Academy of Sciences (NAS) 2006 report on spent nuclear fuel transportation, and by the Presidential Blue Ribbon Commission (BRC) on America's Nuclear Future 2011 draft report. The U.S. Nuclear Regulatory Commission (NRC) in 2005 proposed full-scale testing of a rail cask, and considered 'regulatory limits' testing of both rail and truck casks (SRM SECY-05-0051). The recent U.S. Department of Energy (DOE) cancellation of the Yucca Mountain project, NRC evaluation of extended spent fuel storage (possibly beyond 60-120 years) before transportation, nuclear industry adoption of very large dual-purpose canisters for spent fuel storage and transport, and the deliberations of the BRC, will fundamentally change assumptions about the future spent fuel transportation system, and reopen the debate over shipping cask performance in severe accidents and acts of sabotage. This paper examines possible approaches to full-scale testing for enhancing public confidence in risk analyses, perception of risk, and acceptance of spent fuel shipments. The paper reviews the literature on public perception of spent nuclear fuel and nuclear waste transportation risks. We review and summarize opinion surveys sponsored by the State of Nevada over the past two decades, which show consistent patterns of concern among Nevada residents about health and safety impacts, and socioeconomic impacts such as reduced property values along likely transportation routes. We also review and summarize the large body of public opinion survey research on transportation concerns at regional and national levels. The paper reviews three past cask testing programs, the way in which these cask testing program results were portrayed in films and videos, and examines public and official responses to these three programs: the 1970's impact and fire testing of spent fuel truck casks at Sandia National Laboratories, the 1980's regulatory and demonstration testing of MAGNOX fuel flasks in the United Kingdom (the CEGB 'Operation Smash Hit' tests), and the 1980's regulatory drop and fire tests conducted on the TRUPACT II containers used for transuranic waste shipments to the Waste Isolation Pilot Plant in New Mexico. The primary focus of the paper is a detailed evaluation of the cask testing programs proposed by the NRC in its decision implementing staff recommendations based on the Package Performance Study, and by the State of Nevada recommendations based on previous work by Audin, Resnikoff, Dilger, Halstead, and Greiner. The NRC approach is based on demonstration impact testing (locomotive strike) of a large rail cask, either the TAD cask proposed by DOE for spent fuel shipments to Yucca Mountain, or a similar currently licensed dual-purpose cask. The NRC program might also be expanded to include fire testing of a legal-weight truck cask. The Nevada approach calls for a minimum of two tests: regulatory testing (impact, fire, puncture, immersion) of a rail cask, and extra-regulatory fire testing of a legal-weight truck cask, based on the cask performance modeling work by Greiner. The paper concludes with a discussion of key procedural elements - test costs and funding sources, development of testing protocols, selection of testing facilities, and test peer review - and various methods of communicating the test results to a broad range of stakeholder audiences. (authors)

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Polyolefin Innovations Toward Circularity and Sustainable Alternatives

The unprecedented growth and socioeconomic impacts of polyolefins clearly outline a major success story in the world of polymer science. Polyolefins revolutionizes industries such as health care, construction, and food packaging. Despite the benefits of polyolefins, there is a rising concern for the environment due to high production volume (i.e., fossil fuel consumption), often short usage time, and problems related to waste management and accumulation in the natural environment. Creating a circular economy for polyolefins through effective recycling technologies has the potential to decrease the environmental impact of these materials. This perspective discusses polyolefins and their impact, existing and emerging recycling/upcycling solutions, and recycle-by-design alternatives that are challenging the status quo.

circular economy↗

Advances in Uncertainty and Sensitivity Analysis Methods and Applications in GDSA Framework.

The Spent Fuel and Waste Science and Technology (SFWST) Campaign of the U.S. Department of Energy (DOE) Office of Nuclear Energy (NE), Office of Fuel Cycle Technology (FCT) is conducting research and development (R&D) on geologic disposal of spent nuclear fuel (SNF) and high-level nuclear waste (HLW). Two high priorities for SFWST disposal R&D are design concept development and disposal system modeling. These priorities are directly addressed in the SFWST ''Geologic Disposal Safety Assessment'' (GDSA) control account, which is charged with developing a geologic repository system modeling and analysis capability, and the associated software, ''GDSA Framework'', for evaluating disposal system performance for nuclear waste in geologic media. ''GDSA Framework'' is supported by SFWST Campaign and its predecessor the Used Fuel Disposition (UFD) campaign. This report fulfills the GDSA Uncertainty and Sensitivity Analysis Methods work package (SF-20SN01030403) level 3 milestone — ''Advances in Uncertainty and Sensitivity Analysis Methods and Applications in GDSA Framework'' (M3SF-20SN010304032). It presents high level objectives and strategy for development of uncertainty and sensitivity analysis tools, demonstrates uncertainty quantification (UQ) and sensitivity analysis (SA) tools in GDSA Framework in FY20, and describes additional UQ/SA tools whose future implementation would enhance the UQ/SA capability of ''GDSA Framework''. This work was closely coordinated with the other Sandia National Laboratory GDSA work packages: the GDSA Framework Development work package (SF- 2051\101030404), the GDSA Repository Systems Analysis work package (SF-2051\101030405), and the GDSA PFLOTRAN Development work package (SF-20SN01030406). This report builds on developments reported in previous ''GDSA Framework'' milestones, particularly M2SF- 19SNO1030403.

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Small Scale Electrical Power Generation from Heat Co-Produced in Geothermal Fluids: Mining Operation

Demonstrate the technical and economic feasibility of small scale power generation from low temperature co-produced fluids. Phase I is to Develop, Design and Test an economically feasible low temperature ORC solution to generate power from lower temperature co-produced geothermal fluids. Phase II &III are to fabricate, test and site a fully operational demonstrator unit on a gold mine working site and operate, remotely monitor and collect data per the DOE recommended data package for one year.

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