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At least 991 records · Page 55

Tracking Critical Thermal Metrics throughout the Life Cycle of a Large Observatory Thermal Model

Observatory thermal models for large, complex missions, such as the Wide Field InfraRed Survey Telescope (WFIRST) mission, produce an immense amount of data to be processed. Configuration management of the model throughout the project life cycle has mainly focused on which versions of the subsystem models form the current observatory level configuration. However, the results produced by the model are not nearly as well tracked and traceable. Given the various states of design maturity for each of the components in the WFIRST design, an updated component model is nearly ready to be integrated at the next higher level of assembly about every month or two. With each subsystem model delivery, the observatory model needs to remove the old component, integrate the new one, execute the model, and inspect the results. Usually, this inspection focuses primarily on the newly integrated component. Recently, a Metric Tracking Spreadsheet was developed to help provide a “big picture” view of the entire observatory highlighting key parameters critical to mission performance. This spreadsheet helps track impacts on subsystems by updates of other subsystems that were not intuitively obvious. Metrics tracked include: absorbed environmental loading (to determine effectiveness of sunshield), temperatures of critical avionics, electrical dissipations, heater power predictions, stability of critical optics, parasitic heat leaks in cryogenic region, high level heat flows between elements, and model run time. Producing this data for the same operational configuration with each model update has helped produce a trail of data to evaluate the impact of model updates. While the metrics selected are specific for WFIRST, other large, complex observatories could be well served to establish their own metrics early in the project life cycle to track to quickly assess the impact of any subsystem on other subsystems or the overall system itself.

Thermal Desktop↗

Slow Organic-to-Inorganic Sub-Lattice Thermalization in Methylammonium Lead Halide Perovskites Observed by Ultrafast Photoluminescence

We examine carrier dynamics in polycrystalline methylammonium lead iodide (CH3NH3PbI3) perovskite thin films as functions of temperature and excitation wavelength. At room temperature, long-lived (nanosecond) transient absorption signals indicate negligible carrier trapping. Conversely, in ultrafast photoluminescence, we observe a heretofore unreported large amplitude (50-60%), 45-ps decay process prior to slower recombination. This fast feature persists for temperatures down to the orthorhombic phase transition near 150 K, below which phase coexistence manifests as rapid energy transfer between domains. At 3 K, a transient photoluminescence red-shift indicates formation of bound excitons from photogenerated free carriers with a 16 meV binding energy for the orthorhombic phase. Finally, we show that the fast PL decay component depends on pump photon energy, which we suggest relates excitation of high energy phonon modes associated with the organic component that alters wavefunction overlap. High-level electronic structure and dynamics calculation support the experimental findings. Hence, the fast PL decay relates a characteristic organic-to-inorganic sub-lattice equilibration timescale at optoelectronic-relevant excitation energies.

Chang, Angela Y.↗

Synthesis and Thermal Behavior of a Fused, Tricyclic 1,2,3,4‐Tetrazine Ring System

Abstract This study presents the synthesis and characterization of a fused, tricyclic 1,2,3,4‐tetrazine ring system. The molecule is synthesized in a three‐step process from 5,5′‐dinitro‐bis,1,2,4‐triazole via a di‐N‐amino compound. Oxidation to form the azo‐coupled fused tricyclic 1,2,3,4‐tetrazine is achieved using tert ‐butyl hypochlorite as the oxidant. The di‐N‐amino compound and the desired fused tricyclic 1,2,3,4‐triazine display interesting thermal behavior and are predicted to be high‐performance energetic materials.

Chavez, David E.↗

Thermal Responsive Ion Selectivity of Uranyl Peroxide Nanocages: An Inorganic Mimic of K + Ion Channels

Abstract An actinyl peroxide cage cluster, Li 48+ m K 12 (OH) m [UO 2 (O 2 )(OH)] 60 (H 2 O) n ( m ≈20 and n ≈310; U 60 ), discriminates precisely between Na + and K + ions when heated to certain temperatures, a most essential feature for K + selective filters. The U 60 clusters demonstrate several other features in common with K + ion channels, including passive transport of K + ions, a high flux rate, and the dehydration of U 60 and K + ions. These qualities make U 60 (a pure inorganic cluster) a promising ion channel mimic in an aqueous environment. Laser light scattering (LLS) and isothermal titration calorimetry (ITC) studies revealed that the tailorable ion selectivity of U 60 clusters is a result of the thermal responsiveness of the U 60 hydration shells.

Gao, Yunyi↗

Thermal Unequilibrium of PdSn Intermetallic Nanocatalysts: From In Situ Tailored Synthesis to Unexpected Hydrogenation Selectivity

Effective control on chemoselectivity in the catalytic hydrogenation of C=O over C=C bonds is uncommon with Pd-based catalysts because of the favored adsorption of C=C bonds on Pd surface. Here we report a unique orthorhombic PdSn intermetallic phase with unprecedented chemoselectivity toward C=O hydrogenation. We observed the formation and metastability of this PdSn phase in situ. During a natural cooling process, the PdSn nanoparticles readily revert to the favored Pd 3 Sn 2 phase. Instead, using a thermal quenching method, we prepared a pure-phase PdSn nanocatalyst. Furthermore, PdSn shows an >96% selectivity toward hydrogenating C=O bonds of various α,β-unsaturated aldehydes, highest in reported Pd-based catalysts. Further study suggests that efficient quenching prevents the reversion from PdSn- to Pd 3 Sn 2 -structured surface, the key to the desired catalytic performance. Density functional theory calculations and analysis of reaction kinetics provide an explanation for the observed high selectivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗