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NASA NTRS2014

Hurricane Imaging Radiometer

The Hurricane Imaging Radiometer (HIRAD) is a synthetic thinned array passive microwave radiometer designed to allow retrieval of surface wind speed in hurricanes, up through category five intensity. The retrieval technology follows the Stepped Frequency Microwave Radiometer (SFMR), which measures surface wind speed in hurricanes along a narrow strip beneath the aircraft. HIRAD maps wind speeds in a swath below the aircraft, about 50-60 km wide when flown in the lower stratosphere. HIRAD has flown in the NASA Genesis and Rapid Intensification Processes (GRIP) experiment in 2010 on a WB-57 aircraft, and on a Global Hawk unmanned aircraft system (UAS) in 2012 and 2013 as part of NASA's Hurricane and Severe Storms Sentinel (HS3) program. The GRIP program included flights over Hurricanes Earl and Karl (2010). The 2012 HS3 deployment did not include any hurricane flights for the UAS carrying HIRAD. The 2013 HS3 flights included one flight over the predecessor to TS Gabrielle, and one flight over Hurricane Ingrid. This presentation will describe the HIRAD instrument, its results from the 2010 and 2013 flights, and potential future developments.

Cecil, Daniel J.↗

NASA NTRS2013

An Updated TRMM Composite Climatology of Tropical Rainfall and Its Validation

An updated 15-yr Tropical Rainfall Measuring Mission (TRMM) composite climatology (TCC) is presented and evaluated. This climatology is based on a combination of individual rainfall estimates made with data from the primaryTRMMinstruments: theTRMM Microwave Imager (TMI) and the precipitation radar (PR). This combination climatology of passive microwave retrievals, radar-based retrievals, and an algorithm using both instruments simultaneously provides a consensus TRMM-based estimate of mean precipitation. The dispersion of the three estimates, as indicated by the standard deviation sigma among the estimates, is presented as a measure of confidence in the final estimate and as an estimate of the uncertainty thereof. The procedures utilized by the compositing technique, including adjustments and quality-control measures, are described. The results give a mean value of the TCC of 4.3mm day(exp -1) for the deep tropical ocean beltbetween 10 deg N and 10 deg S, with lower values outside that band. In general, the TCC values confirm ocean estimates from the Global Precipitation Climatology Project (GPCP) analysis, which is based on passive microwave results adjusted for sampling by infrared-based estimates. The pattern of uncertainty estimates shown by sigma is seen to be useful to indicate variations in confidence. Examples include differences between the eastern and western portions of the Pacific Ocean and high values in coastal and mountainous areas. Comparison of the TCC values (and the input products) to gauge analyses over land indicates the value of the radar-based estimates (small biases) and the limitations of the passive microwave algorithm (relatively large biases). Comparison with surface gauge information from western Pacific Ocean atolls shows a negative bias (~16%) for all the TRMM products, although the representativeness of the atoll gauges of open-ocean rainfall is still in question.

(GPCP) Global Precipitation Project analysis↗

NASA NTRS2015

Microelectrospray Thrusters

Propulsion technology is often a critical enabling technology for space missions. NASA is investing in technologies to enable high value missions with very small spacecraft, even CubeSats. However, these nanosatellites currently lack any appreciable propulsion capability. CubeSats are typically deployed and tumble or drift without any ability to transfer to higher value orbits, perform orbit maintenance, or perform de-orbit. Larger spacecraft can also benefit from high precision attitude control systems. Existing practices include reaction wheels with lifetime concerns and system level complexity. Microelectrospray thrusters will provide new propulsion capabilities to address these mission needs. Electric propulsion is an approach to accelerate propellant to very high exhaust velocities through the use of electrical power. Typical propulsion systems are limited to the combustion energy available in the chemical bonds of the fuel and then acceleration through a converging diverging nozzle. However, electric propulsion can accelerate propellant to ten times higher velocities and therefore increase momentum transfer efficiency, or essentially, increase the fuel economy. Fuel efficiency of thrusters is proportional to the exhaust velocity and referred to as specific impulse (Isp). The state-of-the-art (SOA) for CubeSats is cold gas propulsion with an Isp of 50-80 s. The Space Shuttle main engine demonstrated a specific impulse of 450 s. The target Isp for the Mars Exploration Program (MEP) systems is >1,500 s. This propellant efficiency can enable a 1-kg, 10-cm cube to transfer from low-Earth orbit to interplanetary space with only 200 g of propellant. In September 2013, NASA's Game Changing Development program competitively awarded three teams with contracts to develop MEP systems from Technology Readiness Level-3 (TRL-3), experimental concept, to TRL-5, system validation in a relevant environment. The project is planned for 18 months of system development. Due to the ambitious project goals, NASA has awarded contracts to mature three unique methods to achieve the desired goals. Some of the MEP concepts have been developed for more than a decade at the component level, but are now ready for system maturation. The three concepts include the high aspect ratio porous surface (HARPS) microthruster system, the scalable ion electrospray propulsion system (S-iEPS), and an indium microfluidic electrospray propulsion system. The HARPS system is under development by Busek Co. The HARPS thruster is an electrospray thruster that relies on surface emission of a porous metal with a passive capillary wicking system for propellant management. The HARPS thruster is expected to provide a simple, high ΔV and low-cost solution. The HARPS thruster concept is shown in figure 1. Figure 1 includes the thruster, integrated power processing unit, and propellant reservoir.

Dankanich, John↗

NASA NTRS2016

Evaluation of Assimilated SMOS Soil Moisture Data for US Cropland Soil Moisture Monitoring

Remotely sensed soil moisture data can provide timely, objective and quantitative crop soil moisture information with broad geospatial coverage and sufficiently high resolution observations collected throughout the growing season. This paper evaluates the feasibility of using the assimilated ESA Soil Moisture Ocean Salinity (SMOS)Mission L-band passive microwave data for operational US cropland soil surface moisture monitoring. The assimilated SMOS soil moisture data are first categorized to match with the United States Department of Agriculture (USDA)National Agricultural Statistics Service (NASS) survey based weekly soil moisture observation data, which are ordinal. The categorized assimilated SMOS soil moisture data are compared with NASSs survey-based weekly soil moisture data for consistency and robustness using visual assessment and rank correlation. Preliminary results indicate that the assimilated SMOS soil moisture data highly co-vary with NASS field observations across a large geographic area. Therefore, SMOS data have great potential for US operational cropland soil moisture monitoring.

SMOS↗

DOE OSTI2022

Adsorption and exchange reactions of iodine molecules at the alumina surface: modelling alumina-iodine reaction mechanisms

Harnessing aluminum oxidation energy requires navigating the particle's passivation shell composed of alumina. The shell is a barrier to aluminum oxidation but can also exothermically react with halogenated species and therefore contribute to the overall energy generated during aluminum particle combustion. Fluorination reactions with alumina have been studied because fluorine is abundant in binder formulations that commonly surround aluminum particles in an energetic mixture. However, iodine has emerged as an alternative halogenated-based binder or oxidizer because iodine gas provides ancillary benefits such as chemical neutralization of biological agents or sterilization of contaminated environments. Furthermore, this study used density functional theory (DFT) calculations to evaluate potential reaction pathways for aluminum–iodine combustion. Relative to fluorinated fragments such as HF and F – , the adsorption energies associated with HI and I– are nearly triple the exchange reaction energy available from fluorination reactions with alumina (–189 and –278 kJ mol –1 for HI and I – , respectively). However, exchange reactions between iodinated species and the alumina surface are energetically unfavorable. These results explain that through adsorption, alumina surface exothermic reactions with iodine are more energetic than with fluorine fragments. Experiments performed with differential scanning calorimetry (DSC) confirm the higher magnitude of energy generated for iodination compared with fluorination reactions with alumina. Additionally, strong adsorption energies can promote synthesis of new shell chemistries. Adsorption in solution will promote alumina dissolution and iodine precipitation reactions to produce hydroxyl complexes and iodinated species synthesized on the surface of the particle, thereby replacing alumina with alternative passivation shell chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2004

Evaluation of various cleaning methods to remove bacillus spores from spacecraft hardware materials

A detailed study was made of the biological cleaning effectiveness, defined in terms of the ability to remove bacterial spores, of a number of methods used to clean hardware surfaces. Aluminum (Al 6061) and titanium (Ti 6Al-4V) were chosen for the study as they were deemed the two materials most likely to be used in spacecraft extraterrestrial sampler construction. Metal coupons (1 cm x 2.5 cm) were precleaned and inoculated with 5.8 x 10(3) cultivable Bacillus subtilis spores, which are commonly found on spacecraft surfaces and in the assembly environments. The inoculated coupons were subsequently cleaned using: (1) 70% isopropyl alcohol wipe; (2) water wipe; (3) multiple-solvent flight-hardware cleaning procedures used at the Jet Propulsion Laboratory (JPL); (4) Johnson Space Center-developed ultrapure water rinse; and (5) a commercial, semi-aqueous, multiple-solvent (SAMS) cleaning process. The biological cleaning effectiveness was measured by agar plate assay, sterility test (growing in liquid media), and epifluorescent microscopy. None of the cleaning protocols tested completely removed viable spores from the surface of the aluminum. In contrast, titanium was capable of being cleaned to sterility by two methods, the JPL standard and the commercial SAMS cleaning process. Further investigation showed that the passivation step employed in the JPL standard method is an effective surface sterilant on both metals but not compatible with aluminum. It is recommended that titanium (Ti 6Al-4V) be considered superior to aluminum (Al 6061) for use in spacecraft sampling hardware, both for its potential to be cleaned to sterilization and for its ability to withstand the most effective cleaning protocols.

Spores, Bacterial/metabolism↗

NASA NTRS2004

Evaluation of Various Cleaning Methods to Remove Bacillus Spores from Spacecraft Hardware Materials

planetary protection↗

NASA NTRS2017

Long-term Neutron Background Environment Measured by the Dynamic Albedo of Neutrons (DAN) Instrument onboard Mars Science Laboratory (MSL)

The Dynamic Albedo of Neutrons (DAN) instrument onboard Mars Science Laboratory (MSL) consists of a pulsed neutron generator (PNG) and the neutron detector/electronics (DE) module. There are two 3He-proportional counters used in the DE module. One counter is surrounded with a Cd shell enclosure and measures epi-thermal neutrons with >0.4 eV. The second detector does not have a Cd shell enclosure and measures both thermal and epi-thermal neutrons. The main scientific objectives of DAN are two-fold: (1) the primary objective is to measure the bulk hydrogen abundance (in forms of water or hydrated minerals) of the sub-surface and (2) the secondary objective is to measure the background neutron environment at the surface. DAN achieves the first objective by using a pulsed 14 MeV neutron source (ACTIVE mode). Emitted neutrons undergo a series of nuclear interactions with the regolith and lose energy. The DAN DE module then measures the time profile of the neutrons returned from the regolith. Even a small amount of hydrogen, as low as 0.1 weight % in the regolith, can effectively moderate the high energy neutrons [Mitrofanov, et al., ]. The less-moderated (or epi-thermal) neutrons arrive at the detector earlier than the more-moderated (or thermal) neutrons. The shape and magnitude of neutron time profile curves after pulses can be used to estimate the depth distribution of the hydrogen content. When no neutron pulse is used (PASSIVE mode) DAN measures the neutron background environment at the Mars surface. There are two sources of the background neutrons which DAN would measure: one is secondary neutrons generated by galactic cosmic ray (GCR) interactions with atmospheric and surface materials and the other is neutrons from the Multi-Mission Radioisotope Thermoelectric Generator (MMRTG) onboard MSL as a power source. The passive mode data for the first 1300 sols of the MSL mission are presented in this paper. A summary of the DAN surface operation is described by [Mitrofanov et al., 2012; Jun et al., 2013.

Tate, C.↗

DOE OSTI2024

Evaluation of the Stability of Edge-Passivated CZTS Radiation Detectors

CdZnTeSe (CZTS) is a next gen replacement room temperature radiation detector that solves common issues with modern CZT detectors. • Surface states can trap radiation induced carriers and can act as leakage current pathways requiring detectors to passivated for optimal performance. • In this work, we seek to identify the best passivation technique for CZTS detectors.

KLEPPINGER, JOSHUA↗

NASA NTRS1991

An empirical approach to predicting long term behavior of metal particle based recording media

Alpha iron particles used for magnetic recording are prepared through a series of dehydration and reduction steps of alpha-Fe2O3-H2O resulting in acicular, polycrystalline, body centered cubic (bcc) alpha-Fe particles that are single magnetic domains. Since fine iron particles are pyrophoric by nature, stabilization processes had to be developed in order for iron particles to be considered as a viable recording medium for long term archival (i.e., 25+ years) information storage. The primary means of establishing stability is through passivation or controlled oxidation of the iron particle's surface. Since iron particles used for magnetic recording are small, additional oxidation has a direct impact on performance especially where archival storage of recorded information for long periods of time is important. Further stabilization chemistry/processes had to be developed to guarantee that iron particles could be considered as a viable long term recording medium. In an effort to retard the diffusion of iron ions through the oxide layer, other elements such as silicon, aluminum, and chromium have been added to the base iron to promote more dense scale formation or to alleviate some of the non-stoichiometric behavior of the oxide or both. The presence of water vapor has been shown to disrupt the passive layer, subsequently increasing the oxidation rate of the iron. A study was undertaken to examine the degradation in magnetic properties as a function of both temperature and humidity on silicon-containing iron particles between 50-120 deg C and 3-89 percent relative humidity. The methodology to which experimental data was collected and analyzed leading to predictive capability is discussed.

Hadad, Allan S.↗

NASA NTRS1979

Effects of electron irradiation on large insulating surfaces used for European Communications Satellites

Samples of aluminized Kapton used for passive thermal control on the VHF shield and the antenna dish of ESA's OTS satellite and its derivatives were subjected to an incident electron beam of 25 keV and irradiated for 8 hours at room temperature and at -173 C under a vacuum of the 10 to the minus 6 th power torr. Visual observations during electron irradiation, measurements of leakage current and discharge characteristics, and material degradation following completion of irradiation are discussed.

Reddy, J.↗

DOE OSTI2022

Understanding the Origin of the Nonpassivating Behavior of Si-Based Anodes during the Initial Cycles

In this contribution, we combined electrochemical cycling and X-ray photoelectron spectroscopy (XPS) to understand the nonpassivating behavior of the solid electrolyte interphase (SEI) on Si anodes during the first cycles. Based on galvanostatic measurements, we show that the irreversible capacity loss is reduced after the first cycle, and it stays almost constant from the second cycle onwards. XPS was used to determine the root causes of the Coulombic inefficiency, showing that the rate of decomposition of the organic solvents strongly decreased after the first cycle, whereas the rate of salt decomposition is almost unchanged between cycles. We determine that the inhibition of the decomposition reaction of the organic solvent is responsible for the lower Coulombic loss during the second electrochemical cycle in comparison to the first, whereas the nonpassivating behavior toward the salt decomposition is one of the main causes of capacity loss upon cycling. Here, we further revisit the role of cracking in contributing to capacity loss. Whereas high volumetric expansion remains an issue plaguing the performance of Si anodes, our chronoamperometry studies reveal that the SEI formed on Si anodes does not passivate even when the electrode is fully expanded, and no additional surface is exposed. Overall, our work establishes the need to address the chemical and electrochemical instability of the SEI on the Si anode in addition to the more notorious issue of cracking.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2019

Global Assimilation of L-Band Brightness Temperature Observations from SMAP and SMOS into the Catchment Land Surface Model and Contribution to the Skill of Soil Moisture Estimates

The Soil Moisture Active Passive (SMAP) and Soil Moisture Ocean Salinity (SMOS) missions provide global observations of L-band (1.4 GHz) passive microwave brightness temperature (Tb) observations at a resolution of ~40 km every 2-3 days. These observations have been available since 2015 from SMAP and since 2010 from SMOS.Soil moisture estimates from the separate assimilation of SMAP and SMOS Tb observations into land surface models were previously shown to improve over model-only estimates, thereby demonstrating the value of assimilating L-band Tb observations for soil moisture estimation. The assimilation experiments documented in the literature do not, however, establish whether the joint assimilation of SMAP and SMOS Tbs improves the skill of the resulting soil moisture estimates beyond what can be achieved with either set of observations alone. Moreover, because the published SMAP and SMOS results used different assimilation systems and configurations and applied different evaluation data and procedures, it is unclear whether the assimilation of SMAP-only or SMOS-only Tbs results in better soil moisture skill. In this presentation, we compare the results of three separate assimilation experiments for the period from April 2015 to present. The experiments utilize the SMAP Level-4 Soil Moisture (L4_SM) algorithm, which assimilates L-band Tb observations into the NASA Catchment land surface model using a spatially distributed ensemble Kalman filter. Specifically, the three experiments presented here assimilate (i) SMAP Tbs only, as in the L4_SM product, (ii) SMOS Tbs only, after interpolation of 40° incidence angle, and (iii) both SMAP and SMOS Tbs. In all other respects, the configuration of three experiments is identical, as is the validation of the output. Preliminary results suggest that the joint assimilation of SMAP and SMOS Tbs yields the most skillful soil moisture estimates when compared to independent in situ measurements. Moreover, the skill of the SMAP-only assimilation exceeds that of the SMOS-only assimilation. The presentation provides an in-depth evaluation of the skill of the assimilation estimates vs. independent in situ and satellite measurements and in terms of statistics of the observation-minus-forecast residuals and analysis increments.

Reichle, Rolf↗

NASA NTRS2021

Informing Improvements in Freeze/Thaw State Classification Using Subpixel Temperature

Freeze/thaw (FT) processes at the earth’s surface can have a considerable effect on global carbon, energy, and hydrologic cycles. Therefore, an accurate representation of FT is valuable to adequately monitor and model these processes. In this study, we assess the relationship between satellite-based FT products and modeled surface and soil temperatures over North America. In addition, hourly land surface temperature (LST) from the Geostationary Operational Environmental Satellite (GOES) system is also compared to FT classifications. Utilizing the higher spatial resolution temperatures (5 km), we assess subgrid-scale variability and its relationship to coarser microwave FT classifications (>25 km). We also examine product agreement and subpixel characteristics across the land cover, climate, and topography. FT classifications are shown to vary widely depending on these variables, leading to an ambiguous definition of frozen and thawed states. Our results suggest that current products can characterize FT transitions with consistent subfreezing surface characteristics in far northern regions (>50 °N). However, uncertainty associated with FT classifications is shown to increase considerably as latitude decreases. Our results also suggest that fractional FT products, utilizing data inputs, such as LST, would provide a considerable improvement in mountainous regions with high intergrid cell heterogeneity, in regions characterized by ephemeral FT events (i.e., regions <40 °N), as well as during freeze and thaw onset periods. This study also provides insight to improving the representation of surface FT state by providing a clearer definition of the subpixel scale temperature characteristics that govern existing frozen classifications.

Earth observing systems↗

NASA NTRS1999

Mars Orbit Rendezvous Strategy for the Mars 2003/2005 Sample Return Mission

The primary objective of the Mars 2003/2005 Sample Return Project is to return Martian surface materials to Earth from two different sites by the year 2008. The baseline mission plan relies heavily on the use of a Mars orbit rendezvous strategy similar to the lunar orbit rendezvous scheme used for the Apollo missions. The 2003 mission consists of a single spacecraft comprised of a Lander, Rover, and Mars ascent vehicle (MAV). The 2003 mission will be launched on a Delta-III-class launch vehicle in May/June 2003 and arrive at Mars in December 2003/January 2004. The Lander deploys the Rover to collect surface samples from several sites and return them to the Lander where they are transferred to a sample canister onboard the MAV. The MAV is launched into a low Mars orbit (targeted for 600 km circular, 45 deg inclination) and releases the sample canister to await retrieval by an Orbiter launched in 2005. (The sample canister is a passive vehicle with no maneuvering capability.) The duration of Mars surface operations is at most about 90 days. The 2005 mission consists of two separate spacecraft: a Lander/Rover/MAV spacecraft identical to that used for the 2003 mission and an Orbiter carrying an Earth Entry Vehicle (EEV). Both spacecraft will be launched on a single Ariane-5 in August 2005 and arrive at Mars in July/August 2006. A second sample canister is delivered to Mars orbit using the same scenario as was used for the 2003 mission. The Orbiter uses aerocapture for insertion into Mars orbit (targeted for 250 x 1400 km, 45 deg inclination). During its approximately one-year stay at Mars, the Orbiter will search for and attempt to rendezvous first with the 2003 sample canister and then with the 2005 sample canister. After retrieval, each sample canister is transferred to the EEV. The Orbiter departs Mars in July 2007 and returns to Earth in October 2008 on a trajectory targeted for landing at the Utah Test and Training Range (UTTR). After deploying the EEV, the Orbiter performs a deflection maneuver to avoid reentry into Earth's atmosphere.

DAmario, Louis A.↗

NASA NTRS2001

Interannual Variations of Shallow Firn Temperature at Greenland Summit

Firn-temperature profiles are calculated in a thermal model using continuous surface temperatures derived from Automatic Weather Station (AWS) data and passive microwave data in the Greenland Summit region during the period 1987-1999. The results show that significant interannual variations of mean summer (June to August) and annual temperatures occur in the top 15 m, in addition to the normal seasonal cycle of firn temperature. At 5 m depth, the seasonal cycle is damped to 13% of the surface seasonal amplitude, but even at 15 m about 1% or 0.6 C of the seasonal cycle persists. Both summer and mean annual temperatures decrease from 1987 to 1992, followed by a general increasing trend. Interannual variability is 5 C at the surface, but only is only dampened to 3.2 C at 10 m depth and 0.7 C at 15 m depth. Dampening of the interannual variability with depth is slower than dampening of the seasonal cycle, because of the longer time constant of the interannual variation. The warmer spring and summer temperatures experienced in the top 5 m, due to both the seasonal cycle and interannual variations, affect the rate of firn densification, which is non-linearly dependent on temperature. During the 12 year period 1987-1999, the mean annual surface temperature is -29.2 C, and the mean annual 15 m temperature is -30. 1 C, which is more than 1 C warmer than a 15-m borehole temperature representing the period of about 1959 and warmer than the best-fit temperature history by Alley and Koci back to 1500 A.D..

Jun, Li↗

DOE OSTI2024

Modeling the Impact of Grain Size on Corrosion Behavior of Ni-Based Alloys in Molten Chloride Salt via Cellular Automata

Molten chloride salts hold significant promise as both thermal transfer and storage media for next-generation concentrated solar power (CSP) systems. However, molten chlorides pose a considerable corrosion risk to structural materials, particularly Ni-based alloys. One approach to enhancing corrosion resistance is through the optimization of grain structure; however, it remains uncertain whether increasing or decreasing grain size enhances corrosion resistance. A cellular automata (CA) program was developed to evaluate the interplay between grain size and corrosion in Ni-based alloy. Our CA program tracks alloy composition, surface roughness, and thickness loss via a graphical user interface, displaying corrosion and diffusion status, and multiple user input cards for tuning the simulation. CA simulations of Inconel 625 indicate enhanced corrosion resistance with increased grain size, with passivating oxides offering limited protection. Additionally, the temporal evolution of alloy surface roughness demonstrates notable fluctuations, with abrupt increases attributed to corrosion along vertical grain boundaries and sudden decreases to grain detachment from the protective film.

Materials Science↗

NASA NTRS1991

Synergic inversion technique for active and passive microwave remote sensing of the ocean

A unified approach for combining active and passive microwave measurements for remote sensing applications is described. A synergic inversion technique has been developed and applied to the retrieval of geophysical parameters of the ocean surface and of the atmosphere. It is based on the combination of radiometric and radar measurements at the electromagnetic and cell level and not only on the correction of radar measurements by radiometric measurements, or conversely. Such a combination is performed through a common quantity: the bistatic scattering coefficient of the observed surface. This is used in a direct model to simulate combined measurements from active and passive sensors. It requires a rather complete and accurate calculation of the scattering of microwaves by the rough sea surface. Comparisons with experimental models derived for scatterometers and radar altimeters or with data derived from radiometric measurements show that the results of this unified approach are consistent with those from separate microwave sensors, at least for a foam-free sea surface.

Sobieski, Piotr↗