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At least 991 records · Page 55

Accounting for the photochemical variation in stratospheric NO2 in the SAGE III/ISS solar occultation retrieval

The Stratospheric Aerosol and Gas Experiment (SAGE) III has been operating on the International Space Station (ISS) since mid-2017. Nitrogen dioxide (NO2) number density profiles are routinely retrieved from SAGE III/ISS solar occultation measurements in the middle atmosphere. Although NO2 density varies throughout the day due to photochemistry, the standard SAGE NO2 retrieval algorithm neglects these variations along the instrument’s line of sight by assuming that the number density has a constant gradient within a given vertical layer of the atmosphere. This assumption will result in a retrieval bias for a species like NO2 that changes rapidly across the terminator. In this work we account for diurnal variations in retrievals of NO2 from the SAGE III/ISS measurements, and we determine the impact of this algorithm improvement on the resulting NO2 number densities. The first step in applying the diurnal correction is to use publicly available SAGE III/ISS products to convert the retrieved number density profiles to optical depth profiles. The retrieval is then re-performed with a new matrix that applies photochemical scale factors for each point along the line of sight according to the changing solar zenith angle. In general NO2 that is retrieved by accounting for these diurnal variations is more than 10% lower than the standard algorithm below 30 km. This effect is greatest in winter at high latitudes and generally greater for sunrise occultations than sunset. Comparisons with coincident profiles from the Optical Spectrograph and InfraRed Imager System (OSIRIS) show that NO2 from SAGE III/ISS is generally biased high; however the agreement improves by up to 20% in the mid-stratosphere when diurnal variations are accounted for in the retrieval. We conclude that diurnal variations along the SAGE III/ISS line of sight are an important term to consider for NO2 analyses at altitudes below 30 km.

Stratospheric NO2↗

Inverted metamorphic GaInAs solar cell grown by dynamic hydride vapor phase epitaxy

We present an inverted metamorphic rear heterojunction ~1.0 eV GaInAs solar cell deposited by dynamic hydride vapor phase epitaxy (D-HVPE) with high growth rate. This device uses a Ga 1-x In x P compositionally graded buffer (CGB) to bridge the lattice constant gap between the GaAs substrate and the Ga0.71In0.29As emitter layer. High-resolution x-ray diffraction and transmission electron microscopy confirm that the Ga 0.71 In 0.29 As emitter is grown lattice-matched to the in-plane lattice constant of the CGB with minimal generation of defects at the GaInAs/GaInP interface. The device contains a threading dislocation density of 2.3 × 10 6 cm -2 , a level that enables high-performance minority carrier devices and is comparable to previously demonstrated GaInP CGBs grown by D-HVPE. The device exhibits an open-circuit voltage of 0.589 V under a one-sun AM1.5G illumination condition and a bandgap-voltage offset of 0.407 V, indicating metamorphic epitaxial performance nearly equal to state-of-the-art devices. We analyze the dark current of the device and determine that reducing recombination in the depletion region, which can be achieved by reducing the threading dislocation density and optimizing the device doping density, will improve the device performance. Furthermore, the CGB and device layers, comprising ~8 µm of thickness, are grown in under 10 min, highlighting the ability of D-HVPE to produce high-quality metamorphic devices of all types with the potential for dramatically higher throughput compared to present technology.

14 SOLAR ENERGY↗

Multiphase Modeling in a Parallel Plate Fluidized Bed Receiver for Concentrating Solar Power

A novel high temperature particle solar receiver is developed by using a light trapping planar cavity configuration. As particles fall through the cavity, the concentrated solar radiation warms the boundaries of the receiver and in turn heats the particles. Particles flow through the system, forming a packed bed at the lower end, leaving the system from the bottom at a constant flow rate. Air is introduced to the system as the fluidizing medium to improve particle heat transfer and mixing. A laboratory scale cavity receiver is built and a near IR quartz lamp is used to provide flux to the vertical wall of the heat exchanger. The system is modeled using a continuum two-fluid method. The computational model matches the experimental system size and the particle size distribution is assumed monodisperse. A conduction model that accounts for the effects of solid concentration is implemented, and the heat flux boundary condition matches the experimental setup. Radiative heat transfer is estimated using a widely used correlation during the post-processing step to determine an overall heat transfer coefficient. The model is validated against testing data and achieves less than 30% discrepancy and a heat transfer coefficient greater than 1000 W/m2K.

CSP↗

Simulating the Diffusion of Hydrogen in Amorphous Silicates: A ‘Jumping’ Migration Process and its Implications for Solar Wind Implanted Lunar Volatiles

We use molecular dynamics (MD) simulations to better explain the movement of atomic hydrogen in amorphous silica and quantify the planetary science implications of these findings. Previous MD simulations had a large range of predicted values and did not agree well with experiment. Our simulations sample atomic motion for a longer duration and consider a wider range of temperatures than previous simulations. In contrast to constant atomic motion, the hydrogen atoms were shown to undergo random intermittent jumps from one oxygen atom to another, the number of which increase with temperature. Predicted diffusion coefficients had a better agreement to experimental values than previous MD simulations, suggesting the importance of longer simulation durations for better statistics. The low activation energy and jumps observed at lunar temperatures do not support the theory of diurnal variations in OH content for an undamaged amorphous silica surface. Instead, we conclude that energetic solar wind impacts can induce two competing atomic hydrogen motion processes in the exposed surface: A prompt effect that induces jumps in the temperature spike volume, but also a long term effect of damage in the structure that traps atomic hydrogen. We then use SDTrimSP to quantify the damage created during exposure and MD to demonstrate the H retention and trapping near these defects. Damage was shown to be dependent on impact energy, with defects easily retaining implanted hydrogen. MD results like those presented herein on unweathered surfaces are therefore most relevant to magnetic anomalies. As a result, we demonstrate the importance of lunar volatile models to account for the damage state of the substrate when modelling hydrogen diffusion, retention, and subsequent OH/water production.

Liam S. Morrissey↗

Model structure of a cosmic-ray mediated stellar or solar wind

An idealized hydrodynamic model is presented for the mediation of a free-streaming stellar wind by galactic cosmic rays or energetic particles accelerated at the stellar wind termination shock. The spherically-symmetric stellar wind is taken to be cold; the only body force is the cosmic ray pressure gradient. The cosmic rays are treated as a massless fluid with an effective mean diffusion coefficient k proportional to radial distance r. The structure of the governing equations is investigated both analytically and numerically. Solutions for a range of values of k are presented which describe the deceleration of the stellar wind and a transition to nearly incompressible flow and constant cosmic ray pressure at large r. In the limit of small k the transition steepens to a strong stellar wind termination shock. For large k the stellar wind is decelerated gradually with no shock transition. It is argued that the solutions provide a simple model for the mediation of the solar wind by interstellar ions as both pickup ions and the cosmic ray anomalous component which together dominate the pressure of the solar wind at large r.

Lee, M. A.↗

Numerical simulations of the rebound shock model for solar spicules

Using time-dependent numerical simulations, the proposed rebound shock mechanism for spicules has been examined. At temperatures above a critical value, T(c), the radiation is characteristic of the conditions in the optically thin corona and near optically thin transition region. When T less than T(c), the atmosphere has a radiative cooling time, tau(rad) characteristic of chromosphere. The spicule is initiated with a quasi-impulsive force in the low chromosphere, which drives a train of upward propagating rebound shocks along the rigid magnetic flux tube. These shocks then move the transition region upward. The material below the displaced transition region has temperatures and densities similar to those of spicules when T(c) = 20,000 K or more and tau(rad) = 500 s or more, but not when T(c) = 10,000 K, and probably not when tau(rad) = 100 s. For all the cases where the cross sectional area diverges rapidly with height, the upward velocity of the transition region is less than that of spicules. Moreover, the maximum height is less than that of average spicules. Taller, higher velocity spicules result when the magnetic field cross sectional area is constant. In all cases, the rebound shock mechanism produces substantial motions and temperature and density variations in chromospheric and transition region material. It is suggested that this may be a partial explanation for the continuous dynamic state of the lower solar atmosphere.

Sterling, Alphonse C.↗

Two-Fluid and Discrete Element Modeling of a Parallel Plate Fluidized Bed Heat Exchanger for Concentrating Solar Power

A novel high-temperature particle solar receiver is developed using a light trapping planar cavity configuration. As particles fall through the cavity, the concentrated solar radiation warms the boundaries of the receiver and in turn heats the particles. Particles flow through the system, forming a fluidized bed at the lower section, leaving the system from the bottom at a constant flowrate. Air is introduced to the system as the fluidizing medium to improve particle heat transfer and mixing. A laboratory scale cavity receiver is built by collaborators at the Colorado School of Mines and their data are used for model validation. In this experimental setup, near IR quartz lamp is used to provide flux to the vertical wall of the heat exchanger. The system is modeled using the discrete element method and a continuum two-fluid method. The computational model matches the experimental system size and the particle size distribution is assumed monodisperse. A new continuum conduction model that accounts for the effects of solid concentration is implemented, and the heat flux boundary condition matches the experimental setup. Radiative heat transfer is estimated using a widely used correlation during the post-processing step to determine an overall heat transfer coefficient. The model is validated against testing data and achieves less than 30% discrepancy and a heat transfer coefficient greater than 1000 W/m2 K.

concentrating solar power↗

Using resonant energy X-ray diffraction to extract chemical order parameters in ternary semiconductors

II–IV–V 2 materials, ternary analogs to III–V materials, are emerging for their potential applications in devices such as LEDs and solar cells. Controlling cation ordering in II–IV–V 2 materials offers the potential to tune properties at nearly fixed compositions and lattice parameters. While tuning properties at a fixed lattice constant through ordering has the potential to be a powerful tool used in device fabrication, cation ordering also creates challenges with characterization and quantification of ordering. In this work, we investigate two different methods to quantify cation ordering in ZnGeP 2 thin films: a stretching parameter calculated from lattice constants , and an order parameter determined from the cation site occupancies ( S ). We use high resolution X-ray diffraction (HRXRD) to determine and resonant energy X-ray diffraction (REXD) to extract S . REXD is critical to distinguish between elements with similar Z -number ( e.g. Zn and Ge). We found that samples with a corresponding to the ordered chalcopyrite structure had only partially ordered S values. The optical absorption onset for these films occurred at lower energy than expected for fully ordered ZnGeP 2 , indicating that S is a more accurate descriptor of cation order than the stretching parameter. Since disorder is complex and can occur on many length scales, metrics for quantifying disorder should be chosen that most accurately reflect the physical properties of interest.

36 MATERIALS SCIENCE↗

Modelling R Coronae Borealis stars: effects of He-burning shell temperature and metallicity

The R Coronae Borealis (RCB) stars are extremely hydrogen-deficient carbon stars that produce large amounts of dust, causing sudden deep declines in brightness. They are believed to be formed primarily through white dwarf mergers. In this paper, we use mesa to investigate how post-merger objects with a range of initial He-burning shell temperatures from 2.1 to 5.4 × 10 8 K with solar and subsolar metallicities evolve into RCB stars. The most successful model of these has subsolar metallicity and an initial temperature near 3 × 10 8 K. We find a strong dependence on initial He-burning shell temperature for surface abundances of elements involved in the CNO cycle, as well as differences in effective temperature and radius of RCBs. Elements involved in nucleosynthesis present around 1 dex diminished surface abundances in the 10 per cent solar metallicity models, with the exception of carbon and lithium that are discussed in detail. Models with subsolar metallicities also exhibit longer lifetimes than their solar counterparts. In addition, we find that convective mixing of the burned material occurs only in the first few years of post-merger evolution, after which the surface abundances are constant during and after the RCB phase, providing evidence for why these stars show a strong enhancement of partial He-burning products.

79 ASTRONOMY AND ASTROPHYSICS↗

A method of revitalizing Sampson's theory of the Galilean satellites

A method is developed by which Sampson's theory of motion of Jupiter's Galilean satellites can be revitalized by use of algebraic manipulation software on a digital computer. The technique seeks (1) to remove algebraic errors existing in the current Sampson theory, (2) to introduce some neglected effects due to solar interactions and the 3-7 commensurability between the outer two satellites, (3) to allow for nonzero amplitude and phase of the libration, (4) to allow future revision of the arbitrary constants of integration, (5) to express the final results as analytic functions of variations in the numerous arbitrary constants of integration and arbitrary parameters, and (6) to provide analytic partial derivatives by means of which the numerical values of coefficients in the expressions for the coordinates can be adjusted. The level of precision desired is one arc second (Jovicentric) for the coordinates (2, 3.3, 5.2, and 9.1 km, respectively, for satellites I through IV).

Lieske, J. H.↗

A model of coronal holes

It has been noted that coronal holes appear to be associated with regions of diverging magnetic field in the corona. We set out to test the hypothesis that coronal holes may be caused by an increased flow of energy into the solar wind resulting directly from this diverging magnetic field pattern. Simple models were devised to approximate the energy flow down into the transition region and up into the solar wind as a function of the temperature, density, and rate of field line divergence in the corona. By assuming the rate of mechanical energy influx into the corona to be constant, it was then possible to solve numerically for the coronal temperature and density as a function of the rate of field line divergence. The results of these calculations demonstrate that a diverging field pattern can, indeed, bring about reductions in the temperature and density at the base of the corona comparable to those observed in coronal holes.

Adams, W. M.↗

Analysis of dynamic effects in solar thermal energy conversion systems

The paper examines a study the purpose of which is to assess the performance of solar thermal power systems insofar as it depends on the dynamic character of system components and the solar radiation which drives them. Using a dynamic model, the daily operation of two conceptual solar conversion systems was simulated under varying operating strategies and several different time-dependent radiation intensity functions. These curves ranged from smoothly varying input of several magnitudes to input of constant total energy whose intensity oscillated with periods from 1/4 hour to 6 hours.

Hamilton, C. L.↗

Anti-reflection coatings on large area glass sheets

Antireflective coatings which may be suitable for use on the covers of photovoltaic solar modules can be easily produced by a dipping process. The coatings are applied to glass by drawing sheets of glass vertically out of dilute aqueous sodium silicate solutions at a constant speed, allowing the adherent liquid film to dry, then exposing the dried film to concentrated sulfuric acid, followed by a water rinse and dry. The process produces coatings of good optical performance (96.7 percent peak transmission at 0.540 mu M wavelength) combined with excellent stain and soil resistance, and good resistance to abrasion. The process is reproduceable and easily controlled.

Pastirik, E.↗

Chemical abundances in comets

Photoelectric filter photometry and spectrophotometry undertaken to establish homogeneous, quantitative data on chemical abundances in comets is discussed. Absolute column densities of a particular species were derived from a comparison of the absolute flux of an emission feature due to the species with a fluorescence calculation, and converted into species production rates by the use of a Haser model and the species lifetime. Observations of C2 and CN reveal a constant production rate ratio at heliocentric distances up to 1.5-2.0 AU, which implies a compositional homogeneity with depth and the formation of most comets from a homogeneous volume in the solar nebula. Observations of the trace species C3 indicate no apparent variation in relative abundances, while observations of low levels of NH2 and CH imply that NH3 and CH4 are not abundant species. H2O is considered to be the most abundant species based on detections of O, H and OH, while variations in CO or CO2 content may account for the very large differences in cometary gas-to-dust ratios and morphologies.

Ahearn, M. F.↗

Space and planetary environment criteria guidelines for use in space vehicle development. Volume 1: 1982 revision

Guidelines on space and planetary environment criteria for use in space vehicle development are provided. Information is incorporated in the disciplinary areas of atmospheric and ionospheric properties, radiation, geomagnetic field, astrodynamic constants, and meteoroids for the Earth's atmosphere above 90 km, interplanetary space, and the atmosphere and surfaces (when available) of the Moon and the planets (other than Earth) of this solar system. The Sun, Terrestrial Space, the Moon, Mercury, Venus, and Mars are covered.

Smith, R. E.↗

Determination of galactic cosmic ray latitudinal gradient using Earth based detectors

Using cosmic ray intensity data from the Deep River Neutron monitor and the relation between solar wind velocity and heliomagnetic latitude, an attempt is made to evaluate quantitatively the latitudinal gradient of cosmic ray intensity during the periods dominated by a two sector pattern. Assuming a constant orientation of the heliospheric current sheet on a time scale of the order of a year, a relationship is determined between cosmic ray intensity and heliomagnetic latitude.

BADRUDDIN↗

Infrared measurements of atmospheric ethane (C2H6) from aircraft and ground-based solar absorption spectra in the 3000/cm region

A number of prominent Q-branches of the nu-7 band of C2H6 have been identified near 3000/cm in aircraft and ground-based infrared solar absorption spectra. The aircraft spectra provide the column amount above 12 km at various altitudes. The column amount is strongly correlated with tropopause height and can be described by a constant mixing ratio of 0.46 ppbv in the upper troposphere and a mixing ratio scale height of 3.9 km above the tropopause. The ground-based spectra yield a column of 9.0 x 10 to the 15th molecules/sq cm above 2.1 km; combining these results implies a tropospheric mixing ratio of approximately 0.63 ppbv.

Coffey, M. T.↗

Accretion-disk modeling of the UV spectrum of quasars

The thin accretion disk spectrum, including the effect of electron scattering, is calculated for a grid of the accretion parameters. It is shown that the luminosity and spectral slope in the UV and optical bands are uniquely determined by these parameters and depend only weakly on the viscosity parameter. When the model calculations are compared with observations of a sample of QSOs and Seyfert 1 nuclei, the black hole mass is in the range 10 to the 8th to 10 to the 9.5 solar for the QSOs and 10 to the 7.5 to 10 to the 8.5 solar for the Seyferts and for low-luminosity objects. The correlation between the spectral slope and luminosity of QSOs in the UV can be explained by evolution along curves of constant black hole mass and decreasing accretion rate. The relation between the spectrum and the accretion parameters can be used to constrain the cosmological evolution of the objects and imposes severe constraints on the pure luminosity evolution interpretation function for QSOs and Seyferts.

Wandel, Amri↗