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NASA NTRS2018

Effects of Space Weathering on Reflectance Spectra of Ureilites: First Studies

Ureilites are differentiated meteorites (ultramafic rocks interpreted to be mantle residues) that contain as much carbon as the most carbon-rich carbonaceous chondrites (CCs). Reflectance spectra of ureilites are similar to those of some CCs. Hence, ureilitic asteroids may accidentally be categorized as primitive because their spectra could resemble those of C-complex asteroids, which are thought to be CC-like. We began spectral studies of progressively laser-weathered ureilites with the goals of predicting UV-VIS-IR spectra of ureilitic asteroids, and identifying features that could distinguish differentiated from primitive dark asteroids. Space weathering has not previously been studied for ureilites, and, based on space weathering studies of CCs and other C-rich materials, it could significantly alter their reflectance spectra.

REFLECTANCE SPECTRA UREILITES↗
NASA NTRS2019

MODIS Reflective Solar Bands On-Orbit Calibration and Performance

The design of the MODIS instrument was driven by the scientific community's desire to have near-daily global coverage at moderate resolution (1 km) with a comprehensive spectral coverage from visible to long-wave infrared wavelengths. Since their launches in 1999 and 2002, respectively, the Terra and Aqua MODIS instruments have made continuous global observations and generated numerous data products to help users worldwide with their studies of the Earth's system and its short- and long-term changes. The 20 reflective solar bands (RSB) with wavelengths from 0.41 to 2.2 m collect data at three nadir spatial resolutions: 250 m, 500 m, and 1 km. The solar diffuser (SD) coupled with the solar diffuser stability monitor (SDSM) provide a reflectance-based calibration on-orbit. In addition, lunar observations and response trends from pseudo-invariant desert sites are used to characterize the response versus scan- angle changes on-orbit. This paper provides a brief overview of MODIS RSB calibration algorithms, as implemented in the latest Level 1B version 6.1, operational activities, on-orbit performance, remaining challenges and potential improvements. Results from the SD and SDSM measurements show a wavelength and mirror side dependent degradation in RSB responses, with the largest degradation at the shortest wavelengths, particularly for Terra MODIS. Aqua MODIS has experienced far less degradation of its optics and on-board calibrators compared to Terra MODIS, resulting in an overall better performance. With the exception of Aqua band 6, there have been no new noisy or inoperable detectors in the RSB of either instrument during post-launch operations. As the instruments age and continue to endure the space environment, the detectors and optical systems degrade. The challenges associated with incorporating these on-orbit changes to ensure a production of high-quality calibrated L1B data products are also discussed in this paper.

solar diffuser stability monitor↗
NASA NTRSDate not supplied

AN INTRODUCTION TO THE GEONEX LEVEL-1G PRODUCTS: TOP-OF-ATMOSPHERE REFLECTANCE AND BRIGHTNESS TEMPERATURE

This paper introduces the GeoNEX (Geostationary-NASA Earth eXchange) Level-1G products of top-of-atmosphere (TOA) reflectance and brightness temperature. The products use data streams from the latest geostationary (GEO) sensors including the GOES-16/17 ABI and the Himawari-8/9 AHI. The GeoNEX processing pipeline starts by converting digital numbers to physical quantities with the latest radiometric calibration information. It integrates algorithms to automatically detect and remove residual geolocation errors, to estimate the pixel-wise data-acquisition time, and to accurately calculate the solar illumination angles for each pixel in the domain at every time step. The outputs are reprojected to a globally tiled common grid in geographic coordinates designed to facilitate inter-comparisons and/or synergies between the GeoNEX products and existing Earth observation datasets from polar-orbiting satellites. Therefore, the GeoNEX L1G products provide accurate and consistent TOA reflectance and brightness temperature datasets for scientific analyses and downstream product development.

Geostationary satellite, GOES-16, Himawari-8, NASA↗
NASA NTRSDate not supplied

Generation of Land Surface Reflectance with Combined Geo-KOMPSAT-2A AMI and Himawari 8 AHI Observations

The latest generation of geostationary satellites has opened a new era of Earth observations with unprecedented spatiotemporal resolution and spectral range. Together with GOES 16/17 ABI, FY4-A AGRI, and Himawari-8 AHI, a new Korean geostationary satellite (Geo-KOMPSAT-2A AMI) has operationally collected a full-disk image in 16 channels every ten minutes since July 2019, allowing diurnal land surface monitoring over a large proportion of Asia and all of Oceania. Retrieving accurate surface reflectance (SR) over land from GK-2A/AMI is a challenging but high priority objective. One of the challenges is the absence of a spectral band in the 2.2 m SWIR range from AMI, which is required by many atmospheric correction algorithms to retrieve atmospheric aerosol properties. To remedy this issue, we adopt a strategy that combines concurrent GK-2A/AMI and Himawari 8/AHI observations in order to derive AMI SR. We have adapted the NASA Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm to process the data stream from Himawari 8/AHI. The advantages of the MAIAC algorithm is its capability to exploit the high temporal frequency and varying illumination geometry of the geostationary data for advanced cloud/snow detection, aerosol retrieval, and characterization of surface bidirectional reflectance properties. Leveraging the similarities of spectral bands and the sun-target-sensor geometry between AMI and AHI, we are able to create denser time series of observations and enhanced BRDF samples over most of the spatial coverage of AMI (and AHI). The combined stereo-type observations not only help derive SR for AMI but also enhance retrievals of the corresponding AHI surface products. We evaluate the resulting AMI SR using ground (AERONET) observations and corresponding MODIS products. Further, we discuss potential challenges in utilizing the geostationary satellite data for land surface monitoring.

geostationary satellite↗
NASA NTRS2020

ARCSTONE: Calibration of Lunar Spectral Reflectance from Space

Detecting and improving the scientific understanding of global trends in complex Earth systems, such as climate, increasingly depends on assimilating datasets from multiple instruments and platforms over decadal timescales. Calibration accuracy, stability, and inter-consistency among different instruments are key to developing reliable composite data records from sensors in low Earth and geostationary orbits, but achieving sufficiently low uncertainties for these performance metrics poses a significant challenge. Space-borne instruments commonly carry on-board references for calibration at various wavelengths, but these increase mass and mission complexity, and are subject to degradation in the space environment. The Moon can be considered a natural solar diffuser which can be observed as a calibration target by most spaceborne Earth-observing instruments. Since the lunar surface reflectance is effectively time-invariant, establishing the Moon as a high-accuracy calibration reference enables broad inter-calibration opportunities even between temporally non-overlapping instruments and provides an exo-atmospheric absolute radiometric standard. The ARCSTONE mission goal is to establish the Moon as a reliable reference for high-accuracy on-orbit calibration in the visible and near-infrared spectral region. The ARCSTONE instrument is a compact spectrometer, which will be packaged on a CubeSat intended for low Earth orbit. It will measure the lunar spectral reflectance with accuracy < 0.5% (k=1), sufficient to establish an SI-traceable absolute lunar calibration standard when referenced to the spectral solar irradiance across the 350 to 2300 nm spectral range. This lunar reference will help to enable high-accuracy absolute calibration and inter-calibration of past, current, and future Earth-observing sensors, meteorological imagers, and long-term climate monitoring satellite systems. The ARCSTONE team will present the development status of a full-spectral-range (FSR) instrument, the intended approach to calibration and characterization, and the planned path toward mission implementation.

calibration↗
NASA NTRS2019

The Bidirectional Reflectance of Black Silicon Used in Space and Earth Remote Sensing Applications

Space-based astrophysical and remote sensing observations often require the detection and measurement of light originating from distant and relatively faint objects. These observations are highly susceptible to scattered light which may introduce imaging artifacts, obscure object details, and increase measurement noise. This paper describes the initial work of characterizing representative black materials used in coronagraph instruments and other spaceborne instruments. Measurements of “blackness” and the achieved reflectance of black silicon are provided in the spectral range from 400nm to 2500nm using 8o directional hemispherical measurements. The bidirectional reflectance of black silicon was also measured at discrete wavelengths, 633nm, and 1064nm, using the optical scatterometer located at NASA Goddard Space Flight Center’s Diffuser Calibration Laboratory (DCL). A 100mm diameter black silicon sample was fabricated and optically characterized. The BRDF of other well-known black materials such as Z306 and Fractal Black are also presented and discussed.

BRDF↗
NASA NTRS2021

Terra MODIS Sees Solar Eclipses: Analysis of Reflective Solar Band Response at Multiple Radiance Levels

The MODIS imaging spectroradiometer instruments on-board NASA's Terra and Aqua satellites have 20 reflective solar bands (RSB) covering a wavelength range from 400 to 2200 nm. Radiance is calculated from processing raw signals with background, temperature, and electronic contamination corrected. Measured gain is calibrated with a fully Sunlit solar diffuser (SD) at a stable radiance level, considering a slowly changing SD reflectance degradation. These measurements provide time-dependent gain adjustment factors, and the calibration assumes a linear response for each band and detector. Hence, an analysis of the dependence on different radiance levels is warranted. The MODIS design has no mechanism for varying radiance levels, except for an attenuator screen. However, it has been in static configuration for Terra since mid-2003. An external source of radiance attenuation can be utilized during solar eclipse events, while maintaining high stability and accuracy of solar calibration standards. Due to its long mission lifetime, Terra has seen several Sun-Moon near-conjunction events when it coincides with the orbit path where the SD is directly illuminated. As of August 2020, we have identified 7 viable partial solar eclipses in the Terra mission data. We will discuss several results of our study, including comparison of measured SD signal to predicted radiance reduction based on a solar disk radiance model; nominal and outlier behavior as a function of bands, detectors, and mirror-sides; and comparison with other data sets. Our main conclusion from this study is that there is no notable correlation of detector-dependent trend with radiance level for most RSB bands.

Terra↗
NASA NTRS2021

Deconvolution of SNPP VIIRS Solar Diffuser Bidirectional Reflectance Distribution Function On-orbit Change Factor

The Earth-observing Visible Infrared Imaging Radiometer Suite (VIIRS) on the Suomi National Polar-orbiting Partnership satellite regularly calibrates its reflective solar bands (RSBs), primarily through observing an onboard sunlit solar diffuser (SD). The on-orbit change of the value of the SD bidirectional reflectance distribution function (BRDF) is quantified by a numerical factor, called the H-factor, and is determined by the onboard SD stability monitor (SDSM). Because the spectral response function of an SDSM detector spreads in wavelength, the directly measured H-factor is the true H-factor convolved with the spectral response function. To find the true H-factor, we use the traditional direct method and an innovative iterative approach to separately deconvolve the measured H-factor. Our iterative approach relies on two properties of the SDSM detector spectral response function: the central peak width is narrow enough so that the H-factor does not change much over the peak width, and the dominance of the spectral response function’s integral with respect to the wavelength over the width. The iterative approach is more accurate, of a smaller noise impact, much more flexible in terms of interpolation and extrapolation of function values, and faster. We have used deconvolved H-factors to calibrate the NASA SNPP VIIRS RSB Collections 1 and 2 Level-1B products.

SNPP VIIRS↗
NASA NTRSDate not supplied

Calibration of Landsat 8 Aquatic Reflectance Band Data to Spatial Variations in Chlorophyll a, Suspended Sediment, N, and P in Coastal Estuaries of Southern Louisiana

Nutrient enrichment of coastal estuaries is a proven causal agent of harmful algal blooms, fish kills, and hypoxic zones. To enable regional mapping in coastal estuaries of southern Louisiana of Chlorophyll a, suspended sediment, N, and P concentrations, monthly water sample data collected at over 30 stations along a 129 km transect in the Barataria Basin by Turner et al. (2019) were correlated with Landsat 8 aquatic reflectance (ar) band 3 and 4 image data (2013-2016). Results showed significant non-linear correlations (R2 > 0.2) of Landsat ar band 4 values with measured concentrations of Chlorophyll a, total suspended sediment, N, and P. The strongest correlations were revealed between Landsat ar band 4 reflectances and total P concentrations, periodically at R2 values > 0.6. Landsat ar band images revealed detailed variations in total N and P concentrations that were consistent with the measured nutrient declines associated with dilution of freshwater as sampling locations progressed toward more coastal saline waters. Regional map images of ar band 4 in 2019 and 2020 confirmed that recent openings of Bonnet Carre Spillway could have resulted in damage to oyster beds in the brackish Gulf waters near Lake Borgne and the Mississippi River Delta, possibly due to reduced salinity levels and enhanced sediment deposition.

Calibration↗
NASA NTRSDate not supplied

ARCSTONE: Calibration of Lunar Spectral Reflectance from Space ESTO InVEST 2020

Long-term Objective: - Enable on-orbit high-accuracy absolute calibration for the past, current, and future reflected solar sensors in LEO and GEO by providing lunar spectral irradiance as function of satellite viewing geometry and specified wavelength. IIP Objective (complete): - Design, build, and characterize a prototype instrument demonstrating form-fit-function for a 6U CubeSat. InVEST Objective: - Demonstrate high-accuracy measurements of lunar spectral reflectance, < 0.5% (k=1), via 6U CubeSat on-orbit in LEO for 6 months, with validation and data analysis

ARCSTONE↗
NASA NTRS2023

Impact of Satellite Orbit Drift on Modis Earth Scene Observations Used in Calibration of the Reflective Solar Bands

After more than 20 years in orbit, NASA’s Terra and Aqua satellites have both started drifting away from their historically maintained orbits. The MODIS instruments on Terra and Aqua continue to collect valuable Earth observation data, but the changing orbits present a challenge for maintaining accurate calibration. The MODIS reflective solar bands (RSB), spanning the wavelength range from 412 nm to 2130 nm, are calibrated on orbit using a combination of regular data collections from an on-board solar diffuser, the Moon, and pseudo-invariant Earth scenes. Starting in the Collection 6 Level 1B (L1B) data products, the RSB calibration began using data from desert targets for a few of the visible bands to better track changes in the response versus scan angle that could not be captured by the on-board calibration. The use of Earth scene data has been extended recently for Terra MODIS calibration in Collection 6.1 (C6.1) and the upcoming Collection 7 (C7) L1B to also include data from ocean scenes and deep convective clouds (DCC). Drifts in both the orbit inclination and ground track of Terra and Aqua lead to changes in the solar illumination angles and satellite view angles of the Earth scenes. We discuss how these orbital changes impact the desert and DCC targets used for MODIS RSB calibration and present the accompanying changes made to our C6.1 and C7 calibration algorithms. We also discuss remaining future challenges, such as better characterization of bi-directional reflectance distribution functions, and possible alternative calibration strategies.

MODIS↗
NASA NTRS2023

Early Mission Radiometric Performance of NOAA-21 VIIRS Reflective Solar Bands

The Visible Infrared Imaging Radiometer Suite (VIIRS) is a key instrument on the recently launched NOAA-21 (previously JPSS-2) satellite. The VIIRS, like its predecessors on the SNPP and NOAA-20 satellites, provides daily global coverage in 22 spectral bands from 0.41 to 12.0 micrometers. The geometrically and radiometrically calibrated observations are the basis for numerous operational applications and scientific research studies. Fourteen of the 22 bands are reflective solar bands (RSBs), covering wavelengths from 0.41 to 2.25 micrometers. The RSBs were radiometrically calibrated prelaunch and are regularly calibrated on orbit through the onboard solar diffuser (SD) and scheduled lunar observations. The on-orbit SD’s reflectance change is determined by the onboard solar diffuser stability monitor (SDSM). Here, we report our findings on the early mission NOAA-21 VIIRS RSB radiometric performance, and the performance of the SD and the SDSM.

N21 VIIRS↗
NASA NTRSDate not supplied

Exposure of Highly Reflective Far-Ultraviolet Coatings to LEO Environment for TRL Advancement for the Habitable Worlds Observatory

Over the past several years, our team at the NASA Goddard Space Flight Center (GSFC), in collaboration with the Jet Propulsion Laboratory (JPL) and the Naval Research Laboratory (NRL), have developed several new protected Al coating technologies with improved Far-Ultraviolet (FUV) reflectance performance and more robust environmental stability. These include Al protected with lithium-based fluoride (LiF) coatings such as hot deposited LiF (eLiF), XeF 2 -passivated LiF coatings (XeLiF), Li 3 AlF 6 overcoats, AlF 3 (plasma passivated), and XeF 2 passivated MgF 2 coatings (XeMgF 2 ). However, despite these developments, relatively little experimental information exists regarding the long-term stability of these coatings after simultaneous exposure to the Low Earth Orbit (LEO) environment. To evaluate their environmental durability and advance their Technology Readiness Level (TRL), representative samples of these coating technologies, Al+XeLiF, Al+eLiF, Al+Li 3 AlF 6 , Al+AlF 3 , Al+XeMgF 2 , and bare Al as reference samples, were flown onboard the International Space Station (ISS) as part of the Materials International Space Station Experiment 20 (MISSE-20). The MISSE platform is operated by Aegis Aerospace for relatively long-duration (e.g. 6 months) external exposure experiments in a space environment. The coatings were deposited on ULE and Zerodur substrates, and witness samples deposited on the same coatings runs, but on glass slides were left on Earth as control. A subset of the flight samples were fitted with MgF 2 windows to reduce direct exposure to atomic oxygen (AO) and charged particles, and still let through UV and other types of radiation on these samples. After approximately 6 months of exposure in the forward-facing (RAM) direction, the samples were returned to Earth and characterized by performing FUV/NUV/VIS/NIR reflectance measurements to quantify degradation, spectroscopic ellipsometry to evaluate coating thickness and optical constants, atomic force microscopy (AFM) to quantify surface roughness evolution during the flight in the ISS. The MgF 2 protective windows were also analyzed through FUV transmission measurements. Comparison with the witness samples left on the ground and with the flown bare Al samples (with just the naturally occurring Al 2 O 3 layer) provided a quantitative assessment of coating thickness variations, optical performance degradation, and morphological changes induced by prolonged exposure to the LEO environment.

Far Ultraviolet (FUV)↗
DOE OSTI2024

Lateral Beam Shifts and Depolarization Upon Oblique Reflection from Dielectric Mirrors

Abstract Dielectric mirrors comprising thin‐film multilayers are widely used in optical experiments because they can achieve substantially higher reflectance compared to metal mirrors. Here, potential problems are investigated that can arise when dielectric mirrors are used at oblique incidence, in particular for focused beams. It is found that light beams reflected from dielectric mirrors can experience lateral beam shifts, beam‐shape distortion, and depolarization, and these effects have a strong dependence on wavelength, incident angle, and incident polarization. Because vendors of dielectric mirrors typically do not share the particular layer structure of their products, several dielectric‐mirror stacks are designed and simulated, and then the lateral beam shift from two commercial dielectric mirrors and one coated metal mirror is also measured. This paper brings awareness of the tradeoffs between dielectric mirrors and front‐surface metal mirrors in certain optics experiments, and it is suggested that vendors of dielectric mirrors provide information about beam shifts, distortion, and depolarization when their products are used at oblique incidence.

Physics↗
DOE OSTI2022

Grazing-Incidence Texture Tomography and Diffuse Reflectivity Tomography of an Organic Semiconductor Device Array

The use of grazing-incidence scattering methods for the characterization of 2D patterned organic thin films is limited due to the elongated 1D footprint of the X-ray beam on the sample. However, this characteristic feature can be turned into an advantage, when combined with tomographic reconstruction. In this pilot study we show, how the use of a chosen texture reflection and a diffuse reflectivity signal can each provide 2D images of the deposits, simultaneously revealing the organic film's crystal orientation and the location of the metal electrodes in a field-effect transistor structure from a single sequence of diffraction images.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Growth Dynamics and Electron Reflectivity in Ultrathin Films of Chiral Heptahelicene on Metal (100) Surfaces Studied by Spin-Polarized Low Energy Electron Microscopy

Interaction of electrons with chiral matter gives rise to interesting phenomena such as the chirality-induced spin selectivity. The interdependence of reflectivity of spin-polarized low energy electrons and the absolute handedness of chiral molecules is investigated. First, the growth of homochiral films of helical aromatic hydrocarbons, so-called helicenes, on a Cu(100) surface is studied by means of low energy electron microscopy and scanning tunneling microscopy in ultrahigh vacuum. As soon as the coverage exceeds one monolayer, double-layer nucleation and growth is favored such that depletion in the first layer occurs. Spatially resolved work function measurements show that second-layer patches have a lower work function than first-layer areas. Reflectivity spectra of spin-polarized electrons do not show any asymmetry between homochiral films of the enantiomers. Laterally resolved work function measurements do not confirm work function differences such as those reported earlier for photoelectron studies of chiral peptide films on ferromagnetic substrates.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Time dependence of reflected entropy in rational and holographic conformal field theories

We calculate the time dependence of the reflected entropy of two disconnected regions after a global quench in (1 + 1)-dimensional conformal field theories and in large temperature limit. For rational conformal field theories, we find that the time evolution of the reflected entropy is the same as that of the mutual information. We get the same result for holographic theories in the limit where the separation between disconnected regions is much smaller than their respective sizes. We discuss how this result is consistent with the quasi-particle picture of Calabrese and Cardy.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2021

The Markov gap for geometric reflected entropy

The reflected entropy S R (A : B) of a density matrix ρ AB is a bipartite correlation measure lower-bounded by the quantum mutual information I(A : B). In holographic states satisfying the quantum extremal surface formula, where the reflected entropy is related to the area of the entanglement wedge cross-section, there is often an order-N 2 gap between S R and I. We provide an information-theoretic interpretation of this gap by observing that S R - I is related to the fidelity of a particular Markov recovery problem that is impossible in any state whose entanglement wedge cross-section has a nonempty boundary; for this reason, we call the quantity S R - I the Markov gap. We then prove that for time-symmetric states in pure AdS 3 gravity, the Markov gap is universally lower bounded by log(2)ℓ AdS /2G N times the number of endpoints of the cross-section. We provide evidence that this lower bound continues to hold in the presence of bulk matter, and comment on how it might generalize above three bulk dimensions. Finally, we explore the Markov recovery problem controlling S R - I using fixed area states. This analysis involves deriving a formula for the quantum fidelity — in fact, for all the sandwiched Rényi relative entropies — between fixed area states with one versus two fixed areas, which may be of independent interest. We discuss, throughout the paper, connections to the general theory of multipartite entanglement in holography.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗