A Highly Sensitive Real-time Subsurface Sensor for CO2 Leakage Monitoring
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54 ENVIRONMENTAL SCIENCES↗
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Recent Advances in Radar Polarimetry and Polarimetric SAR Interferometry
The development of Radar Polarimetry and Radar Interferometry is advancing rapidly, and these novel radar technologies are revamping Synthetic Aperture Radar Imaging decisively. In this exposition the successive advancements are sketched; beginning with the fundamental formulations and high-lighting the salient points of these diverse remote sensing techniques. Whereas with radar polarimetry the textural fine-structure, target-orientation and shape, symmetries and material constituents can be recovered with considerable improvements above that of standard amplitude-only Polarization Radar ; with radar interferometry the spatial (in depth) structure can be explored. In Polarimetric-Interferometric Synthetic Aperture Radar (POL-IN-SAR) Imaging it is possible to recover such co-registered textural plus spatial properties simultaneously. This includes the extraction of Digital Elevation Maps (DEM) from either fully Polarimetric (scattering matrix) or Interferometric (dual antenna) SAR image data takes with the additional benefit of obtaining co-registered three-dimensional POL-IN-DEM information. Extra-Wide-Band POL-IN-SAR Imaging - when applied to Repeat-Pass Image Overlay Interferometry - provides differential background validation and measurement, stress assessment, and environmental stress-change monitoring capabilities with hitherto unattained accuracy, which are essential tools for improved global biomass estimation. More recently, by applying multiple parallel repeat-pass EWB-POL-D(RP)-IN-SAR imaging along stacked (altitudinal) or displaced (horizontal) flight-lines will result in Tomographic (Multi- Interferometric) Polarimetric SAR Stereo-Imaging , including foliage and ground penetrating capabilities. It is shown that the accelerated advancement of these modern EWB-POL-D(RP)-IN-SAR imaging techniques is of direct relevance and of paramount priority to wide-area dynamic homeland security surveillance and local-to-global environmental ground-truth measurement and validation, stress assessment, and stress-change monitoring of the terrestrial and planetary covers. In addition, various closely related topics of (i) acquiring additional and protecting existing spectral windows of the Natural Electromagnetic Spectrum (NES) pertinent to Remote Sensing; (ii) mitigating against common "Radio Frequency Interference (RFI)" and intentional Directive Jamming of Airborne & Space borne POL-IN-SAR Imaging Platforms are appraised.
Boerner, Wolfgang-Martin↗
NASA DEVELOP’s Approach to Building Individual and Institutional Capacity to Use Earth Observations for Atmospheric Monitoring and Decision Making
NASA DEVELOP, an Applied Sciences’ Capacity Building program, introduces individuals and institutions to the applications of NASA Earth observation data in an effort to help inform decision making. The program employs early career professionals to conduct rapid feasibility studies tailored specific to partner needs. Each year, DEVELOP conducts 50-60 feasibility studies that highlight the capabilities of Earth observations for measuring and monitoring a wide range of environmental phenomena. For this presentation, example projects will be highlighted that focus on monitoring air quality and pollution, wildfire emissions, and greenhouse gasses such as methane. An overview of example projects, the user communities involved, satellite data used, and lessons learned will be shared.
Capacity Building↗
Ames National Laboratory Annual Site Environmental Report for CY2021
The primary purpose of this report is to summarize the performance of Ames National Laboratory’s environmental programs, present highlights of significant environmental activities, and confirm compliance with environmental regulations and requirements for calendar year 2021. This report is a working requirement of Department of Energy Order 231.1B, Environment, Safety and Health Reporting. It includes descriptions of the Laboratory’s site, mission, the status of its compliance with applicable environmental regulations, its planning and activities to maintain compliance, and a comprehensive review of its environmental protection, surveillance and monitoring activities. Ames National Laboratory is located on the campus of Iowa State University (ISU) and occupies 13 buildings owned by the Department of Energy (DOE). See the Laboratory’s Web page for location and Laboratory overview. The Laboratory also leases space in ISU owned buildings. In 2021, the Laboratory accumulated and disposed of hazardous waste under a U.S. Environmental Protection Agency (EPA) issued generator number. All waste was handled according to applicable EPA, State, and local regulations and DOE Orders. The Laboratory operates as a Small Quantity Generator (SQG) of hazardous waste. There were no radiological air emissions or exposures to the general public due to Laboratory activities in 2021 (See U.S. Department of Energy Air Emissions Annual Report in Appendix A.) The Laboratory has an established Environmental Radiological Protection Program (Plan 10200.041) per DOE Order 458.1 requirements. Plans, policies, and procedures are in place to protect the public and the environment against undue risk from radiation associated with DOE radiological activities. As indicated in prior Site Environmental Reports, formal pollution prevention awareness, waste minimization and recycling programs have been in practice since 1990, with improvements implemented most recently in 2017 with Iowa State University’s shift toward single-stream recycling. Included in recycling efforts are items such as batteries, monitors, corrugated cardboard, lamps, miscellaneous electronic office equipment, mixed paper, newsprint, food/beverage containers, and laboratory glassware. Ames National Laboratory also recycles/reuses salvageable metal, used oil, and foamed polystyrene peanuts, and encourages chemical redistribution and sharing among research groups. Ames National Laboratory reported its contractual performance to DOE-Ames Site Office (AMSO) through the Laboratory’s Performance Evaluation Measurement Plan (PEMP), and a performance level of “B+” was achieved in 2021 for Sustain Excellence and Enhance Effectiveness of Integrated Safety, Health, and Environmental Protection As reported in Site Environmental Reports for prior years, the Laboratory’s Environmental Management System (EMS) has been integrated into the Laboratory’s Integrated Safety Management System (ISMS) since 2005. The integration of EMS into Laboratory business practices allows the Laboratory to systematically review, address and respond to environmental impacts. In addition to DOE-identified objectives and targets, the EMS Steering Committee recommends annual environmental goals for the Laboratory. Due to the COVID-19 pandemic and limited onsite work staff, goals of reducing water usage and travel/commuting to promote the reduction of scope 3 greenhouse gases were achieved. All contract deliverables and environmental compliance activities were still met during this time.
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
Controlling Malaria and Other Diseases Using Remote Sensing
Remote sensing offers the vantage of monitoring a vast area of the Earth continuously. Once developed and launched, a satellite gives years of service in collecting data from the land, the oceans, and the atmosphere. Since the 1980s, attempts have been made to relate disease occurrence with remotely sensed environmental and geophysical parameters, using data from Landsat, SPOT, AVHRR, and other satellites. With higher spatial resolution, the recent satellite sensors provide a new outlook for disease control. At sub-meter to I 10m resolution, surface types associated with disease carriers can be identified more accurately. The Ikonos panchromatic sensor with I m resolution, and the Advanced Land Imager with 1 Om resolution on the newly launched Earth Observing-1, both have displayed remarkable mapping capabilities. In addition, an entire array of geophysical parameters can now be measured or inferred from various satellites. Airborne remote sensing, with less concerns on instrument weight, size, and power consumption, also offers a low-cost alternative for regional applications. NASA/GSFC began to collaborate with the Mahidol University on malaria and filariasis control using remote sensing in late 2000. The objectives are: (1) To map the breeding sites for the major vector species; (2) To identify the potential sites for larvicide and insecticide applications; (3) To explore the linkage of vector population and transmission intensity to environmental variables; (4) To monitor the impact of climate change and human activities on vector population and transmission; and (5) To develop a predictive model for disease distribution. Field studies are being conducted in several provinces in Thailand. Data analyses will soon begin. Malaria data in South Korea are being used as surrogates for developing classification techniques. GIS has been shown to be invaluable in making the voluminous remote sensing data more readily understandable. It will be used throughout this study to clearly demonstrate the spatial relationship between the disease intensities, geophysical variables, and socioeconomic parameters. Asides from malaria and filariasis, application of remote sensing to the control of other diseases have been vigorously pursued by NASA's Environment and Health Initiative. The current program includes projects on Rift Valley fever, St. Louis encephalitis, dengue fever, ebola, African dust and diseases, meningitis, asthma, bartonellosis, cholera, and urban health concerns. Results from these projects indicate that remote sensing will play an increasingly important role in disease control in the future.
Kiang, Richard K.↗
Future space development scenarios: Environmental considerations
The formation of positive attitudes and values concerning the environment of space, as the basis for assuming a wise stewardship role, is becoming increasingly important as many nations begin their journeys into space. A strong emphasis should be placed on fostering an international space environmental ethics. The object of environmental assessment and management in space should be to define what interplanetary regulatory procedures are needed to avoid unnecessary environmental damage and to monitor the effectiveness of such avoidance. The first requirement for research is to narrow the field of concern to areas where there could be an increased scale of development in space in the immediate future. Research needs to be focused on methodologies for defining the environmental systems involved (e.g., the lunar surface) and then recognizing key variables in the system that are fragile and need to be respected. Criteria for environmental quality should emerge which identify, in the case of lunar surface, how much mining activity can be safely undertaken and what quantity of exhaust gases can be released over a given period of time. Only then will humans be most able to evaluate the likely consequences of ventures into space.
Tangum, Richard↗
Genome-wide DNA methylation patterns harbour signatures of hatchling sex and past incubation temperature in a species with environmental sex determination
Conservation of thermally sensitive species depends on monitoring organismal and population-level responses to environmental change in real time. Epigenetic processes are increasingly recognized as key integrators of environmental conditions into developmentally plastic responses, and attendant epigenomic data sets hold potential for revealing cryptic phenotypes relevant to conservation efforts. Here, we demonstrate the utility of genome-wide DNA methylation (DNAm) patterns in the face of climate change for a group of especially vulnerable species, those with temperature-dependent sex determination (TSD). Due to their reliance on thermal cues during development to determine sexual fate, contemporary shifts in temperature are predicted to skew offspring sex ratios and ultimately destabilize sensitive populations. Using reduced-representation bisulphite sequencing, we profiled the DNA methylome in blood cells of hatchling American alligators (Alligator mississippiensis), a TSD species lacking reliable markers of sexual dimorphism in early life stages. We identified 120 sex-associated differentially methylated cytosines (DMCs; FDR < 0.1) in hatchlings incubated under a range of temperatures, as well as 707 unique temperature-associated DMCs. We further developed DNAm-based models capable of predicting hatchling sex with 100% accuracy (in 20 training samples and four test samples) and past incubation temperature with a mean absolute error of 1.2°C (in four test samples) based on the methylation status of 20 and 24 loci, respectively. Though largely independent of epigenomic patterning occurring in the embryonic gonad during TSD, DNAm patterns in blood cells may serve as nonlethal markers of hatchling sex and past incubation conditions in conservation applications. These findings also raise intriguing questions regarding tissue-specific epigenomic patterning in the context of developmental plasticity.
59 BASIC BIOLOGICAL SCIENCES↗
Wetland mapping from digitized aerial photography
Computer assisted interpretation of small scale aerial imagery was found to be a cost effective and accurate method of mapping complex vegetation patterns if high resolution information is desired. This type of technique is suited for problems such as monitoring changes in species composition due to environmental factors and is a feasible method of monitoring and mapping large areas of wetlands. The technique has the added advantage of being in a computer compatible form which can be transformed into any georeference system of interest.
Scarpace, F. L.↗
Sub-city Scale Hourly Air Quality Forecasting by Combining Models, Satellite Observations, and Ground Measurements
While multiple information sources exist concerning surface-level air pollution, no individual source simultaneously provides large-scale spatial coverage, fine spatial and temporal resolution, and high accuracy. It is, therefore, necessary to integrate multiple data sources, using the strengths of each source to compensate for the weaknesses of others. In this study, we propose a method incorporating outputs of NASA’s GEOS Composition Forecasting model system with satellite information from the TROPOMI instrument and ground measurement data on surface concentrations. Although we use ground monitoring data from the Environmental Protection Agency network in the continental United States, the model and satellite data sources used have the potential to allow for global application. This method is demonstrated using surface measurements of nitrogen dioxide as a test case in regions surrounding five major US cities. The proposed method is assessed through cross-validation against withheld ground monitoring sites. In these assessments, the proposed method demonstrates major improvements over two baseline approaches which use ground-based measurements only. Results also indicate the potential for near-term updating of forecasts based on recent ground measurements.
C. Malings↗
Application of ERTS imagery in estimating the environmental impact of a freeway through the Knysna area of South Africa
In the coastal areas north-east and south-west of Knysna, South Africa lie natural forests, lakes and lagoons highly regarded by many for their aesthetic and ecological richness. A freeway construction project has given rise to fears of the degradation or destruction of these natural features. The possibility was investigated of using ERTS imagery to estimate the environmental impact of the freeway and found that: (1) All threatened features could readily be identified on the imagery. (2) It was possible within a short time to provide an area estimate of damage to indigenous forest. (3) In several important respects the imagery has advantages over maps and aerial photos for this type of work. (4) The imagery will enable monitoring of the actual environmental impact of the freeway when completed.
Williamson, D. T.↗
Genesis Solar Wind Sample Curation Documentation
Introduction: A scientist with experience as a sample science analyst, provider of flight hardware for multiple missions, and senior engineer in an ISO 2000-rated manufacturing plant has described the timeline of key participants in any PI-led sample return mission, the breadth of the organizations involved [1,2], and, of interest to this meeting, choosing the types of data to preserve and issues of future data accessibility. This work broadens that perspective by giving similar lessons from Genesis sample curation point-of-view. Curation participation regarding data gathering was part of the mission review process from the beginning. Genesis’ story illustrates outcome of several choices about types of data to record and preserve. Precision analysis of solar wind atoms captured in pure, ultraclean substrates is the driving science goal; therefore, detailed documentation was captured from all mission and curation phases and from investigator laboratories because these processes affect the final analytical results [3]. Pre-flight: Design and fabrication of the spacecraft. Like many modern small sample return missions, Genesis was a tightly managed team integrated across science, engineering and curation. Communication across the team was excellent, and, for the most part, the hands-on engineering technicians understood the impacts of “small choices” they routinely make, and the eyes-on oversight of manufacturing processes by scientists was mindful of details. The payload was designed by the Jet Propulsion Laboratory and the spacecraft by Lockheed Martin. Solar wind collectors and instruments were fabricated by multiple vendors and laboratories. The main portion of the payload was assembled at JSC. Fabrication procedures and contamination-control data (with witness coupons) were stored primarily at JSC. The original composition, dimensions and configuration of components, results of thermal testing, etc. are still needed for interpretation of analytical data. At times, these must be estimated from secondary information acquired pre-flight. Moreover, some files (e.g., original 3-D models and early Powerpoint) cannot be opened using software. Archived curation data includes 2-D drawings, material usage lists, QA documentation and analyses of consumables used during fabrication. Important chemical information still resides in archived hardware, paints and lubricants, material coupons, cleaning coupons, environmental witness plates and reference materials from manufacturing facilities. Purity and cleanliness of collector substrates. Semi-conductor vendors provided surface cleanliness data and some purity data. Purity for specific elements of interest was verified by science team members in their laboratories [4]. Curation archived procurement and shipping records, analysis reports, and non-proprietary fabrication data. A physical archive of flight collector reference materials is maintained for future use so additional data can be collected as analytical techniques improve. These are of increased value due to the hard landing upon re-entry. Cleaning and cleanliness assessments of flight hardware. Cleaning of the science canister payload was performed at JSC in a dedicated ISO 4 cleanroom using ultrapure water (UPW). The cleanliness of this UPW was monitored throughout processing. The archive for the clean lab also includes airborne particle counts, airborne molecular and inorganic contamination measurements as well as cleanroom construction material coupons and witness coupons. Hardware cleanliness was assessed by particle counts in rinse water batches. This information is recorded in batch cleaning forms and logbooks, and are, perhaps, of decreased value due to the hard landing. Post-flight: Curation-generated data. The curation handling history of each Genesis sample is documented in a typical astromaterials sample database which captures sample location, physical description and characterization data. Samples have a “shelf life”. Crucial to the preservation of samples is ongoing documentation of the sample environment, initially under curatorial control but is now a separate facility function with requires coordination. PI-generated data. Data on sample characterization and cleaning techniques continues to be generated by sample users [5]. These are often captured in LPSC abstracts, but these “engineering” results often are not publishable as stand-alone papers. We are actively looking for ways to make this information more accessible to users. Ion implants into samples have aided science return and can be shared among investigators. These (and similar) materials should be added to the curatorial collection with appropriate process and characterization data generated externally. Summary: Complete data archives for returned astromaterial samples must be broad in types and formats, and inclusive of environmental monitoring.
Genesis↗
Creep and Environmental Durability of EBC/CMCs Under Imposed Thermal Gradient Conditions
Interest in SiC fiber-reinforced SiC ceramic matrix composite (CMC) environmental barrier coating (EBC) systems for use in high temperature structural applications has prompted the need for characterization of material strength and creep performance under complex aerospace turbine engine environments. Stress-rupture tests have been performed on SiC/SiC composites systems, with varying fiber types and coating schemes to demonstrate material behavior under isothermal conditions. Further testing was conducted under exposure to thermal stress gradients to determine the effect on creep resistance and material durability. In order to understand the associated damage mechanisms, emphasis is placed on experimental techniques as well as implementation of non-destructive evaluation; including electrical resistivity monitoring. The influence of environmental and loading conditions on life-limiting material properties is shown.
Appleby, Matthew↗
Universal Approach to Rapid Amplified Plasmonic Sensing Using Helix Defect Phase Transition Polymers
Abstract Permittivity sensing is a critically important analytical tool for bioscience, environmental, and industrial applications. The response time for commonly used plasmonic permittivity sensors is fundamentally set by the reaction kinetics of chemically adsorbed analytes. In this work, the proposal is to overcome this limit by combining plasmonic sensors with phase transition materials possessing a rapid amplified electrostatic response such as quadrupole moment induced molecular helix reversal. As a proof‐of‐concept, rapid sensing of CO 2 on a phase transition polytetrafluoroethylene substrate and amplification of permittivity response in plasmonic Fabry–Perot sensor is shown. The demonstrated universal approach holds promise for a wide range of applications in fast, real time sensing and monitoring of biological and environmental processes.
Shugayev, Roman↗
Southern Idaho Health & Air Quality: Monitoring Atmospheric Mixing Heights Post-Wildfire Through the Use of NASA Earth Observations
Wildfire smoke has long-lasting impacts on public and environmental health. Currently, agencies that monitor smoke base their decisions on an analysis of how fires burn, the direction the smoke moves from the fire source, and unverified estimates of mixing height. Mixing heights describe the maximum altitude to which a smoke plume rises. Satellite imagery provides more continuous and accurate coverage of mixing heights than current in situ methods. Thus, the team developed a software tool that processes and extracts mixing height observations from Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) Vertical Feature Mask granules. The team partnered with the National Oceanic and Atmospheric Administration’s National Weather Service, the Bureau of Land Management’s National Interagency Fire Center, and the National Park Service’s Fire Management Program Center to analyze historic fire events in southern Idaho. To do so, they used Suomi National Polar-orbiting Partnership (Suomi NPP) Visible Infrared Imaging Radiometer Suite (VIIRS), and Terra and Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) to verify where a CALIPSO pass intersects thermal anomalies and smoke plumes. The software extracts features of relevance from the hdf file of each CALIPSO transect to locate layers of continuous aerosols. The maximum altitude at which the aerosol ends is recorded as the mixing height, along with a matching latitude and longitude. The satellite-derived values can be used to validate past mixing height predictions and evaluate the accuracy and systematic bias of different estimation methods. These results may allow agencies to make better comparisons and subsequent smoke pollution management, prevention, and public health decisions if the spatial and temporal differences between predictions and observations can be resolved.
DEVELOP Project Summary↗
Los Alamos National Laboratory 2022 Annual Site Environmental Report (Rev. 2)
Los Alamos National Laboratory (Laboratory) annual site environmental reports are prepared each year by the Laboratory’s environmental organizations as required by U.S. Department of Energy Order 231.1B, Administrative Change 1, Environment, Safety, and Health Reporting, and Order 458.1, Administrative Change 4, Radiation Protection of the Public and the Environment. The chapters in this report discuss our compliance with environmental laws, regulations, and orders (Chapter 2, Compliance Summary); how we manage the Laboratory’s environmental performance and assure the quality of data from analysis of environmental samples (Chapter 3, Environmental Programs and Analytical Data Quality); how we monitor for air emissions of radioactive materials and for weather conditions (Chapter 4, Air Quality); how we monitor for effects of Laboratory operations on groundwater quality (Chapter 5, Groundwater Protection); how we monitor the levels of chemicals and radionuclides in storm water runoff and sediment (Chapter 6, Watershed Quality); how we monitor for the levels and effects of chemicals and radionuclides in plants, animals, soil, and vegetation (Chapter 7, Ecosystem Health); and finally, what radioactive dose or risk from chemical exposure that members of the public could experience as a result of Laboratory operations (Chapter 8, Public Dose and Risk Assessment).
54 ENVIRONMENTAL SCIENCES↗
ToF-SIMS evaluation of PEG-related mass peaks and applications in PEG detection in cosmetic products
Polyethylene glycols (PEGs) are used in industrial, medical, health care, and personal care applications. The cycling and disposal of synthetic polymers like PEGs pose significant environmental concerns. Detecting and monitoring PEGs in the real world calls for immediate attention. This study unveils the efficacy of time-of-flight secondary ion mass spectrometry (ToF-SIMS) as a reliable approach for precise analysis and identification of reference PEGs and PEGs used in cosmetic products. By comparing SIMS spectra, we show remarkable sensitivity in pinpointing distinctive ion peaks inherent to various PEG compounds. Moreover, the employment of principal component analysis effectively discriminates compositions among different samples. Notably, the application of SIMS two-dimensional image analysis visually portrays the spatial distribution of various PEGs as reference materials. The same is observed in authentic cosmetic products. The application of ToF-SIMS underscores its potential in distinguishing PEGs within intricate environmental context. ToF-SIMS provides an effective solution to studying emerging environmental challenges, offering straightforward sample preparation and superior detection of synthetic organics in mass spectral analysis. These features show that SIMS can serve as a promising alternative for evaluation and assessment of PEGs in terms of the source, emission, and transport of anthropogenic organics.
36 MATERIALS SCIENCE↗
The Baltimore Community Weather Station Network: Filling the Urban Measurement Desert
Quantification and understanding of how heat, rainfall, and air quality vary within cities are needed to identify the area with the worst conditions, develop solutions to extreme weather, and assess the impact of proposed policies. However, neighborhood-level variability is not well quantified because there are few environmental measurement stations within cities. In Baltimore City, a community-based network of weather stations to address this issue has been developed through a partnership between universities, state agencies, and Baltimore residents. The weather stations are hosted by community partners, and the data collected are enabling the mapping of urban weather across the city and the testing of models and proposed mitigation strategies. In addition, the network provides direct community involvement, with resulting benefits of increased community engagement, education, and empowerment. Researchers have an opportunity to democratize the scientific process and ensure that local knowledge and lived experiences of city residents inform future decision-making. The approach could be used as a model for other cities that apply similar monitoring instruments for other environmental exposures.
community↗
Idaho National Laboratory Site Environmental Surveillance Report: First Quarter 2022
This report for the first quarter of 2022 contains results from the INL Site environmental surveillance program’s monitoring of the U.S. Department of Energy’s Idaho National Laboratory (INL) Site’s onsite, boundary and distant location environment, January 1 through March 31, 2022. All sample types (media) and the sampling schedule followed during 2022 are listed in Appendix A. This report contains results for the following sample types: • Air, including particulate air filters, charcoal cartridges, and atmospheric moisture, • Quarterly composites, • Precipitation, • Milk, and • Large game animals
99 GENERAL AND MISCELLANEOUS↗