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DOE OSTI2020

A Critical Review of High Burnup Fuel Fragmentation, Relocation, and Dispersal under Loss-Of-Coolant Accident Conditions

High burnup fuel in excess of ~6268 GWd/MTU has been observed to severely fragment when subjected to temperature transient conditions as in a loss-of-coolant accident. In the event of cladding failure, the severely fragmented fuel can relocate into the balloon region and potentially disperse through the burst opening into the reactorâ€™s primary system. This observation has led to implementation of several independent test programs designed to focus on various aspects of fuel fragmentation, relocation, and dispersal. The purpose of this review is to perform a critical, holistic assessment of fuel fragmentation, relocation, and dispersal under loss-of-coolant conditions to identify data gaps in the experimental data base. Phenomena have been identified and well defined through the various testing programs, and general agreement regarding the governing parameters (temperature, burnup, heating rate, cladding deformation, etc.) has been established. However, there is a significant data gap connecting research to commercial application. Furthermore, previous research attempted to evaluate the problem holistically, but has yet to provide a comprehensive understanding of the problem. Major identified data gaps consist of (1) a comprehensive understanding of pretransient fuel rod conditions (fuel temperature, fuel stress, rod internal pressures, microstructure, etc.), (2) definition of prototypic loss-of-coolant accident conditions (heating rate, fuel temperatures, fuel stress), (3) identification of the differences between nuclear and electrical integral loss-of-coolant accident tests, and connection of fuel rod performance (cladding ballooning, burst opening, potential relocation, fragmentation susceptibility, etc.) to fuel fragmentation, relocation, and dispersal severity. Finally, the content of this manuscript provides a clear path for connecting testing and data acquisition to commercial application by providing concrete means for filling data gaps and prioritized testing regimes.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

NASA NTRS1986

Forbidden coronal iron line emission in the Puppis A shock front: The effect of inhomogeneities

We have obtained CCD images of the shock front at the eastern rim of Puppis A in (Fe X) lambda 6374 and (Fe XIV) lambda 5303 and have compared the optical data to Einstein HRI soft X-ray data. The observed part of the remnant is complex, containing density irregularities. Optical and X-ray data are consistent in showing a nearly flat gradient of ionization behind the shock. To determine conditions in the shock, scans of surface brightness across it in the optical lines were compared to surface brightnesses predicted by idealized Sedov models. We were unable to match both the red and green line scans by a simple, single-component model, and have ascribed the failure to the presence of the density inhomogeneities. Our result has important implications for the determination of SNR shock front models by means of fitting X-ray data with Sedov models.

Teske, Richard G.↗

NASA NTRS1987

Forbidden coronal iron-like emission in the Puppis A shock front - The effect of inhomogeneities

CCD images of the shock front at the eastern rim of Pup A, obtained in the forbidden lines of Fe X (6374 A) and Fe XIV (5303 A), are reported and compared to Einstein high-resolution-image soft X-ray data. The observed part of the remnant is complex, containing density irregularities. Optical and X-ray data are consistent in showing a nearly flat gradient of ionization temperature behind the shock. To determine conditions in the shock, scans of surface brightness across it in the optical lines were compared to surface brightnesses predicted by idealized Sedov models. It was not possible to match both the red and green line scans by a simple, single-component model, and the failure is ascribed to the presence of the density inhomogeneities. This result has important implications for the determination of SNR shock-front models by fitting X-ray data with Sedov models.

Teske, Richard G.↗

NASA NTRS2006

Proteomic Retrieval from Nucleic Acid Depleted Space-Flown Human Cells

Compared to experiments utilizing humans in microgravity, cell-based approaches to questions about subsystems of the human system afford multiple advantages, such as crew safety and the ability to achieve statistical significance. To maximize the science return from flight samples, an optimized method was developed to recover protein from samples depleted of nucleic acid. This technique allows multiple analyses on a single cellular sample and when applied to future cellular investigations could accelerate solutions to significant biomedical barriers to human space exploration. Cell cultures grown in American Fluoroseal bags were treated with an RNA stabilizing agent (RNAlater - Ambion), which enabled both RNA and immunoreactive protein analyses. RNA was purified using an RNAqueous(registered TradeMark) kit (Ambion) and the remaining RNA free supernatant was precipitated with 5% trichloroacetic acid. The precipitate was dissolved in SDS running buffer and tested for protein content using a bicinchoninic acid assay (1) (Sigma). Equal loads of protein were placed on SDS-PAGE gels and either stained with CyproOrange (Amersham) or transferred using Western Blotting techniques (2,3,4). Protein recovered from RNAlater-treated cells and stained with protein stain, was measured using Imagequant volume measurements for rectangles of equal size. BSA treated in this way gave quantitative data over the protein range used (Fig 1). Human renal cortical epithelial (HRCE) cells (5,6,7) grown onboard the International Space Station (ISS) during Increment 3 and in ground control cultures exhibited similar immunoreactivity profiles for antibodies to the Vitamin D receptor (VDR) (Fig 2), the beta isoform of protein kinase C (PKC ) (Fig 3), and glyceraldehyde-3-phosphate dehydrogenase (GAPDH) (Fig 4). Parallel immunohistochemical studies on formalin-fixed flight and ground control cultures also showed positive immunostaining for VDR and other biomarkers (Fig 5). These results are consistent with data from additional antigenic recovery experiments performed on human Mullerian tumor cells cultured in microgravity (8).

Hammond, D. K.↗

DOE OSTI2024

A Review of the Resuspension of Radioactively Contaminated Particles by Vehicle and Pedestrian Traffic—Current Theory, Practice, Gaps, and Needs

Here, the resuspension of radioactively contaminated particles in a built environment, such as from urban surfaces like foliage, building exteriors, and roadways, is described empirically by current plume and dosimetry models used for hazard assessment and long-term risk purposes. When applying these models to radiological contamination emergencies affecting urban areas, the accuracy of the results for recent contamination deposition is impacted in two main ways. First, the data supporting the underlying resuspension equations was acquired for open, quiescent conditions with no vehicle traffic or human activities, so it is not necessarily representative of the urban environment. Second, mechanical disturbance by winds in urban canyons and during emergency operations caused by vehicle traffic and human activities are not directly considered by the equations. Accordingly, plume and dosimetry models allow the user to input certain compensating values, but the models do not necessarily supply users instructions on what values to use. This manuscript reviews the available literature to comprehensively and consistently pool data for resuspension due to mechanically induced resuspension applicable to urban contamination. Because there are few studies that directly measured radioactive resuspension due to vehicles and pedestrians, this review novelly draws on a range of other studies involving non-radioactive particles, ranging from outdoor air pollution emissions to indoor allergen transport. The results lead to tabulated, recommended values for specific conditions in the emergency phase to help users of plume and dosimetry models maintain the conservativeness needed to properly capture the potential radiation dose posed by mechanically induced resuspension. These values are of benefit to model users until better data are available. The results also suggest the types of data that may result in improved plume and dose modeling.

61 RADIATION PROTECTION AND DOSIMETRY↗

DOE OSTI2020

Photoproduction of η mesons off the proton for 1.2 < E γ < 4.7GeV using CLAS at Jefferson Laboratory

Photoproduction cross sections are reported for the reaction $\gamma p\to p\eta$ using energy-tagged photons and the CLAS spectrometer at Jefferson Laboratory. The $\eta$ mesons are detected in their dominant charged decay mode, $\eta\to \pi^+\pi^-\pi^0$, and results on differential cross sections are presented for incident photon energies between 1.2 and 4.7 GeV. These new $\eta$ photoproduction data are consistent with earlier CLAS results but extend the energy range beyond the nucleon resonance region into the Regge regime. The normalized angular distributions are also compared with the experimental results from several other experiments, and with predictions of $\eta$ MAID\,2018 and the latest solution of the Bonn-Gatchina coupled-channel analysis. Differential cross sections $d\sigma/dt$ are presented for incident photon energies $E_\gamma > 2.9$ GeV ($W > 2.5$ GeV), and compared with predictions which are based on Regge trajectories exchange in the $t$-channel (Regge models). Overall, the data confirm the expected dominance of $\rho$, $\omega$ vector-meson exchange in an analysis by the Joint Physics Analysis Center.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

NASA NTRSDate not supplied

Effects of Mild Hypobaric Hypoxia on Visual Field Impairment

INTRODUCTION: The primary objective of the Exploration Atmosphere (EA) study is to validate a new prebreathe protocol necessary before exposure to a suited hypobaric environment during extravehicular activity (EVA) from a habitat ‘exploration atmosphere’ of 56.5kPa (8.2 psia), 34% O2, 66% N2. Prebreathe protocols must be time and resource efficient while also controlling Decompression Sickness (DCS) risk to within acceptable limits. The habitat hypobaric exploration atmosphere also results in a mildly hypoxic environment (piO2 = 128mmHg). As a secondary objective of the EA study, we characterized the effects of 11-day exposure to a mild hypobaric hypoxic environment on visual performance. METHODS: Two, 11-day hypobaric chamber tests were performed (EA-1and EA-2, n=8 each) in NASA’s 20-foot chamber at Johnson Space Center where subjects lived in the exploration atmosphere. Subjects also underwent simulated 6-hour EVAs at 85% O2 and 29.6 kPa during EVA on days 3, 5, 7, 9, and 11. Visual acuity (VA), a measure of spatial resolution, and contrast sensitivity (CS), a measure of ability to distinguish ever finer increments of brightness, were assessed on non-EVA days by using gapped Landolt C testing. The luminance was controlled by using a booth, a light monitor, and a lighting rheostat. EA-1 data had revealed problems in lighting control impacting consistency of the data. Procedures were subsequently updated for the EA-2 test. RESULTS: EA-1 data revealed large variance and data recording errors and was removed from the analysis. One participant left the study at Test Day 3 during EA-2. EA-2 ANOVA results showed CS (mean change=0.010 logCSWeber) and VA (mean change, -0.016 logMAR) between pre-test and 11-day test phases; however, neither VA nor CS changes were statistically significant. There were non-statistically significant declines in VA across test phases. DISCUSSION: Overall, visual field performance did not exhibit clinically significant changes (3 lines or greater change in LogMar chart) during exposure to the mild hypoxic exploration atmosphere environment compared to pre-test baseline. The consistency and stability of VA data during EA-2 suggests that the mild hypobaric hypoxic environment did not cause clinically significant negative impacts to participants’ visual field performance.

Visual Acuity↗

NASA NTRSDate not supplied

Effects of Mild Hypobaric Hypoxia on Visual Field Impairment

Visual Acuity↗

NASA NTRS2011

Accessing Recent Trend of Land Surface Temperature from Satellite Observations

Land surface temperature (Ts) is an important element to measure the state of terrestrial ecosystems and to study surface energy budgets. In support of the land cover/land use change-related international program MAIRS (Monsoon Asia Integrated Regional Study), we have collected global monthly Ts measured by MODIS since the beginning of the missions. The MODIS Ts time series have approximately 11 years of data from Terra since 2000 and approximately 9 years of data from Aqua since 2002, which makes possible to study the recent climate, such as trend. In this study, monthly climatology from two platforms are calculated and compared with that from AIRS. The spatial patterns of Ts trends are accessed, focusing on the Eurasia region. Furthermore, MODIS Ts trends are compared with those from AIRS and NASA's atmospheric assimilation model, MERRA (Modern Era Retrospective-analysis for Research and Applications). The preliminary results indicate that the recent 8-year Ts trend shows an oscillation-type spatial variation over Eurasia. The pattern is consistent for data from MODIS, AIRS, and MERRA, with the positive center over Eastern Europe, and the negative center over Central Siberia. The calculated climatology and anomaly of MODIS Ts will be integrated into the online visualization system, Giovanni, at NASA GES DISC for easy use by scientists and general public.

Shen, Suhung↗

NASA NTRS1995

Soft x-ray properties of the binary millisecond pulsar J0437-4715

We obtained a light curve for the 5.75 ms pulsar J0437-4715 in the 65-120 A range with 0.5 ms time resolution using the Deep Survey instrument on the EUVE satellite. The single-peaked profile has a pulsed fraction of 0. 27 +/- 0.05, similar to the ROSAT data in the overlapping energy band. A combined analysis of the EUVE and ROSAT data is consistent with a power-law spectrum of energy index alpha = 1.2-1.5, intervening column density NH = (5-8) x 10(exp 19)/sq cm, and luminosity 5.0 x 10(exp 30) ergs/s in the 0.1-2. 4 keV band. We also use a bright EUVE/ROSAT source only 4.3 deg from the pulsar, the Seyfert galaxy RX J0437.4-4711 (= EUVE J0437-471 = lES 0435-472), to obtain an independent upper limit on the intervening absorption to the pulsar, NH less than 1.2 x 10(exp 20)/sq cm. Although a blackbody spectrum fails to fit the ROSAT data, two-component spectral fits to the combined EUVE/ROSAT data are used to limit the temperatures and surface areas of thermal emission that might make partial contributions to the flux. A hot polar cap of radius 50-600 m and temperature (1.0-3.3) x 10(exp 6) K could be present. Alternatively, a larger region with T = (4-12) x 10(exp 5) K and area less than 200 sq km, might contribute most of the EUVE and soft X-ray flux, but only if a hotter component were present as well. Any of these temperatures would require some mechanism(s) of surface reheating to be operating in this old pulsar, the most plausible being the impact of accelerated electrons and positrons onto the polar caps. The kinematically corrected spin-down power of PSR J0437-4715 is only 4 x 10(exp 33) ergs/s, which is an order of magnitude less than that of the lowest-luminosity gamma-ray pulsars Geminga and PSR B1055-52. The absence of high-energy gamma-rays from PSR J0437-4715 might signify an inefficient or dead outer gap accelerator, which in turn accounts for the lack of a more luminous reheated surface such as those intermediate-age gamma-ray pulsars may have.

Halpern, Jules P.↗

NASA NTRS2001

Soft X-Ray Properties of the Binary Millisecond Pulsar J0437-4715

We obtained a light curve for the 5.75 ms pulsar J0437-4715 in the 65-120 A range with 0.5 ms time resolution using the Deep Survey instrument on the EUVE satellite. The single-peaked profile has a pulsed fraction of 0.27 +/- 0.05, similar to the ROSAT data in the overlapping energy band. A combined analysis of the EUVE and ROSAT data is consistent with a power-law spectrum of energy index alpha = 1.2 - 1.5, intervening column density N(sub H) = (5 - 8) x 10(exp 19)/sq cm, and luminosity 5.0 x 10(exp 30) ergs/s in the 0.1 - 2.4 keV band. We also use a bright EUVE/ROSAT source only 4.2 min. from the pulsar, the Seyfert galaxy RX J0437.4-4711 (= EUVE J0437-471 = IES 0435-472), to obtain an independent upper limit on the intervening absorption to the pulsar, N(sub H) less than 1.2 x 10(exp 20)/sq cm. Although a blackbody spectrum fails to fit the ROSAT data, two-component spectral fits to the combined EUVE/ROSAT data are used to limit the temperatures and surface areas of thermal emission that might make partial contributions to the flux. A hot polar cap of radius 50 - 600 m and temperature (1.0 - 3.3) x 10(exp 6) K could be present. Alternatively, a larger region with T = (4 - 12) x 10(exp 5) K and area less than 200 sq km, might contribute most of the EUVE and soft X-ray flux, but only if a hotter component were present as well. Any of these temperatures would require some mechanism(s) of surface reheating to be operating in this old pulsar, the most plausible being the impact of accelerated electrons and positrons onto the polar caps. The kinematically corrected spin-down power of PSR J0437-4715 is only 4 x 10(exp 33) ergs/s, which is an order of magnitude less than that of the lowest-luminosity gamma-ray pulsars Geminga and PSR B1055-52. The absence of high-energy gamma-rays from PSR J0437-4715 might signify an inefficient or dead outer gap accelerator, which in turn accounts for the lack of a more luminous reheated surface such as those intermediate-age gamma-ray pulsars may have.

Halpern, Jules P.↗

DOE OSTI2024

Phase Identification in Synchrotron X-ray Diffraction Patterns of Ti–6Al–4V Using Computer Vision and Deep Learning

X-ray diffraction patterns contain information about the atomistic structure and microstructure (defect population) of materials, extracting detailed information from diffraction patterns is complex, demanding and relies on prior knowledge. Here, we hypothesize that deep-learning techniques can help to perform an effective and accurate analysis with high throughput rates. To demonstrate this concept, we applied a novel deep learning framework to determine the evolution of the β-phase volume fraction in a Ti–6Al–4V alloy during heat-treatment from video sequences of 2D diffraction patterns recorded in transmission and with highly monochromatic radiation in a synchrotron beamline. In particular, we studied the impact of network design on prediction reliability and computational performance. Networks of different architectures were trained using 3008 experimental 2D patterns. A well-tuned model was found to reproduce the phase fractions of another experimental data set, consisting of 1100 diffraction patterns, with a mean-square error as small as 2.6 x 10 -4 . The average prediction error of β-phase volume fraction was within 1.6 x 10 -2 (in each diffraction pattern) of the values obtained by conventional methods. Our work demonstrates that convolutional neural networks can evaluate high energy X-ray diffraction patterns with a remarkable level of reliability. Furthermore, it demonstrates the significance of network design on the reliability of predictions and computational performance. The most complex models do not necessarily result in highest accuracy and may even fail to learn from the data.

36 MATERIALS SCIENCE↗

NASA NTRS1988

Does vector-free gravity simulate microgravity? Functional and morphologic attributes of clinorotated nerve and muscle grown in cell culture

Cocultured Xenopus neurons and myocytes were subjected to non-vectorial gravity by clinostat rotation to determine if microgravity, during space flights, may affect cell development and communications. Clinorotated cells showed changes consistent with the hypothesis that cell differentiation, in microgravity, is altered by interference with cytoskeleton-related mechanisms. We found: increases in the myocyte and its nuclear area, "fragmentation" of nucleoli, appearance of neuritic "aneurysms", decreased growth in the presence of "trophic" factors, and decreased yolk utilization. The effects were most notable at 1-10 rpm and depended on the onset and duration of rotation. Some parameters returned to near control values within 48 hrs after cessation of rotation. Cells from cultures rotated at higher speeds (>50 rpm) appeared comparable to controls. Compensation by centrifugal forces may account for this finding. Our data are consistent, in principle, with effects on other, flighted cells and suggest that "vector-free" gravity may simulate certain aspects of microgravity. The distribution of acetylcholine receptor aggregates, on myocytes, was also altered. This indicates that brain development, in microgravity, may also be affected.

NASA Discipline Cell Biology↗

NASA NTRS2006

Low-Complexity Adaptive Lossless Compression of Hyperspectral Imagery

A low-complexity, adaptive predictive technique for lossless compression of hyperspectral imagery is described. This technique is designed to be suitable for implementation in hardware such as a field programmable gate array (FPGA); such an implementation could be used for high-speed compression of hyperspectral imagery onboard a spacecraft. The predictive step of the technique makes use of the sign algorithm, which is a relative of the least mean square (LMS) algorithm from the field of low-complexity adaptive filtering. The compressed data stream consists of prediction residuals encoded using a method similar to that of the JPEG-LS lossless image compression standard. Compression results are presented for several datasets including some raw Airborne Visible/ Infrared Imaging Spectrometer (AVIRIS) datasets and raw Atmospheric Infrared Sounder (AIRS) datasets. The compression effectiveness obtained with the technique is competitive with that of the best of previously described techniques with similar complexity.

lossless data compression↗

DOE OSTI2023

JGI Plant Gene Atlas: an updateable transcriptome resource to improve functional gene descriptions across the plant kingdom

Abstract Gene functional descriptions offer a crucial line of evidence for candidate genes underlying trait variation. Conversely, plant responses to environmental cues represent important resources to decipher gene function and subsequently provide molecular targets for plant improvement through gene editing. However, biological roles of large proportions of genes across the plant phylogeny are poorly annotated. Here we describe the Joint Genome Institute (JGI) Plant Gene Atlas, an updateable data resource consisting of transcript abundance assays spanning 18 diverse species. To integrate across these diverse genotypes, we analyzed expression profiles, built gene clusters that exhibited tissue/condition specific expression, and tested for transcriptional response to environmental queues. We discovered extensive phylogenetically constrained and condition-specific expression profiles for genes without any previously documented functional annotation. Such conserved expression patterns and tightly co-expressed gene clusters let us assign expression derived additional biological information to 64 495 genes with otherwise unknown functions. The ever-expanding Gene Atlas resource is available at JGI Plant Gene Atlas (https://plantgeneatlas.jgi.doe.gov) and Phytozome (https://phytozome.jgi.doe.gov/), providing bulk access to data and user-specified queries of gene sets. Combined, these web interfaces let users access differentially expressed genes, track orthologs across the Gene Atlas plants, graphically represent co-expressed genes, and visualize gene ontology and pathway enrichments.

59 BASIC BIOLOGICAL SCIENCES↗

NASA NTRS1983

Use of VAS multispectral data for sea surface temperature determination

The Visible Infrared Spin Scan Radiometer Atmospheric Sounder (VAS) is a radiometer possessing eight visible channel detectors and six thermal detectors that sense infrared radiation in 12 spectral bands. Housed in the GOES satellite, VAS spins in a west to east direction at 100 rpm and achieves spatial coverage at resolutions of 1 km in the visible and 7 or 14 km in the infrared by stepping a scan mirror in a north to south direction. Designed for multipurpose applications, the VAS can be operated in two different modes: (1) a multi-spectral imaging (MSI) mode, and (2) a dwell sounding (DS) mode. The MSI mode of operation is used for sea surface temperature (SST) determination. Currently, a full-disk MSI image for SST determination is received every hour, 18 hours a day during weekdays. This MSI mode of operation for SST consists of data obtained from wavelengths centered at 3.9 microns (channel 12), 11.6 microns (channel 8), and 12.6 microns (channel 7) as well as visible data.

Bates, J.↗

NASA NTRS1989

Estimation of velocity perturbations in satellite fragmentation events

The magnitude, variance and directionality of the velocity perturbations of the fragments of a satellite can shed valuable information regarding the nature and intensity of the fragmentation. Up until now, the only method used to calculate the three orthogonal components of the velocity change consisted of inverting the process of evaluating the changes in the orbital elements of the fragments due to velocity perturbing forces. But the traditional method failed in five different cases: (1) when the parent satellite's orbit was circular; (2) and (3) when the true anomaly of the parent was either 0 deg or 180 deg; and (4) and (5) when the argument of latitude of the parent was 90 deg or 270 deg. Described here is a new method of calculating the velocity perturbations which is free from the shortcomings of the traditional method and could be used in all occasions, provided the fragmentation data and the orbital elements data are consistent with one another.

Tan, Arjun↗

NASA NTRS1988

Infrared Measurements of Atmospheric Gases Above Mauna Loa, Hawaii, in February 1987

Infrared solar absorption spectra recorded at 0.02/ cm resolution from the National Oceanic and Atmospheric Administration (NOAA) Geophysical Monitoring for Climate Change (GMCC) program station at Mauna Loa, Hawaii (latitude 19.5 deg N, longitude 155.6 deg W, elevation 3.40 km), in February 1997 have been analyzed to determine simultaneous total vertical column amounts for 13 atmospheric gases. Average tropospheric concentrations of CO2, N2O, CH4, and CHCIF2 and the daytime diurnal variations or the total columns of NO and NO2 have also been inferred. The retrieved total columns (in molecules /sq cm) of the nondiurnally varying gases are 1.6 +/- 0.2 x 10(exp 15) for HCl, 5.9 +/- 1.2 x 10(exp 15) for HNO3, 2.0 +/- 0.2 x 10(exp 21) for H2O16, 4.4 +/- 0.7 x 10(exp 18) for H2O18, 2.7 +/- 0.1 x 10(exp 17) for HDO, 2.3 +/- 0.2 x 10(exp 19) for CH4, 5.0 +/- 0.5 x 10(exp 21) for CO2, 6.7 +/- 0.8 x 10(exp 18) for O3, 4.3 +/- 0.4 x 10(exp 18) for N2O, 1.0 +/- 0.2 x 10(exp 16) for C2H6, and 9.7 +/- 2.5 x 10(exp 14) for CHClF2. We compare the total column measurements of HCl and HNO3 with previously reported ground-based, aircraft, and satellite measurements. The results for HCl are or particular interest because of the expected temporal increase in the concentration of this gas in the stratosphere. However, systematic differences among stratospheric HCl total column measurements from 1978 to 1980 and the absence of observations of free tropospheric HCl above Mauna Loa make it impossible to obtain a reliable estimate of the trend in the total burden of HCl. The measured HNO3 total column is consistent with aircraft measurements from approx. 12 km altitude. The O3 total column deduced from the IR spectra agrees with correlative Mauna Loa Umkehr measurements within the estimated error limits. The column-averaged D/H ratio of water vapor is (68 +/- 9) x- 10(exp -6), which is 0.44 +/- 0.06 times the reference value of 155.76 x 10(exp -6) for standard mean ocean water (SMOW). This large depletion in the D content of water vapor is similar to published measurements of the upper troposphere and lower stratosphere. Average tropospheric concentrations deduced for CO2, N2O, and CH4 are in good agreement with correlative NOAA GMCC surface data, indicating consistency between the measurement techniques for determining tropospheric volume mixing ratios. Results of the present study indicate that Mauna Loa is a favorable site for infrared monitoring of atmospheric gases. The site is particularly favorable for monitoring the tropospheric volume mixing ratios of long-lived gases, since the high altitude of the tropopause reduces corrections required to account for the decrease in volume mixing ratio in the stratosphere.

Rinsland, C. P.↗