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At least 991 records · Page 55

Updated U.S. Low-Temperature Heating and Cooling Demand by County and Sector

This dataset includes U.S. low-temperature heating and cooling demand at the county level in major end-use sectors: residential, commercial, manufacturing, agricultural, and data centers. Census division-level end-use energy consumption, expenditure, and commissioned power database were dis-aggregated to the county level. The county-level database was incorporated with climate zone, numbers of housing units and farms, farm size, and coefficient of performance (COP) for heating and cooling demand analysis. This dataset also includes a paper containing a full explanation of the methodologies used and maps. Residential data were updated from the latest Residential Energy Consumption Survey (RECS) dataset (2015) using 2020 census data. Commercial data were baselined off the latest Commercial Building Energy Consumption Survey (CBECS) dataset (2012). Manufacturing data were baselined off the latest Manufacturing Energy Consumption Survey (MECS) dataset (2021).

15 GEOTHERMAL ENERGY↗

Data driven discovery and quantification of hyperspectral leaf reflectance phenotypes across a maize diversity panel

Abstract Estimates of plant traits derived from hyperspectral reflectance data have the potential to efficiently substitute for traits, which are time or labor intensive to manually score. Typical workflows for estimating plant traits from hyperspectral reflectance data employ supervised classification models that can require substantial ground truth datasets for training. We explore the potential of an unsupervised approach, autoencoders, to extract meaningful traits from plant hyperspectral reflectance data using measurements of the reflectance of 2151 individual wavelengths of light from the leaves of maize ( Zea mays ) plants harvested from 1658 field plots in a replicated field trial. A subset of autoencoder‐derived variables exhibited significant repeatability, indicating that a substantial proportion of the total variance in these variables was explained by difference between maize genotypes, while other autoencoder variables appear to capture variation resulting from changes in leaf reflectance between different batches of data collection. Several of the repeatable latent variables were significantly correlated with other traits scored from the same maize field experiment, including one autoencoder‐derived latent variable (LV8) that predicted plant chlorophyll content modestly better than a supervised model trained on the same data. In at least one case, genome‐wide association study hits for variation in autoencoder‐derived variables were proximal to genes with known or plausible links to leaf phenotypes expected to alter hyperspectral reflectance. In aggregate, these results suggest that an unsupervised, autoencoder‐based approach can identify meaningful and genetically controlled variation in high‐dimensional, high‐throughput phenotyping data and link identified variables back to known plant traits of interest.

Tross, Michael C.↗

The Distributed Wind Cost Taxonomy

To date, there has been no standard method or tool to analyze the installed and operational costs for distributed wind turbine systems. This report describes the development of a classification system, or taxonomy, for distributed wind turbine project costs. The taxonomy establishes a framework to help collect, sort, and compare distributed wind cost data that mirrors how the industry categorizes information. The taxonomy organizes costs so they can be aggregated from installers, developers, vendors, and other sources without losing cost details. Developing a peer-reviewed taxonomy is valuable to industry stakeholders because a common understanding the details of distributed wind turbine costs and balance of station costs is a first step to identifying potential high-value cost reduction opportunities. Addressing cost reduction potential can help increase distributed wind's competitiveness and propel the U.S. distributed wind industry forward. The taxonomy can also be used to perform cost comparisons between technologies and track trends for distributed wind industry costs in the future. As an initial application and piloting of the taxonomy, preliminary cost data were collected for projects of different sizes and from different regions across the contiguous United States. Following the methods described in this report, these data are placed into the established cost categories.

17 WIND ENERGY↗

CMPLE: Correlation Modeling to Decode Photosynthesis Using the Minorize–Maximize Algorithm

In plant genomic experiments, correlations among various biological traits (phenotypes) give new insights into how genetic diversity may have tuned biological processes to enhance fitness under diverse conditions. Consequently, knowing how the correlations are affected by genetic (G) and environmental (E) factors helps develop climate-resilient plants. However, the current literature lacks any method for assessing the effect of predictors on pairwise correlations among multiple phenotypes together with easily interpretable model parameters. To address this need, we propose to model pairwise correlations directly in terms of G and E and develop a computationally efficient inference procedure. Two major novelties in our methodology are (1) the use of a composite pairwise likelihood method to avoid the positive definiteness restriction on the correlation matrix and (2) the use of a novel Minorize–Maximize (MM) algorithm for the efficient estimation of a large number of parameters. The proposed method shows excellent numerical performance on synthetic datasets. Here, the analysis of the motivating data on cowpea reveals that the rates of solar energy storage by photosynthesis (the aggregate trait) are differentially affected by different genetic loci through two distinct processes: “photoinhibition” which results from photodamage caused by excess light, and “photoprotection” which protects plants from photodamage but also results in energy loss.

Correlation modeling↗

Combinatorial appraisal of transition states for in situ pair distribution function analysis

In situ total scattering measurements are increasingly utilized to follow atomic and nanoscale structural details of phase transitions and other transient processes in materials. This contribution presents an automated method and associated tool set to analyze series of diffraction and pair distribution function data with a linear combination of end-member states. It is demonstrated that the combinatorial appraisal of transition states (CATS) software tracks phase changes, relative phase fractions and length scales of interest in experimental data series. Here it is further demonstrated, using a series of local structure data simulations, that the misfit of such a model can reveal details of phase aggregation and growth related to the pair distribution function's sensitivity to interphase correlations. CATS may be applied to quantitative evaluation of many transient processes, including amorphous-to-crystalline phase transitions, the evolution of solid-solution behaviors, the precipitation and growth of aggregates, and other atomic to nanoscale details of crystallization and phase transformation phenomena.

36 MATERIALS SCIENCE↗

Localization of polyhydroxybutyrate in sugarcane using Fourier-transform infrared microspectroscopy and multivariate imaging

Background: Slow-degrading, fossil fuel-derived plastics can have deleterious effects on the environment, especially marine ecosystems. The production of bio-based, biodegradable plastics from or in plants can assist in supplanting those manufactured using fossil fuels. Polyhydroxybutyrate (PHB) is one such biodegradable polyester that has been evaluated as a possible candidate for relinquishing the use of environmentally harmful plastics. Results: PHB, possessing similar properties to polyesters produced from non-renewable sources, has been previously engineered in sugarcane, thereby creating a high-value co-product in addition to the high biomass yield. This manuscript illustrates the coupling of a Fourier-transform infrared microspectrometer, equipped with a focal plane array (FPA) detector, with multivariate imaging to successfully identify and localize PHB aggregates. Principal component analysis imaging facilitated the mining of the abundant quantity of spectral data acquired using the FPA for distinct PHB vibrational modes. PHB was measured in the chloroplasts of mesophyll and bundle sheath cells, acquiescent with previously evaluated plant samples. Conclusion: This study demonstrates the power of IR microspectroscopy to rapidly image plant sections to provide a snapshot of the chemical composition of the cell. While PHB was localized in sugarcane, this method is readily transferable to other value-added co-products in different plants.

36 MATERIALS SCIENCE↗

Status and Trends in the U.S. Voluntary Green Power Market (2013 Data)

Voluntary green power markets are those in which consumers and institutions voluntarily purchase renewable energy to match their electricity needs. This report surveys utilities, competitive suppliers, renewable energy certificate (REC) marketers, and, for the first time, the community choice aggregation market. This report finds that the voluntary market totaled 62 million megawatt-hours in 2013. Approximately 5.4 million customers are purchasing green power. This report presents data and analysis on voluntary market sales and customer participation, products and premiums, green pricing marketing, and administrative expenses. The report also details trends in REC tracking systems, REC pricing in voluntary and compliance markets, community and crowd-funded solar, and interest in renewable energy by the information and communication technologies sector.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

A Retrospective Analysis of the Benefits and Impacts of U.S. Renewable Portfolio Standards

This is the second in a series of reports exploring the costs, benefits, and other impacts of state renewable portfolio standards (RPS), both retrospectively and prospectively. This report focuses on the benefits and impacts of all state RPS programs, in aggregate, for the year 2013 (the most-recent year for which the requisite data were available). Relying on a well-vetted set of methods, the study evaluates a number of important benefits and impacts in both physical and monetary terms, where possible, and characterizes key uncertainties. The prior study in this series focused on historical RPS compliance costs, and future work will evaluate costs, benefits, and other impacts of RPS policies prospectively.

54 ENVIRONMENTAL SCIENCES↗

Multi-Angle Snowflake Camera Value-Added Product

The Multi-Angle Snowflake Camera (MASC) addresses a need for high-resolution multi-angle imaging of hydrometeors in freefall with simultaneous measurement of fallspeed. As illustrated in Figure 1, the MASC consists of three cameras, separated by 36°, each pointing at an identical focal point approximately 10 cm away. Located immediately above each camera, a light aims directly at the center of depth of field for its corresponding camera. The focal point at which the cameras are aimed lies within a ring through which hydrometeors fall. The ring houses a system of near-infrared emitter-detector pairs, arranged in two arrays separated vertically by 32 mm. When hydrometeors pass through the lower array, they simultaneously trigger all cameras and lights. Fallspeed is calculated from the time it takes to traverse the distance between the upper and lower triggering arrays. The trigger electronics filter out ambient light fluctuations associated with varying sunlight and shadows. The microprocessor onboard the MASC controls the camera system and communicates with the personal computer (PC). The image data is sent via FireWire 800 line, and fallspeed (and camera control) is sent via a Universal Serial Bus (USB) line that relies on RS232-over-USB serial conversion. See Table 1 for specific details on the MASC located at the Oliktok Point Mobile Facility on the North Slope of Alaska. The value-added product (VAP) detailed in this documentation analyzes the raw data (Section 2.0) using Python: images rely on OpenCV image processing library and derived aggregated statistics rely on some clever averaging. See Sections 4.1 and 4.2 for more details on what variables are computed.

47 OTHER INSTRUMENTATION↗

Organic Speciation and Interactions in ALSEP. One Step Partitioning Process of MinorActinides, Lanthanides, and Fission Products

Research conducted in this project focused on speciation characterization of the ALSEP extraction system (similar to the TALSPEAK-like application) which addresses recovery of minor actinides and lanthanides from PUREX raffinate. The ALSEP (Actinide-Lanthanide Separation) system proposes a trivalent minor actinide/lanthanide group extraction followed by a selective actinide strip to effectively partition minor actinides, lanthanides, and other fission products. The group extraction is achieved by a mixed organic solvent, combining acidic and neutral extracting ligands. The objective of this work is investigation the interactions of the acidic and neutral ligands with each other in the extraction organic solvent and with desired metals. Four combinations of a cation-exchange ligand (either HDEHP or HEH[EHP]) and a neutral solvating ligand (either TODGA or T2EHDGA) in n-dodecane were studied. Interligand dimers in these combinations were investigated with NMR and FTIR, the strongest interaction was observed for HDEHP+TODGA and weakest for T2EHDGA+HEH[EHP]. Complexes of the trivalent Am and lanthanides Nd, Eu, Ho, Pr in these binary ligand mixtures were probed with spectroscopic (UV–vis, time-resolved fluorescence, XAFS and SAXS-spectroscopies) and extraction (Job’s plot, slope analysis) methods; co-extracted water and nitric acid were analyzed by titration methods. Comparison of the collected spectra showed significant shifting for both DGA ligands with HDEHP, while both combinations of HEH[EHP]+DGA displayed much smaller spectral changes. Data were modeled with HypSpec program, and stability constants for extracted complexes were calculated. Aggregation in these systems were studied by SAXS (small-angle X-ray scattering) spectroscopy and interfacial tension, size of aggregates were measured. Two PhD students graduated (2017, 2018) and one student continues her PhD study.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

SoDaH: the SOils DAta Harmonization database, an open-source synthesis of soil data from research networks, version 1.0

Data collected from research networks present opportunities to test theories and develop models about factors responsible for the long-term persistence and vulnerability of soil organic matter (SOM). Synthesizing datasets collected by different research networks presents opportunities to expand the ecological gradients and scientific breadth of information available for inquiry. Synthesizing these data is challenging, especially considering the legacy of soil data that have already been collected and an expansion of new network science initiatives. To facilitate this effort, here we present the SOils DAta Harmonization database (SoDaH; https://lter.github.io/som-website, last access: 22 December 2020), a flexible database designed to harmonize diverse SOM datasets from multiple research networks. SoDaH is built on several network science efforts in the United States, but the tools built for SoDaH aim to provide an open-access resource to facilitate synthesis of soil carbon data. Moreover, SoDaH allows for individual locations to contribute results from experimental manipulations, repeated measurements from long-term studies, and local- to regional-scale gradients across ecosystems or landscapes. Finally, we also provide data visualization and analysis tools that can be used to query and analyze the aggregated database. The SoDaH v1.0 dataset is archived and available at https://doi.org/10.6073/pasta/9733f6b6d2ffd12bf126dc36a763e0b4 (Wieder et al., 2020).

54 ENVIRONMENTAL SCIENCES↗

Elemental abundances in stone meteorites.

Measurement of abundances of Na, Al, Sc, Cr, Mn, Fe, Co, and Cu by instrumental neutron activation analyses of 103 chondrites and 17 achondrites. Various sources of error in the method, including sampling errors, are discussed in detail. Examination of the patterns of coherence of the elements determined suggests the presence of effects of fractionation during condensation from the solar nebula of matter parental to chondrites. Such effects seem to be exhibited both in the abundances of lithophilic elements, perhaps being related to varied temperatures of accretion and in the abundances of those elements which would be affected by metal-silicate fractionation in the solar nebula. Atomic abundances relative to Si vary little in carbonaceous chondrites, suggesting that efficient mixing processes operated on these meteorites prior to or during their formation. It is suggested that, at present, no single class of carbonaceous chondrites is clearly more primitive than another. Carbonaceous and unequilibrated ordinary chondrites may represent aggregates of material accreted from the solar nebula at relatively low temperatures. The present data support a model of equilibration and minor mobilization of nonvolatile elements within small domains of chondrites after accretion. Such a model would be consistent with the petrologic types of Van Schmus and Wood (1967).

Schmitt, R. A.↗

EarthSat spring wheat yield system test 1975

The results of an operational test of the EarthSat System during the period 1 June - 30 August 1975 over the spring wheat regions of North Dakota, South Dakota, and Minnesota are presented. The errors associated with each sub-element of the system during the operational test and the sensitivity of the complete system and each major functional sub-element of the system to the observed errors were evaluated. Evaluations and recommendations for future operational users of the system include: (1) changes in various system sub-elements, (2) changes in the yield model to affect improved accuracy, (3) changes in the number of geobased cells needed to develop an accurate aggregated yield estimate, (4) changes associated with the implementation of future operational satellites and data processing systems, and (5) detailed system documentation.

Source record↗

The chaotic solar nebula - Evidence for episodic condensation in several distinct zones

Abundances of rare earth elements in Allende inclusions are considered along with the rim sequence on coarse-grained chondrules. It is found that in at least several zones the nebula went through episodes of condensation and gas/grain separation. Four separate zones are required to make the two types of fine-grained aggregates and the two types of coarse-grained chondrules. Other types of inclusions in Allende, such as the olivine aggregates, may well require additional condensation zones. All of these conclusions are based on data from one meteorite. Although the details of the gas/grain separation mechanism in these zones is not well understood, it is clear that a single monotonic-cooling condensation sequence followed by isolation of grains from gas cannot account for the observations.

Boynton, W. V.↗

Scaling water and energy fluxes in climate systems - Three land-atmospheric modeling experiments

Three numerical experiments that investigate the scaling of land-surface processes - either of the inputs or parameters - are reported, and the aggregated processes are compared to the spatially variable case. The first is the aggregation of the hydrologic response in a catchment due to rainfall during a storm event and due to evaporative demands during interstorm periods. The second is the spatial and temporal aggregation of latent heat fluxes, as calculated from SiB. The third is the aggregation of remotely sensed land vegetation and latent and sensible heat fluxes using TM data from the FIFE experiment of 1987 in Kansas. In all three experiments it was found that the surface fluxes and land characteristics can be scaled, and that macroscale models based on effective parameters are sufficient to account for the small-scale heterogeneities investigated.

Wood, Eric F.↗

Dynamic modeling of orographically induced precipitation

Local orography governs the triggering of cloud formation and the enhancement of processes such as condensation and hydrometeor nucleation and growth in mountainous regions. Intense, lengthy precipitation events are typical upwind of the topographic divide, with sharply decreasing magnitude and duration on the lee side. Differences in mean annual precipitation of several hundred percent between windward slopes of orographic barriers and adjacent valleys or lee side slopes are not unusual. Because much of the streamflow in areas such as the western United States is derived from mountainous areas that are remote and often poorly instrumented, modeling of orographic precipitation has important implications for water resources management. Models of orographically induced precipitation differ by their treatment of atmospheric dynamics and by the extent to which they rely on bulk parameterization of cloud and precipitation physics. Adiabatic ascent and a direct proportionality between efficiency and orographically magnified updrafts are the most frequent assumptions in orographic precipitation modeling. Space-time discretization (i.e., resolution) is a major issue because of the high spatial variability of orographic precipitation. For a specific storm, relative errors as large as 50 to 100% are common in the forecast/hindcast of precipitation intensity and can be even larger in the case of catastrophic storms. When monthly or seasonal timescales are used to evaluate model performance, the magnitude of such errors decreases dramatically, reaching values as low as 10 to 15%. Current research is focusing on the development of data assimilation techniques to incorporate radar and satellite observations, and on the development of aggregation and disaggregation methodologies to address the implications of modeling a multiscale problem at restricted spatial and temporal resolutions.

Barros, Ana Paula↗

Stratospheric Sulfuric Acid and Black Carbon Aerosol Measured During POLARIS and its Role in Ozone Chemistry

Stratospheric aerosol can affect the environment in three ways. Sulfuric acid aerosol have been shown to act as sites for the reduction of reactive nitrogen and chlorine and as condensation sites to form Polar Stratospheric Clouds, under very cold conditions, which facilitate ozone depletion. Recently, modeling studies have suggested a link between BCA (Black Carbon Aerosol) and ozone chemistry. These studies suggest that HNO3, NO2, and O3 may be reduced heterogeneously on BCA particles. The ozone reaction converts ozone to oxygen molecules, while HNO3 and NO2 react to form NOx. Finally, a buildup of BCA could reduce the single-scatter albedo of aerosol below a value of 0.98, a critical value that has been postulated to change the effect of stratospheric aerosol from cooling to warming. Correlations between measured BCA amounts and aircraft usage have been reported. Attempts to link BCA to ozone chemistry and other stratospheric processes have been hindered by questions concerning the amount of BCA that exists in the stratosphere, the magnitude of reaction probabilities, and the scarcity of BCA measurements. The Ames Wire Impactors (AWI) participated in POLARIS as part of the complement of experiments on the NASA ER-2. One of our main objectives was to determine the amount of aerosol surface area, particularly BCA, available for reaction with stratospheric constituents and assess if possible, the importance of these reactions. The AWI collects aerosol and BCA particles on thin Palladium wires that are exposed to the ambient air in a controlled manner. The samples are returned to the laboratory for subsequent analysis. The product of the AWI analysis is the size, surface area, and volume distributions, morphology and elemental composition of aerosol and BCA. This paper presents results from our experiments during POLARIS and puts these measurements in the context of POLARIS and other missions in which we have participated. It describes modifications to the AWI data analysis procedures in which the collection of BCA is modeled as a fractal aggregate. The new analysis results in an increase in BCA surface area of approximately 24 and an increase in mass of 7-10 from the previous method. For the current study, BCA surface area is used in computer models that attempt to predict measured NOx/NOy ratios and O3 depletion rates. Inclusion of the HNO3 reaction with BCA in one model tends to improve the agreement of calculated to measured NOx/NOy ratio. However, it was found that these trends are viable only if the reactions are catalytic.

Strawa, Anthony W.↗