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At least 991 records · Page 55

Analysis of historic fires to determine most frequent challenging events

The fire probabilistic risk assessment framework for nuclear power plants relies on experimental data to determine expected fire behavior or to validate models to predict fire conditions in the plant. To support reducing the uncertainty in this experimental data, a research effort was conducted to identify the most frequent and challenging fire scenarios using historic fire data from nuclear power plants in the United States. To support this effort, an electronic version of the publicly available Updated Fire Event Database developed by Electric Power Research Institute was produced resulting in data on 2111 fire events, 540 events were labelled as being challenging fires with 74.2% of these challenging fire events being due to eleven selected fire types. In conclusion, of these fire types, electrical and electronic equipment, transient combustibles, and liquid fires were the most frequent of the challenging fires. The fire scenario specifics were characterized for each of the eleven selected types and then related to existing fire experiments.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Electronic structure theory on modeling short-range noncovalent interactions between amino acids

While short-range noncovalent interactions (NCIs) are proving to be of importance in many chemical and biological systems, these atypical bindings happen within the so-called van der Waals envelope and pose an enormous challenge for current computational methods. We introduce SNCIAA, a database of 723 benchmark interaction energies of short-range noncovalent interactions between neutral/charged amino acids originated from protein x-ray crystal structures at the “gold standard” coupled-cluster with singles, doubles, and perturbative triples/complete basis set [CCSD(T)/CBS] level of theory with a mean absolute binding uncertainty less than 0.1 kcal/mol. Subsequently, a systematic assessment of commonly used computational methods, such as the second-order Møller−Plesset theory (MP2), density functional theory (DFT), symmetry-adapted perturbation theory (SAPT), composite electronic-structure methods, semiempirical approaches, and the physical-based potentials with machine learning (IPML) on SNCIAA is carried out. It is shown that the inclusion of dispersion corrections is essential even though these dimers are dominated by electrostatics, such as hydrogen bondings and salt bridges. Overall, MP2, ωB97M-V, and B3LYP+D4 turned out to be the most reliable methods for the description of short-range NCIs even in strongly attractive/repulsive complexes. SAPT is also recommended in describing short-range NCIs only if the δMP2 correction has been included. The good performance of IPML for dimers at close-equilibrium and long-range conditions is not transferable to the short-range. We expect that SNCIAA will assist the development/improvement/validation of computational methods, such as DFT, force-fields, and ML models, in describing NCIs across entire potential energy surfaces (short-, intermediate-, and long-range NCIs) on the same footing.

Chemistry↗

New Empirical Formulation for the Sublimational Breakup of Graupel and Dendritic Snow

Abstract Ice fragments are generated by sublimation of ice particles in subsaturated conditions in natural clouds. Conceivably, such sublimational breakup would be expected to cause ice multiplication in natural clouds. Any fragment that survives will grow to become ice precipitation that may sublimate and fragment further. As a first step toward assessing this overlooked process, a formulation is proposed for the number of ice fragments from sublimation of ice particles for an atmospheric model. This is done by amalgamating laboratory observations from previously published studies. The concept of a “sublimated mass activity spectrum” for the breakup is applied to the dataset. The number of ice fragments is determined by the relative humidity over ice and the initial size of the parent ice particles. The new formulation applies to dendritic crystals and heavily rimed particles only. Finally, a thought experiment is performed for an idealized scenario of subsaturation with in-cloud descent. Scaling analysis yields an estimate of an ice enhancement ratio of about 5 (10) within a weak deep convective downdraft of about 2 m s −1 , for an initial monodisperse population of dendritic snow (graupel) particles of 3 L −1 and 2 mm. During descent, there is a dynamic equilibrium between continual emission of fragments and their depletion by sublimation. A simplified bin microphysics parcel model exhibits this dynamical quasi equilibrium, consistent with the thought experiment. The fragments have average lifetimes of around 90 and 70 s for dendrites and graupel, respectively. Sublimational breakup is predicted to cause significant secondary ice production.

54 ENVIRONMENTAL SCIENCES↗

Two-Phase Equation of State for Al 2 O 3

Two-phase equation of state (EOS) for AI 2 O 3 (alumina) is calibrated using the experimental/simulation calibration data uploaded to the caldata repository. The two phases are solid α-Al 2 O 3 (corundum, sapphire, ruby) and its melt. The enthalpy of formation is set to that available from the NIST-JANAF database at T = 0K, P =1 bar. The expected applicability range of the EOS is from the ambient conditions to temperatures of ~ 5000 K and pressures of ~ 50-100 GPa.

36 MATERIALS SCIENCE↗

Tracking the PACE of household energy usage: Energy usage impacts of projects financed through Property Assessed Clean Energy programs in California

This report examines the household-level energy impacts of residential property assessed clean energy (R-PACE) projects using normalized metered energy consumption methods. Our analysis covers projects that occurred through an R-PACE program between 2009 and 2017 and includes more than 25,000 electricity meters and 15,000 gas meters. We employ a comparison group, drawn from other R-PACE households with similar locational and usage characteristics whose projects were implemented at different times, to control for some non-project and non-weather factors that may impact energy use. We find that projects consisting of energy efficiency technologies save, on average, about 3% of household electricity usage and 3.5% of household gas usage. R-PACE financing, however, can be used to install central heating or air conditioning equipment for the first time. These projects would be expected to increase energy consumption. Since our data do not directly indicate which projects are new installations, we develop a simple algorithm for identifying them. Removing these inferred installation projects yields average savings of about 5% for electricity and 6% for gas for those households that remain in the sample. Given the mild California climate and the results of another study of similar California projects using similar methods, these results are in line with expectations. Solar PV projects yield large reductions in grid electricity use, averaging 69% of household consumption. We estimate that, collectively, all R-PACE projects installed in California through 2019 would generate annual reductions in grid-tied electricity consumption of 506 GWh (mostly due to solar PV) and gas consumption reductions of 2 million therms in a normal weather year. These impacts are equivalent to the electricity consumption of about 74,000 California households (including both efficiency and PV generation) and the gas consumption of about 4700 California households.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

A Micromorphic Length-Scale Coupling Framework for the Determination of Higher-Order Constitutive Models and the Multi-Scale Simulation of Heterogeneous Materials [Thesis]

Heterogeneous materials and materials with complex microstructures pose a unique challenge in the development of accurate models of their response to external stimuli. These difficulties principally arise due to the difficulty in characterizing and modeling the constituents and their interactions. It is usually possible, though non-trivial, to construct an explicit representation of the microstructure (a direct numeric simulation or DNS) but the method by which the complex modes of deformation and other processes can be homogenized to a reduced-order approximation is frequently unclear. Many homogenization approaches are ad-hoc and lack a strong justification beyond ease of computation. Furthermore, the homogenization approach can, in some cases, not utilize the full breadth of information available in the computation of the macro-scale stresses and deformation measures. It is also noteworthy that homogenization, by its very nature, will tend to obfuscate details of processes occurring at the lower length-scale. It is therefore of interest to include as much information as possible in the construction of the reduced-order model so as to be predictive in a variety of loading environments. We here present a length-scale bridging technique based upon the micromorphic continuum mechanics of Eringen which incorporates volume and surface area averages as a part of its construction. This approach enforces the balance equations at the micro-scale and then studies the effect of the spatially varying nature on the macro-scale. This leads, naturally, to further balance equations which are solved at the macro-scale. This work details a homogenization framework which arises naturally from the micromorphic construction of Eringen attempting to introduce no definitions beyond which are justifiable from micro-structural considerations. One of the results of this effort is the so-called “micromorphic filter” which has been developed and applied to several DNS to demonstrate its effectively. In order to determine the macroscopic degrees of freedom we utilize the special case of an overlap coupling technique where the macro-scale is fully constrained to the micro-scale. This enables us to study the resulting material properties as expected but also allows us to further study the boundary conditions on the additional degrees of freedom at the macro-scale.

42 ENGINEERING↗

Fuel-Cladding Eutectic Study of Legacy Fast Flux Test Facility (FFTF) MFF HT9/U-10Zr Metallic Fuel

This report presents the first systematic investigation of fuel-cladding eutectic interaction (FCEI) in irradiated HT9/U-10Zr metallic fuel from the Fast Flux Test Facility (FFTF) Materials Fuels Form (MFF) program, using differential scanning calorimetry (DSC) coupled with scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). Two irradiated fuel cross-sections, MNT07H (9.5 at% burnup, x/L = 0.78) and MNT08H (7.0 at% burnup, x/L = 0.93), were subjected to three successive isothermal annealing rounds (R1–R3) at 820°C for 20 minutes each, yielding a cumulative transient duration of one hour. This study directly addresses a recognized gap in the existing FCEI database, which previously lacked irradiated HT9/U-10Zr data at burnup levels above 8 at%. Two principal findings emerge from the study. First, for both samples, FCEI remained spatially confined within the pre-existing fuel-cladding chemical interaction (FCCI) zone boundaries after R3, with no measurable eutectic penetration into unaffected cladding beyond the original FCCI layer. This self-limiting behavior is consistent with historical Fuel Behavior Test Apparatus (FBTA) results and is attributed to the near-eutectic phase composition of the FCCI zone, which rapidly absorb the available eutectic-forming constituents and then stall penetration once the FCCI zone is consumed. A comparison with unirradiated surrogate data further supports this mechanism: whereas a U–34 at.% Fe sample would be expected to show ~176 µm of iron penetration under comparable conditions, the irradiated samples exhibited only ~20 µm, a discrepancy attributed to irradiation-induced interfacial porosity and pre-existing FCCI composition gradients. Second, for MNT08H, FCEI was observed exclusively on the half of the cladding circumference where pre-existing steady-state FCCI was present, with no detectable FCEI on the opposite half. Three hypotheses are proposed to explain this asymmetry: the inhibiting role of a zirconium-rich rind at the fuel-cladding interface; the chemical sequestration of iron by redistributed zirconium within the fuel matrix; and the persistence of fuel-cladding gaps on the FCEI-free half that preclude direct contact. All three hypotheses require further experimental investigation. The results extend the empirical FCEI database into higher-burnup territory and demonstrate the viability of DSC-based testing as a substitute for the no-longer-available FBTA apparatus. Future work will include additional cross-section testing, compilation of the full FCEI dataset, model evaluation, and DSC testing of ternary fuel compositions to broaden the experimental basis for safety assessment of sodium-cooled fast reactor systems.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Seeding Supermassive Black Holes with Self-interacting Dark Matter: A Unified Scenario with Baryons

Observations show that supermassive black holes (SMBHs) with a mass of ~10 9 M ⊙ exist when the universe is just 6% of its current age. We propose a scenario where a self-interacting dark matter halo experiences gravothermal instability and its central region collapses into a seed black hole. The presence of baryons in protogalaxies could significantly accelerate the gravothermal evolution of the halo and shorten collapse timescales. The central halo could dissipate its angular momentum remnant via viscosity induced by the self-interactions. The host halo must be on high tails of density fluctuations, implying that high-z SMBHs are expected to be rare in this scenario. We further derive conditions for triggering general relativistic instability of the collapsed region. Furthermore, our results indicate that self-interacting dark matter can provide a unified explanation for diverse dark matter distributions in galaxies today and the origin of SMBHs at redshifts z ~ 6–7.

79 ASTRONOMY AND ASTROPHYSICS↗

Dayside auroral-oval plasma density and conductivity enhancements due to magnetosheath electron precipitation.

Demonstration that magnetosheath electrons precipitating into the dayside auroral oval are a significant source of ionization and consequently will lead to electrical conductivity enhancements within the oval. By assuming that the electrons are maintained isotropic by strong pitch-angle diffusion as they precipitate into the ionosphere, the precipitation heat flux can be simply related to solar-wind energy density and consequently to the level of magnetic activity. For quiet solar-wind conditions, the heat fluxes of 1 to 10 ergs/sq cm/sec expected and observed lead to height-integrated Pedersen conductivity enhancements of 4 to 15 mhos. During magnetic storms the conductivity enhancements could increase by a factor of 3 to 5. Since the precipitating electrons are soft, the Hall conductivity enhancements are smaller than the Pedersen conductivity enhancements. For typical electric fields the computed conductivity enhancements lead to field-aligned currents bounding the enhancements in order-of-magnitude agreement with observation. The topside ionosphere should also have a density enhancement over the auroral oval on the dayside.

Kennel, C. F.↗

Auroral emissions and particle precipitation in the noon sector.

Comparison of airborne optical measurements during December 1969 with satellite particle measurements made earlier in 1969. The latitudinal distributions of H beta, 4278-A and 6300-A emissions during quiet periods are observed to agree with what would be expected from the latitudinal distribution of particle precipitation during similar conditions. In particular, there is a belt 200 to 500 km wide (at ionospheric heights) in which the magnetosheath plasma penetrates down to low altitudes through the cusps in the dayside magnetosphere and in which both H beta and 6300-A emissions are observed. There are brighter red arcs with green lower borders within this belt. It is suggested that these are produced by narrow regions of precipitation of slightly more energetic electrons embedded in the cusp fluxes. Poleward of this belt the flux of particles is low, and the atmospheric emissions are very weak, except for occasional narrow regions of electron precipitation (without measurable protons) and the corresponding polar-cap aurora (without the H beta emission).

Heikkila, W. J.↗

The influence of laser ranging on selenodetic control.

A mathematical model for performing an adjustment, using laser distances to improve coordinates of points on the earth and on the moon, as well as the orientation of these two bodies in space, is presented. The observation equations are given, and the orientation of the earth and the moon are defined in terms of three Eulerian angles. Numerical experiments were performed to investigate the expected accuracies of parameters in the adjustment model under differing conditions. The results indicate that the statistics both for the coordinates of points on earth and on the moon, and for the orientation parameters of the two bodies are favorable. However, very high correlations exist between some of the parameters; therefore, the recovery of these parameters from a simultaneous adjustment is questionable.

Mueller, I. I.↗

A variational approach to the question of temporal stability of equilibrium models of solar prominences. I - The formal theory

A Lagrangian approach to the equations describing small amplitude departures from equilibrium of solar prominences is presented. Seven quantities are derived which, by analogy to the concepts of energy, momentum, and angular momentum, are conserved under conditions corresponding to ignorable coordinates of classical mechanics. It is expected that these conservation laws will be useful as criteria of accuracy in obtaining eigenfrequencies for the perturbation equations when numerical techniques are used. The method is capable of handling complicated spatial dependences and has internal criteria for assessing the accuracy of any given numerical convergence scheme.

Lerche, I.↗

The need for an optical transition detection system in the NTF

Methods for transition detection were studied. The very high test and model costs necessitate testing of any new configuration over a range of Reynolds numbers for correlation with data obtained in conventional tunnels. The Reynolds number variations will be carried out at constant dynamic pressure, i.e., constant aeroelastic condition, by varying test temperature. Boundary layer transition cannot be expected to occur at the full scale location at significantly less than full-scale Reynolds numbers, and transition patterns will change with varying Reynolds number. Knowledge of the location of transition on model surfaces is essential for correct interpretation of drag data. The importance of transition, the limitations of artificial transition fixing, and their relation to the NTF are reviewed. The calculated minimum roughness height to instantaneously trip transition on a model transport wing over a range of Reynolds numbers of interest is shown in the NTF.

Fancher, M. F.↗

Metamorphic P-T paths and Precambrian crustal growth in East Antarctica

The metamorphic constraints on crustal thicknesses in Archean and post-Archean terranes are summarized along with possible implications for tectonic processes. It is important to recognize that P-T estimates represent perturbed conditions and should not be used to estimate steady state geothermal gradients or crustal thicknesses. The example is cited of the Dora Maira complex in the French Alps, where crustal rocks record conditions of 35 kbar and 800 C, implying their subduction to depths of 100 km or more, followed by subsequent uplift to the surface. Therefore such P-T estimates tell more about processes than crustal thicknesses. More importantly, according to the author, are determinations of P-T paths, particularly coupled with age measurements, because these may provide constraints on how and when perturbed conditions relax back to steady state conditions. P-T paths are illustrated that should be expected from specific tectonic processes, including Tibetan style collision, with and without subsequent extension, rifting of thin or thickened crust, and magmatic accretion. Growth of new crust, associated with magmatic accretion, for example, could possibly be monitored with these P-T paths.

Harley, S. L.↗

Operating characteristics of a 60 cm and a 10 cm electric arc-driven shock-tube

This paper describes the current status of the operating characteristics of the electric arc-driven shock-tube facility at Ames Research Center, focusing on its potential usefulness in the current and anticipated future applications. The paper specifically addresses the questions as to: (1) how well the behavior of the arc driver is understood and controlled, (2) how well the facility is equipped to test low-density, very-high-velocity nonequilibrium flow regimes, and (3) how closely the facility is expected to produce an equilibrium hypersonic flow when operated in shock-tunnel modes. For these issues, it is shown that: (1) a plasma kinetics model of the exploding wire closely describes the arc behavior in the driver, (2) the facility can produce a spectroscopically-clean flow in a low density regime with a shock velocity of 13 km/sec in air when used with an aluminum driven tube, and (3) when operated as a shock-tunnel, the high enthalpy flow in the test section is expected to deviate only slightly from the perfect equilibrium flow conditions at enthalpies corresponding to flight speeds of 5 km/sec or less.

Sharma, Surendra P.↗

Isotope Ratio Monitoring Gas Chromatography Mass Spectrometry (IRM-GCMS)

On Earth, the C-13 content of organic compounds is depleted by roughly 13 to 23 permil from atmospheric carbon dioxide. This difference is largely due to isotope effects associated with the fixation of inorganic carbon by photosynthetic organisms. If life once existed on Mars, then it is reasonable to expect to observe a similar fractionation. Although the strongly oxidizing conditions on the surface of Mars make preservation of ancient organic material unlikely, carbon-isotope evidence for the existence of life on Mars may still be preserved. Carbon depleted in C-13 could be preserved either in organic compounds within buried sediments, or in carbonate minerals produced by the oxidation of organic material. A technique is introduced for rapid and precise measurement of the C-13 contents of individual organic compounds. A gas chromatograph is coupled to an isotope-ratio mass spectrometer through a combustion interface, enabling on-line isotopic analysis of isolated compounds. The isotope ratios are determined by integration of ion currents over the course of each chromatographic peak. Software incorporates automatic peak determination, corrections for background, and deconvolution of overlapped peaks. Overall performance of the instrument was evaluated by the analysis of a mixture of high purity n-alkanes of know isotopic composition. Isotopic values measured via IRM-GCMS averaged withing 0.55 permil of their conventionally measured values.

Freeman, K. H.↗

Transverse ion heating in multicomponent plasmas along auroral zone field lines

This paper considers plasma modes that can occur in a multicomponent plasma, such as an O(+)-H(+) plasma, along auroral zone field lines and the effect of these plasma modes on heavy-ion acceleration. A simulation study of ion heating by ion cyclotron, lower hybrid, and ion-ion hybrid waves is conducted using parameters that pertain to different regions of the aurora. Three different auroral regions are identified, in which various types of heating occur; these regions are distinguished by the plasma conditions found there and by the instability that would be expected to be dominant in the ion-heating process. It is shown that, when a small amount of helium ions are added into the predominantly hydrogen and oxygen plasma, two ion-ion hybrid modes exist: hydrogen-helium and oxygen-helium modes (in addition to the lower hybrid mode). The effect of ion heating by these wave modes is discussed.

Ashour-Abdalla, Maha↗