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At least 991 records · Page 55
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NASA NTRS1979

The origin of metal clasts in the Bencubbin meteoritic breccia

The Bencubbin meteorite is a shock-welded breccia consisting of a diverse collection of metal and silicate clasts. Several types of evidence suggest that the metal clasts in Bencubbin retain chemical abundances that were established during condensation. The Cr, Ni, P and trace element abundances are consistent with condensation calculations and are much closer to the predicted compositions of metal condensates than the CM metal particles. In addition, petrographic and chemical evidence strongly suggest that the breccia components were incorporated as solid clasts within the breccia prior to a shock heating event of very short duration, which did not produce significant metamorphic effects.

Newsom, H. E.↗
NASA NTRS1979

Materials testing for spacecraft use

A technique has been developed for determining the outgassing characteristics of materials intended for spacecraft use. A measurement of the total mass loss (TML) and of the collected volatile condensable materials (CVCM) is used as a guide for selecting those materials low in outgassing. The data were used to compare the outgassing from two conductive black paints. In addition, the apparatus was also used in an attempt to simulate expected launch temperatures by collecting the outgassed molecules on a glass plate, which simulates a nearby thermal control surface. The glass plate was then irradiated in vacuum by simulated sunlight. Transmittance patterns of the clean glass plate and also with the condensed material on it were compared with the transmittance pattern after irradiation of the condensate. The transmittance patterns showed a drastic change. The resultant discoloration indicated the detrimental effects of the contamination and aided in selecting the better conductive paint. Additional tests utilizing an aluminized mirror collector plate have been run to show the effect of irradiation upon the CVCM from certain different classes of materials often used on spacecraft.

Park, J. J.↗
NASA NTRS1979

A reconsideration of nucleation phenomena in light of recent findings concerning the properties of small clusters, and a brief review of some other particle growth processes

The paper examines mechanisms of nucleation and growth by condensation and coagulation in the light of recent research on properties of small clusters. Homogeneous, hetero-molecular, and heterogeneous nucleation is analyzed, and expressions for the rate of formation of a stable condensed phase and evaluation of the free energy of formation of charged droplets are given. Application of high-pressure mass spectrometry which makes possible a direct determination of intensity spectra for cluster distributions, measurement of the thermodynamic properties of individual ion clusters and determination of cluster entropy and bond energy is discussed. Finally, coagulation of the condensed phase is considered, noting that concentration and mean particle size vary during coagulation, but the shape distribution is time independent, leading to the concept of a self-preserving aerosol size distribution.

Castleman, A. W., Jr.↗
NASA NTRS1980

Primordial refractory metal particles in the Allende meteorite

Refractory metal particles containing Os, Re, W, Mo, Ir, and Ru were observed in a Ca-Al-rich inclusion in the Allende meteorite. These particles are the closest to unaltered primordial metal condensates from a nebula yet reported, and appear to have been isolated from the nebula before the condensation of refractories was complete. Computer calculations of condensation indicate that the temperature of isolation appears to be close to the calculated temperature of first formation of oxides (about 1620 K at 0.0001 atm) indicating that isolation may have been effected by coating of the particles by oxides.

Blander, M.↗
NASA NTRS1980

A method of order reduction for structural dynamics

This paper presents a new method of order reduction based on recent work of a similar nature applicable to system dynamics and control. This method provides a practical computational procedure for producing a condensed model which exactly preserves the slowest n1 modes (where n1 is the number of 'slow' eigenvalues) of the total n modes of the original model for almost any set of n1 degrees of freedom retained in the condensed model. The method can also be used to compute the eigensolutions corresponding to the n1 slowest modes of the original structural dynamics problem. The accuracy of the condensed model and the speed/accuracy performance of the eigensolver are compared with standard methods for a 90 DOF cantilevered plate.

Anderson, L. R.↗
NASA NTRS1980

The evolution of the dust shell of Nova Serpentis 1978

Photometric measurements of Nova Serpentis 1978 from V to 19.5 microns covering the first 240 days of the nova's development are reported. A free-free expansion phase was followed by the condensation of a dust shell that became optically thick at both visible and infrared wavelengths. Carbon grains grew to radii of approximately 0.3 microns during the condensation period. The grains appeared to sputter or evaporate for a period of approximately 100 days following infrared maximum. It is found that the condensed carbon comprised 2% of the ejected mass, which implies that carbon abundance was enhanced in the nova shell. The angular expansion rate of the shell yields a distance of approximately 5 kpc and a luminosity of approximately 3000 solar luminosities for Nova Serpentis 1978.

Gehrz, R. D.↗
NASA NTRS1980

Effect of silicone oil on solid propellant combustion in small motors

The feasibility of reducing troublesome nozzle blockage (by condensation deposits) in laboratory-scale solid rockets by addition of a silicone oil as a propellant ingredient was explored experimentally. An aluminized composite propellant and its counterpart with 1% silicone oil replacing part of the binder were fired in a 63.5 mm diameter, end-burning, all-metal burner. Pressure-time histories were recorded for all of the tests by a Taber gauge mounted at the downstream end of the chamber; temperature-time data at the nozzle throat were obtained in some of the runs by thermocouples having junctions positioned at the wall but insulated from the metal. Deposition of condensables on the nozzle walls causing a progressive increase in the chamber pressure with time was noted. The fraction of firings exhibiting practically no condensation was 59% with silicone and 32% without. On the average, temperature readings at the nozzle throat were higher with the silicone propellants. Although various phenomena may contribute to these findings, the results are not understood completely.

Ramohalli, K.↗
NASA NTRS1980

Si-rich Fe-Ni grains in highly unequilibrated chondrites

Consideration is given to the Si contents of Fe-Ni grains in highly unequilibrated chondrites, which have undergone little metamorphosis and thus best preserve the record of processes in the solar nebula. Electron microprobe determinations of silicon content in grains of the Bishunpur chondrite are presented for the six Si-bearing Fe-Ni grains for which data could be obtained, five of which were found to be embedded in olivine chondrules. In addition, all grains are found to be Cr-rich, with Cr increased in concentration towards the grain edge, and to be encased in FeS shells which evidently preserved the Si that entered the FeNi at higher temperatures. A mechanism for the production of Si-bearing metal during the condensation of the cooling solar nebula is proposed which considers the metal to have condensed heterogeneously while the mafic silicates condensed homogeneously with amounts of required undercooling in the low-pressure regions where ordinary and carbonaceous chondrites formed, resulting in Si mole fractions of 0.003 at nebular pressures less than 0.000001 atm.

Rambaldi, E. R.↗
NASA NTRS1980

Advection fog formation and aerosols produced by combustion-originated air pollution

The way in which pollutants produced by the photochemical reaction of NO(X) and SO(X) affect the quality of the human environment through such phenomena as the formation of advection fog is considered. These pollutants provide the major source of condensation nuclei for the formation of fog in highways, airports and seaports. Results based on the monodisperse, multicomponent aerosol model show that: (1) condensation nuclei can grow and form a dense fog without the air having attained supersaturation; (2) the mass concentration range for NO(X) is one-third that of SO(X); and (3) the greater the mass concentration, the particle concentration, and the radius of condensation nuclei, the denser the fog that is formed.

Hung, R. J.↗
NASA NTRS1981

Organic compounds in meteorites and their origins

The current investigation represents an extensively updated version of a review conducted by Anders et al. (1973). The investigation takes into account the literature through mid-1980. It is pointed out that Type 1 carbonaceous chondrites (C1) contain 6% of their cosmic complement of carbon, mainly in the form of organic matter. Most authors now agree that this material represents primitive prebiotic matter. The principal questions remaining are what abiotic processes formed the organic matter, and to what extent these processes took place in locales other than the solar nebula, such as interstellar clouds or meteorite parent bodes. The problem is approached in three stages. It is attempted to reconstruct the physical conditions during condensation from the clues contained in the inorganic matrix of the meteorite. The condensation behavior of carbon under these conditions is determined on the basis of thermodynamic calculations. Model experiments on the condensation of carbon are performed, and the synthesized compounds are compared with those actually found in meteorites.

Hayatsu, R.↗
NASA NTRS1980

Single isotope fractionation of (16)O(-) implications for early history of solar system

Chemical fractionation processes are investigated with emphasis on selective single isotope fractionation in polyisotopic systems, particularly in oxygen. The related temperature parameters of meteoritic condensates and of their source medium are investigated by a thermometric method that is independent of assumptions regarding temperatures and pressures in the solar nebula. The crucial nonlinear chemical fractionation of O-16 was demonstrated experimentally. The effect was achieved in condensed CO2 formed from CO with C-12 O-16 selectively excited by H Ly alpha. The effect was verified by mass spectrometric measurements. The meteorite paleotemperature estimates were advanced from defining only thermal exposure to evaluating time and temperature independently. Grain temperatures at condensation of refractory inclusion materials are indicated to be less than 900 K in agreement with radiation temperature considerations and observations in circumstellar dust shells.

Arrhenius, G.↗
NASA NTRS1978

User's Manual for Thermal Analysis Program of Axially Grooved Heat Pipe (HTGAP)

A computer program that numerically predicts the steady state temperature distribution inside an axially grooved heat pipe wall for a given groove geometry and working fluid under various heat input and output modes is described. The program computes both evaporator and condenser film coefficients. The program is able to handle both axisymmetric and nonaxisymmetric heat transfer cases. Non-axisymmetric heat transfer results either from non-uniform input at the evaporator or non-uniform heat removal from the condenser, or from both. The presence of a liquid pool in the condenser region under one-g condition also causes non-axisymmetric heat transfer, and its effect on the pipe wall temperature distribution is included in the present program. The hydrodynamic aspect of an axially grooved heat pipe is studied in the Groove Analysis Program (GAP). The present thermal analysis program assumes that the GAP program (or other similar programs) is run first so that the heat transport limit and optimum fluid charge of the heat pipe are known a priori.

Kamotani, Y.↗
NASA NTRS1982

Use of thermocapillary migration in a controllable heat valve

In accordance with the Marangoni effect, immiscible droplets in a host fluid in which a temperature gradient exists move in the direction of increasing temperature. It is proposed that this thermocapillary migration could be used to construct a 'liquid wick' that would return the condensed vapor at the condenser end of a heat pipe back to the evaporator, thus completing the fluid circuit. The droplets would be formed by capillary pressure forcing the condensate through a perforated diaphragm whose temperature would control the droplet flux, and hence the heat flux between the two ends of the heat pipe, thus making it a controllable heat valve.

Schmid, L. A.↗
NASA NTRS1982

Numerical simulation of the development of mean monsoon circulation in July

Eight different experiments are carried out, ranging from 8 to 20 days, with a primitive equation model consisting of five atmospheric layers and one oceanic layer. The purpose is to investigate the relative importance of radiative heating and deep cumulus condensation, orography, and initial conditions for the development of the mean monsoon circulation from June to July in the 0-180 deg E, 25 deg S - 55 deg N region. Two alternative initial states are used, one based on the observed monthly mean June pressure distribution, the other on the mean June zonal average pressure distribution. Whereas large-scale condensation and actual land and sea distributions are included in every experiment, deep cumulus cone condensation and radiative heating are always taken together. It is found that the means sea level pressure distribution and low-level flow pattern produced by these simulations are in the main determined by the diabatic heating distribution and are influenced somewhat by orography; they are, however, almost independent of the initial state. The low pressure systems are found to develop faster when diurnal variation of solar radiation is allowed for; this is thought to be due mainly to the more vigorous cumulus activity during the day.

Kuo, H. L.↗
NASA NTRS1983

HCl in rocket exhaust clouds - Atmospheric dispersion, acid aerosol characteristics, and acid rain deposition

Both measurements and model calculations of the temporal dispersion of peak HCl (g + aq) concentration in Titan III exhaust clouds are found to be well characterized by one-term power-law decay expressions. The respective coefficients and decay exponents, however, are found to vary widely with meteorology. The HCl (g), HCl (g + aq), dewpoint, and temperature-pressure-altitude data for Titan III exhaust clouds are consistent with accurately calculated HCl/H2O vapor-liquid compositions for a model quasi-equilibrated flat surface aqueous aerosol. Some cloud evolution characteristics are also defined. Rapid and extensive condensation of aqueous acid clearly occurs during the first three min of cloud rise. Condensation is found to be intensified by the initial entrainment of relatively moist ambient air from lower levels, that is, from levels below eventual cloud stabilization. It is pointed out that if subsequent dilution air at stabilization altitude is significantly drier, a state of maximum condensation soon occurs, followed by an aerosol evaporation phase.

Pellett, G. L.↗
NASA NTRS1983

Effect of humidity on jet engine axial-flow compressor performance

Two problems related to the ingestion of humid air into jet engine axial compressors have been studied: (1) the changes in the performance of the compressor in the absence of condensation and (2) the changes in the entry conditions to the compressor when condensation occurs. Regarding the first, the extent of changes are predicted and also measured in the case of a six-stage compressor operated with air-methane gas mixture utilizing the similarities in the thermodynamic properties between water vapor and methane. For the condensation process in an inlet, a model is described that takes into account the presence of micro particulates and the flow field changes in the vicinity of the inlet wall. Finally, the effects of humidity on engine performance are discussed in relation to engine trim and control schemes.

Ehresman, C. M.↗
NASA NTRS1983

Is Titan wet or dry?

Titan's dense and cold nitrogen atmosphere contains a small amount of methane under conditions at least approaching those at which one or both constituents would condense. The possibility of methane and nitrogen rain clouds and global methane oceans has been discussed widely. From specific features of radio occultation and other Voyager results, however, it is concluded that nitrogen does not condense on Titan and that Titan has neither global methane oceans nor a global cloud of liquid methane droplets. Certain results indirectly support the conjecture that methane does not condense at any location. However, other considerations favor a methane ice haze high in the troposphere, and liquid and solid methane might exist on the surface and as low clouds at polar latitudes.

Eshleman, V. R.↗
NASA NTRS1983

A helium-3 refrigerator employing capillary confinement of liquid cryogen

A condensation refrigerator suitable for operation in a zero gravity space environment was constructed. The condensed liquid refrigerant is confined by surface tension inside a porous metal matrix. Helium-4 and helium-3 gases were condensed and held in a copper matrix. Evaporative cooling of confined liquid helium-4 resulted in a temperature of 1.4K. Using a zeolite adsorption pump external to the cryostat, a temperature of 0.6 K was achieved through evaporative cooling of liquid helium-3. The amount of time required for complete evaporation of a controlled mass of liquid helium-4 contained in the copper matrix was measured as a function of the applied background power. For heating powers below 18 mW the measured times are consistent with the normal boiling of the confined volume of liquid refrigerant. At background powers above 18 mW the rapid rise in the temperature of the copper matrix the signature of the absence of confined liquid occurs in a time a factor of two shorter than that expected on the basis of an extrapolation of the low power data.

Ennis, D. J.↗