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At least 991 records · Page 55

Impact of Coupled Radiation and Ablation on the Aerothermodynamics of Meteor Entries

A high-fidelity approach for simulating the aerothermodynamic environments of meteor entries is developed. Two primary components of this model are coupled radiation and coupled ablation. Coupled radiation accounts for the impact of radiation on the flow field energy equations, while coupled ablation explicitly models the injection of ablation products within the flow field and radiation simulations. For a meteoroid with a velocity of 20 km/s, coupled radiation reduces the stagnation point radiative heating by over 60%. For altitudes below 40 km, the impact of coupled radiation on the flow field structure is shown to be fundamentally different, as a result of the large optical thicknesses, than that seen for reentry vehicles, which do not reach such altitudes at velocities greater than 10 km/s. The impact of coupled ablation (with coupled radiation) is shown to provide at least a 70% reduction in the radiative heating relative to the coupled-radiation-only cases. This large reduction is partially the result of the low ionization energies, relative to air species, of ablation products. The low ionization energies of ablation products, such as Mg and Ca, provide strong photoionization and atomic line absorption in regions of the spectrum that air species do not. MgO and CaO are also shown to provide significant absorption. Turbulence is shown to impact the distribution of ablation products through the shock- layer, which results in up to a 100% increase in the radiative heating downstream of the stagnation point. To create a database of heat transfer coefficients the developed model was applied to a range of cases. This database considered velocities ranging from 14 to 20 km/s, altitudes ranging from 20 to 50 km, and nose radii ranging from 1 to 100 m. The heat transfer coefficients from these simulations are below 0.045 for the range of cases (with turbulence), which is significantly lower than the canonical value of 0.1.

Johnston, Christopher O.↗

Electron impact excitation of atomic oxygen - Revised cross sections

Revised cross-section values for the excitation of three O I resonance transitions at 1304, 1027, and 989 A, by electron impact on atomic oxygen are presented from threshold to 300 eV. These results are smaller than the excitation cross sections used in some airglow models by a factor of about 2.8. The revised values are in good agreement with recent quantum-scattering calculations. The downward revision is required by new laboratory studies in which the direct and dissociative cross sections for 1304 A excitation were normalized with small probable error to the O and O2 ionization cross sections. The results also reflect new advances in VUV optical calibration techniques. A number of outstanding airglow problems are simplified by these revisions.

Zipf, E. C.↗

Constraints on molecular gas in cooling flows and powerful radio galaxies

We searched for molecular gas in a heterogeneous sample of five radio-loud galaxies (three of which are inferred to be in cooling flow clusters) using the Swedish-European Southern Observatory (Swedish-ESO) Submillimeter Telescope. We do not detect CO in emission in any of the cluster sources at a 3 sigma level of typically 15 mK. White et al. (1991) have suggested column densities of N(sub H) approximately 10(exp 21)/sq cm in these clusters with a spatial covering factor of order unity and a total mass of M approximately 10(exp 12) solar mass. Our limits are inconsistent with these column densities and spatial covering factor unless the molecular gas is very cold (kinetic temperature close to 2.7 K) or there only a few clouds along each line of sight. We estimate minimum temperatures in the range approximately 20-30 K. We find that clouds of atomic and molecular hydrogen require strict fine-tuning of parameter space in order to satisfy the requirements for the large column densities N(sub H) approximately 10(exp 21)/sq cm, unit covering factor, and a small number of clouds along the line of sight. Currently the only way molecular gas can be responsible for the X-ray absorption and still be consistent with our observations is if (1) there is of order one cloud along the line of sight and (2) the optical depth in C-12 1 to 0 is less than 10. In addition, we present a Very Large Array (VLA) image of NGC 4696 which suggests this object is a member of the class of 'amorphous cooling flow radio sources.' The C-12 1 to 0 line is detected in emission in PKS 0634-206, a classical double radio galaxy which is rich in extended optical emission line gas. The estimated molecular gas mass is M(sub mol) approximately 3 x 10(exp 9) solar mass and is much larger than that of the ionized component detected in hydrogen alpha suggesting that the emission-line nebula is radiation bounded.

O'Dea, Christopher P.↗

Hg(+) Frequency Standards

In this paper we review the development of Hg(+) microwave frequency standards for use in high reliability and continuous operation applications. In recent work we have demonstrated short-term frequency stability of 3 x 10(exp -14)/nu(sub tau) when a cryogenic oscillator of stability 2-3 x 10(exp 15) was used a the local oscillator. The trapped ion frequency standard employs a Hg-202 discharge lamp to optically pump the trapped Hg(+)-199 clock ions and a helium buffer gas to cool the ions to near room temperature. We describe a small Hg(+) ion trap based frequency standard with an extended linear ion trap (LITE) architecture which separates the optical state selection region from the clock resonance region. This separation allows the use of novel trap configurations in the resonance region since no optical pumping is carried out there. A method for measuring the size of an ion cloud inside a linear trap with a 12-rod trap is currently being investigated. At approx. 10(exp -12), the 2nd order Doppler shift for trapped mercury ion frequency standards is one of the largest frequency offsets and its measurement to the 1% level would represent an advance in insuring the very long-term stability of these standards to the 10(exp -14) or better level. Finally, we describe atomic clock comparison experiments that can probe for a time variation of the fine structure constant, alpha = e(exp 2)/2(pi)hc, at the level of 10(exp -20)/year as predicted in some Grand Unified String Theories.

Prestage, John D.↗

Investigations of Arcjet Flow Thermochemistry

An experimental and numerical investigation of the thermochemical state of arcjet flows is currently being conducted at NASA Ames Research Center. The experimental approach relies on the use of laser- and emission-spectroscopic diagnostic techniques in three regions of the flow. A fiber optic sensor is used to record spectrally resolved emission signals from the electrode package region, where the flow is most likely to be in thermochemical equilibrium. A second emission diagnostic measurement is made in the shock layer formed over a blunt-body test article placed in the stream, and a CCD camera is used to simultaneously record spectral emission from several measurement locations along the stagnation streamline. Downstream of the nozzle exit, but upstream of the test article, Laser-Induced Fluorescence (LIF) of atomic nitrogen is used to assess the nonequilibrium distribution of flow enthalpy in the free stream. Results from the measurements are compared with predictions from a two-temperature, axisymmetric flow model that solves the nozzle and shock-layer flows.

Fletcher, Douglas G.↗

The influence of velocity-changing collisions on resonant degenerate four-wave mixing

The phase-conjugate signal observed in resonant degenerate four-wave mixing on the 6 3P2 to 7 3S1 transition of atomic Hg in an Hg-Ar discharge is investigated. At a fixed Ar pressure the variation of the signal with pump powers is explained by a model that includes the effects of velocity-changing collisions (VCCs). As the Ar pressure was varied from 0 to 1 torr, an increase in the phase-conjugate signal was observed and is ascribed to a change in the discharge dynamics with Ar pressure and to the influence of VCCs. To further clarify the role of collisions and optical pumping, degenerate four-wave mixing spectra are examined as a function of pump power. Line shapes are briefly discussed.

Richardson, W. H.↗

Trend analysis of in-situ spectral reflectance data from the Thermal Control Surfaces Experiment (TCSE)

The Thermal Control Surfaces Experiment (TCSE) on the LDEF was a comprehensive experiment that combined in-space measurements with extensive pre- and post-flight analyses of thermal control surfaces to determine the effects of exposure to the low earth orbit (LEO) space environment. The TCSE is the first space experiment to directly measure in-situ total hemispherical reflectance of thermal control surfaces in the same way they are routinely measured in the laboratory. In-space optical measurements performed by the TCSE provide the unique opportunity for trend analysis of the performance of materials in the space environment. Such trend analysis of flight data offers the potential to develop an empirical life time prediction model for several thermal control surfaces. For material research, trend analysis of the TCSE flight data, particularly the spectral data, can provide insight into the damage mechanisms of space exposure. Trend analysis for the TCSE samples has been limited to those materials that were not significantly eroded by the atomic oxygen (AO) environment. The performance of several materials on the LDEF mission was dominated by AO effects. Trend analysis was performed on both the detailed spectral reflectance measurements (in-space, pre-flight, and post-flight) and on the integrated solar absorptance. Results of this analysis for the five selected TCSE materials are presented along with the spectral flight data. Possible degradation and effects mechanisms will be discussed to better understand and predict the behavior of these materials in the LEO space environment.

Wilkes, Donald R.↗

In Situ identification of mineral resources with an X-ray-optical "Hand-Lens" instrument

The recognition of material resources on a planetary surface requires exploration strategies not dissimilar to those employed by early field geologists who searched for ore deposits primarily from surface clues. In order to determine the location of mineral ores or other materials, it will be necessary to characterize host terranes at regional or subregional scales. This requires geographically broad surveys in which statistically significant numbers of samples are rapidly scanned from a roving platform. To enable broad-scale, yet power-conservative planetary-surface exploration, we are developing an instrument that combines x-ray diffractometry (XRD), x-ray fluorescence spectrometry (XRF), and optical capabilities; the instrument can be deployed at the end of a rover's robotic arm, without the need for sample capture or preparation. The instrument provides XRD data for identification of mineral species and lithological types; diffractometry of minerals is conducted by ascertaining the characteristic lattice parameters or "d-spacings" of mineral compounds. D-spacings of 1.4 to 25 angstroms can be determined to include the large molecular structures of hydrated minerals such as clays. The XRF data will identify elements ranging from carbon (Atomic Number = 6) to elements as heavy as barium (Atomic Number = 56).

Marshall, J.↗

Investigation of Third Order Optical Nonlinearity and Reverse Saturable Absorption of Octa-alkoxy Metallophthalocyanines

In recent years, there has been a growing interest in the development of passive optical power limiters for the protection of the human eye and solid-state sensors from damage caused by energetic light pulses and also for other switching applications. One of the key issues involved is the search for appropriate materials that show effective reverse saturable absorption. Phthalocyanines seem to be good candidates for such applications because of their higher third order nonlinearity and the unique electronic absorption characteristics. A series of 1,4,8,11,15, 18,22,25-octa-alkoxy metallophthalocyanines containing various central metal atoms such as zinc, copper, palladium, cobalt and nickel were characterized for their third order nonlinearity and for their nonlinear absorptive properties to evaluate their suitability to function as reverse saturable absorbers.

Sanghadasa, Mohan↗

Stable Polyimides for Terrestrial and Space Uses

Polyimides of a recently developed type have an attractive combination of properties, including low solar absorptivity (manifested as low color) when cast into thin films, resistance to atomic oxygen and ultraviolet radiation, solubility in organic solvents, high glass-transition temperatures, and high thermal stability. The focus of the development work was on polymers that can endure the space environment and that have specific combinations of properties for use on Gossamer spacecraft. Because of their unique combination of properties, these polymers are also expected to find use in a variety of other applications on Earth as well as in space. Examples of other space applications include membranes on antennas, second-surface mirrors, thermal optical coatings, and multilayer thermal insulation. For both terrestrial and space applications, these polyimides can be processed into various forms, including films, fibers, foams, threads, adhesives, and coatings.

Connell, John W.↗

Technology Development for the Modification of High Aspect Ratio Geometries for Thermal and Environmental Control

A key technology development driver in environmental control systems and next generation optics are discussed utilizing thin film development borrowed from the semiconductor industry. The optical and physical properties of spacecraft radiator coatings are dictated by orbital environmental conditions. For example, coatings must adequately dissipate charge buildup when orbital conditions, such as polar, geostationary or gravity neutral, result in surface charging. Current dissipation techniques include depositing a layer of ITO (indium tin oxide) on the radiator surface in a high temperature process. The application of these enhanced coatings must be such that the properties in question are tailored to mission-specific requirements. The multi-billion-dollar semiconductor industry has adopted Atomic Layer Deposition (ALD) for self-assembly and atomic-scale placement. ALD is a cost-effective nanoadditive-manufacturing technique that allows for the conformal coating of substrates with atomic control in a benign temperature and pressure environment. By using ALD, modification of these coatings can be accomplished during coating application preprocessing. The preprocessing is rendered directly on the coating dry pigment before binding. Through the introduction of paired precursor gases, thin films can be deposited on a myriad of substrates ranging from glass, polymers, aerogels, metals, powders, and other high aspect-ratio micro- and nano- structures. By providing atomic-level control, where single layers of atoms can be deposited, the fabrication of metal transparent films, precise nano-laminates, and coatings of nano-channels and pores is achievable. A method has been demonstrated for the ALD of In2O3 and films on a variety of substrates from Si(100) wafers, glass slides, and on Z93P pigments resulting in a direct spaceflight application. Results will be presented that verify the chemical composition of ALD pigments and charge dissipation properties when the pigment goes through its binding and coating process and we present early results of ALD for carbon nanotube formation and encapsulation.

Dwivedi, Vivek H.↗

Effects of long term space environment exposure on optical substrates and coatings (S0050-2)

Eastman Kodak Company included twelve substrate and coating samples on the Long Duration Exposure Facility (LDEF) structure. There were three Fused Silica and three Ultra Low Expansion (ULE) uncoated glass samples, two ULE samples with a high reflectance silver coating, two Fused Silica samples with an antireflectance coating, and two Fused silica samples with a solar rejection coating. A set of duplicate control samples was also manufactured and stored in a controlled environment for comparison purposes. Kodak's samples were included as a subset of the Georgia Institute of Technology tray, which was located on row 5-E, tray S0050-2. This placed the samples on the trailing edge of the structure, which protected them from the effects of atomic oxygen bombardment. An evaluation of the flight samples for effects from the 5 year mission showed that a contaminant was deposited on the samples, a micrometeoroid impact occurred on one of the samples, and the radiation darkening which was expected for the glass did not occur. The results are listed in more detail.

Harvey, Keith↗

MISSE Thermal Control Materials with Comparison to Previous Flight Experiments

Many different passive thermal control materials were flown as part of the Materials on International Space Station Experiment (MISSE), including inorganic coatings, anodized aluminum, and multi-layer insulation materials. These and other material samples were exposed to the low Earth orbital environment of atomic oxygen, ultraviolet radiation, thermal cycling, and hard vacuum, though atomic oxygen exposure was limited for some samples. Materials flown on MISSE-1 and MISSE-2 were exposed to the space environment for nearly four years. Materials flown on MISSE-3, MISSE-4, and MISSE-5 were exposed to the space environment for one year. Solar absorptance, infrared emittance, and mass measurements indicate the durability of these materials to withstand the space environment. Effects of short duration versus long duration exposure on ISS are explored, as well as comparable data from previous flight experiments, such as the Passive Optical Sample Assembly (POSA), Optical Properties Monitor (OPM), and Long Duration Exposure Facility (LDEF).

Finckenor, Miria↗

Micrometeoroid Impacts and Optical Surface Scatter in Space Environment

This presentation will discuss the results of an attempt to use laboratory test data and empirically derived models to quantify the degree of surface damage and associated light scattering that might be expected from hypervelocity particle impacts in space environment. Micrometeoroid sizes are predicted to be predominantly in the mass range 10(exp -5) g or less, with most having diameters near 1 micrometer, but some larger than 120 micrometers, with velocities near 20 km/s. In a laboratory test, latex (p = 1.1 g/cu cm) and iron (7.9 g/cu cm) particles with sizes ranging from 0.75 micrometer to 1.60 micrometer and with velocities ranging from 2.0 km/s to 18.5 km/s, were shot at a dielectric coated gold mirror. Scanning electron and atomic force microscopy were used to measure crater dimensions that were then associated with particle impact energies. These data were then fitted to empirical models derived from solar cell and other spacecraft surface components returned from orbit, as well as studies of impact craters studied on glassy materials returned from the lunar surface, to establish a link between particle energy and impact crater dimension. Published estimates of the Martian and Saturnian meteoroid environments were used as the sources of particle flux estimates. From these data, an estimate of total expected damaged area was computed and this result produced an estimate of expected surface scatter from the modeled environment.

Heaney, James B.↗

A theoretical study of the low-lying states of Ti2 and Zr2

The low-lying states of Ti2 and the valence isoelectronic Zr2 are examined theoretically by means of a multireference configuration-interaction (MRCI) method. MRCI calculations demonstrate that two of the Zr2 states are very low-lying and that the resulting vertical excitation is consistent with the optical spectrum of Zr2. The ground state is predicted for Ti2 on the basis of valence correlation with the MRCI method and the average coupled-pair functional technique. Calculations of the inner-shell correlation effects are estimated and found to lower the 3Delta g state to a ground state, and another to a very low-lying state. The ground state of Ti2 is assigned to 3Delta g since it is lower than the other state at all levels of correlation and is derived from the same atomic asymptote. This conclusion is supported by the lack of an electron-spin resonance signal but contradicts the absence of subcomponents on the Raman spectral lines.

Bauschlicher, Charles W., Jr.↗

Analysis of surfaces from the LDEF A0114, phase 4

Progress made from 1 Mar. to 31 Aug. 1991 is presented. The work concentrated on profilometry measurements of eroded and corroded sample surfaces, optical transmission measurements, analysis of the pinhole camera, and x-ray photoelectron spectroscopic (XPS) analysis of some samples. The following papers are presented: (1) observation of Be-7 on the surface of the Long Duration Exposure Facility (LDEF) Spacecraft; (2) measurement of the passive attitude control performance of a recovered spacecraft; (3) effects on LDEF exposed copper flim and bulk; (4) measurements of erosion characteristics for metal and polymer surfaces using profilometry; (5) the interactions of atmospheric cosmogenic radionuclides with spacecraft surfaces; (6) pinhole cameras as sensors for atomic oxygen in orbit; and (7) interaction of atomic oxygen with solid surfaces in low earth orbit- results from LDEF experiment A0114.

Gregory, John C.↗

PING Gamma Ray and Neutron Measurements of a Meter-Sized Carbonaceous Asteroid Analog

Determining the elemental composition of carbonaceous (spectral type C) asteroids is still one of the basic problems when studying these objects. The only main source of elemental composition information for asteroids is from their optical, NIR and IR properties, which include their spectral reflectance characteristics, albedo, polarization, and the comparison of optical spectroscopy with meteorite groups corresponding to asteroids of every spectral type. Unfortunately, these sources reflect observations from widely contrasting spatial scales that presently yield a void in the continuum of microscopic and macroscopic evidence, a lack of in situ measurement confirmation, and require deeper sensing techniques to discern the nature of these asteroids. The Probing In situ with Neutrons and Gamma rays (PING) instrument is ideally suited to address this problem because it can be used to determine the bulk elemental composition, H and C content, the average atomic weight and density of the surface and subsurface layers of C-type asteroids, and can provide measurements used to determine the difference between and distinguish between different types of asteroids. We are currently developing the PING instrument that combines gamma ray and neutron detectors with a 14 Me V pulsed neutron generator to determine the in-situ bulk elemental abundances and geochemistry of C-type asteroids with a spatial resolution of 1 m down to depths of tens of cm to 1 m. One aspect of the current work includes experimentally testing and optimizing PING on a known meter-sized Columbia River basalt C-type asteroid analog sample that has a similar composition and the same neutron response as that of a C-type asteroid. An important part of this effort focuses on utilizing timing measurements to isolate gamma rays produced by neutron inelastic scattering, neutron capture and delayed activation processes. Separating the gamma ray spectra by nuclear processes results in higher precision and sensitivity elemental composition measurements. Using gated data acquisition techniques allows for the unambiguous identification of gamma ray lines from different isotopes and nuclear processes, especially in situations when limited detector resolution results in overlapping gamma ray lines that cannot be individually resolved. In this paper, we will present the PING basalt layering experimental data, taken at the test facility at NASA Goddard Space Flight Center using the time tagged event-by-event data analysis technique, compared to our MCNPX computer simulation results for the C-type asteroid and basalt layering simulant models. Comparison of these data will show the advantages, validity, and measurement sensitivity of PING's nuclear interrogation methods to obtain more precise and sensitive in situ bulk elemental composition and density measurements of the subsurface of asteroids.

Bodnarik, J.↗

Extinction and scattering in the Orion Nebula - Comparison of optical and VLA 21 centimeter studies

We have compared VLA 21 cm continuum maps of M42 with extinction-corrected H-beta images and found that much of M42 has an excess of H-beta surface brightness. This is interpreted as reflection by particles lying close to the principal ionization front. Comparison of column densities of H I near M42 and extinction (C(H-beta)) indicates an excellent area-by-area correlation, establishing that most of the extinction in M42 arises in the neutral lid that lies on the near side of the nebula. A more quantitative comparison of (C(H-beta)) and N(H I), the column density, is consistent with this conclusion and indicates a dust scattering cross section per hydrogen atom that is similar to the value for the general interstellar medium. The usual model for extinction in the Trapezium region is that it occurs very near the stars and produces an anomalous reddening curve through modification of the nature or size distribution of the particles. These new results question the basic assumptions and conclusions of that model.

O'Dell, C. R.↗