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At least 991 records · Page 55

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NASA NTRS1972

Relation of the diffuse reflectance remission function to the fundamental optical parameters.

The Kubelka-Munk equations describing the diffuse reflectance of a powdered sample were compared to equations obtained using a uniformly-sized rough-surfaced spherical particle model. The comparison resulted in equations relating the remission function and the Kubelka-Munk constants to the index of refraction, the absorption coefficient, and the average particle diameter of a powdered sample. Published experimental results were used to test the equation relating to the remission function to the fundamental optical parameters.

Simmons, E. L.↗

NASA NTRS1973

On the He-H2 thermal opacity in planetary atmospheres.

The pressure-induced absorption coefficient for He-H2 mixtures is poorly known for the range of physical conditions in the atmospheres of the major planets, largely because of the uncertainty in the overlap parameter of the induced dipole moment. We have reduced this uncertainty by examining the extent to which the published measurements and the existing theory specify this parameter. Furthermore, we show that this parameter should be quite accurately determined if laboratory measurements of this opacity are extended to frequencies below 300/cm.

Trafton, L.↗

NASA NTRS1973

On ultraviolet absorption by molecular hydrogen in stellar atmospheres.

The total LTE opacity expected for a variety of temperatures and pressures has been calculated for a mixture of solar composition. The absorption coefficient for the H2 singlet transition between 1300 and 2000 A was obtained from computations at 5000 K by Sando and Dalgarno (1971). It is found that a correct estimate of the resonance broadening in Lyman-alpha wings leads to important modifications of the UV opacity.

Praderie, F.↗

NASA NTRS1973

Amplified laser absorption - Detection of nitric oxide.

Experimental results are reported for the power loss of a carbon monoxide gas laser due to the absorption of small amounts of nitric oxide placed in an intra-laser-cavity absorption cell. It was found, for the particular experimental conditions employed, that the absorption coefficient of nitric oxide at 1900.04/cm is enhanced more than two orders of magnitude when it is in the intracavity cell. Finally, the experimental results are compared with theoretical calculations.

Chackerian, C., Jr.↗

NASA NTRS1973

Thermal shielding by subliming volume reflectors in convective and intense radiative environments.

The behavior of dielectric materials having densely packed internal scattering centers subject to extreme convective and radiative environments is analyzed. Experiments have shown that these materials act as volume reflectors of incident radiation even when the exposed surface is being eroded by thermochemical ablation. The analysis was applied to interpret experiments of subliming Teflon models exposed to combined radiative and convective fluxes up to 1.7 kW/sq cm for several seconds. Results show that, although the exposed surface receded at an apparently steady rate, the internal temperature climbed continually, due to internal absorption of radiation and would have caused failure internally if the test duration were extended a few seconds. Thus, performance is time-limited by the internal absorption coefficient. Results were obtained for larger configurations and other materials. Typically, Teflon shells may withstand radiant fluxes up to 20 kW/sq cm for about 5 sec and fritted quartz up to 50 kW/sq cm for about 8 sec (corresponding to the Jupiter entry).

Howe, J. T.↗

NASA NTRS1973

Preliminary data on the optical properties of solid ammonia and scattering parameters for ammonia cloud particles.

The infrared absorption spectrum of solid ammonia is obtained from 2 to 125 microns as a composite of the published measurements. From this, the absorption coefficient and the complex refractive index are calculated as a function of frequency by integration of the Kramers-Kroenig dispersion relations. These data are used in a Mie theory analysis to obtain the basic parameters for scattering of long wavelength radiation by solid ammonia particles; this is believed to be an important process in radiative transfer within the atmospheres of the giant planets.

Taylor, F. W.↗

NASA NTRS1973

Spectral line absorption measurement using optical cavities.

A simple technique using a conventional gas laser with spherical mirrors having identical radii of curvature in the nonoscillating regime for spectral line absorption measurements is described and applications for laser work are suggested. The theory of the measurement carried out in the geometrical optical approach for Doppler-broadened lines was checked experimentally and conditions are specified for which measurement inaccuracies of the order of 1% for the peak value of the line absorption coefficient can be obtained. Since the device provides a fine adjustment of the cavity losses, formation of the diffraction modes could be observed in the preoscillating regime of the optical cavity.

Blanaru, D. L.↗

NASA NTRS1973

A thick-thin approximation for radiative transfer.

First- and second-order formulations of a thick-thin approximate technique for application to the solution of energy transport when nongray radiation is important are presented. The virtue of the technique is that it eliminates the cumbersome integral terms which usually appear. It is shown that the temperature distributions calculated with the technique agree well with the results of more rigorous calculations if a proper value of the critical optical depth, which separates the thick and thin regions of the spectrum, is used. The proper value of the critical optical depth is less than one and may be less than 0.5. It is also shown that the jump boundary conditions which are frequently employed with the Rosseland, or diffusion, approximation should incorporate the Planck mean absorption coefficient for a nongray gas. This is in contradiction to suggestions appearing in the literature.

Olstad, W. B.↗

NASA NTRS1972

Effect of radiometric errors on accuracy of temperature-profile measurement by the spectral-scanning method.

The spectral-scanning method may be used to determine the temperature profile of a jet- or rocket-engine exhaust stream by measurements of gas radiation and transmittance at two or more wavelengths. A single, fixed line of sight is used, using immobile radiators and radiometers outside of the gas stream, and there is no interference with the flow. A given radiometric error causes an error in computed temperatures. The ratio between temperature error and radiometric error depends on profile shape, path length, temperature level, the strength of line absorption, and the absorption coefficient and its temperature coefficient. These influence the choice of wavelengths for any given gas. Conditions for minimum temperature error are derived. Numerical results are presented for a two wavelength measurement on a family of profiles that may be expected in a practical case of H2 - O2 combustion. Under favorable conditions, the fractional error in temperature approximates the fractional error in radiant-flux measurement.

Buchele, D. R.↗

NASA NTRS1973

Theory for radiatively driven harmonic acoustic waves in a confined gas.

A detailed theoretical study is made of radiatively driven acoustic waves inside a closed cylindrical tube. The formulation accounts for all the essential phenomena for a gas in vibrational equilibrium - namely, gas motion, longitudinal and radial viscous dissipation, longitudinal and radial heat conduction, and radiative transfer with spectral detail included. An approximate expression is derived for the pressure response. This solution is applicable to arbitrary spectral distribution of the radiative absorption coefficient, under conditions attainable in the laboratory. The solution includes both tuned and untuned acoustic conditions as well as the spectrophone limit - that is, the condition where the length of the tube is much smaller than the length of the acoustic wave. The influence of spectral detail on the pressure response is illustrated.

Chapman, G. T.↗

NASA NTRS1974

Rotationsal and vibrational spectra of molecular ions: Feasibility of laboratory and astrophysical observation

The rotational spectra of a number of small molecular ions should be detectable in the microwave or millimeter wave regions in laboratory experiments using currently available techniques. The dipole moments and absorption coefficients of polar diatomics CO(+) and NO(+) as well as asymmetric isotopically enriched species, like O-18O-16(+), NE-20NE-22(+), and OC-18 O-16(+) are calculated to be sufficiently large to allow observation of their spectra. In addition to the detailed molecular structure information which such spectral data would provide, precise knowledge of the transition frequencies would render likely the detection of certain of these ions in the interstellar sources or in planetary atmospheres. All of these ions also possess vibrational spectra which should be detectable in the infrared region in laboratory or astrophysical sources.

Woods, R. C.↗

NASA NTRS1974

Microwave spectra of some sulfur and nitrogen compounds

A computer-controlled microwave spectrometer was used to catalog reference spectra for chemical analysis. The apparatus, software, and experimental procedures are described. Tables of absorption frequencies, peak absorption coefficients, and integrated intensities are included for 13 sulfur compounds, 14 nitrogen compounds, and 1 compound containing both sulfur and nitrogen. The frequency range covered was 26,500 to 40,000 MHz for most compounds and 18,000 to 40,000 MHz for some.

White, W. F.↗

NASA NTRS1974

Sound-absorbing slabs and structures based on granular materials (bound and unbound)

Sound absorbing slabs and structures made up of bound or unbound granular materials are considered and how to manufacture these elements at the building site. The raw material is a single grain powder (sand, expanded blast furnace slag, etc.) that imparts to the end products an apparent porosity of 25-45% and an energy dissipation within the structure leading to absorption coefficients that can be compared with those of mineral wool and urethane.

Petre-Lazar, S.↗

NASA NTRS1974

Highly efficient special sound absorbing solutions

Highly efficient special sound absorbing structures with the following criteria are considered: (1) A distribution surface of the sound absorbing material greater than that of the building element on which the structure is placed; (2) The highest possible absorption coefficient in the widest possible frequency band; and (3) adaptability to different construction and aesthetic conditions.

Ionescu, M.↗

NASA NTRS1974

High resolution solar X-ray studies

Two high resolution solar X-ray payloads and their launches on Aerobee rockets with pointing system are described. The payloads included 5 to 25A X-ray spectrometers, multiaperture X-ray cameras, and command box attitude control inflight by means of a television image radioed to ground. Spatial resolution ranged from five arc minutes to ten arc seconds and spectral resolution ranged from 500 to 3000. Several laboratory tasks were completed in order to achieve the desired resolution. These included (1) development of techniques to align grid collimators, (2) studies of the spectrometric properties of crystals, (3) measurements of the absorption coefficients of various materials used in X-ray spectrometers, (4) evaluation of the performance of multiaperture cameras, and (5) development of facilities.

Blake, R. L.↗

NASA NTRS1973

Measurement of plasma temperature and density using laser absorption

A laser radiation absorption technique, suitable for temporal measurement of the electron density, the temperature, or a simultaneous determination of both, in an LTE plasma, is discussed. The theoretical calculation of the absorption coefficient for a hydrogen plasma is outlined; some results are presented for visible wavelengths. Measurements of electron density and temperature are presented and shown to be in good agreement with those values obtained by other methods. Finally, the possible use of the argon ion laser for simultaneous electron density and temperature measurement is discussed, and the theoretical curves necessary for its application to hydrogen plasma diagnostics are shown.

Billman, K. W.↗

NASA NTRS1973

The extreme wings of atomic emission and absorption lines

Consideration of the extreme wings of atomic and molecular emission and absorption lines in low pressure gases. Classical and semiclassical results are compared with accurate quantal calculations of the self-broadening of Lyman-alpha in the hydrogen absorption spectrum that arises from quasimolecular transition. The results of classical, quantal, and semiclassical calculations of the absorption coefficient in the red wing are shown for temperatures of 500, 200, and 100 K. The semiclassical and quantal spectra agree well in shape at 500 K. Various other findings are discused.

Dalgarno, A.↗

NASA NTRS1974

Preliminary infrared radiometry of Venus from Mariner 10

The intensity of emission at 45 micrometers, measured with high spatial resolution along a single crossing of the Venus disk, is presented. On the average, the observed darkening toward the limb varies nearly linearly with the cosine of the emission angle. The brightness temperature, extrapolated to normal emission, is 255 K. The limb darkening curve, interpreted in a linear approximation, implies that the atmosphere is quite opaque, with an absorption coefficient of 0.24 per kilometer. Changes in curvature present in the limb darkening curve suggest the existence of thermal inhomogeneities with scale comparable to that of the dark markings shown by ultraviolet images.

Chase, S. C.↗