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At least 991 records · Page 55

Feasibility of Electrostriction for Measurement of the Critical Temperature in the Critical Viscosity Experiment

The large compressibility of a pure fluid near its critical point is a potential means of measuring the critical temperature. At the suggestion of Prof. Ferrell we observed electrostriction in xenon by applying a large voltage across a small, open capacitor immersed in the sample and then measuring the capacitance change caused by the subsequent increase in the xenon's local density. This scheme was attractive because the compressibility is a large, well-understood effect and because we were already familiar with low-voltage capacitance measurements. We found qualitative agreement with our initial expectations based on the fluid's compressibility. However, we also found an additional effect comparable in size to the expected electrostriction but proportional to the applied voltage. We have no explanation for this effect. Thus, given the Science Panel's recommendation against investing extensive effort in this direction, we are abandoning further development of an alternate means for measuring the critical temperature.

Berg, Robert F.↗

Measurement of Density, Sound Velocity, Surface Tension, and Viscosity of Freely Suspended Supercooled Liquids

Non-contact methods have been implemented in conjunction with levitation techniques to carry out the measurement of the macroscopic properties of liquids significantly cooled below their nominal melting point. Free suspension of the sample and remote methods allow the deep excursion into the metastable liquid state and the determination of its thermophysical properties. We used this approach to investigate common substances such as water, o-terphenyl, succinonitrile, as well as higher temperature melts such as molten indium, aluminum and other metals. Although these techniques have thus far involved ultrasonic, electromagnetic, and more recently electrostatic levitation, we restrict our attention to ultrasonic methods in this paper. The resulting magnitude of maximum thermal supercooling achieved have ranged between 10 and 15% of the absolute temperature of the melting point for the materials mentioned above. The physical properties measurement methods have been mostly novel approaches, and the typical accuracy achieved have not yet matched their standard equivalent techniques involving contained samples and invasive probing. They are currently being refined, however, as the levitation techniques become more widespread, and as we gain a better understanding of the physics of levitated liquid samples.

Supercooling Liquids↗

Nanocoatings for Wicking of Low-Viscosity Cryogens Project

The goal of this project is to develop smart, switchable materials systems for use in thermal management systems, including the evaluation of wicking nanocoatings for use in the transport and storage of cryogens.

TechPort Portfolio System↗